ACS Energy Letters 最新文献_第9页

Steric Hindrance Manipulation in Polymer Electrolytes toward Wide-Temperature Solid-State Lithium Metal Batteries 宽温固态锂金属电池中聚合物电解质的位阻操纵

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.4c03602

Jie Huang, Bin Qiu, Feng Xu, Jinyu Gao, Peixin Zhang, Chuanxin He, Hongwei Mi

{"title":"Steric Hindrance Manipulation in Polymer Electrolytes toward Wide-Temperature Solid-State Lithium Metal Batteries","authors":"Jie Huang, Bin Qiu, Feng Xu, Jinyu Gao, Peixin Zhang, Chuanxin He, Hongwei Mi","doi":"10.1021/acsenergylett.4c03602","DOIUrl":"https://doi.org/10.1021/acsenergylett.4c03602","url":null,"abstract":"Solid-state lithium metal batteries (LMBs) based on polymer electrolytes have become a hot topic for next-generation energy storage owing to their high specific energy, flexibility, and simple preparation process. However, poor electrolyte–electrode interface reactions and intrinsically slow Li+ transfer kinetics limit the development of solid-state LMBs. Here, a tris(4-fluorophenyl)phosphine (T4FPP) additive with strong steric hindrance and weak coordination is introduced to remodel the Li+ coordination environment to facilitate electrolyte bulk and interface charge transfer. Furthermore, theoretical analysis combined with in situ/ex situ characterizations demonstrate that the addition of T4FPP helps to construct an anion-dominated solvation structure through molecular crowding and form a LiF/Li2O-rich SEI layer. Ultimately, the LFP|Li full cell based on the T4FPP modified electrolyte works normally even at 10 C with a reversible specific capacity of 88.9 mAh g–1. Simultaneously, the electrochemical performance at 0–60 °C further verified the wide temperature range adaptability of the electrolyte.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"183 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143724014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lattice-Matched Ta3N5/Nb5N6 Interface Enables a Bulk Charge Separation Efficiency of Close to 100% 晶格匹配的Ta3N5/Nb5N6接口使大量电荷分离效率接近100%

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c00603

Yitong Liu, Zeyu Fan, Ronghua Li, Andraž Mavrič, Iztok Arčon, Matjaz Valant, Gregor Kapun, Beibei Zhang, Chao Feng, Zemin Zhang, Tingxi Chen, Yanning Zhang, Yanbo Li

{"title":"Lattice-Matched Ta3N5/Nb5N6 Interface Enables a Bulk Charge Separation Efficiency of Close to 100%","authors":"Yitong Liu, Zeyu Fan, Ronghua Li, Andraž Mavrič, Iztok Arčon, Matjaz Valant, Gregor Kapun, Beibei Zhang, Chao Feng, Zemin Zhang, Tingxi Chen, Yanning Zhang, Yanbo Li","doi":"10.1021/acsenergylett.5c00603","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00603","url":null,"abstract":"The interface between the semiconductor light absorber and the metal electrode is critical for facilitating the extraction of photogenerated charges in photoelectrodes. Achieving a lattice-matched semiconductor/electrode interface with low defect density is highly desirable but remains a challenge for Ta3N5 photoanodes. In this study, we synthesized niobium nitride thin film electrodes with controllable crystallographic phases to achieve a lattice-matched Ta3N5/Nb5N6 back contact. This results in an enhanced crystallinity of the Ta3N5 film and reduced interfacial defect density. Consequently, the photoanode with the lattice-matched back contact attains a record half-cell solar-to-hydrogen conversion efficiency of 4.1%, attributed to the bulk carrier separation efficiency of nearly 100%. This work highlights lattice-matching as an effective strategy to enhance the efficiency of thin film-based solar energy conversion devices.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"72 1","pages":""},"PeriodicalIF":22.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143713427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Operando Optical Microscopy for Visualization of Dendrite Growth in an Argyrodite LPSCl–Polymer Composite Electrolyte 用光学显微镜观察银柱石lpscl -聚合物复合电解质中枝晶生长

