Materials and Corrosion-werkstoffe Und Korrosion最新文献

{"title":"Masthead: Materials and Corrosion. 1/2025","authors":"","doi":"10.1002/maco.202570012","DOIUrl":"https://doi.org/10.1002/maco.202570012","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"3"},"PeriodicalIF":1.6,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202570012","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Contents: Materials and Corrosion. 1/2025","authors":"","doi":"10.1002/maco.202570013","DOIUrl":"https://doi.org/10.1002/maco.202570013","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"4-8"},"PeriodicalIF":1.6,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202570013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanism of Carbon Steel Corrosion in Accelerated Corrosion Tests","authors":"Kateryna Popova,&nbsp;Tomáš Prošek","doi":"10.1002/maco.202414606","DOIUrl":"https://doi.org/10.1002/maco.202414606","url":null,"abstract":"<p>Understanding the effect of parameters of cyclic accelerated corrosion tests on the corrosion response is crucial for proper test design. The real-time corrosion rate of carbon steel was measured using electrical resistance sensors in seven tests and was statistically evaluated. A synergistic effect of the chloride concentration and duration of transition phases was explained based on the surface electrolyte distribution. In contrast to the field, the steel corrosion rate increased between particular chloride deposition phases due to the formation of porous red rust with low protection ability. This implies that the corrosivity of future corrosion tests needs to be reduced.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"486-509"},"PeriodicalIF":1.6,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414606","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on the Hot Corrosion Behavior of Nitrogen-Containing Nickel-Based Cladding Layer in Na2SO4 + NaCl Mixed Salt at 700°C","authors":"Zhixin Yang,&nbsp;Yunhai Su,&nbsp;Shuo Feng,&nbsp;Taisen Yang,&nbsp;Zhiyong Dai,&nbsp;Haoxing Li,&nbsp;Yang Yang","doi":"10.1002/maco.202414651","DOIUrl":"https://doi.org/10.1002/maco.202414651","url":null,"abstract":"<div>\u0000 \u0000 <p>Based on the core idea of replacing Ni with N, this article designs a nitrogen-containing nickel-based alloy powder for plasma cladding. The corrosion behavior of Inconel 625 and the nitrogen-containing nickel-based cladding layer in a mixture of 75% Na₂SO₄ + 25% NaCl at 700°C was studied, and its mechanism was analyzed. The results of corrosion weight loss show that the corrosion weight loss per unit area of Inconel 625 is 2.95 times that of the nitrogen-containing nickel-based alloy. The results of XRD, SEM of surface corrosion and elemental distribution indicate that the phase compositions of Inconel 625 and the nitrogen-containing nickel-based alloy after corrosion are basically the same, all containing Cr₂O₃, NiO, Fe₂O₃, NiCr₂O₄, and Ni₃S₂. NiFe₂O₄ was also detected in the nitrogen-containing nickel-based cladding layer. Through the cross-sectional morphology and elemental distribution after the corrosion of the cladding layer, it can be seen that a chromium-depleted layer appears in Inconel 625 after corrosion, while it was not observed in the nitrogen-containing nickel-based cladding layer. In summary, the corrosion resistance of the nitrogen-containing nickel-based cladding layer to the Na₂SO₄ + NaCl molten salt is better than that of Inconel 625. It can be proved through the corrosion mechanism and XPS that Cr₂O₃ plays a crucial role in it.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"581-590"},"PeriodicalIF":1.6,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Synergistic Effect of Two Alloying Elements on the Microstructures and Properties of Zn–2.5Al–3Mg Alloys","authors":"Longyue Ma,&nbsp;Wenxuan Chen,&nbsp;Guorong Zhou,&nbsp;Xinying Teng,&nbsp;Shui Yu,&nbsp;Mengmeng Zhang,&nbsp;Jin Sun","doi":"10.1002/maco.202414634","DOIUrl":"https://doi.org/10.1002/maco.202414634","url":null,"abstract":"<div>\u0000 \u0000 <p>The present study investigates the microstructure, hardness, and corrosion behavior of Zn–2.5Al–3Mg alloys with the addition of two elements (Zr–Si, Zr–Sb, and Zr–Ti). This analysis includes SEM/EDS, Brinell hardness testing, electrochemical measurements, and XPS. The SEM results indicate that the Zn–2.5Al–3Mg alloy, with added Zr and Ti elements, exhibits finer grains and a more homogeneous