ACS Energy Letters 最新文献_第10页

Ionic Structured Redox-Mediating Polymeric Sulfurs for Lithium–Sulfur Batteries 锂硫电池用离子结构氧化还原介质聚合物硫

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-04-21 DOI: 10.1021/acsenergylett.5c00808

Won Il Kim, Jong Chan Shin, Min Ju Kim, Gun Jang, Minjae Lee, Ho Seok Park

{"title":"Ionic Structured Redox-Mediating Polymeric Sulfurs for Lithium–Sulfur Batteries","authors":"Won Il Kim, Jong Chan Shin, Min Ju Kim, Gun Jang, Minjae Lee, Ho Seok Park","doi":"10.1021/acsenergylett.5c00808","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00808","url":null,"abstract":"Polymeric sulfur demonstrates immense capabilities as a promising active material for lithium–sulfur batteries (LSBs) owing to their ability to capture lithium polysulfides (LiPS) through the formation of covalent bonds. Herein, we demonstrate an ionic structured polymeric sulfur (IP-S) as a redox mediating matrix, which provides structural stability, an ionic conductive pathway, and a uniform distribution of active materials within the electrode. In particular, the cationic structure of IP-S was attributed to the facilitated LiPS conversion kinetics with the high utilization of sulfur. Consequently, the IP-S electrode delivered the high specific capacity of 1398.8 mAh gsulfur–1 with a low-capacity fading rate of 0.071% over 400 cycles. Moreover, with a high sulfur loading (6.87 mgsulfur cm–2), the IP-S electrode achieved a high initial capacity of 7.23 mAh cm–2. Therefore, this work provides the rational design of ionic structured polymeric sulfur for high performance LSBs as well as the correlation between the ionic structure and the electrochemical property.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"108 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143853253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ionic Structured Redox-Mediating Polymeric Sulfurs for Lithium–Sulfur Batteries 锂硫电池用离子结构氧化还原介质聚合物硫

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-21 DOI: 10.1021/acsenergylett.5c0080810.1021/acsenergylett.5c00808

Won Il Kim, Jong Chan Shin, Min Ju Kim, Gun Jang, Minjae Lee* and Ho Seok Park*,

{"title":"Ionic Structured Redox-Mediating Polymeric Sulfurs for Lithium–Sulfur Batteries","authors":"Won Il Kim, Jong Chan Shin, Min Ju Kim, Gun Jang, Minjae Lee* and Ho Seok Park*, ","doi":"10.1021/acsenergylett.5c0080810.1021/acsenergylett.5c00808","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00808https://doi.org/10.1021/acsenergylett.5c00808","url":null,"abstract":"Polymeric sulfur demonstrates immense capabilities as a promising active material for lithium–sulfur batteries (LSBs) owing to their ability to capture lithium polysulfides (LiPS) through the formation of covalent bonds. Herein, we demonstrate an ionic structured polymeric sulfur (IP-S) as a redox mediating matrix, which provides structural stability, an ionic conductive pathway, and a uniform distribution of active materials within the electrode. In particular, the cationic structure of IP-S was attributed to the facilitated LiPS conversion kinetics with the high utilization of sulfur. Consequently, the IP-S electrode delivered the high specific capacity of 1398.8 mAh gsulfur–1 with a low-capacity fading rate of 0.071% over 400 cycles. Moreover, with a high sulfur loading (6.87 mgsulfur cm–2), the IP-S electrode achieved a high initial capacity of 7.23 mAh cm–2. Therefore, this work provides the rational design of ionic structured polymeric sulfur for high performance LSBs as well as the correlation between the ionic structure and the electrochemical property.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 5","pages":"2410–2418 2410–2418"},"PeriodicalIF":19.3,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling Electrode–Electrolyte Interface Dynamics for Aqueous Zn Batteries 揭示水锌电池的电极-电解质界面动力学

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-04-20 DOI: 10.1021/acsenergylett.5c00445

Xuesong Zhao, Mengdie Yan, Jialu Bi, Kangren Kong, Liqi Liu, Liya Chen, Yihong Jin, Mengqi Zhou, Chaojiang Niu, Zhaoming Liu, Ruikang Tang, Liguang Wang, Jun Lu, Huilin Pan