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c00281

Xiuyu Jin, Di Huang, Qiusu Miao, Ziting Zhu, Wei Tong, Alvaro Videla, Gao Liu

引用次数: 0

Polyoxometalates (POMs) as Proton Conductors 多金属氧酸盐（pom）作为质子导体

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c0037310.1021/acsenergylett.5c00373

Apu Saha, Rupam Sahoo, Shyam Chand Pal, Sayaka Uchida and Madhab C. Das*,

{"title":"Polyoxometalates (POMs) as Proton Conductors","authors":"Apu Saha, Rupam Sahoo, Shyam Chand Pal, Sayaka Uchida and Madhab C. Das*, ","doi":"10.1021/acsenergylett.5c0037310.1021/acsenergylett.5c00373","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00373https://doi.org/10.1021/acsenergylett.5c00373","url":null,"abstract":"The development of solid-state proton conductors (SSPCs) is of significant interest for their deployment as proton exchange membranes in fuel cell (PEMFC) technology. The aqueous medium synthesis with ample intrinsic proton sources has made crystalline polyoxometalates (POMs) promising SSPCs over others. Herein, we aim to showcase the solitary POMs and their hybrids (with polymers and MOFs/COFs) as SSPCs by organizing them based on the approaches taken up (intrinsic or extrinsic) to install various protonic sources while positioning them within specific components of the POM frameworks. Particular attention is paid with a critical discussion on whether the conductivity is purely protonic or a combination of protonic and other ionic conductivity (majorly originating from charge balancing counterions) and thus recommend the terminology to be used. The “Critical Discussion” section provides in-depth insights which are often overlooked, while the future recommendations are made in “Future Outlook”.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 4","pages":"1958–1998 1958–1998"},"PeriodicalIF":19.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural Feature Design for Carbon Materials toward Sodium Storage: Insights and Prospects 面向钠存储的碳材料结构特征设计：见解与展望

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c0023110.1021/acsenergylett.5c00231

Shaorui Chen, Tianzhao Hu, Tong Yu, Xianyou Luo, Lei Zhang* and Feng Li*,

{"title":"Structural Feature Design for Carbon Materials toward Sodium Storage: Insights and Prospects","authors":"Shaorui Chen, Tianzhao Hu, Tong Yu, Xianyou Luo, Lei Zhang* and Feng Li*, ","doi":"10.1021/acsenergylett.5c0023110.1021/acsenergylett.5c00231","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00231https://doi.org/10.1021/acsenergylett.5c00231","url":null,"abstract":"Sodium-ion batteries are an attractive alternative to lithium-ion batteries due to the abundance and cost-effectiveness and are suitable for large-scale energy storage. Carbon materials, notable for their availability, economic viability, high capacity, and stability, stand out as potential anode materials. The sodium storage performance of carbon materials is inherently determined by their structural features. Manipulating these features is key to optimizing the storage behavior. This Perspective systematically evaluates the classification and structural distinctions of existing carbon-based materials for sodium-ion batteries, summarizing different sodium storage processes and electrochemical behaviors. Structural features are categorized into intrinsic (e.g., arrangement and distribution of carbon atoms) and extrinsic (e.g., heteroatoms). The sodium storage processes and behaviors associated with these features and the corresponding regulation strategies are explored in depth. Finally, the challenges and future directions for developing high-performance carbon anodes are proposed, aiming to provide actionable insights for advancing research and commercialization efforts.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 4","pages":"1931–1952 1931–1952"},"PeriodicalIF":19.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lattice-Matched Ta3N5/Nb5N6 Interface Enables a Bulk Charge Separation Efficiency of Close to 100% 晶格匹配的Ta3N5/Nb5N6接口使大量电荷分离效率接近100%

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c0060310.1021/acsenergylett.5c00603

Yitong Liu, Zeyu Fan, Ronghua Li, Andraž Mavrič, Iztok Arčon, Matjaz Valant, Gregor Kapun, Beibei Zhang, Chao Feng, Zemin Zhang, Tingxi Chen, Yanning Zhang and Yanbo Li*,