structure compared to the other two combinations (Zr–Si and Zr–Sb). Electrochemical analysis indicated that the Zn–2.5Al–3Mg–0.2(Zr–Ti) alloy exhibited the best corrosion resistance among all the samples tested. Furthermore, XPS identified that the corrosion products of the Zn–2.5Al–3Mg–0.2(Zr–Ti) alloy mainly consist of dense Zn₅(OH)₆(CO₃)₂, ZnAl₂O₄, and MgAl₂O₄. An exploration into the corrosion resistance mechanism of the Zn–2.5Al–3Mg–0.2(Zr–Ti) alloy showed that the dense corrosion products formed during the corrosion process gradually accumulate and fill corrosion gaps. This accumulation hinders the progression of corrosion into the metal, ultimately enhancing the alloy's corrosion resistance.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"519-532"},"PeriodicalIF":1.6,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Impact of Humidity on High Temperature Corrosion of Ferritic-Austenitic Model Alloys in the Presence of KCL","authors":"P. Kingsbery,&nbsp;T. John,&nbsp;C. Stephan-Scherb","doi":"10.1002/maco.202414575","DOIUrl":"https://doi.org/10.1002/maco.202414575","url":null,"abstract":"&lt;p&gt;This study investigates the impact of humidity on the corrosion behavior of an Fe–18Cr–12Ni alloy in environments containing KCl, as a deposit, and either laboratory air or &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 \u0000 &lt;mrow&gt;\u0000 &lt;msub&gt;\u0000 &lt;mstyle&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 \u0000 &lt;mtext&gt;SO&lt;/mtext&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 &lt;/mstyle&gt;\u0000 \u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; at 560°C for exposure times up to 330 h. Corrosion characteristics were analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD) with subsequent Rietveld analysis to quantify the obtained reaction products. Samples exposed to lab air and KCl showed half the weight gain in humid air than in dry atmospheres (&lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 \u0000 &lt;mrow&gt;\u0000 &lt;mn&gt;0.80&lt;/mn&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 \u0000 &lt;mfrac&gt;\u0000 &lt;mrow&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 \u0000 &lt;mtext&gt;mg&lt;/mtext&gt;\u0000 &lt;/mrow&gt;\u0000 \u0000 &lt;msup&gt;\u0000 &lt;mtext&gt;cm&lt;/mtext&gt;\u0000 \u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msup&gt;\u0000 &lt;/mfrac&gt;\u0000 \u0000 &lt;mo&gt;±&lt;/mo&gt;\u0000 \u0000 &lt;mn&gt;0.06&lt;/mn&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 \u0000 &lt;mfrac&gt;\u0000 &lt;mtext&gt;mg&lt;/mtext&gt;\u0000 \u0000 &lt;mrow&gt;\u0000 &lt;mtext&gt;cm&lt;/mtext&gt;\u0000 \u0000 &lt;msup&gt;\u0000 &lt;mspace&gt;&lt;/mspace&gt;\u0000 \u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msup&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/mfrac&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; at 30.00% &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 \u0000 &lt;mrow&gt;\u0000 &lt;mo&gt;±&lt;/mo&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; 0.07% relative humidity (r.H.) vs. &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 \u0000 &lt;mrow&gt;\u0000 ","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"572-580"},"PeriodicalIF":1.6,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414575","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrosion Behavior of Bactericidal Surfaces Based on Silver and Copper Ion Implantation","authors":"Amadeu Concustell,&nbsp;Alejandro Pérez-Alonso,&nbsp;Marc Bahillo,&nbsp;Sílvia Molas,&nbsp;Raül Bonet,&nbsp;Jordi Orrit-Prat,&nbsp;Jaume Caro,&nbsp;Joan Muñoz","doi":"10.1002/maco.202414581","DOIUrl":"https://doi.org/10.1002/maco.202414581","url":null,"abstract":"<div>\u0000 \u0000 <p>Titanium is a commonly used material in biomedical applications due to its excellent biocompatibility and mechanical properties. In addition, the surface incorporation of metal ions with bactericidal behavior proves to be very interesting in preventing bacterial colonization in biomedical titanium implants. This study investigates the corrosion resistance and stability of a series of Ti substrates implanted with Ag and Cu ions, as well as a combination of both. Characterization results indicate that the dense native oxide layer naturally present in Ti may contain more defects in the implanted materials due to the implantation process, especially when Ag is implanted. The material co-implanted with Ag and Cu presents an outer oxide layer with Ag and Cu nanoparticles which are the source of ions that can act as bactericidal agents. Finally, the study shows that the implantation of Ag and/or Cu ions does not lead to a deterioration of the corrosion resistance of Ti under simulated physiological conditions.