{"title":"Unveiling Electrode–Electrolyte Interface Dynamics for Aqueous Zn Batteries","authors":"Xuesong Zhao, Mengdie Yan, Jialu Bi, Kangren Kong, Liqi Liu, Liya Chen, Yihong Jin, Mengqi Zhou, Chaojiang Niu, Zhaoming Liu, Ruikang Tang, Liguang Wang, Jun Lu, Huilin Pan","doi":"10.1021/acsenergylett.5c00445","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00445","url":null,"abstract":"Aqueous Zn batteries are a promising solution for energy storage due to their safety and cost-effectiveness. However, conventional Zn anodes face challenges such as slow interfacial kinetics and structural collapse at high rates and Zn utilization. Here, we design an integrated Zn anode with an embedded heterophase boundary framework (HPF-Zn) that could regulate the chemical environment and charge transport kinetics for uniform, fast Zn deposition. Well-designed in situ Raman spectra clearly visualize the dynamic interface evolution under various conditions, confirming rapid Zn2+ replenishment at the interface for HPF-Zn anode. Consequently, the HPF-Zn anode achieves 60× the cycle life of conventional Zn anodes with nearly 100% Zn utilization. Zn||V2O5 full cells exhibit excellent cycling stability, retaining 80% capacity over 5500 cycles (N/P = 5.6) and 2500 cycles (N/P = 3.2). Moreover, Ah-level pouch cells demonstrate superior durability. This work advances our understanding of dynamic interfaces and highlights a strategy for stabilizing electrode–electrolyte interfaces via heterophase boundary design.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"30 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143853118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling Electrode–Electrolyte Interface Dynamics for Aqueous Zn Batteries 揭示水锌电池的电极-电解质界面动力学

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-20 DOI: 10.1021/acsenergylett.5c0044510.1021/acsenergylett.5c00445

Xuesong Zhao, Mengdie Yan, Jialu Bi, Kangren Kong, Liqi Liu, Liya Chen, Yihong Jin, Mengqi Zhou, Chaojiang Niu, Zhaoming Liu, Ruikang Tang, Liguang Wang*, Jun Lu* and Huilin Pan*,

{"title":"Unveiling Electrode–Electrolyte Interface Dynamics for Aqueous Zn Batteries","authors":"Xuesong Zhao, Mengdie Yan, Jialu Bi, Kangren Kong, Liqi Liu, Liya Chen, Yihong Jin, Mengqi Zhou, Chaojiang Niu, Zhaoming Liu, Ruikang Tang, Liguang Wang*, Jun Lu* and Huilin Pan*, ","doi":"10.1021/acsenergylett.5c0044510.1021/acsenergylett.5c00445","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00445https://doi.org/10.1021/acsenergylett.5c00445","url":null,"abstract":"Aqueous Zn batteries are a promising solution for energy storage due to their safety and cost-effectiveness. However, conventional Zn anodes face challenges such as slow interfacial kinetics and structural collapse at high rates and Zn utilization. Here, we design an integrated Zn anode with an embedded heterophase boundary framework (HPF-Zn) that could regulate the chemical environment and charge transport kinetics for uniform, fast Zn deposition. Well-designed in situ Raman spectra clearly visualize the dynamic interface evolution under various conditions, confirming rapid Zn2+ replenishment at the interface for HPF-Zn anode. Consequently, the HPF-Zn anode achieves 60× the cycle life of conventional Zn anodes with nearly 100% Zn utilization. Zn||V2O5 full cells exhibit excellent cycling stability, retaining 80% capacity over 5500 cycles (N/P = 5.6) and 2500 cycles (N/P = 3.2). Moreover, Ah-level pouch cells demonstrate superior durability. This work advances our understanding of dynamic interfaces and highlights a strategy for stabilizing electrode–electrolyte interfaces via heterophase boundary design.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 5","pages":"2400–2409 2400–2409"},"PeriodicalIF":19.3,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Perspective on the Reaction Mechanisms of CO2 Electrolysis CO2电解反应机理研究进展

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-04-18 DOI: 10.1021/acsenergylett.4c03599

Brian Seger, Georg Kastlunger, Alexander Bagger, Soren B. Scott

引用次数: 0

Performance-Limiting Factors of Hydrocarbon Ionomeric Binders for Fuel Cells and Electrolyzers 燃料电池和电解槽用烃类离子单体粘结剂的性能限制因素

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-04-18 DOI: 10.1021/acsenergylett.5c00487

Jong-Ho Choi, Tanya Agarwal, Heemin Park, Jiyoon Jung, Ain Uddin, Su Min Ahn, Jeffrey Michael Klein, Albert S. Lee, Michelle Lehmann, Cy Fujimoto, Eun Joo Park, Tomonori Saito, Rod L. Borup, Yu Seung Kim

