{"title":"Tanning Performance of a Novel Chrome-Free Complex Tanning Agent: Penetration and Distribution","authors":"Zhen Wang, Ya-nan Wang, Yue Yu, B. Shi","doi":"10.34314/jalca.v116i8.4356","DOIUrl":"https://doi.org/10.34314/jalca.v116i8.4356","url":null,"abstract":"Penetration of tanning agent in leather plays an important role in tanning performance and properties of finished leather. A novel complex tanning agent composed of Al–Zr salts and highly-oxidized starch ligand, named TWLZ, was used for chrome-free tanning. The masking effect of highly-oxidized starch reduced the electropositivity of metal complexes, which should help penetration of TWLZ and moderate its fixation during tanning. The effects of tanning agent dosage, basification method and pretreatment method on the distribution of TWLZ in leather were investigated. Using 8% TWLZ and basifying with magnesium oxide benefited the penetration and distribution of TWLZ throughout the cross-section of leather. Pretreatment with an amphoteric organic tanning agent could regulate the charge state of the hide, balance the penetration and fixation of TWLZ, and thus show uniform distribution and satisfactory tanning performance. This work will guide the establishment of TWLZ chrome-free tanning system.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"29 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85185652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research on Sheepskin Contour Extraction Method Based on Computer Vision Measurement Technology","authors":"Hu Lianhua, Xiang Chengyi, Z. Feng","doi":"10.34314/jalca.v116i8.4355","DOIUrl":"https://doi.org/10.34314/jalca.v116i8.4355","url":null,"abstract":"Manual trimming of sheepskin is intensive labor, and the working environment is full of rotten smells. The tannery is facing increasingly severe recruitment difficulties. This paper uses computer vision technology to study automatic recognition of sheepskin contours, which is the basis for the subsequent automatic trimming of sheepskin. After observing and analyzing the raw sheepskin images collected by an industrial array camera, a method of sheepskin contour extraction based on computer vision measurement technology is proposed in this paper. This method uses the fast Otsu threshold algorithm based on the pixel set to perform binary image segmentation. Combined with morphological processing for edge defect filling and topology analysis of boundary contour tracking algorithm to extract maximum contour information, it has a pixel-level three-dimensional de-noising preprocessing function and can accurately extract the sheepskin contour in the raw sheepskin image. The experimental results show that using the fast Otsu threshold algorithm proposed in this paper for binary segmentation to extract sheepskin contours, the detection rate is nearly 160% faster than the traditional Otsu algorithm, the edge protection is better, the error segmentation is reduced by nearly 3% and it has good anti-noise performance. It can meet the industrial production requirements of subsequent automatic cutting of sheepskin.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"22 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84358578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Vedaraman, K. Srinivas, D. Krishnamoorthy, V. Aparna, V. Anand, A. Raj, M. A. Javid, C. Muralidharan, J. Sundar, K. Iyappan, K. C. Velappan
{"title":"Development of Improved Liming Process based on Automated pH Monitoring and Control System","authors":"N. Vedaraman, K. Srinivas, D. Krishnamoorthy, V. Aparna, V. Anand, A. Raj, M. A. Javid, C. Muralidharan, J. Sundar, K. Iyappan, K. C. Velappan","doi":"10.34314/jalca.v116i6.4309","DOIUrl":"https://doi.org/10.34314/jalca.v116i6.4309","url":null,"abstract":"The control of pH of a process plays an important role in many chemical or biological reactions. The monitoring and control of pH of processes like wastewater treatment, manufacturing food and leather making facilitate to reduce pollution and improve the quality of the final product. The focus of this study is to optimize the usage of lime and recycling of spent liquor through continuous monitoring system of pH to achieve near zero residue from liming operation. But the challenges are nonlinear behaviour of the system and frequent fouling of pH sensors. The system developed monitors the pH values and controls the cycling time and the addition of lime as per the user set profile. The real time data of pH values in the process is logged on to the PC for further analysis. The efficacy of the system developed was validated at lab level and can be easily scaled up for implementation in industries. The results showed that the effluent from leather making can be minimized by adopting automated pH monitoring and control systems.