{"title":"Ephedra extract-mediated gold nanoparticles on Kaolin: A natural approach for reduction and stabilization, with evaluation of antioxidant and anti-ovarian cancer activities","authors":"Hui Yang , Cui Wang , Qingjiang Wang , Feng Han","doi":"10.1016/j.jsamd.2025.100853","DOIUrl":"10.1016/j.jsamd.2025.100853","url":null,"abstract":"<div><div>A straightforward, efficient, and environmentally friendly method has been developed to synthesize gold nanoparticles (Au NPs) supported on kaolin with no harmful additives, ephedra flower extract acts as a biogenic stabilizing and reducing agent. An analysis of the Au NPs/Kaolin composite's structural properties was conducted using FE-SEM, TEM, EDX, and XRD assays. The biological activity of the composite was evaluated through cytotoxicity tests using the MTT assay. In addition, its potential anti-ovarian cancer properties were tested against several ovarian cancer cell lines, including TOV-21G, OV-90, SW 626, and UWB1.289, with IC50 values found to be 112, 250, 278, and 243 μg/mL, respectively. The ovarian cancer cell lines showed a dose-dependent decline in % cell viability. The HUVEC cell line was also used to evaluate the material's biocompatibility with normal cells. Based on the results, the bio-composite material is found promising as a therapeutic agent for treating human ovarian cancer.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 2","pages":"Article 100853"},"PeriodicalIF":6.7,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143137617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Seyyedeh Fatemeh Hosseini , Mir Saeed Seyed Dorraji , Shiva Mohajer , Seyedeh Narges Saeedi , Masoumeh Kianfar , Alexandr V. Koshelev , Nataliya A. Arkharova , Denis N. Karimov
{"title":"Synergistic photothermal conversion and visible-light photodegradation of antibiotic in S-type TiO2 derived Ti3C2-MXene loaded on NaYF4: Tm3+, Er3+, Yb3+ @BiOI","authors":"Seyyedeh Fatemeh Hosseini , Mir Saeed Seyed Dorraji , Shiva Mohajer , Seyedeh Narges Saeedi , Masoumeh Kianfar , Alexandr V. Koshelev , Nataliya A. Arkharova , Denis N. Karimov","doi":"10.1016/j.jsamd.2025.100851","DOIUrl":"10.1016/j.jsamd.2025.100851","url":null,"abstract":"<div><div>Here, the collaboration of photocatalysis and photothermal conversion has been defined as an efficient strategy for converting unusable near-infrared (NIR) light to operational ultraviolet–visible (UV–vis) photons. For this, a new heterostructured photocatalyst NaYF<sub>4</sub>: Tm<sup>3+</sup>, Er<sup>3+</sup>, Yb<sup>3+</sup> @ BiOI was successfully synthesized using a simple hydrothermal approach paired with electrostatic self-assembly. The results show that BiOI can indirectly use the NIR portion to produce electron-hole pairs due to the presence of upconversion nanoparticles (UCNPs). On the other hand, loading TiO<sub>2</sub> derived Ti<sub>3</sub>C<sub>2</sub> MXenes on NaYF<sub>4</sub>: Tm<sup>3+</sup>, Er<sup>3+</sup>, Yb<sup>3+</sup> @ BiOI increased tetracycline (TC) degradation to 36% and 90%, compared to narrow band gap BiOI, within 120 min under NIR light irradiation and sunlight irradiation, respectively. Moreover, the reaction rate of UCNP@BiOI@TiO<sub>2</sub>–Ti<sub>3</sub>C<sub>2</sub> was found to be 2.85 times higher under sunlight compared to NIR. It can be attributed to the synergistic photocatalytic and photothermal effects triggered by NIR light. In addition, the broad photoresponse range of TiO<sub>2</sub> and the Schottky junction formed by Ti<sub>3</sub>C<sub>2</sub> MXenes between TiO<sub>2</sub> and BiOI facilitate charge separation while reducing photo-generated electron-hole pair recombination. The reduced recombination rate in the synthesized heterojunction was further substantiated by the larger photocurrent response and smaller EIS arc. Excellent catalytic activity is explained by the S-scheme mechanism, which produces holes at the valence band and superoxide radicals at the conductive band in the BiOI and Ti<sub>3</sub>C<sub>2</sub>, respectively. Significantly, the cycling results demonstrated that the photocatalysts had the requisite reusability and recyclability for real-world applications. The cooperative MXene and UCNPs utilized in this study provide a helpful basis for the logical design of full-spectrum photocatalysts.