ACS Energy Letters 最新文献

{"title":"Making from Breaking: Degradation Inversion Enables Vapor-Phase Synthesis of Halide Perovskites in Ambient Conditions","authors":"Austin G. Kuba, Florent Sahli, Mostafa Othman, Kerem Artuk, Quentin Jeangros, Aïcha Hessler-Wyser, Christophe Ballif, Christian M. Wolff","doi":"10.1021/acsenergylett.4c03395","DOIUrl":"https://doi.org/10.1021/acsenergylett.4c03395","url":null,"abstract":"Vapor phase deposition of formamidinium-rich perovskites is hampered by the decomposition of formamidine in the vapor phase. We use the reversibility of this reaction to establish a dynamic equilibrium that enables the vapor-phase synthesis of formamidinium iodide from the “degradation products” s-triazine, ammonia, and hydrogen iodide and thereby convert lead halide thin films to lead halide perovskites. Finally, we produce the first proof of concept solar cells via this innovative process.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"67 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Origin of Solid Electrolyte Interphase Heterogeneity on Lithium Metal Anodes and Its Mitigation with Electrolyte Additives","authors":"Aoxuan Wang, Ting Yang, Linxue Zhang, Changdong Li, Hao Chen, Yumeng Zhao, Jiayan Luo","doi":"10.1021/acsenergylett.5c00594","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00594","url":null,"abstract":"Lithium metal anode (LMA) stands as a promising candidate for next-generation high-energy-density batteries, yet its viability is critically compromised by heterogeneous solid electrolyte interphase (SEI) formation. This interfacial inhomogeneity manifested as spatially fluctuating Li⁺ transport kinetics provokes erratic lithium deposition and dendrite propagation. Here, we reveal that current strategies to homogenize SEI are impeded by an overlooked origin: crystallographic anisotropy-driven adsorption bias of electrolyte components across polycrystalline Li (poly-Li) surfaces, thereby dictating SEI heterogeneity. We further decouple the correlation between lattice orientation and adsorption energetics by engineering a dual-additive electrolyte [fluoroethylene carbonate (FEC) and propane sultone (PS)]. These additives establish plane adsorption uniformity, forming a homogeneous SEI that spatially synchronizes Li⁺ flux. When paired with a high-loading LiCoO₂ cathode (3.86 mAh cm^–2), the stabilized anode enables 80% capacity retention over 380 cycles under ultralean conditions (N/P = 2.30, E/C = 2.34 g Ah^–1), tripling the cycle life versus conventional electrolytes while suppressing dendritic failure modes.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"112 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unexpected Planar Gliding and Microcracking Induced by Neutron Irradiation in Single-Crystalline LiCoO2 Cathodes","authors":"Kang Wu, Lihua Mo, Tiancheng Yi, Zhigang Zhang, Yoshihiro Kuroiwa, Sangwook Kim, Peilin Ran, Wen Yin, Fangwei Wang, Quanzhi Yu, Tianjiao Liang, Jinkui Zhao, Enyue Zhao","doi":"10.1021/acsenergylett.5c00828","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00828","url":null,"abstract":"Lithium-ion batteries have become increasingly vital in powering aerospace applications, where radiation resistance is a mission-critical battery property. Little is known about the effects of space irradiation on battery materials in operation, particularly neutron irradiation. Understanding the structural and electrochemical failure mechanisms of battery materials in radiation environments is thus crucial for high-performance aerospace applications. Here, we investigate LiCoO₂ (LCO) cathode degradation under simulated space radiation at the China Spallation Neutron Source. Broad-spectrum neutron exposure (ranging from meV to GeV) induces microcracks and stress in LCO crystals, impairing Li⁺ diffusion and destabilizing the oxygen framework. <i>Operando</i> neutron studies reveal that capacity loss stems from irradiation-triggered interlayer planar gliding during Li de/intercalation. Finally, we show that the irradiation damage can be effectively mitigated by reducing the LCO crystalline particle size. Thus, our work provides the critical knowledge for designing radiation-resistant cathode materials for critical applications.