{"title":"Lattice-Matched Ta3N5/Nb5N6 Interface Enables a Bulk Charge Separation Efficiency of Close to 100%","authors":"Yitong Liu, Zeyu Fan, Ronghua Li, Andraž Mavrič, Iztok Arčon, Matjaz Valant, Gregor Kapun, Beibei Zhang, Chao Feng, Zemin Zhang, Tingxi Chen, Yanning Zhang and Yanbo Li*, ","doi":"10.1021/acsenergylett.5c0060310.1021/acsenergylett.5c00603","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00603https://doi.org/10.1021/acsenergylett.5c00603","url":null,"abstract":"The interface between the semiconductor light absorber and the metal electrode is critical for facilitating the extraction of photogenerated charges in photoelectrodes. Achieving a lattice-matched semiconductor/electrode interface with low defect density is highly desirable but remains a challenge for Ta3N5 photoanodes. In this study, we synthesized niobium nitride thin film electrodes with controllable crystallographic phases to achieve a lattice-matched Ta3N5/Nb5N6 back contact. This results in an enhanced crystallinity of the Ta3N5 film and reduced interfacial defect density. Consequently, the photoanode with the lattice-matched back contact attains a record half-cell solar-to-hydrogen conversion efficiency of 4.1%, attributed to the bulk carrier separation efficiency of nearly 100%. This work highlights lattice-matching as an effective strategy to enhance the efficiency of thin film-based solar energy conversion devices.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 4","pages":"1911–1920 1911–1920"},"PeriodicalIF":19.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polyoxometalates (POMs) as Proton Conductors 多金属氧酸盐（pom）作为质子导体

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c00373

Apu Saha, Rupam Sahoo, Shyam Chand Pal, Sayaka Uchida, Madhab C. Das

引用次数: 0

Operando Optical Microscopy for Visualization of Dendrite Growth in an Argyrodite LPSCl–Polymer Composite Electrolyte 用光学显微镜观察银柱石lpscl -聚合物复合电解质中枝晶生长

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.5c0028110.1021/acsenergylett.5c00281

Xiuyu Jin, Di Huang, Qiusu Miao, Ziting Zhu, Wei Tong, Alvaro Videla and Gao Liu*,

{"title":"Operando Optical Microscopy for Visualization of Dendrite Growth in an Argyrodite LPSCl–Polymer Composite Electrolyte","authors":"Xiuyu Jin, Di Huang, Qiusu Miao, Ziting Zhu, Wei Tong, Alvaro Videla and Gao Liu*, ","doi":"10.1021/acsenergylett.5c0028110.1021/acsenergylett.5c00281","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00281https://doi.org/10.1021/acsenergylett.5c00281","url":null,"abstract":"Herein, we demonstrate the utility of optical microscopy as an accessible technique for the in situ visualization of dendrite growth within polymer–sulfide composite solid-state electrolytes. The composite electrolyte features in situ polymerization and cross-linking of the polymer between ceramic particles, which opens up extensive opportunities for accelerated materials discovery, given the vast array of acrylate/methacrylate monomers available. Specifically, the cross-linked polymer poly(triethylene glycol dimethacrylate) (poly(TEGDMA)) was observed to effectively fill pores and inhibit dendrite growth at the lithium metal interface, attributed to its glassy state at room temperature. This work represents the first application of optical microscopy to illustrate that the incorporation of glassy, undoped polymers such as poly(TEGDMA) can serve as a viable strategy for dendrite suppression in solid-state composite electrolytes.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 4","pages":"1953–1957 1953–1957"},"PeriodicalIF":19.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsenergylett.5c00281","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Steric Hindrance Manipulation in Polymer Electrolytes toward Wide-Temperature Solid-State Lithium Metal Batteries 宽温固态锂金属电池中聚合物电解质的位阻操纵

IF 19.3 1区材料科学

ACS Energy Letters Pub Date : 2025-03-27 DOI: 10.1021/acsenergylett.4c0360210.1021/acsenergylett.4c03602