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 2","pages":"Article 100851"},"PeriodicalIF":6.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143203651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fabrication of highly efficient quartz crystal microbalance ammonia sensor based on Cu-BTC nanocomposites","authors":"Kobra Vazirinezhad , Fatemeh Shariatmadar Tehrani , Sedigheh Zeinali , Maryam Tohidi","doi":"10.1016/j.jsamd.2025.100850","DOIUrl":"10.1016/j.jsamd.2025.100850","url":null,"abstract":"<div><div>Today, the measurement of ammonia gas as a corrosive and irritating gas in the environment is very crucial. Therefore, a simple and efficient method for its detection is very important. A quartz crystal microbalance (QCM) gas sensor modified with porous nanomaterials is proposed as a new device with high performance at ambient temperature. Metal-organic frameworks (MOFs), as a type of nanoporous material, have attracted great attention in the field of gas sensing due to their unique properties, such as high adsorption sites for gas molecules compared to other conventional sensing materials. In this work, nanocomposite films of Cu-BTC (MOF containing copper as a metal node and 1,3,5-benzene tricarboxylic acid as an organic linker) with different carbon nanotube (CNT) weight percentages are fabricated on a QCM for the detection of low amounts of ammonia at room temperature. The size and morphology, chemical, crystalline structure, and porosity properties of the synthesized Cu-BTC and Cu-BTC/CNT nanocomposites were examined by field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and BET techniques, respectively. All Cu-BTC/CNT nanocomposites showed a higher response and sensitivity to ammonia gas than both Cu-BTC and CNT individually. In this work, the best sensing behavior is observed in Cu-BTC/CNT10 nanocomposite, with a sensitivity of 8.18 Hz ppm<sup>−1</sup><sup>,</sup> a limit of detection (LOD) of 1.97 ppm, and a limit of quantification (LOQ) of 6.57 ppm in exposure to ammonia vapors. This sensor exhibited good repeatability and reversibility, reasonable selectivity towards other volatile organic compounds (VOCs)<strong>,</strong> and long-term stability during 7 weeks of testing.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 2","pages":"Article 100850"},"PeriodicalIF":6.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143137618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles","authors":"Baiyuan Tian , Chuang Zhu , Manting Gu , Minhao Xu , Wenxuan He","doi":"10.1016/j.jsamd.2025.100849","DOIUrl":"10.1016/j.jsamd.2025.100849","url":null,"abstract":"<div><div>This study aims to discover innovative thermal storage materials that fulfill the specifications of concentrated solar power systems. Thermal storage materials based on ternary eutectic (Hitec) with nano-SiO<sub>2</sub> and nano-MgO are investigated. Simultaneous thermal analysis and laser flash analysis are used to study the main properties of materials. The results indicate that the inclusion of nano-SiO<sub>2</sub> and nano-MgO reduces the melting point while enhancing the latent heat of the base salt. Doping the base salt with 0.3 wt% nano-SiO<sub>2</sub> and 0.7 wt% nano-MgO results in molten salt nanocomposites with an average specific heat of 2.16 J/(g⋅K), which is 54.3% higher than that of the base salt. This surpasses the specific heat of the base salt mixed with a single type of nanoparticle. The thermal conductivity of this nanocomposite is increased by 13.13% to 0.836 W/(m⋅K) compared to the base salt. Furthermore, this study demonstrated that the effect of interfacial thermal resistance on specific heat capacity and heat transfer characteristics is the opposite. While the nanoparticles can increase the specific heat capacity of the molten salt, they can also reduce the heat transfer rate within this material.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 2","pages":"Article 100849"},"PeriodicalIF":6.7,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143203534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jeong Woo Hong, Sang Ho Lee, Jin Park, Min Seok Kim, Seung Ji Bae, Won Suk Koh, Gang San Yun, In Man Kang