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"5 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering an Adaptive Inner Helmholtz Plane Enables High-Voltage Sodium-Ion Batteries","authors":"Zhigao Chen, Ruigeng Du, Chenyang Liu, Ji Kong, Zihao Li, Yiran Ying, Chao Shen, Ting Jin, Keyu Xie","doi":"10.1021/acsenergylett.5c00593","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00593","url":null,"abstract":"Elevating the cutoff voltage of layered oxide cathodes (LOCs) is an indispensable way to achieve high-energy-density sodium-ion batteries (SIBs). However, undesired interfacial parasitic reactions impede the stable operation of LOCs at high voltages. Herein, we rationally designed an adaptive inner Helmholtz plane (IHP) to regulate the interfacial chemistry of the LOCs. An electron-deficient ligand was employed to anchor with the anions and expel the free solvents within the IHP of LOCs at high voltages, thereby preventing anionic decomposition of the electrolytes and reducing HF generation. Moreover, the anion-anchored IHP facilitates the formation of a robust inorganic-rich cathode electrolyte interphase (CEI) on the LOCs. Benefiting from the tailored IHP, O3-NaNi_1/3Fe_1/3Mn_1/3O₂ (NNFMO) exhibits significantly enhanced cycling stability at an ultrahigh voltage of 4.5 V. Our work paves a new way for regulating interfacial chemistry by tailoring the electric double layer of LOCs for high-energy and long-life SIBs.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"2 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent Advances in Solid-State Batteries","authors":"Kelsey B. Hatzell, Linda F. Nazar","doi":"10.1021/acsenergylett.5c01015","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c01015","url":null,"abstract":"Sanchez, A. J.; Dasgupta, N. P. Lithium Metal Anodes: Advancing our Mechanistic Understanding of Cycling Phenomena in Liquid and Solid Electrolytes. &lt;i&gt;J. Am. Chem. Soc.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;146&lt;/i&gt;, 4282–4300. DOI: 10.1021/jacs.3c05715. Surendran, V.; Thangadurai, V. Solid-State Lithium Metal Batteries for Electric Vehicles: Critical Single Cell Level Assessment of Capacity and Lithium Necessity. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2025&lt;/b&gt;, &lt;i&gt;10&lt;/i&gt;, 991–1001. 10.1021/acsenergylett.4c03331. Szymanski, N. J.; Bartel, C. J. Computationally Guided Synthesis of Battery Materials. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;9&lt;/i&gt;, 2902–2911. DOI: 10.1021/acsenergylett.4c00821. Yang, J.; Lin, J.; Brezesinski, T.; Strauss, F. Emerging Superionic Sulfide and Halide Glass–Ceramic Solid Electrolytes: Recent Progress and Future Perspectives. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;9&lt;/i&gt;, 5977–5990. DOI: 10.1021/acsenergylett.4c02460. Zhang, X.; Osenberg, M.; Ziesche, R. F.; Yu, Z.; Kowal, J.; Dong, K.; Lu, Y.; Manke, I. Visualizing the Future: Recent Progress and Challenges on Advanced Imaging Characterization for All-Solid-State Batteries. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2025&lt;/b&gt;, &lt;i&gt;10&lt;/i&gt;, 496–525. DOI: 10.1021/acsenergylett.4c02476. Lin, L.; Ayyaswamy, A.; Zheng, Y.; Fan, A.; Vishnugopi, B. S.; Mukherjee, P.; Hatzell, K. B. Nonintuitive Role of Solid Electrolyte Porosity on Failure. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;9&lt;/i&gt;, 2387–2393. DOI: 10.1021/acsenergylett.4c00744. Chen, S.; Cao, Q.; Tang, B.; Yu, X.; Zhou, Z.; Bo, S.-H.; Guo, Y. Chemomechanical Pairing of Alloy Anodes and Solid-State Electrolytes. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;9&lt;/i&gt;, 5373–5382. DOI: 10.1021/acsenergylett.4c01983. Cheng, D.; Tran, K.; Rao, S.; Wang, Z.; van der Linde, R.; Pirzada, S.; Yang, H.; Yan, A.; Kamath, A.; Meng, Y. S. Manufacturing Scale-Up of Anodeless Solid-State Lithium Thin-Film Batteries for High Volumetric Energy Density Applications. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2023&lt;/b&gt;, &lt;i&gt;8&lt;/i&gt;, 4768–4774. DOI: 10.1021/acsenergylett.3c01839. Nelson, D. L.; Sandoval, S. E.; Pyo, J.; Bistri, D.; Thomas, T. A.; Cavallaro, K. A.; Lewis, J. A.; Iyer, A. S.; Shevchenko, P.; Di Leo, C. V.; McDowell, M. T. Fracture Dynamics in Silicon Anode Solid-State Batteries. