Journal of The European Ceramic Society最新文献_第6页

Progress of porous ceramics applied for solar thermochemical CO production 多孔陶瓷在太阳能热化学CO生产中的应用进展

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-15 DOI: 10.1016/j.jeurceramsoc.2025.117826

Xuezhi Li , Yin’e Liu , Yifan Liu , Xintong Xu , Huihui Kong , Xiaoyan Zhang

{"title":"Progress of porous ceramics applied for solar thermochemical CO production","authors":"Xuezhi Li , Yin’e Liu , Yifan Liu , Xintong Xu , Huihui Kong , Xiaoyan Zhang","doi":"10.1016/j.jeurceramsoc.2025.117826","DOIUrl":"10.1016/j.jeurceramsoc.2025.117826","url":null,"abstract":"<div><div>Using metal oxides as carriers, the solar-driven two-step reaction can efficiently convert CO2 into clean fuel, thereby promoting carbon emission reduction and renewable energy production simultaneously. The solar-to-fuel conversion efficiency is directly determined by the design, parameters, composition, and structure of the solar reactor. This work is comprehensively reviewed based on state of the art CeO2 and perovskites. It covers key aspects such as the mechanism of thermochemical CO2 decomposition by metal oxides, the influence of metal ion doping on redox reaction activity, and the impact of morphological specificity and pore structure on thermal radiation, mass transfer properties, and fuel generation kinetics. Additionally, prospective porous structure fabrication technologies with high applicability potential but currently underexplored in thermochemical cycles are highlighted. Key insights are presented for the design and fabrication of porous ceramics in solar thermal chemical fuel synthesis, bridging sustainable energy conversion with technological advancements.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117826"},"PeriodicalIF":6.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145118715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Formation of a helium-bubble-free region in irradiated SiC via Mg ion implantation: Irradiation experiments combined with first-principles calculations 镁离子注入辐照SiC中无氦泡区形成：结合第一性原理计算的辐照实验

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-15 DOI: 10.1016/j.jeurceramsoc.2025.117825

Jun Hui , Min Liu , Shuo Wang , Jia Peng Chen , Biao Wang

引用次数: 0

Role of powder microstructure in aerosol-deposited alumina coatings 粉末微观结构在气溶胶沉积氧化铝涂层中的作用

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-15 DOI: 10.1016/j.jeurceramsoc.2025.117828

Zhenying Yang , Mehdi Jadidi , Kailin Chen , Shuyi Zhou , Yu Zou , Ali Dolatabadi , Thomas W. Coyle

{"title":"Role of powder microstructure in aerosol-deposited alumina coatings","authors":"Zhenying Yang , Mehdi Jadidi , Kailin Chen , Shuyi Zhou , Yu Zou , Ali Dolatabadi , Thomas W. Coyle","doi":"10.1016/j.jeurceramsoc.2025.117828","DOIUrl":"10.1016/j.jeurceramsoc.2025.117828","url":null,"abstract":"<div><div>The selection of feedstock powder particles is critical for coating formation in aerosol deposition (AD). AD favors sub-micrometer-sized powders, which are susceptible to aggregation and agglomeration. This study investigates the effect of powder characteristics on coating formation using two types of alumina powders: one consisting of dense, single particles, and the other of agglomerated particles. The morphology, microstructure, and mechanical properties of the coatings deposited on Si substrates were strongly influenced by the powder morphology and pretreatment. Without pretreatment, dense particle powders caused substrate erosion, whereas agglomerated powders produced thick coatings. Ball milling was employed to modify both types of powders, introducing surface defects with reduction in particle and crystallite size. Thick coatings were deposited using ball-milled dense or agglomerated powders. Although deposition with agglomerated powders was easier, coatings from dense powders exhibited higher density and hardness. Differences in particle behavior upon impact were discussed and related to coating microstructure.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117828"},"PeriodicalIF":6.2,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Atmosphere-dependent in-situ ceramic whisker formation and performance enhancement in Al2O3-C refractories Al2O3-C耐火材料中随气氛变化的原位陶瓷晶须形成及性能增强

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-13 DOI: 10.1016/j.jeurceramsoc.2025.117824