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"591-603"},"PeriodicalIF":1.6,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrosion Behavior of 110SS Steel in Self-Generated Acid at High Temperature","authors":"Juan Du,&nbsp;Qi Zou,&nbsp;Pengfei Chen,&nbsp;Yiquan Shi,&nbsp;Pingli Liu,&nbsp;Jinming Liu,&nbsp;Yaoshun Yuan,&nbsp;Xiang Chen,&nbsp;Hui Shu","doi":"10.1002/maco.202414624","DOIUrl":"https://doi.org/10.1002/maco.202414624","url":null,"abstract":"<div>\u0000 \u0000 <p>The corrosion behavior of hydrogen sulfide corrosion-resistant alloy steel 110SS in the self-generated acid system at (ultra-) high temperature was studied. The results of the weight loss experiment showed that the corrosion rate of 110SS steel decreased with the increase of temperature at 120°C–200°C. The comprehensive study of SEM-EDS and XPS showed that FeCO₃ was formed on the surface of 110SS steel. With the increase in temperature, FeCO₃ became dense, and the corrosion rate of self-generated acid decreased. In addition, when the temperature is 120°C, the results of weight loss experiment and 3D laser scanning show that the corrosion of 110SS steel is strong, and the corrosion phenomenon is inhibited after adding oleic imidazoline. SEM and electrochemical experiments show that the oleic imidazoline corrosion inhibitor can be stably adsorbed on the surface of 110SS steel and reduce its corrosion in the self-generated acid.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"557-571"},"PeriodicalIF":1.6,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrosion Resistance and Structure of Cr−O−N Coatings Formed in Vacuum Arc Plasma Fluxes With PIIID","authors":"Alexandr S. Kuprin,&nbsp;Hanna Y. Rostova,&nbsp;Elena N. Reshetnyak,&nbsp;Bogdan Warcholinski,&nbsp;Adam Gilewicz,&nbsp;Ilya O. Klimenko,&nbsp;Konrad Trzciński,&nbsp;Maria Gazda,&nbsp;Jacek Ryl,&nbsp;Miroslaw Sawczak","doi":"10.1002/maco.202414543","DOIUrl":"https://doi.org/10.1002/maco.202414543","url":null,"abstract":"<div>\u0000 \u0000 <p>Cr−O−N-based vacuum arc coatings are very promising for the wear and corrosion protection of various steel parts. The aim of the work was to determine the effect of frequency and amplitude of the pulsed bias voltage (U_B) on the elemental and phase composition, mechanical, and corrosion properties of Cr−O−N coatings. They have an amorphous structure with embedded nanosized solid solution crystallites based on CrN with a cubic structure and Cr₂O₃ with a rhombohedral structure. The increase in the bias voltage results in a reduction in the grain size of the Cr₂O₃ and CrN phases by about four times to about 5 nm, as well as a change in the CrN phase content in the coating. The lattice parameter increases slightly for the Cr₂O₃ phase but decreases for the CrN phase. The increase in the pulse frequency results in an increase in the CrN phase content in the coating and the lattice constant of both phases and a slight decrease in the crystallite size. The hardness of Cr−O−N coatings slightly increased with the U_B from 26 ± 1 GPa (DC) to 28 ± 1 GPa (−300 V, pulsed), and the elastic modulus ranges from 290 to 310 GPa. The greatest changes were observed in corrosion resistance. With an increase in the bias voltage and pulse frequency, the corrosion current of Cr−O−N coatings on steel in 3% NaCl solution decreased by three orders of magnitude compared to coatings deposited at DC voltage and by five orders of magnitude compared to the base steel. Therefore, the use of a pulsed bias voltage with a frequency of at least 10 kHz and an amplitude of 700 V can significantly increase the corrosion resistance of Cr−O−N coatings on steel substrates.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"542-556"},"PeriodicalIF":1.6,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The High Temperature Corrosion and Oxidation 2023 Workshop","authors":"","doi":"10.1002/maco.202470118","DOIUrl":"https://doi.org/10.1002/maco.202470118","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1582"},"PeriodicalIF":1.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142868104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}