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;9&lt;/i&gt;, 6085–6095. DOI: 10.1021/acsenergylett.4c02800. Sun, K.; Thorsteinsson, G.; Zhao, D.; Owen, C.; Ponnekanti, A.; Herman, Z.; Parris, B.; Kothari, I.; Steingart, D. A. Chemo-mechanics and Morphological Dynamics of Si Electrodes in All-Solid-State Li-Ion Batteries. &lt;i&gt;ACS Energy Lett.&lt;/i&gt; &lt;b&gt;2025&lt;/b&gt;, &lt;i&gt;10&lt;/i&gt;, 1229–1234. DOI: 10.1021/acsenergylett.5c00132. Wang, C.; Jing, Y.; Zhu, D.; Xin, H. Atomic Origin of Chemomechanical Failure of Layered Cathodes in All-Solid-State Batteries. &lt;i&gt;J. Am. Chem. Soc.&lt;/i&gt; &lt;b&gt;2024&lt;/b&gt;, &lt;i&gt;146&lt;/i&gt;, 17712–17718. DOI: 10.1021/jacs.4c02198. Wang, X.-X.; Guan, D.-H.; Miao, C.-L.; Kong, D.-C.; Zheng, L.-J.; Xu, J.-J. Metal–Organic Framework-Based Mixed Conduct","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"44 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the Role of Guanidinium for Enhanced Charge Extraction in Inverted Perovskite Solar Cells","authors":"Weidong Xu, Ganghong Min, Felix Utama Kosasih, Yueyao Dong, Ziyuan Ge, Qichun Gu, Muzi Chen, Richard A. Pacalaj, Tong Wang, Thomas Webb, Tian Du, Marcello Righetto, Guanjie He, Mischa Hillenius, Elizabeth von Hauff, Giorgio Divitini, Caterina Ducati, Martyn A. McLachlan, Franco Cacialli, Saif A. Haque, Artem A. Bakulin, James R. Durrant, Chieh-Ting Lin, Samuel D. Stranks, Thomas J. Macdonald","doi":"10.1021/acsenergylett.5c00469","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00469","url":null,"abstract":"The incorporation of guanidinium (Gua) cations has significantly enhanced the optoelectronic properties of various perovskite compositions. When combined with other A-site cations in perovskite solar cells (PSCs), Gua cations not only enhance the power conversion efficiency of the solar cells but often improve their overall stability. While most studies examining the impact of Gua focus on PSCs with the n-i-p (conventional) structure, fewer have investigated its effects on the mechanism and performance of the p-i-n (inverted) structure. We investigate how partially substituting A-site cations with Gua affects the performance of PSCs and the associated charge carrier dynamics. Enhanced performance is observed in Gua-substituted inverted PSCs, primarily due to improved short-circuit current density and fill factor values. Our spectroscopic and microscopic analyses reveal that these enhancements stem from accelerated charge transport within the perovskite layer combined with inhibited ion migration following Gua incorporation, attributed to the reduction of localized inhomogeneities, which also notably enhance device stability. Our findings elucidate the role of Gua in inverted PSCs, showing negligible impact on open-circuit voltage but significant improvement in charge extraction efficiency. This contrasts with previous reports on conventional structures, where performance enhancement is primarily attributed to trap state reduction, resulting in higher open-circuit voltage.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"49 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"F-Free Pressure-Sensitive Adhesives as Dry-Coating Process Binders for Ultrahigh-Loading Graphite Anodes","authors":"Jiseong Kim, Jong Seok Park, Jung-je Woo, Sinho Choi, Jiyoung Ma, Jinsoo Kim, Sunghun Choi","doi":"10.1021/acsenergylett.5c00612","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00612","url":null,"abstract":"High-loading electrode engineering is a cost-effective and practical method of increasing the energy density by minimizing the content of inactive materials in the cell. However, sluggish Li-ion intercalation at the graphite anodes during the charging process results in capacity limitations and cycling deterioration. For the first time, we present herein a pressure-sensitive adhesive (PSA) based on F-free styrene–butadiene rubber (SBR). When subjected to external pressure calendaring at room temperature, PSA-SBR becomes highly sticky, enabling a solvent-free dry-coating process. This approach results in the formation of flexible, freestanding electrode films and creates an open-channel interface on the graphite surface, thereby reducing interfacial resistance. Additionally, it establishes a low-resistance solid electrolyte interphase, particularly when using a fluoroethylene carbonate additive, leading to a stable cell performance with an areal capacity of 10.6 mAh cm^–2. This binder shows potential applicability to other high-loading electrodes with significant interfacial resistances.