{"title":"Design and analysis of quasi-vertical multi-fin GaN power devices based on epitaxially grown GaN-on-sapphire","authors":"Jeong Woo Hong, Sang Ho Lee, Jin Park, Min Seok Kim, Seung Ji Bae, Won Suk Koh, Gang San Yun, In Man Kang","doi":"10.1016/j.jsamd.2025.100848","DOIUrl":"10.1016/j.jsamd.2025.100848","url":null,"abstract":"<div><div>This study presents the design and analysis of a quasi-vertical multi-fin gallium nitride (GaN) power device based on GaN-on-sapphire epitaxy, simulated using three-dimensional technology computer-aided design. The proposed structure aims to overcome the limitations of lateral high-electron-mobility transistors for high-power applications, as well as to address the cost issues associated with fully vertical GaN structures. Device optimization began with a single-fin structure and progressed incrementally. First, we determined the optimal doping concentration for n-type GaN in the drift region and channel, followed by the application and analysis of the trench drain, source field plate, and multi-fin structures. The optimized device achieves impressive performance, with a specific on-resistance of 0.85 mΩ cm<sup>2</sup>, a breakdown voltage of 1263 V, and a Baliga's figure of merit of 1.87 GW cm<sup>−2</sup>. This study's systematic optimization and structural analysis provide valuable insights into enhancing device characteristics for high-power semiconductor applications and contribute to a deeper understanding of the electrical properties of quasi-vertical fin-type power devices.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100848"},"PeriodicalIF":6.7,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sumanta Sahoo , Abdullah Al Mahmud , Ankur Sood , Ganesh Dhakal , Santosh K. Tiwari , Sunmi Zo , Hong Mi Kim , Sung Soo Han
{"title":"Microwave-assisted facile synthesis of graphitic-C3N4/reduced graphene oxide/MoS2 composite as the bifunctional electrocatalyst for electrochemical water splitting","authors":"Sumanta Sahoo , Abdullah Al Mahmud , Ankur Sood , Ganesh Dhakal , Santosh K. Tiwari , Sunmi Zo , Hong Mi Kim , Sung Soo Han","doi":"10.1016/j.jsamd.2024.100843","DOIUrl":"10.1016/j.jsamd.2024.100843","url":null,"abstract":"<div><div>Bifunctional electrocatalysts have shown considerable research attention in the field of water splitting in the last few years. The current work reports a simple microwave (MW)-assisted synthetic approach for the fabrication of nanocomposite based on graphitic-C<sub>3</sub>N<sub>4</sub>, reduced graphene oxide (rGO), and MoS<sub>2</sub>. Notably, the ternary composite was synthesized through ultrafast MW irradiation within a short duration by a cost-effective synthetic route. The synthesized composite served as the suitable electrocatalyst for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The overpotential of the composite was 172 mV for HER and 380 mV for OER. Moreover, the Tafel slopes for HER and OER were 147 and 97 mV dec<sup>−1</sup> for HER and OER, respectively. It is further interesting to note that the composite also displayed admirable stability of 24 h for overall water splitting. Inclusively, the current work demonstrated an efficient rGO-supported MW-assisted inexpensive synthetic approach for the development of 2D bifunctional electrocatalysts.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100843"},"PeriodicalIF":6.7,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Harnessing Z-scheme charge transfer in ultrathin C3N5/TiO2@Ti3C2Cl2 MXene nanosheets for sustainable water purification, hydrogen evolution, and biocompatibility","authors":"Mojtaba Rostami , Ghodsi Mohammadi Ziarani , Alireza Badiei , Jahan bakhsh Ghasemi , Mohammad Khazaei , Milad Jourshabani , Byeong Kyu Lee","doi":"10.1016/j.jsamd.2024.100846","DOIUrl":"10.1016/j.jsamd.2024.100846","url":null,"abstract":"<div><div>MXenes have recently emerged as one of the most promising conductive supports for photocatalytic water remediation and hydrogen evolution reaction (HER) electrocatalysts. This study presented the synthesis of a novel nanocomposite, TiO<sub>2</sub>@Ti<sub>3</sub>C<sub>2</sub>Cl<sub>2</sub>, using a one-step molten salt-shielded (MS<sup>3</sup>) method under an air atmosphere at a low temperature of 1000 °C. A unique aspect of this process was the successful extraction of