Mohammad Kamal Hossain , Abdullah Aljishi , Firoz Khan , Anwar Ul-Hamid , Md Mosaddequr Rahman
{"title":"Fabrication and wetting characteristics of copper thin film: An active layer for SPR-based sensor applications","authors":"Mohammad Kamal Hossain , Abdullah Aljishi , Firoz Khan , Anwar Ul-Hamid , Md Mosaddequr Rahman","doi":"10.1016/j.jsamd.2024.100839","DOIUrl":"10.1016/j.jsamd.2024.100839","url":null,"abstract":"<div><div>In this work, a simple and two-step process was demonstrated to develop multifunctional Cu-based thin films that would be suitable for thin film photoactive devices. Cu thin films on quartz glass substrates were prepared using a sputtering technique followed by a thermal treatment. The samples were annealed at high temperatures such as 200, 400, and 600 °C for 2 h in a tubular furnace. Surface morphology and elemental composition were investigated using a high-resolution scanning electron microscope (FESEM) and SEM-aided energy dispersion spectroscopy (EDS), respectively. At high temperatures, the thin films were found to have clusters and voids. Detailed studies on optical properties such as ultraviolet–visible (UV–vis) absorptions, energy band gaps and Urbach energies have been carried out. A red shift in absorption edges (from 464 to 616 nm), a decrease in energy band gaps (from 2.38 to 1.54 eV) and an increase in Urbach energies (from 193 to 272 meV) were observed for those samples annealed at higher temperatures. Sessile drop tests were carried out to find the wetting contact angle (WCA) and to demonstrate the hydrophobicity of the thin film of pristine Cu and those treated at high temperatures. An approximate WCA of 71.9° was determined for the Cu thin film. Following treatment at 200 °C and 400 °C, respectively, the samples' surfaces increased in hydrophobicity by 92.4° and 85.2°. Nevertheless, the same thin film's WCA was decreased and its hydrophilicity increased during additional annealing. Cu-based thin films have been suggested as the active layer in an SPR sensor model, and the spectrum and angular resolved reflectance properties have been thoroughly investigated. At spectral wavelengths of 600, 700, and 800 nm, the optimum thickness of Cu thin film was determined to be 40 nm at SPR angles of 44.7°, 42.7°, and 42.15°.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100839"},"PeriodicalIF":6.7,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ternary Bi2O3/(BiO)2CO3/g-C3N4 multi-heterojunction nanoflakes for highly efficient photocatalytic degradation of dyes and xanthates under visible light","authors":"E. Hashemi, R. Poursalehi, H. Delavari","doi":"10.1016/j.jsamd.2024.100834","DOIUrl":"10.1016/j.jsamd.2024.100834","url":null,"abstract":"<div><div>To enhance the separation efficiency of photogenerated carriers, the formation of photocatalysts with strong interfacial contact heterojunctions is considered an effective approach for the removal of diverse environmental contaminants. In this study, a ternary heterojunction photocatalyst, Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub>, demonstrated a multifunctional high photocatalytic performance in the degradation of various dyes, including methyl orange (MO), methylene blue (MB), rhodamine B (RB) and xanthates such as potassium ethyl xanthate (PEX), potassium amyl xanthate (PAX) and sodium isopropyl xanthate (SIPX), under visible light irradiation. The Bi₂O₃/(BiO)₂CO₃/g-C₃N₄ photocatalyst was synthesized by heating a mixture of urea and arc discharge synthesized Bi₂O₃-based nanoparticles at 550 °C. This photocatalyst exhibited higher photocatalytic activity compared to Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub>. The photocatalysts were characterized and studied by FTIR, XRD, FESEM-EDS elemental mapping, HR-TEM, UV–visible, BET and PL. The formation of an interface between Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub> significantly improved photocatalytic performance by facilitating the effective separation of photogenerated electron-hole pairs. Stability tests of Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> during the degradation of MO demonstrated the photocatalyst's excellent stability and reusability, indicating its potential for practical applications in mineral processing wastewater treatment. Reactive species trapping experiments revealed that holes (h⁺) played the most significant role in photodegradation, followed by hydroxyl radicals (<sup>•</sup>OH), while superoxide radicals (<sup>•</sup>O₂⁻) had a lesser impact. Study of two possible photocatalytic mechanisms suggested that the transfer of photogenerated carriers in Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> is more likely to follow a double Z-scheme photocatalytic system. The enhanced photocatalytic performance of Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> can be attributed to considerable specific surface area, stronger visible light absorption and most importantly, well-matched band potentials between Bi₂O₃, (BiO)₂CO₃, and g-C₃N₄. The promising photocatalytic performance of Bi<sub>2</sub>O<sub>3</sub>/(BiO)<sub>2</sub>CO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub>, introduces a notable photocatalyst for photodegradation of dyes and xanthates in mineral processing wastewater.