Journal of The Chinese Chemical Society最新文献_第7页

Phosphine-mediated one-pot reactions: Syntheses of β-acylated alkylidene indandiones and furo[2,3-f]dibenzotropones via MBH-type annulation/acylation or Wittig reaction 膦介导的一锅反应：通过mbh型环化/酰化或Wittig反应合成β-酰化烷基烯二酮和呋喃[2,3-f]二苯并托酮

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-11-07 DOI: 10.1002/jccs.202400275

Po-Chung Chien, You-Jie Chen, Gangababu Marri, Yi-Ru Chen, Ching-Fen Chang, Pei-Shan Wu, Wenwei Lin

引用次数: 0

Theoretical investigation of Diels–Alder reaction mechanism and regioselectivity with functionalized fullerene derivatives 功能化富勒烯衍生物Diels-Alder反应机理及区域选择性的理论研究

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-11-04 DOI: 10.1002/jccs.202400206

Batoul Makiabadi, Fereshteh Naderi, Mohammad Zakarianezhad

引用次数: 0

Synthesis, structural characterization, water ad-/de-sorption isotherm, and CO2 uptakes of a 2D Cu(I) metal organic framework with 1,3,5-tris(4-pyridylethynyl)benzene (L) and Tricyanomethanide (tcm−) ligands 含 1,3,5-三(4-吡啶乙炔基)苯 (L) 和三氰基甲烷 (tcm-) 配体的二维 Cu(I)金属有机框架的合成、结构表征、水吸附/脱附等温线和二氧化碳吸收率

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-28 DOI: 10.1002/jccs.202400268

Chih-Chieh Wang, Yu-Ching Wu, Yu-Chen Chung, En-Che Yang, Gene-Hsiang Lee, Su-Ying Chien, Po-Ya Chang, Hwo-Shuenn Sheu

{"title":"Synthesis, structural characterization, water ad-/de-sorption isotherm, and CO2 uptakes of a 2D Cu(I) metal organic framework with 1,3,5-tris(4-pyridylethynyl)benzene (L) and Tricyanomethanide (tcm−) ligands","authors":"Chih-Chieh Wang, Yu-Ching Wu, Yu-Chen Chung, En-Che Yang, Gene-Hsiang Lee, Su-Ying Chien, Po-Ya Chang, Hwo-Shuenn Sheu","doi":"10.1002/jccs.202400268","DOIUrl":"https://doi.org/10.1002/jccs.202400268","url":null,"abstract":"A d10 Cu(I) two-dimensional (2D) metal–organic framework (MOF) with chemical formulas, {[Cd(L)(tcm)(H2O)]⋅2H2O}n (1) (L = 1,3,5-tris(4-pyridylethynyl)benzene; tcm−1 = tricyanomethanide) was synthesized and structurally characterized by single crystal X-ray diffraction method. In 1, the coordination geometry of Cu(I) ion is distorted tetrahedral coordinated to four N atoms from three L and one tcm− ligands. A 2D puckered honeycomb-like layer is formed via the bridges of Cu(I) ions and L ligands with tris-monodentate coordination mode. Two 2D layers are mutually interpenetrated via the π–π stacking interaction between benzene ring of L ligand and pyridyl ring of neighboring L ligand to form a two-fold interpenetrated 2D net and then arranged orderly to construct its 3D supramolecular network. Thermal stability and in-situ temperature-dependent structural variations of 1 are performed by TG analysis associated with temperature-dependent PXRD measurement. The water vapor ad-/de-sorption isotherm and CO2 adsorption isotherm of 1 are measured and discussed.","PeriodicalId":17262,"journal":{"name":"Journal of The Chinese Chemical Society","volume":"71 12","pages":"1464-1472"},"PeriodicalIF":1.6,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of low-cost microporous activated carbon adsorbents for CO2 capture from Palmyra palm fruit shell waste biomass 合成低成本微孔活性炭吸附剂，用于从棕榈果壳废物生物质中捕获二氧化碳

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-27 DOI: 10.1002/jccs.202400261

Shobanaboyina Swapna, Manne Parusha Ramudu, Police Vishnu Vardhan Reddy, Gande Ravi Kumar, Gaddameedi Hima Bindu, Challa Prathap, Dosali Mallesh

{"title":"Synthesis of low-cost microporous activated carbon adsorbents for CO2 capture from Palmyra palm fruit shell waste biomass","authors":"Shobanaboyina Swapna, Manne Parusha Ramudu, Police Vishnu Vardhan Reddy, Gande Ravi Kumar, Gaddameedi Hima Bindu, Challa Prathap, Dosali Mallesh","doi":"10.1002/jccs.202400261","DOIUrl":"https://doi.org/10.1002/jccs.202400261","url":null,"abstract":"Using chemical activation techniques at dissimilar carbonization temperatures, activated carbon adsorbents were produced from Palmyra palm fruit biomass in this work. X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS-elemental analysis, and N2 adsorption studies were among the characterization techniques used to assess the characteristics of the carbon adsorbents. The carbon adsorbents from Palmyra palm fruit were used to absorb CO2 in a temperature range of 25–70°C. The findings of the characterization showed that these carbons have a large surface area and microporosity. The temperature of carbonization and the activating agent had an impact on the surface characteristics. The samples with the highest adsorption capacity, 4.70 mmol/g at 25°C, were the activated carbons made by treating them with KOH and then carbonizing them at 750°C. The physicochemical properties of the adsorbents provided an explanation for their high adsorption capacity. The adsorbents showed simple desorption and maintained constant activity during ten cycles of recycling.","PeriodicalId":17262,"journal":{"name":"Journal of The Chinese Chemical Society","volume":"71 12","pages":"1435-1447"},"PeriodicalIF":1.6,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Basic understanding of Cu-SSZ-13 in catalyzing low-temperature selective catalytic reduction of NOx by ammonia Cu-SSZ-13 在催化氨对氮氧化物的低温选择性催化还原中的基本认识

