Journal of Non-crystalline Solids最新文献

{"title":"Shaping the future of high-temperature sensing: A review of silicon-based precursor-derived ceramic technology","authors":"Weiting Xu ,&nbsp;Yan Gao ,&nbsp;Xingang Luan","doi":"10.1016/j.jnoncrysol.2025.123572","DOIUrl":"10.1016/j.jnoncrysol.2025.123572","url":null,"abstract":"<div><div>This paper reviews the high-temperature properties of polymer-derived ceramics (PDCs) and their applications in high-temperature sensors. PDCs have demonstrated immense potential in aerospace and energy industries due to their exceptional high-temperature chemical stability and mechanical properties, including oxidation resistance, corrosion resistance, and creep resistance, as well as their outstanding electrical properties, such as high-temperature semiconductor and piezoresistive characteristics. This review provides an in-depth discussion of the applications of PDCs in high-temperature pressure sensors, strain gauges, temperature sensors, and heat flux sensors. It also explores methods to optimize the fabrication process of PDCs using additive manufacturing techniques and Ultrafast High-temperature Sintering (UHS). Additionally, the potential value of PDCs in high-temperature sensors is highlighted, along with the challenges and future directions for technological advancement. Some specific recommendations are provided to guide future research.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"663 ","pages":"Article 123572"},"PeriodicalIF":3.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143895113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular interactions in GO/C-S-H composites: Influence of calcium ions and functional groups","authors":"Shenyan Shang ,&nbsp;Junfei Zhang ,&nbsp;Luyao Duan ,&nbsp;Lei Zhang","doi":"10.1016/j.jnoncrysol.2025.123569","DOIUrl":"10.1016/j.jnoncrysol.2025.123569","url":null,"abstract":"<div><div>Despite advances in nanomaterial reinforcement, the molecular mechanisms by which graphene oxide (GO) enhances the toughness of calcium silicate hydrate (C-S-H) gel remain unclear, particularly in relation to the role of functional groups and calcium ions. This study investigates the mechanical and structural properties of GO enhanced C-S-H composites using molecular dynamics simulations under tensile and pull-out conditions. The results highlight the crucial roles of free calcium ions (Ca²⁺) and oxidized functional groups in determining interfacial interactions and material performance. Hydroxyl groups significantly enhance tensile strength and Young's modulus, while carboxyl groups improve shear resistance through mechanical interlocking. The study also shows that increasing GO nanosheet proportion of interface area strengthens the composite by enhancing interfacial bonding energy. Furthermore, the migration of a small number of Ca²⁺ ions toward GO nanosheets helps mitigate performance degradation caused by silicate chain damage. These insights contribute to optimizing GO/C-S-H composites for improved mechanical properties, with implications for advanced construction materials.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"662 ","pages":"Article 123569"},"PeriodicalIF":3.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fluoroalkane modified silica aerogels with excellent strength and self-cleaning property","authors":"Youmei Gao ,&nbsp;Chang Ru ,&nbsp;Shengnan Liu ,&nbsp;Xiaoyan Yuan ,&nbsp;Lixia Ren","doi":"10.1016/j.jnoncrysol.2025.123574","DOIUrl":"10.1016/j.jnoncrysol.2025.123574","url":null,"abstract":"<div><div>Silica aerogel, regarded as one of the lightest solid materials with porous structures, shows properties such as low thermal conductivity, high porosity, and extensive surface area, making it highly suitable for application in pipeline thermal insulation, aerospace engineering, oil-water separation, and various other fields. However, due to the neck effect in the pearl-like network formed by the direct and random interconnection between silica nanoparticles, the mechanical property is poor. Although the mechanical property is enhanced by modifying silica aerogels with inorganic and organic compounds, the thermal insulation is usually sacrificed with enhancing of mechanical property. In this study, low surface energy fluoroalkane modified silica aerogels (SAF) are prepared to enhance the compressive mechanical and superhydrophobic properties. In order to balance the mechanical property and the thermal insulation property, SAF with different contents of fluoroalkanes are studied in detail. The compressive strength of SAF with 10 % molar ratio of fluoroalkanes is greatly enhanced while the thermal conductivity keeps the same as unmodified silica aerogel to balance the mechanical and thermal insulation properties. Study on the structure and property of SAF aerogels shows that the mechanical property is enhanced at proper molar content of fluoroalkanes, which probably thickens the necks between silica particles and lower the crosslinking density. The SAF aerogels shows excellent insulation against thermal and cold conditions. Furthermore, the surfaces of SAF aerogels are superhydrophobic by introducing low surface energy fluoroalkanes, and show self-cleaning property, facilitating the application of silica aerogels.