copper from molten salt using iron bars without any chemical agents. The synthesized TiO<sub>2</sub>@Ti<sub>3</sub>C<sub>2</sub>Cl<sub>2</sub> was subsequently coupled with low band-gap carbon nitride (C<sub>3</sub>N<sub>5</sub>) via an ultrasonic (US) technique, forming a Z-scheme ternary (C<sub>3</sub>N<sub>5</sub>/TiO<sub>2</sub>@Ti<sub>3</sub>C<sub>2</sub>Cl<sub>2</sub>) nanocomposites with a 2D/0D/2D structure. The ternary nanocomposite exhibited remarkable photocatalytic performance, achieving 100% efficiency in degrading dye molecules under optimal conditions, which included a pH of 5, a nanophotocatalyst dose of 100 ppm, a rhodamine B (Rh B) concentration of 10 ppm, room temperature, and a reaction time of 30 min. The C<sub>3</sub>N<sub>5</sub>/TiO<sub>2</sub>@Ti<sub>3</sub>C<sub>2</sub>Cl<sub>2</sub>/Cu composite also exhibited promising electrocatalytic performance for HER with a Tafel slope of 103 mV.dec<sup>−1</sup> and an overpotential of 51 mV at a current density of 10 mA cm<sup>−2</sup> under alkaline conditions. The significant improvement in photocatalytic water remediation and HER performance is likely due to several key factors: the strong interfacial coupling between the 2D/0D/2D materials, which promotes efficient charge separation; the reduced recombination rate of electron-hole pairs, enhancing photocatalytic efficiency; the highly improved electron-transfer processes, which accelerate reaction kinetics; and the increased number of exposed photo- and electrocatalytic active sites, providing more surface area for reactions. These combined effects result in better overall performance for photocatalytic and HER applications. Furthermore, the MTT assay demonstrated a reduction in the toxicity of C<sub>3</sub>N<sub>5</sub> upon forming the ternary nanocomposite. These findings suggest that the synthesized ternary nanocomposite enhances photocatalytic and HER efficiency and reduces toxicity, making it a valuable material for environmental and energy applications.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100846"},"PeriodicalIF":6.7,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hang Ning , Shaoyun Chen , Yan'e Liu , Bo Qu , Yanyu Zheng , Xiaoying Liu , Wenjie Li , Rui Wang , Nairong Chen , Dongxian Zhuo
{"title":"Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing","authors":"Hang Ning , Shaoyun Chen , Yan'e Liu , Bo Qu , Yanyu Zheng , Xiaoying Liu , Wenjie Li , Rui Wang , Nairong Chen , Dongxian Zhuo","doi":"10.1016/j.jsamd.2024.100844","DOIUrl":"10.1016/j.jsamd.2024.100844","url":null,"abstract":"<div><div>High-performance resins that can withstand temperature changes are required to expand the application potential of additive manufacturing (3D printing) in response to increasing demand from various fields. In this study, a novel 3D-printing polybutadiene polyurethane acrylate photosensitive resin named HTPBMA was prepared by mixing hydroxyl-terminated polybutadiene (HTPB) as the base material with other active diluent monomers and photoinitiators, including hydroxypropyl methacrylate (HPMA). The resulting resins exhibited good rheological properties and rapid photocuring ability, depending on the type and proportion of diluent monomer. In particular, the tensile strength and elongation at break of the sample with a 65:35 HTPBMA:HPMA ratio at −25 °C were 32.9 MPa and 246.1%, respectively, being 2.13 and 1.58 times the values at room temperature, respectively. These results indicate that HTPBMA exhibits excellent low-temperature performance and physical properties. The enhancement mechanism can likely be attributed to introducing of a flexible carbon chain as well as increased cross-linking density (υ<sub><em>e</em></sub>). These advantages suggest that the novel photosensitive resin designed and prepared in this study can be used for photocuring 3D printing and maintain excellent performance under extreme climatic conditions. Thus, the proposed HTPBMA has broad application prospects in aerospace and materials science, especially in shoe materials and tires.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100844"},"PeriodicalIF":6.7,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Saïd Douhi , Salesabil Labihi , Adil Eddiai , Soufian Lakrit , Mounir El Achaby , Ahmed Jamal Abdullah Al-Gburi