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100834"},"PeriodicalIF":6.7,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Exploring modified cyclodextrins for enhanced encapsulation and release of ethinyl estradiol: Physicochemical characterization and kinetic modeling","authors":"Mehrdad Hadadian, Behnam Mahdavi, Esmail Rezaei-Seresht","doi":"10.1016/j.jsamd.2024.100837","DOIUrl":"10.1016/j.jsamd.2024.100837","url":null,"abstract":"<div><div>Ethinyl estradiol (EE) is a synthetic derivative of steroids that is prescribed for treating sexual diseases. Cyclodextrins (CDs) can enhance the solubility, side effects, and physical characteristics of steroids by the formation of an inclusion complex. This study has aimed to provide a comparison between the encapsulated ethinyl estradiol with carboxymethyl-β-CD (CM-β-CD) and β-CD. For this purpose, different steps of the experiments were monitored using FT-IR, XRD, BET, DLS, and Zeta analyses. The morphology of the prepared inclusion complexes was investigated using FE-SEM imaging that shows nano-sized products with non-spherical structures. The thermal stability of EE and its final compounds were assessed through TGA analysis. In addition, encapsulation efficiency (EE%), phase solubility study, <em>in vitro</em> drug release, and their related kinetic studies were conducted by using the UV–visible spectroscopic method. The obtained data reveals that CM-β-CD/EE has roughly 1.5-fold higher water solubility. Besides, the cumulative release for CM-β-CD/EE was found to be 97%, while it was 46% for β-CD/EE. In contrast, the efficacy of the encapsulation process for β-CD was fairly more impressive than CM-β-CD by 97.5 and 90.62, respectively. Phase solubility kinetic study shows the negative enthalpy by −10.91∗10<sup>4</sup> J/mol for β-CD/EE and −8.32∗10<sup>4</sup> for CM-β-CD/EE denoting the favored complexation process and the negative entropy by −2.9∗10<sup>2</sup> J/mol.K for β-CD/EE and −2.07∗10<sup>2</sup> J/mol.K for CM-β-CD/EE implying an increase in the order of systems for both complexes. Moreover, the study of the kinetic <em>in vitro</em> drug release exhibits two different mathematical models for products with the same release mechanism, non-Fickian, which is governed by multiple processes.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100837"},"PeriodicalIF":6.7,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jun Cao , Junchao Zhang , Huiyi Tang , Xiaoyu Shen , Kexing Song , Yanjun Zhou , Chengqiang Cui
{"title":"Investigation on the microstructure evolution and strengthening behavior of rolled bonding Cu strip","authors":"Jun Cao , Junchao Zhang , Huiyi Tang , Xiaoyu Shen , Kexing Song , Yanjun Zhou , Chengqiang Cui","doi":"10.1016/j.jsamd.2024.100835","DOIUrl":"10.1016/j.jsamd.2024.100835","url":null,"abstract":"<div><div>The relationship and influencing mechanism among the reduction rate, the strengthening behavior and the microstructure evolution of rolled Cu strips were studied. It was found that with the increase of reduction rate, the uneven deformation behavior of the Cu strip was divided into three zones. The grain size in Zone I was refined accompanied by large-scale entangled dislocations, and a nanosheet layered texture was formed. The primary reason for the increase in the strength of the Cu strip is the combined strengthening effect of dislocation, grain boundary and texture, as well as the strengthening effect provided by some lattice friction. The grain orientation exhibited periodic transitions between <110> and <111>, <001>, which provides assistance for grain refinement and dislocation accumulation. The grains in the fracture zone of the Cu strip are elongated and refined during stretching, and flow towards the central axis of the cross-section. The fracture mechanism has shifted from cutting to a chip edge/point to a combined action of multiple mechanisms, which is also accompanied by a gradual increase in the “tearing angle\".</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100835"},"PeriodicalIF":6.7,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. López Antón , J.P. Andrés , J.A. González , A. García-Gómez , V. Zhukova , A. Chizhik , M. Salaheldeen , A. Zhukov