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"72 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83495117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Production of Carboxymethyl Starches from Oxidized Starches and Determination of Their Tanning Characteristics","authors":"Cigdem Ozkan, H. Ozgunay","doi":"10.34314/jalca.v116i6.4311","DOIUrl":"https://doi.org/10.34314/jalca.v116i6.4311","url":null,"abstract":"Hydrogen peroxide and sodium metaperiodate oxidation of starch and their possible utilization in tanning/retanning were examined in our previous studies. In the present part, accordingly with our previous findings, hydrogen peroxide and sodium metaperiodate oxidation products having appropriate molecular weight/size were selected and additionally carboxymethylated. The yields of the processes (carboxymethyl starches) were characterized comprehensively and the effect of carboxymethylation process on structures and tanning abilities were tried to be identified. The characterization results revealed that the carboxymethyl groups were successfully included into the structure and the water solubility of oxidized starches (especially periodate oxidized ones) increased by carboxymethylation process. From the evaluation of the tanning results and considering its properties i.e. gentle tanning effect with less astringency and correspondingly a relatively soft leather handle and smooth grain, it is concluded that dialdehyde carboxymethyl starch (CMS 1:0.7) can be utilized as yet another good alternative sustainable green tanning/retanning agent from starch.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"35 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72920539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Valorisation of Tannery Waste and Animal By-Product for Acoustics Applications","authors":"Tesfay Gebryergs, C. Sivaranjani, N. Fathima","doi":"10.34314/jalca.v116i6.4308","DOIUrl":"https://doi.org/10.34314/jalca.v116i6.4308","url":null,"abstract":"Disposal of chromium-containing solid wastes generated from the leather industry poses a major threat to tanners worldwide. Herein, we propose a strategy to utilize chrome shaving waste for sound absorption application by blending it with natural fiber, wool. The composites were prepared at various ratios with different thickness by compression molding method and subjected to characterizations like scanning electron microscope, porosity measurements, and tensile strength analysis. The sound absorption behavior of the composites was evaluated using the two-microphone impedance tube method. The results indicate that the composites with higher thickness show better sound absorption at higher frequencies when compared to the natural wool and composites with lesser thicknesses. Thus, this material can be used as a sound-absorbing material thereby paving the alternative use of leather waste utilization.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":" 10","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72384000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vimudha Muralidharan, R. Ramesh, B. Madhan, S. Palanivel
{"title":"Biochemical and Physical Changes in Goatskin during Bacterial Putrefaction","authors":"Vimudha Muralidharan, R. Ramesh, B. Madhan, S. Palanivel","doi":"10.34314/jalca.v116i6.4310","DOIUrl":"https://doi.org/10.34314/jalca.v116i6.4310","url":null,"abstract":"The quality of the raw animal skin decides the final quality of leather. Preservation processes of raw animal skins until leather making predominantly uses salting as a popular method owing to the bacteriostatic effect provided by salt. The detrimental impact caused by the usage of salt from the leather processing is well established. This necessitates the quest for developing an economical, efficacious and environment-friendly preservation system. The present work investigates the effects on the physical and chemical characteristics of the animal skin caused by the putrefactive bacteria with respect to time. Physical changes were studied using visual examination, SEM analysis, and histological staining techniques where the structural deterioration was evidently established. Changes in biochemical aspects were studied by observing degradation in proteoglycan levels and collagen from the goat skin taken at various time intervals. Furthermore, the microorganisms that were responsible for the degradation of various skin components were isolated from the skin over the period of 36 hours from flaying. The occurrence of collagen-degrading organisms within 6 hours of initiation of putrefaction and increased number of proteolytic and collagenolytic bacteria at the end of 36-hours observation were indicative of tremendous skin spoilage leading to deteriorated quality of raw material.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"1552 ","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72432924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Masood Aslam, T. Khan, S. Naqvi, Geoff Holmes, Rafea Naffa