Jie Huang, Bin Qiu, Feng Xu, Jinyu Gao, Peixin Zhang, Chuanxin He and Hongwei Mi*,

{"title":"Steric Hindrance Manipulation in Polymer Electrolytes toward Wide-Temperature Solid-State Lithium Metal Batteries","authors":"Jie Huang, Bin Qiu, Feng Xu, Jinyu Gao, Peixin Zhang, Chuanxin He and Hongwei Mi*, ","doi":"10.1021/acsenergylett.4c0360210.1021/acsenergylett.4c03602","DOIUrl":"https://doi.org/10.1021/acsenergylett.4c03602https://doi.org/10.1021/acsenergylett.4c03602","url":null,"abstract":"Solid-state lithium metal batteries (LMBs) based on polymer electrolytes have become a hot topic for next-generation energy storage owing to their high specific energy, flexibility, and simple preparation process. However, poor electrolyte–electrode interface reactions and intrinsically slow Li+ transfer kinetics limit the development of solid-state LMBs. Here, a tris(4-fluorophenyl)phosphine (T4FPP) additive with strong steric hindrance and weak coordination is introduced to remodel the Li+ coordination environment to facilitate electrolyte bulk and interface charge transfer. Furthermore, theoretical analysis combined with in situ/ex situ characterizations demonstrate that the addition of T4FPP helps to construct an anion-dominated solvation structure through molecular crowding and form a LiF/Li2O-rich SEI layer. Ultimately, the LFP|Li full cell based on the T4FPP modified electrolyte works normally even at 10 C with a reversible specific capacity of 88.9 mAh g–1. Simultaneously, the electrochemical performance at 0–60 °C further verified the wide temperature range adaptability of the electrolyte.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"10 4","pages":"1921–1930 1921–1930"},"PeriodicalIF":19.3,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Integration of Microstructural Image Data into Machine Learning Models for Advancing High-Performance Perovskite Solar Cell Design 将微结构图像数据集成到机器学习模型中，以推进高性能钙钛矿太阳能电池设计

IF 22 1区材料科学

ACS Energy Letters Pub Date : 2025-03-26 DOI: 10.1021/acsenergylett.5c00626

Haotian Liu, Antai Yang, Chengquan Zhong, Xu Zhu, Hao Meng, Zhuo Feng, Jixin Tang, Chen Yang, Jingzi Zhang, Jiakai Liu, Kailong Hu, Xi Lin

{"title":"Integration of Microstructural Image Data into Machine Learning Models for Advancing High-Performance Perovskite Solar Cell Design","authors":"Haotian Liu, Antai Yang, Chengquan Zhong, Xu Zhu, Hao Meng, Zhuo Feng, Jixin Tang, Chen Yang, Jingzi Zhang, Jiakai Liu, Kailong Hu, Xi Lin","doi":"10.1021/acsenergylett.5c00626","DOIUrl":"https://doi.org/10.1021/acsenergylett.5c00626","url":null,"abstract":"Perovskite microstructure is one of the key factors limiting the effectiveness of current machine learning (ML) approaches for designing perovskite solar cells (PSCs) with high power conversion efficiency (PCE). This work develops a multimodal convolutional neural network to extract microstructural features from scanning electron microscopy (SEM) images of perovskite thin films. The model dynamically adjusts the weights of different modal information, including material composition, processing techniques, and microstructure, to enhance predictive accuracy. The model achieves an impressive coefficient of determination (R2) of 0.79 on the 1,583 SEM images data set. By introducing six SEM image features to describe the grain size of PSCs, we found that a grain boundary length density (GBLD) below 5.96 and an equivalent circular diameter (ECD) above 0.83 significantly enhance the PCE. Additional experiments confirmed the effectiveness of the results, and by improving these parameters to alter the crystallization, the PCE was increased to 24.61%, and the consistency of the results demonstrated the effectiveness and rationality of the multimodal model.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"59 1","pages":"1884-1891"},"PeriodicalIF":22.0,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143713429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0