{"title":"Tuning of magnetic properties and giant magnetoimpedance effect in multilayered microwires","authors":"R. López Antón , J.P. Andrés , J.A. González , A. García-Gómez , V. Zhukova , A. Chizhik , M. Salaheldeen , A. Zhukov","doi":"10.1016/j.jsamd.2024.100821","DOIUrl":"10.1016/j.jsamd.2024.100821","url":null,"abstract":"<div><div>We studied the magnetic properties and Giant Magnetoimpedance (GMI) effect in amorphous Co-rich microwires with similar chemical compositions and different diameters with magnetic (Co, Permalloy) and non-magnetic (Cu) layers deposited by magnetic sputtering onto glass-coating. Studies of magnetic properties and GMI effect of as-prepared microwires and the same microwires with deposited magnetic and non-magnetic layers reveal substantial impact of such layers on GMI effect and hysteresis loops. Both as-prepared samples present soft magnetic properties and high GMI effect. The contribution of magnetic layers is observed in hysteresis loop at higher magnetic field, with hysteresis loops similar to those observed in microwires with mixed amorphous-crystalline structure. Meanwhile, both magnetic and non-magnetic layers affect low field hysteresis loops of both samples. Additionally, the GMI ratio, ΔZ/Z, and magnetic field dependences of GMI ratio are substantially affected by the presence of magnetic and non-magnetic layers deposited onto glass-coating. We discussed the observed experimental dependences considering both change of the internal stresses originated by the sputtered layer as well as the magnetostatic interaction between the amorphous ferromagnetic nucleus and deposited magnetic layers.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"9 4","pages":"Article 100821"},"PeriodicalIF":6.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142743194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmad Hasanzadeh , Atefeh Alipour , Sajedeh Ghasemi , Saadi Hosseini , Naser Farrokhi , Peng-Yuan Wang , Ali Zarrabi , Javad Mohammadi , Hosein Shahsavarani
{"title":"Proanthocyanidin-Imbued cellulosic 3-Dimensional intrinsic aligned Nanostructures: A novel approach for dental and bone regeneration using dental pulp derived stem cells","authors":"Ahmad Hasanzadeh , Atefeh Alipour , Sajedeh Ghasemi , Saadi Hosseini , Naser Farrokhi , Peng-Yuan Wang , Ali Zarrabi , Javad Mohammadi , Hosein Shahsavarani","doi":"10.1016/j.jsamd.2024.100820","DOIUrl":"10.1016/j.jsamd.2024.100820","url":null,"abstract":"<div><div>Developing effective scaffolds to address significant bone and dental defects is crucial in regenerative osteal and dental medicine. Traditional methods utilizing synthetic micropatterned scaffolds have effectively stimulated osteogenic and odontogenic differentiation of stem cells through parallel, 3D topographic, hexagonal, and elongated architectural features. However, these approaches face significant cost, scalability, and biocompatibility challenges. Recent advancements have highlighted the potential of decellularized plant scaffolds, such as those derived from <em>Beaucarnea recurvata</em> leaves (BLDS). These offer intrinsic microstructural advantages with solving reproducibility, scalability, incurred cost, and biocompatibility challenges. This study explores the enhancement of BLDS using grape seed proanthocyanidin extract (GSPE), a natural polyphenol known for its beneficial effects on bone and dental stem cell differentiation. By functionalizing BLDS with GSPE, we investigated its impact on osteogenic and odontogenic differentiation of human dental pulp-derived mesenchymal stem cells (DPDMSCs). The modified scaffolds exhibited improved physicochemical properties, including enhanced cell proliferation, protein absorption, scaffold interactions, and upregulated osteogenic and dental marker gene expression. SEM imaging revealed significant cellular growth and morphological changes indicative of successful differentiation. Furthermore, BLDS-GSPE demonstrated increased ALP activity and mineral deposition, suggesting its potential as a cost-effective, reproducible and biocompatible alternative for bone and dental repair compared to conventional synthetic biomaterials.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"9 4","pages":"Article 100820"},"PeriodicalIF":6.7,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142703188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Van-Hao Vu , Khanh-Huyen Bui , Khoa D.D. Dang , Manh Duong-Tuan , Dung D. Le , Tung Nguyen-Dang
{"title":"Finding environmental-friendly chemical synthesis with AI and high-throughput robotics","authors":"Van-Hao Vu , Khanh-Huyen Bui , Khoa D.D. Dang , Manh Duong-Tuan , Dung D. Le , Tung Nguyen-Dang","doi":"10.1016/j.jsamd.2024.100818","DOIUrl":"10.1016/j.jsamd.2024.100818","url":null,"abstract":"<div><div>Recent environmental challenges have resulted in tremendous interest in Green Chemistry, which includes designing chemical products and processes that reduce the use of environmentally harmful substances. Until now, finding new environmental chemical synthesis has mainly been a trial-and-error process, requiring trained expertise and a lot of work. Here, we report a high-throughput process, combining AI techniques and robotic synthesis, allowing us to find a more environmentally friendly way to synthesize an existing material. The model materials in this