{"title":"Learning to Recognize Irregular Features on Leather Surfaces","authors":"Masood Aslam, T. Khan, S. Naqvi, Geoff Holmes, Rafea Naffa","doi":"10.34314/jalca.v116i5.4291","DOIUrl":"https://doi.org/10.34314/jalca.v116i5.4291","url":null,"abstract":"As part of industrial quality control in the leather industry, it is important to identify the abnormal features in wet-blue leather samples. Manual inspection of leather samples is the current norm in industrial settings. To comply with the current industrial standards that advocate large-scale automation, visual inspection based leather processing is imperative. Visual inspection of irregular surfaces is a challenging problem as the characteristics of the abnormalities can take a variety of shape and color variations. The aim of this work is to automatically categorize leather images into normal or abnormal by visual analysis of the surfaces. To achieve this aim, a deep learning based approach is devised that learns to recognize regular and irregular leather surfaces and categorize leather images on its basis. To this end, we propose an ensemble of multiple convolutional neural networks for classifying leather images. The proposed ensemble network exhibited competitive performance obtaining 92.68% test accuracy on our own curated leather images dataset.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"18 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88534878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qiaoping Xia, Y. Wang, Meina Zhang, Zongcai Zhang, H. Dai
{"title":"Effects of a Clean Subcritical Degreasing System on Wool Fibers","authors":"Qiaoping Xia, Y. Wang, Meina Zhang, Zongcai Zhang, H. Dai","doi":"10.34314/jalca.v116i5.4292","DOIUrl":"https://doi.org/10.34314/jalca.v116i5.4292","url":null,"abstract":"It makes sense to use environmentally friendly methods of degreasing in fur-making process. In this study, subcritical n-pentane was used to degrease wool fibers. Thermogravimetric analysis (TGA) was used to observe and analyze the properties of the subcritical n-pentane degreased wool fibers. The results showed that the thermal stability of the fibers increased. Fourier Transform Infrared (FTIR) spectroscopy was used to analyze the structural changes of macromolecular chains in wool fibers. It was found that when the pressure was higher than 0.4 MPa, the wool fibers underwent a conformational change with the α-helix changing to β-folding. If the pressure was as high as 0.6 MPa, the disulfide bonds in the wool fibers scale layer appeared to break. X-ray powder diffraction experiment was used to study changes in wool fiber aggregation morphology. It was demonstrated that the crystalline zone of wool fibers changed and the fibers index grew, from 22.89% to 30.19%. Field emission scanning electron microscopy and ultra-depth of field microscopy was used to analyze changes in the surface morphology of wool fibers. The results suggested that after the treatment, the wool fibers were not damaged and the impurities on the wool surface were reduced.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"45 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84568179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Oxidized Maltodextrin: A Novel Ligand for Aluminum–Zirconium Complex Tanning","authors":"Xu Guo, Yue Yu, Ya-nan Wang, B. Shi","doi":"10.34314/jalca.v116i5.4293","DOIUrl":"https://doi.org/10.34314/jalca.v116i5.4293","url":null,"abstract":"Hydrogen peroxide (H2O2) oxidized maltodextrin was prepared as the ligand for aluminum–zirconium complex tanning. The effects of catalyst dosage, initiation temperature, and H2O2 dosage on maltodextrin oxidation were investigated. FT-IR analysis demonstrated that carboxyl groups were successfully introduced into oxidized maltodextrin. The carboxyl content and degradation degree of oxidized maltodextrin increased with the increase of H2O2 dosage. Maltodextrin oxidized by 40% H2O2 and 0.015% Cu–Fe catalyst at an initiation temperature of 70°C (OD-40) with moderate carboxyl group (6.75 mmol/g) and molecular weight (Mw 450) promoted the penetration and fixation of aluminum–zirconium salts in leather and showed better tanning performance, such as hydrothermal stability and porosity of leather, than traditional citric acid ligand.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"146 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77670137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qian Zhang, Jie Liu, Xiu-Ling Liu, Hui Liu, Yadi Hu, K. Tang
{"title":"Collagen Fiber Opening of Cattle Hides in Urea/Calcium Hydroxide Solutions","authors":"Qian Zhang, Jie Liu, Xiu-Ling Liu, Hui Liu, Yadi Hu, K. Tang","doi":"10.34314/jalca.v116i5.4290","DOIUrl":"https://doi.org/10.34314/jalca.v116i5.4290","url":null,"abstract":"In the beamhouse, liming might directly affect the structure and performance of collagen, as well as the quality of resultant leather. However, the influences of composition and content of liming agents on liming mechanism are quite complicated. In this study, calcium hydroxide and urea were utilized in liming. The solution pH, hide swelling ratio and non-collagenous protein removal were quantitatively analyzed. The morphologies of both limed and fresh hides were studied by optical microscopy. The reaction mechanism of fiber opening up of cattle hides was analyzed and speculated by the combination of thermogravimetric analysis and Fourier transformation infrared spectroscopy. It was found that the fiber bundles of hides limed by urea/calcium hydroxide have a better opening up effect than that by pure calcium hydroxide. The mechanism of liming in an urea/calcium hydroxide solution system was proposed.","PeriodicalId":17201,"journal":{"name":"Journal of The American Leather Chemists Association","volume":"47 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2021-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86700474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}