Yuqi Guo , Ning Liao , Guoping He , Tianbin Zhu , Shengli Jin , Yawei Li

{"title":"Atmosphere-dependent in-situ ceramic whisker formation and performance enhancement in Al2O3-C refractories","authors":"Yuqi Guo , Ning Liao , Guoping He , Tianbin Zhu , Shengli Jin , Yawei Li","doi":"10.1016/j.jeurceramsoc.2025.117824","DOIUrl":"10.1016/j.jeurceramsoc.2025.117824","url":null,"abstract":"<div><div>Al2O3-C refractories are critical for flow control in continuous casting, yet the relationship between their structure evolution and high-temperature properties remains insufficiently understood. This study systematically investigates the synergistic effects of additives (Si, Al) and heat-treatment atmospheres (coke-bed vs. N2) on the microstructure and performance of Al2O3-C refractories. The results demonstrated that: 1) Compared to coke-bed treatment, N₂ atmosphere reduces the in-situ formation temperature of SiC and AlN whiskers by 100–200 °C, while facilitating columnar Sialon formation at 1400 °C. 2) N2 treatment achieves optimal pore size distribution at 1200 °C due to accelerated whisker formation, whereas coke-bed requires 1400 °C for comparable refinement. 3) The N2-derived microstructure, featuring optimized porosity and minimized oxygen contamination, significantly improves thermal shock resistance and oxidation resistance. This work advances the understanding of in-situ ceramic phase formation (SiC/AlN/Sialon) and its role in tailoring the service performance of Al2O3-C refractories.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117824"},"PeriodicalIF":6.2,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145106138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Atomically dispersed Fe-Co in electrospun SiC fiber matrix for enhanced electromagnetic wave absorption and desirable thermal stability 原子分散的Fe-Co在静电纺SiC纤维基体中增强电磁波吸收和理想的热稳定性

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-13 DOI: 10.1016/j.jeurceramsoc.2025.117821

Chen Tang , Mengying Liu , Bowen Han , Jiayi Ye , Lei Dong , Xiaohang Yang , Jiaju Meng , Weiyan Wang , Zhaowei Liu , Kang Zhao , Yufei Tang

{"title":"Atomically dispersed Fe-Co in electrospun SiC fiber matrix for enhanced electromagnetic wave absorption and desirable thermal stability","authors":"Chen Tang , Mengying Liu , Bowen Han , Jiayi Ye , Lei Dong , Xiaohang Yang , Jiaju Meng , Weiyan Wang , Zhaowei Liu , Kang Zhao , Yufei Tang","doi":"10.1016/j.jeurceramsoc.2025.117821","DOIUrl":"10.1016/j.jeurceramsoc.2025.117821","url":null,"abstract":"<div><div>The aerospace industry urgently demands high-performance electromagnetic wave absorbing materials that maintain stability under extreme temperatures. In this work, Fe-Co co-doped SiC nanofibers were developed via precision electrospinning and controlled pyrolysis. An atomic-scale dispersion of Fe and Co was achieved through a metal-polymer coordination strategy. These dopants function as active sites that promote phase nucleation, while also serving as electron donors to enhance polarization loss. Subsequent tuning of doping concentration enables synergy among conductive loss, polarization loss and magnetic loss. The optimized nanofiber exhibits outstanding performance, demonstrating an RLmin of −58.49 dB at 14.88 GHz with a 1.25 mm thickness, as well as a maximum EAB of 4.77 GHz. Remarkably, the material also demonstrates desirable thermal stability in argon atmospheres up to 1200 °C, even after oxidation at 800 °C for 30 min, it retains an RLmin of −26.35 dB and EAB of 3.04 GHz. This work establishes a new paradigm in doping-induced phase engineering, providing transformative strategy for developing next-generation extreme-environment electromagnetic wave absorbers.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117821"},"PeriodicalIF":6.2,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145106137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Indium-doped BaHfO3 electrolytes with oxygen vacancies engineering for high proton conductivity and low-temperature solid oxide fuel cells 用于高质子电导率和低温固体氧化物燃料电池的掺铟BaHfO3电解质氧空位工程

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-12 DOI: 10.1016/j.jeurceramsoc.2025.117819

Zezhong Wang , Ying Li , Wenlong Huang , Jie Zheng , Yongtao Huang

{"title":"Indium-doped BaHfO3 electrolytes with oxygen vacancies engineering for high proton conductivity and low-temperature solid oxide fuel cells","authors":"Zezhong Wang , Ying Li , Wenlong Huang , Jie Zheng , Yongtao Huang","doi":"10.1016/j.jeurceramsoc.2025.117819","DOIUrl":"10.1016/j.jeurceramsoc.2025.117819","url":null,"abstract":"<div><div>The development of electrolyte materials with high ionic conductivity at low operating temperatures (400–600 °C) remains a critical challenge for solid oxide fuel cells (SOFCs). Proton-conducting ceramics have emerged as promising candidates due to their low activation energy for proton transport, making them suitable for low-temperature SOFC applications. In this study, a series of BaHf1-xInxO3-δ (x = 0, 0.05, 0.10, 0.15, and 0.20) ceramics were synthesized via solid-state reaction. The dominant proton conductivity, accompanied by oxygen ion conduction, was confirmed through defect equilibrium model, concentration cell studies, and H/D isotope experiments. X-ray photoelectron spectroscopy (XPS) revealed that indium doping significantly enhances oxygen vacancy concentration, thereby facilitating proton conduction. Compared to undoped BaHfO3, indium doping markedly increased ionic conductivity and reduced the activation energy for grain boundary conduction. The BaHf0.85In0.15O2.925 (BHI15) electrolyte exhibited a low (ASR) area-specific ohmic resistance of 0.20 Ω cm2 and achieved an exceptional power output of 956 mW cm⁻² at 550 °C. These findings underscore the effectiveness of indium doping in enhancing proton conductivity, offering a viable strategy for designing high-performance electrolytes for low-temperature SOFCs.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117819"},"PeriodicalIF":6.2,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