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-16 DOI: 10.1002/jccs.202400205

Yujie Wang, Tao Zhu, Yunzhe Zhao, Xiaobin Hao

引用次数: 0

Cover: Journal of the Chinese Chemical Society 10/2024 封面中国化学会志 10/2024

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-15 DOI: 10.1002/jccs.1857

引用次数: 0

Contents and Masthead: Journal of the Chinese Chemical Society 10/2024 内容和刊头：中国化学会志 10/2024

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-15 DOI: 10.1002/jccs.1858

引用次数: 0

Preview: Journal of the Chinese Chemical Society 10/2024 预览：中国化学会志 10/2024

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-15 DOI: 10.1002/jccs.202410001

引用次数: 0

Bioinspired synthesis of ZrO2-Zr3Er4O12-based mixed nanomaterial; characterization and analyzing its potential as an electrode material in energy-based devices and its electrocatalytic property zro2 - zr3er4o12基混合纳米材料的仿生合成表征和分析其作为能量基器件电极材料的潜力及其电催化性能

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-10-08 DOI: 10.1002/jccs.202400187

Sundus Azhar, Khuram Shahzad Ahmad, Isaac Abrahams, Tenzin Ingsel, Ram K. Gupta, Munirah D. Albaqami, Saikh Mohammad, Mahwash Mahar Gul

{"title":"Bioinspired synthesis of ZrO2-Zr3Er4O12-based mixed nanomaterial; characterization and analyzing its potential as an electrode material in energy-based devices and its electrocatalytic property","authors":"Sundus Azhar, Khuram Shahzad Ahmad, Isaac Abrahams, Tenzin Ingsel, Ram K. Gupta, Munirah D. Albaqami, Saikh Mohammad, Mahwash Mahar Gul","doi":"10.1002/jccs.202400187","DOIUrl":"https://doi.org/10.1002/jccs.202400187","url":null,"abstract":"The sustainable and ecofriendly synthesis of transition metal oxide-based nanomaterials has always been a matter of concern. In this study, a bioinspired synthesis route was adopted to synthesize ZrO2-Zr3Er4O12-based mixed nanomaterial using leaf extract of medicinal plant Amaranthus viridis as reducing and stabilizing agent in replacement of the obnoxious chemicals which are a great threat to the sustainable environment. The synthesized material revealed the spherical shaped morphology through scanning electron microscopy, whereas crystal size of 15.7 nm was observed through Xray-diffraction, and band gap value of 2.7 eV was acquired using Tauc plot. Newly synthesized ZrO2-Zr3Er4O12 nanocomposite was then investigated for its role as electrocatalyst in a generation of energy through the hydrogen evolution reaction and oxygen evolution reaction. The ZrO2-Zr3Er4O12-based electrocatalyst showed better potential for hydrogen evolution reaction measurements with the overpotential value of 242 mV. Furthermore, the notable capacitance value of 495.6 F/g was obtained through cyclic voltammetry for energy storage studies. The cyclic stability was also analyzed using linear sweep voltammetry and results showed promising stability for 2000 cycles. Consequently, the green and economical synthesis route as well as promising electrochemical behavior of ZrO2-Zr3Er4O12-based electrode make it feasible choice for large scale application.","PeriodicalId":17262,"journal":{"name":"Journal of The Chinese Chemical Society","volume":"71 12","pages":"1427-1434"},"PeriodicalIF":1.6,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142860427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study on the effects of beta cyclodextrin-zinc oxide nanoparticles as heterogeneous catalysts in microbial oil fermentation 研究β-环糊精-氧化锌纳米颗粒作为异相催化剂在微生物油脂发酵中的作用

IF 1.6 4区化学

Journal of The Chinese Chemical Society Pub Date : 2024-09-29 DOI: 10.1002/jccs.202400244

Janice Ravi Kumar, Dayanandan Anandan, Viswanathan Kaliyaperumal

{"title":"Study on the effects of beta cyclodextrin-zinc oxide nanoparticles as heterogeneous catalysts in microbial oil fermentation","authors":"Janice Ravi Kumar, Dayanandan Anandan, Viswanathan Kaliyaperumal","doi":"10.1002/jccs.202400244","DOIUrl":"https://doi.org/10.1002/jccs.202400244","url":null,"abstract":"In order to study the catalytic activity of beta cyclodextrin-encapsulated zinc oxide (ZnO) nanoparticles in microbial oil synthesis, rice-washed waste water (RWW) was used as the fermentation medium and streptomyces fradiae as the microbe. The introduction of zinc oxide nanoparticles during fermentation had an impact on output and growth. The biomass percentage was 1.5 times greater and the fatty acid profile was better than in the control samples. The analysis of the induction period (IP) revealed that samples containing zinc oxide nanoparticles had maximum oxidation stability for up to 120 days of storage, along with a considerable reduction in autoxidation. The cetane number and calorific value, however, increased with the addition of ZnO nanoparticles. A new study discovered that the use of ZnO nanoparticles encapsulated in β-CD led to much increased production (63.5 g/L) of microbial oil than the control sample (42.5 g/L). Therefore, it is anticipated that these nanoparticles would find utility in energy-related applications.","PeriodicalId":17262,"journal":{"name":"Journal of The Chinese Chemical Society","volume":"71 11","pages":"1377-1384"},"PeriodicalIF":1.6,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0