{"title":"Nonaqueous Gel Casting of AlN Ceramics using Epoxy","authors":"Yixuan HE, Xiao‐Hong Wang, Wenzhong LU","doi":"10.5755/j02.ms.39132","DOIUrl":"https://doi.org/10.5755/j02.ms.39132","url":null,"abstract":"The AlN ceramics manufactured by a nonaqueous gel casting process were studied. It was shown that trimethylolpropane triglycidyl ether (TMPGE) and tetraethylenepentamine (TEPA) were suitable for the gel casting process through a nucleophilic addition reaction. This system cured at room temperature and avoided oxygen inhibition. The rheological behaviors of the slurries and bending strength of green bodies obtained under different conditions were investigated. Suspensions with a high-solid loading of 59 vol.% and low viscosity (678 mPa·s) were obtained with 1 wt.% dispersant, 20 wt.% TMPGE, and TEPA: TMPGE=1:5. The results showed that the bending strength of the green body is not only associated with the content of TMPGE, TEPA, and solid loading, but also the drying process. The bending strength greatly improved and reached 34.9 MPa after drying at 130 °C, which was strong enough for subsequent processing. With the increase of solid loading, sintered AlN ceramics exhibited higher relative density and thermal conductivity, reaching 99.6% and 152 W/(m·K) at 59 vol.%, while the optimized bending strength of 274 MPa was obtained at 55 vol.%. Meanwhile, complex-shaped ceramics without cracks were prepared.","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"31 3","pages":"297-302"},"PeriodicalIF":0.0,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://matsc.ktu.lt/index.php/MatSc/article/download/39132/16773","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147881081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation and Performance of Filled Resin Based on Long Afterglow Materials in Gingival Wall Lifting Surgery","authors":"Yijun ZOU, Yine MEI, Yuling PANG","doi":"10.5755/j02.ms.38204","DOIUrl":"https://doi.org/10.5755/j02.ms.38204","url":null,"abstract":"The study was conducted to solve the problems of low monomer conversion rate and insufficient curing depth of dental resin complexes during curing in gingival wall elevation procedures. A dental composite resin was prepared by modifying the blue emitting long afterglow luminescent material. Then it was applied in the treatment of oral caries for experimental research. The results showed that the afterglow of the SMSED material showed high brightness and blue, with its thermoluminescence peak higher than that of the control group, reaching a maximum of 3 × 106. The curing performance was better. It was 9.17 % higher than CAED and 10.27 % higher than SAED. The accuracy of the measurements for the different resins in the study was about 5.67 %. In addition, the double bond conversion rate of the composite resin doped with 1 wt.% increased by 114.16 % compared to the composite resin without SMSED doping. The structure and size of composite resins containing 1 wt.% research materials were more stable. Overall, the cell survival rate for 1 – 3 days was higher than 70 %, indicating that the modified composite resin had lower toxicity to L929 cells. Overall, the performance of the dental composite resin prepared by modifying the blue emitting long afterglow luminescent material is significantly improved, indicating its effectiveness and practicality. It can be practically applied in the treatment of dental caries in gingival wall lifting surgery.","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"31 3","pages":"411-418"},"PeriodicalIF":0.0,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://matsc.ktu.lt/index.php/MatSc/article/download/38204/16712","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147908227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Pollution Reduction and Carbon Reduction Technology Based on Pressure Swing Physical Adsorption Method in Power Enterprises","authors":"Yujia ZHANG, Gangqiang ZHANG","doi":"10.5755/j02.ms.38104","DOIUrl":"https://doi.org/10.5755/j02.ms.38104","url":null,"abstract":"With the increasing global attention to environmental issues and climate change, power companies, as an important energy production sector, are facing severe challenges in reducing pollution and carbon emissions. In view of this, this study is based on the metal organic framework MIL-101(Cr), physically encapsulating metalloporphyrins and synthesizing a FeTPP@MIL-101(Cr) complex. Then, the surface characteristics and adsorption performance of the composite are evaluated, and the pressure swing physical adsorption method is introduced to achieve the goal of carbon reduction and pollution reduction. The ICP-OES loading results showed that the corresponding encapsulation amounts in MIL@-A and MIL@-B composites were 5.24% and 3.20%, respectively. Moreover, when the temperature increased from 273 K to 298 