引用次数: 0

A Perspective on the Reaction Mechanisms of CO2 Electrolysis CO2电解反应机理研究进展

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-18 DOI: 10.1021/acsenergylett.4c0359910.1021/acsenergylett.4c03599

Brian Seger*, Georg Kastlunger, Alexander Bagger and Soren B. Scott,

引用次数: 0

Performance-Limiting Factors of Hydrocarbon Ionomeric Binders for Fuel Cells and Electrolyzers 燃料电池和电解槽用烃类离子单体粘结剂的性能限制因素

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-18 DOI: 10.1021/acsenergylett.5c0048710.1021/acsenergylett.5c00487

Jong-Ho Choi, Tanya Agarwal, Heemin Park, Jiyoon Jung, Ain Uddin, Su Min Ahn, Jeffrey Michael Klein, Albert S. Lee, Michelle Lehmann, Cy Fujimoto, Eun Joo Park, Tomonori Saito, Rod L. Borup and Yu Seung Kim*,

{"title":"Performance-Limiting Factors of Hydrocarbon Ionomeric Binders for Fuel Cells and Electrolyzers","authors":"Jong-Ho Choi, Tanya Agarwal, Heemin Park, Jiyoon Jung, Ain Uddin, Su Min Ahn, Jeffrey Michael Klein, Albert S. Lee, Michelle Lehmann, Cy Fujimoto, Eun Joo Park, Tomonori Saito, Rod L. Borup and Yu Seung Kim*, ","doi":"10.1021/acsenergylett.5c0048710.1021/acsenergylett.5c00487","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00487https://doi.org/10.1021/acsenergylett.5c00487","url":null,"abstract":"The move toward nonfluorinated hydrocarbon ionomers for fuel cells and electrolyzers is driven by potential restrictions on polyfluoroalkyl substances such as Nafion. This study examines the key limitations of hydrocarbon ionomers through half- and single-cell experiments with model hydrocarbon ionomers. Half-cell tests reveal three major performance barriers: undesirable adsorption, electrochemical oxidation, and low gas permeability. Competitive sulfate adsorption helps counteract ionomer adsorption and oxidation. These findings align with single-cell performance data, which further reveal additional oxygen mass transport limitations likely caused by localized electrode flooding. Together, these findings offer valuable insights to guide the development of high-performance, fluorine-free hydrocarbon ionomers for next-generation fuel cells and electrolyzers.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 5","pages":"2392–2399 2392–2399"},"PeriodicalIF":19.3,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Urban Energy Reconfiguration: China’s Hydrogen-Blended Gas Networks as a Catalyst for Global Carbon-Neutral Cities 城市能源重构：中国氢混合气网络作为全球碳中和城市的催化剂

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-17 DOI: 10.1021/acsenergylett.5c0077510.1021/acsenergylett.5c00775

Yuxin Zhao*,

引用次数: 0

Sulfide-Based Anode-Free Solid-State Batteries: Key Challenges and Emerging Solutions 基于硫化物的无阳极固态电池：主要挑战和新兴解决方案

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-04-17 DOI: 10.1021/acsenergylett.5c0051710.1021/acsenergylett.5c00517

Jiwei Wang, and , Hongli Zhu*,

{"title":"Sulfide-Based Anode-Free Solid-State Batteries: Key Challenges and Emerging Solutions","authors":"Jiwei Wang,  and , Hongli Zhu*, ","doi":"10.1021/acsenergylett.5c0051710.1021/acsenergylett.5c00517","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00517https://doi.org/10.1021/acsenergylett.5c00517","url":null,"abstract":"Sulfide-based anode-free solid-state batteries (AFSSBs) have emerged as a transformative technology for next-generation energy storage, offering compelling advantages in energy density, safety, and manufacturing scalability. However, these batteries face significant challenges, particularly rapid capacity degradation that currently limits their practical implementation. This comprehensive review critically examines three fundamental issues affecting AFSSBs: nonuniform lithium nucleation on bare current collectors, unstable interfaces between plated lithium and sulfide electrolytes, and formation of interfacial voids during cycling. We systematically evaluate recent strategic advances in addressing these challenges, including metal seed coatings, conversion reaction-based compounds, and carbon-based interlayers. The review also analyzes the crucial role of advanced characterization techniques, from cryo-FIB-SEM to operando methods, in understanding failure mechanisms and validating improvement strategies. Finally, we present a forward-looking perspective on research directions necessary for commercialization. This work provides a thorough framework for understanding and advancing sulfide-based AFSSBs toward practical applications in next-generation energy storage systems.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 5","pages":"2377–2391 2377–2391"},"PeriodicalIF":19.3,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsenergylett.5c00517","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0