{"title":"Design, characterization, and electromagnetic performance of a flexible wideband RF antenna using composite materials","authors":"Saïd Douhi , Salesabil Labihi , Adil Eddiai , Soufian Lakrit , Mounir El Achaby , Ahmed Jamal Abdullah Al-Gburi","doi":"10.1016/j.jsamd.2024.100847","DOIUrl":"10.1016/j.jsamd.2024.100847","url":null,"abstract":"<div><div>Traditional microwave and microelectronic technologies typically use metal components for high efficiency, but their rigidity and susceptibility to corrosion limit their suitability for wearable applications. To meet the demand for flexible, high-performance materials in wearable communication systems, this study investigates the use of Poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) combined with calcium- and zirconium-doped barium titanate (BCZT) as a novel substrate for microwave applications. A flexible wideband antenna was developed using a PVDF-HFP/BCZT composite, with BCZT particles enhancing the composite's thermal stability, crystallinity, and dielectric performance. Conductive fabric was employed for the antenna's radiating elements, supporting both flexibility and user comfort. The antenna was fabricated via laser cutting and tested in free space and on a human body model, achieving a resonant frequency of 5.94 GHz, a return loss of −48.32 dB, and a wide bandwidth of 5.10–6.40 GHz, with VSWR below 2 and a radiation efficiency of 60%. Specific absorption rate (SAR) testing with a multilayer human tissue model yielded values of 1.22 W/kg (1g) and 0.366 W/kg (10g), in compliance with international safety standards. Experimental results closely aligned with simulations, demonstrating the potential of PVDF-HFP/BCZT-based antennas as eco-friendly, high-performance solutions for wearable technologies, achieving an effective balance between flexibility and efficiency.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100847"},"PeriodicalIF":6.7,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhiyang Fan , Xiaoyu Gong , Bei Li , Peichen Yu , Xinyang Liu , Hongyu Zhou , Yinsheng He , Wenyue Zheng
{"title":"The formation of strain-induced martensite and its influence on hydrogen compatibility of metastable austenitic stainless steels: A state-of knowledge review","authors":"Zhiyang Fan , Xiaoyu Gong , Bei Li , Peichen Yu , Xinyang Liu , Hongyu Zhou , Yinsheng He , Wenyue Zheng","doi":"10.1016/j.jsamd.2024.100842","DOIUrl":"10.1016/j.jsamd.2024.100842","url":null,"abstract":"<div><div>Austenitic stainless stainless steels (ASS) are an important type of material used in hydrogen storage and handling equipment because of their exceptional corrosion resistance and mechanical qualities. Nevertheless, the hydrogen sensitivities of metastable ASS would be a notable concern since the strain-induced martensitic transformation (SIMT) can take place during the fabrication process. Hence, we performed tensile experiments on 304L and 316L alloys containing varying amounts of Ni content, simulating actual material deformation conditions. We conducted an analysis of the impact of Ni content on SIMT and presented a detailed description of the martensite nucleation and growth process. Subsequently, we conducted an analysis of the orientation connection of the martensitic transition using TEM. Subsequently, we summarized the effects of SIMT and hydrogen on the tensile, creep, and fatigue properties of materials. It was generally observed that in a hydrogen environment, SIMT, as a high-speed diffusion channel for hydrogen, exacerbates the detrimental effect of hydrogen on the material's mechanical properties. The significance of minimizing SIMT to enhance the hydrogen performance of metastable ASS is emphasized, and this article concluded by summarizing the practical methods for reducing the SIMT: optimizing the alloy composition, controlling the deformation temperature, and using post-forming annealing treatment. Through discussion, it was concluded that controlling the deformation temperature is not recommended as a method to eliminate strain-induced martensite.</div></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"10 1","pages":"Article 100842"},"PeriodicalIF":6.7,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}