K, the adsorption capacity of all test gases on the three samples showed a decreasing trend. Under ideal atmospheric pressure conditions, the adsorption capacity of MIL@-A encapsulation for CO2 did not decrease and increased, while the adsorption capacity for N2 was relatively small, but still had a certain adsorption capacity. The above results indicate that combining the pressure swing physical adsorption method with FeTPP@MIL-101(Cr) complexes can effectively adsorb pollutants generated by power enterprises, achieve predetermined goals, and help promote clean production in power enterprises.","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://matsc.ktu.lt/index.php/MatSc/article/download/38104/16711","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147884316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-09-06DOI: 10.1007/s11003-024-00838-y
V. V. Golovko, V. A. Kostin, V. V. Zhukov
{"title":"Influence of Nanomodification on the Microstructure of the Metal of Welded Joints of Low-Alloy Steels","authors":"V. V. Golovko, V. A. Kostin, V. V. Zhukov","doi":"10.1007/s11003-024-00838-y","DOIUrl":"https://doi.org/10.1007/s11003-024-00838-y","url":null,"abstract":"<p>The inoculation of nano-sized particles of refractory Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, MgO, ZrO<sub>2</sub> oxides into the welding bath was studied. The inoculation of oxides with a low-level mismatch to the δ-Fe lattice and increased wetting with liquid iron ( MgO, ZrO<sub>2</sub>) contributes to the growth of dendrites, which are formed during melt crystallization. Metal modification with MgO, ZrO<sub>2</sub> oxides decreases the hardness of polygonal ferrite and increases the content of lower bainite in the microstructure of joints, brittle fracture resistance of the joint metal. Metal modification with Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> oxides contributes to an increase in the hardness of polygonal ferrite, the content of upper bainite in the joint microstructure, and the strength of welded joints of low-alloy steels.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"28 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-19DOI: 10.1007/s11003-024-00841-3
B. K. Hanulich
{"title":"Stress State of a Soft Interlayer under Conditions of Plane and Axisymmetric Strains","authors":"B. K. Hanulich","doi":"10.1007/s11003-024-00841-3","DOIUrl":"https://doi.org/10.1007/s11003-024-00841-3","url":null,"abstract":"<p>The stress state of a soft interlayer under contact strengthening, when tensile stresses are greater than the yield strength of the interlayer metal and less than the stresses causing a general yield, is considered. The analytical expressions under plain strain and axisymmetric tension are obtained. In the first case, the stresses are determined using the Airy stress function as a corresponding polynomial, in the second case – based on the stress function of the fifth degree, built on the corresponding Legendre polynomial. The stresses satisfy the differential equations of equilibrium and boundary conditions.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"57 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-14DOI: 10.1007/s11003-024-00837-z
I. B. Ivasenko, O. R. Berehulyak, T. S. Mandziy, V. M. Posuvailo, R. A. Vorobel
{"title":"Modeling of Laser-Modified Layer Reinforced With Silicon Carbide Particles on an Aluminum Alloy","authors":"I. B. Ivasenko, O. R. Berehulyak, T. S. Mandziy, V. M. Posuvailo, R. A. Vorobel","doi":"10.1007/s11003-024-00837-z","DOIUrl":"https://doi.org/10.1007/s11003-024-00837-z","url":null,"abstract":"<p>Methods of modeling silicon carbide particles of asymmetric shape as well as the methods of image analysis of the surface layer of the aluminum alloy reinforced with silicon carbide particles were developed. A 3D modeling of the distribution of silicon carbide particles of different sizes and filling percentages in the surface layer of the aluminum alloy was carried out. The distribution of silicon carbide areas in different cross-section planes and with different volumetric filling of the strengthened layer was established.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"06 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-14DOI: 10.1007/s11003-024-00839-x
V. F. Gorban, M. O. Krapivka, O. M. Myslyvchenko