study are to replace nitrate salts (NO<sub>3</sub><sup>−</sup>), which might be responsible for algae bloom if leaked into open water, with a chloride salt (Cl<sup>−</sup>), a naturally abundant ion, in the synthesis of a metal-organic framework (MOF), Zn-HKUST-1. Our high-throughput process starts with using large language models (LLM)-based literature summary to create a database on the synthesis of Zn-HKUST-1 with NO<sub>3</sub><sup>−</sup>, so that optimized concentrations of Cl<sup>−</sup> can be suggested. Subsequently, these suggestions are tested with automatic robotic processes, increasing the speed and precision of the experiments, and finding the optimal synthesis condition. Then, by using human verification as a foundation, we developed an AI-based automated classification algorithm to automatically sort the acquired images into crystals and non-crystals, focusing on low-resource settings. We successfully obtained MOF crystals from ZnCl<sub>2</sub> precursors with this process, which proves that our process holds the promise to accelerate the discovery of new Green Chemistry processes.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100818"},"PeriodicalIF":6.7,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143093096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liangzheng Ji , Jing Zhang , Guoqi Zhang , Pan Liu
{"title":"A polyamide-facilitated soldering approach for Mini LED precise alignment leveraging 3D interfacial networks","authors":"Liangzheng Ji , Jing Zhang , Guoqi Zhang , Pan Liu","doi":"10.1016/j.jsamd.2024.100817","DOIUrl":"10.1016/j.jsamd.2024.100817","url":null,"abstract":"<div><div>Driven by the need for improved quality, energy efficiency, and visual innovation, display technology has evolved from CRT to Mini LED. However, the transfer process in Mini LED assembly poses challenges in precision. This study addressed the displacement issue during the transfer process by investigating the synergistic effects of solder and functional organic chemicals. Through the Mini LED assembly process, with the Mini LED size measuring 150 μm (length) ∗ 100 μm (width) ∗ 70 μm (thickness), polyamide was identified as a facilitator for precise alignment, which enhanced self-alignment capabilities by 68.8 % and improved the accuracy on self-aligned distance from 12.5 μm to 21.1 μm in Mini LED packaging. Through the powder coalescence approach, further extensive analysis using XPS, SEM, FTIR, and DSC reveals the synergistic effects. It supports the proposed three-dimensional polyamide-tin ion coordination interfacial network construction mechanism that facilitates solder-to-solder self-alignment and coalescence. This study provides insight into such a polymer-metal ion 3D coordination network for Mini LED precise alignment, which is promising for mass production.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"9 4","pages":"Article 100817"},"PeriodicalIF":6.7,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142722580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Elham Lori Zoudani, Nam-Trung Nguyen, Navid Kashaninejad
{"title":"Surface engineering for enhanced wicking: The role of laser machining and surface roughness","authors":"Elham Lori Zoudani, Nam-Trung Nguyen, Navid Kashaninejad","doi":"10.1016/j.jsamd.2024.100819","DOIUrl":"10.1016/j.jsamd.2024.100819","url":null,"abstract":"<div><div>Wicking is an efficient liquid-handling strategy used in biomedicine, textile engineering, and environmental monitoring. Laser micromachining is a powerful method that induces unidirectional wicking by altering a surface's physical and chemical properties in one step. This research examines how laser machining affects the wicking dynamics of open microchannels. Microchannels were fabricated on a pre-laser-machined hydrophobic square on a silicon substrate, and their wicking performance, i.e., flow rate, water meniscus shape, and durability, was evaluated under various conditions, including different laser parameters, channel orientation, and engraving designs. Depending on its distribution, surface roughness, influenced by laser parameters, is critical in enhancing or hindering wicking. The laser can create two distinct wicking modes on a single platform. Increased roughness slows wicking in horizontally oriented channels, while in vertically oriented channels, it significantly boosts the capillary rate. The durability of wicking also depends on surface roughness properties; microchannels with tightly structured textures maintain durable wicking independent of their capillary flow rate. This study provides insights into how laser machining influences wicking dynamics in microstructures, offering strategies for optimizing microfluidic devices.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"9 4","pages":"Article 100819"},"PeriodicalIF":6.7,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142703194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}