First Ga2Se3 infrared transparent chalcogenide ceramics 第一种Ga2Se3红外透明硫系陶瓷

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-12 DOI: 10.1016/j.jeurceramsoc.2025.117823

Mathieu Chevereau , Emmanuel Véron , Séverine Brassamin , David Le Coq , Laurent Calvez , Xiang-Hua Zhang , Louisiane Verger , Sébastien Chenu

引用次数: 0

Achieving ultra-high Q×f values in Y2O3 ceramics by Sm substitution and enhancing electrical insulation 通过Sm取代和提高电绝缘性实现Y2O3陶瓷的超高Q×f值

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-12 DOI: 10.1016/j.jeurceramsoc.2025.117822

Zitao Shi , Xiao Zhang , Aopu Zhang , Shuren Zhang , Bin Tang

{"title":"Achieving ultra-high Q×f values in Y2O3 ceramics by Sm substitution and enhancing electrical insulation","authors":"Zitao Shi , Xiao Zhang , Aopu Zhang , Shuren Zhang , Bin Tang","doi":"10.1016/j.jeurceramsoc.2025.117822","DOIUrl":"10.1016/j.jeurceramsoc.2025.117822","url":null,"abstract":"<div><div>Reducing the dielectric loss of Y2O3 ceramics is crucial for enhancing their performance in high-frequency communication applications. In this study, Y2-xSmxO3 (0 ≤x ≤ 2) ceramics were sintered using a one-step method within a temperature range of 1475°C to 1750°C. The phase composition of the system varies with x: cubic (0 ≤x ≤ 0.8), dual-phase (0.8˂x ≤ 1.2), and monoclinic (1.2 <x ≤ 2). The bond valence of Y atoms decreases from 2.8967 v.u. (x = 0) to 2.6819 v.u. (x = 0.8), resulting in an increase in the εr from 10.8–12.3. The Y1.6Sm0.4O3 ceramic (εr=11.9 ± 0.4, τf=−44.9 ± 0.5 ppm/°C) achieves an ultra-high Q×f value of 164,176 ± 5750 GHz at 12.2 GHz. Complex impedance spectroscopy analysis reveals a strong correlation between the conductive activation energy (Ea) and the Q×f values. Compared to Y2O3 ceramics (Ea=1.66 eV), Y1.6Sm0.4O3 ceramic exhibits a higher Ea (1.91 eV), suggesting that the improved insulating properties in this system contribute to its low dielectric loss.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117822"},"PeriodicalIF":6.2,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145118098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Corrigendum to “Textured K0.5Na0.5NbO3 piezoelectric ceramics produced by vat photopolymerization-based additive manufacturing” [J. Eur. Ceram. Soc. 46 (2026) 117776] “基于还原光聚合的增材制造的织构K0.5Na0.5NbO3压电陶瓷”的更正[J]。欧元。陶瓷。Soc. 46 (2026) 117776]

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-12 DOI: 10.1016/j.jeurceramsoc.2025.117813

Mahmoud Mobin , Oleg V. Mishin , Cenk Abdurrahmanoglu , Vincenzo Esposito , Astri Bjørnetun Haugen

引用次数: 0

Enhancement of photoelectrochemical responses via annealing of air-based sputtered TiN films in controlled atmospheres 控制气氛下气基溅射TiN薄膜退火对光电化学反应的增强

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-11 DOI: 10.1016/j.jeurceramsoc.2025.117817

Guan-Sheng Wang, Xin-Xian Yang, Fu-Hsing Lu

{"title":"Enhancement of photoelectrochemical responses via annealing of air-based sputtered TiN films in controlled atmospheres","authors":"Guan-Sheng Wang, Xin-Xian Yang, Fu-Hsing Lu","doi":"10.1016/j.jeurceramsoc.2025.117817","DOIUrl":"10.1016/j.jeurceramsoc.2025.117817","url":null,"abstract":"<div><div>This study demonstrates the significant enhancement of the photoelectrochemical performance of air-based sputter-deposited TiN films via annealing in an N2/H2 atmosphere. For comparison, the films were also annealed in air and N2, with all three atmospheres subjected to varying nitrogen/oxygen partial pressures. X-ray diffraction results showed that the relative intensities of rutile TiO2 increased with decreasing the nitrogen/oxygen partial pressures. The preferred orientation of TiO2 shifted from (101) in air and N2 to a stable (110) in N2/H2, facilitating the formation of faceted TiO2. An optimal photocurrent density of 3650 ± 160 µA/cm2 was achieved at 1000 °C for 5 h in N2/H2, surpassing values reported in the literature. The enhanced performance is attributed to large-faceted TiO2 grains, oxygen vacancies in TiO2, and synergistic effects of low resistivity and plasmonic properties of TiN. This facile approach offers a promising strategy for advancing photoelectrochemical applications.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117817"},"PeriodicalIF":6.2,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145061050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0