{"title":"Formation Conditions and Properties of High-Entropy Alloys Creating σ-Phase","authors":"V. F. Gorban, M. O. Krapivka, O. M. Myslyvchenko","doi":"10.1007/s11003-024-00839-x","DOIUrl":"https://doi.org/10.1007/s11003-024-00839-x","url":null,"abstract":"<p>High-entropy alloys (HEA) based on the renewal of elements of the V–IX groups of the Periodic Table, which are capable of forming σ-phase with each other, are studied. The formation of the σ-phase in the range of electronic concentration of 6.7-8 el/at was monitored. The effect of electron concentration on the content of the σ-phase in HEA-containing elements forming the σ-phase in a two-component system is shown. The conditions for the formation of a single-phase structure of the σ-phase during crystallization of multicomponent HEA are determined. The limits of the existence of a 100% high-entropy phase are established and the influence of lattice parameters on their properties is revealed. A decrease in the size of the parameters c and an of the σ-phase leads to an increase in both the hardness and modulus of elasticity of alloys with a single-phase structure of the high-entropy σ-phase.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"6 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-13DOI: 10.1007/s11003-024-00830-6
O. T. Tsyrulnyk, O. Z. Student, O. I. Zvirko, D. O. Demianchuk, O. I. Venhryniuk
{"title":"Assessment of Hydrogen Embrittlement of Operated Pipe Steel Using the J-Integral Method","authors":"O. T. Tsyrulnyk, O. Z. Student, O. I. Zvirko, D. O. Demianchuk, O. I. Venhryniuk","doi":"10.1007/s11003-024-00830-6","DOIUrl":"https://doi.org/10.1007/s11003-024-00830-6","url":null,"abstract":"<p>Fracture due to hydrogen embrittlement is a major concern for the reliability and safety of hydrogen transportation via gas pipelines. Pipe steels are characterized by high plasticity, therefore, methods of nonlinear fracture mechanics, including the <i>J</i>-integral method, are preferred for determining the fracture toughness. The influence of preliminary electrochemical hydrogen charging under a moderate mode on fracture toughness of API 5L X67 steel in the as-delivered and 34-year operated on the gas main pipeline conditions was studied. A methodological feature of the experiments is the use of different rates of mechanical loading of specimens with cracks. The influence of the long-term operation of steel on its resistance to brittle fracture is revealed, depending on the test conditions.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"10 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-13DOI: 10.1007/s11003-024-00832-4
Ya.L. Ivanytskyi, Z. Ya. Blikharskyi, O. P. Maksymenko, O. V. Panchenko, Ya. Z. Blikharskyi
{"title":"Development of the Methodology for Monitoring the Technical State of Bridge Structures and Establishment of Safe Operating Period","authors":"Ya.L. Ivanytskyi, Z. Ya. Blikharskyi, O. P. Maksymenko, O. V. Panchenko, Ya. Z. Blikharskyi","doi":"10.1007/s11003-024-00832-4","DOIUrl":"https://doi.org/10.1007/s11003-024-00832-4","url":null,"abstract":"<p>A methodology for determining the technical state of reinforced concrete bridge structures was developed. It is based on establishing the depth and location of the largest deflection using a laser projection system, as well as an approach to finding the stress-strain state (SSS) along the height of the beam. An energy approach, which foresees the energy of elastic-plastic deformation calculation of concrete and reinforcement was used for this. The specific fracture energy as an invariant characteristic of concrete strength under tension, compression, and also tension of reinforcement were established experimentally. The true diagrams of deformation and fracture of concrete samples taken from the structure were plotted. The results of experimental studies of SSS during the bending of a reinforced concrete beam agree well with those calculated by the finite element method.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"6 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-08-13DOI: 10.1007/s11003-024-00833-3
H. V. Krechkovska, A. A. Voitovich, A. R. Dzyubyk, B. I. Kindratskyi, O. S. Lampitskyi, L. I. Bohun
{"title":"Differences in Structure and Properties of the Beam Metal of the Bridge Structure","authors":"H. V. Krechkovska, A. A. Voitovich, A. R. Dzyubyk, B. I. Kindratskyi, O. S. Lampitskyi, L. I. Bohun","doi":"10.1007/s11003-024-00833-3","DOIUrl":"https://doi.org/10.1007/s11003-024-00833-3","url":null,"abstract":"<p>The mechanical properties of 15KhSND steel of the beam of the bridge structure were analyzed. The characteristics of strength, plasticity, and resistance to brittle fracture of the steel of its wall correspond to the regulated values. The values of strength and plasticity of the steel shelf do not exceed the normalized limits, but the low values of its impact strength and brittle cleavages on the sample microfractures indicate a tendency to brittle fracture. The resistance to brittle fracture of the metal from the beam shelf decreased in three times on the longitudinal samples, and two times on the transverse ones as compared to the inherent brittle fracture resistance of steel from the beam wall.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"10 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142206048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}