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"16 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Janus Solid Electrolyte with Ionic and Electronic Dual Conductive Face Guiding Lithium Deposition Oriental To Connect with Lithium Metal Anode","authors":"Xinhong Qi, Yihang Li, Shichen Zhang, Xuehua Ruan, Xiaobin Jiang, Xiangcun Li, Gaohong He","doi":"10.1021/acsenergylett.5c00495","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00495","url":null,"abstract":"Polymer solid electrolytes show facile flexibility and processability, but the trade-off between ionic conductivity and lithium dendrite inhibition ability restricts their practical applications. Herein, polyacrylonitrile (PAN)/carbon nanotube (CNT) with one face electronic conductive membrane is merged with in situ polymerized ionic conductive polyethylene glycol diacrylate (PEGDA)/ethylene carbonate (EC)/dimethylcarbamide (DMC)/lithium bistrifluoromethane sulfonimide (LiTFSI) to construct Janus solid electrolyte PAN/CNT@PEDL. The ionic conductive face of PAN@PEDL is responsible for transporting Li⁺ and separating the cathode/anode. The other face of PAN-CNT@PEDL with ionic and electronic conductive peculiarity transports Li⁺ and electrons simultaneously, guiding Li⁺ deposition oriental in it and its interface connecting with the Li anode rather than puncturing electrolyte. The Janus solid electrolyte holds a high ionic conductivity of 3.48 mS cm^–1 at 30 °C and orientated Li⁺ deposition ability. Both Li||Li and LiFePO₄(LFP)||Li cells show improved cycling performances. The concept of Janus ionic/ionic and electronic conductive solid electrolytes proposes a new perspective for designing solid electrolytes.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"76 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent Advances in Solid-State Batteries","authors":"Kelsey B. Hatzell*,&nbsp; and ,&nbsp;Linda F. Nazar*,&nbsp;","doi":"10.1021/acsenergylett.5c0101510.1021/acsenergylett.5c01015","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c01015https://doi.org/10.1021/acsenergylett.5c01015","url":null,"abstract":"","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 5","pages":"2315–2317 2315–2317"},"PeriodicalIF":19.3,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Subzero Temperature Operation of Aqueous Zn Metal Batteries by Tailoring Electrolyte Solvation Structure","authors":"Qiao Ni, Lumin Zheng, Orapa Tamwattana, Jaekyun Yoo, Songyan Bai, Myeong Hwan Lee, Joo Hyeon Noh, Chuan Wu, Kisuk Kang","doi":"10.1021/acsenergylett.5c00548","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00548","url":null,"abstract":"The declining performance of aqueous zinc metal batteries (AZMBs) at colder temperatures, especially due to aqueous electrolyte solidification and reduced capacity retention at subzero temperatures, poses a considerable challenge. Here, we report a cheap and ecofriendly aqueous electrolyte formulation comprising low-concentration zinc chloride salt and a common antifreeze agent. We show that the glycerin antifreeze co-solvent effectively interacts with free water molecules and weakens the zinc-ion primary solvation structures, thereby considerably mitigating their detrimental effect at low temperatures. Consequently, the optimized electrolyte successfully outputs a depressed liquid–glass transition point down to −99.2 °C and a record-high Zn plating/stripping Coulombic efficiency of ∼99.94% at −40 °C, as well as ∼70% of its room-temperature capacity at −40 °C, opening up a new opportunity for practical AZMBs.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"71 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}