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"662 ","pages":"Article 123574"},"PeriodicalIF":3.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143891885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation on diffusion characteristics and performance of wide-spectrum chalcogenide GRIN with high refractive index","authors":"Song Shi ,&nbsp;Kelun Xia ,&nbsp;Guang Jia ,&nbsp;Miaomiao Wu ,&nbsp;Jierong Gu ,&nbsp;Yuqing Duan ,&nbsp;Heqi Ren ,&nbsp;Chenjie Gu ,&nbsp;Zijun Liu ,&nbsp;Xiang Shen","doi":"10.1016/j.jnoncrysol.2025.123551","DOIUrl":"10.1016/j.jnoncrysol.2025.123551","url":null,"abstract":"<div><div>Gradient refractive index materials (GRINs) provide greater design freedom for aberration correction in wide-spectrum optical systems. In this paper, the GRINs with high refractive index and wide spectrum were successfully prepared by thermal diffusion of double-layer As₅₀Se_50-xTe_x chalcogenide glasses (ChGs). The GRINs have a refractive index spanning from 2.8 to 3.0 and a maximum refractive index difference (<em>Δn</em>) is 0.224. The spectral range with no significant attenuation of transmittance covers 1.5 to 18 µm. The diffusion characteristics of the GRINs were analyzed with a maximum diffusion depth of 400 μm. The values of the collision frequency factor and activation energy at different diffusion temperatures were obtained by utilizing Arrhenius law. The effect of temperature on the diffusion process was dominant over concentration. The axial refractive index distribution of GRINs is computed by converting the relationship between Te concentration and refractive index of the matrix glass. Furthermore, the dispersion characteristics of the GRINs were calculated. The Abbe number is negative, which is quite different from the dispersion characteristics presented by conventional infrared materials.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"661 ","pages":"Article 123551"},"PeriodicalIF":3.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of doping different concentrations of TiO2 nanoparticles to PMMA on its structural, thermal and optical properties for optical applications","authors":"Najlaa D. Alharbi ,&nbsp;Manal T.H. Moselhy ,&nbsp;Osiris W. Guirguis","doi":"10.1016/j.jnoncrysol.2025.123558","DOIUrl":"10.1016/j.jnoncrysol.2025.123558","url":null,"abstract":"<div><div>The aim of the present work is to analyze the macrostructure, thermal and optical properties of nanocomposite films prepared from poly(methyl methacrylate) doped with titanium dioxide using solution casting process for optoelectronic applications. The films were examined using Fourier transform infrared (FTIR) spectroscopy, which showed that the addition of TiO_2<img>NPs completely disperses into the PMMA matrix and causes significant changes in the width, intensity and positions of PMMA vibration peaks. Differential thermal analysis (DTA) and thermogravimetric analysis (TGA/DTGA) were used to study the thermal stability of the synthesized nanocomposite films. The melting point, area and shape of the thermal peaks in the DTA results varied, indicating different levels of crystallinity. According to TGA analysis, the nanocomposites decomposed in three stages and were thermally stable. The optical transmittance, absorption and reflectance spectra of the films were measured in the visible region. As the concentration of TiO_2<img>NPs increased to 8 wt %, the results showed that the transmittance decreases and the absorption increases, reaching the maximum opacity (≈27 %). The linear optical parameters showed that the absorption coefficient, extinction coefficient, refractive index, dielectric constants, and optical conductivity increased with the increase of TiO_2<img>NPs incorporated into PMMA matrix. The Urbach energy values ​​increased from 0.220 to 0.247 eV (≈12 %), while a slight decrease in the direct band gap values ​​from 2.910 to 2.899 eV and the indirect band gap from 2.615 to 2.568 eV was found after the incorporation of TiO_2<img>NPs, indicating the presence of a structural defect in the PMMA matrix. Using the Wemple-DiDomenico model, the linear dispersion parameters, linear optical susceptibility and nonlinear optical properties such as third nonlinear optical susceptibility and nonlinear refractive index were calculated and found to be functions of the TiO_2<img>NPs concentration. The results indicate that the prepared nanocomposite films can be considered as a promising candidate for use in optoelectronic applications.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"661 ","pages":"Article 123558"},"PeriodicalIF":3.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Fe88Pr10Al2 metallic glass with excellent magnetocaloric effect near the ice point","authors":"Z.B. Li ,&nbsp;J.M. Yuan ,&nbsp;T.G. Zhai ,&nbsp;Q. Wang ,&nbsp;D. Ding ,&nbsp;L. Xia","doi":"10.1016/j.jnoncrysol.2025.123576","DOIUrl":"10.1016/j.jnoncrysol.2025.123576","url":null,"abstract":"<div><div>A ternary Fe₈₈Pr₁₀Al₂ alloy was successfully vitrified into amorphous ribbons in the present work. The ternary alloy shows improved glass formability by Al substitution for B. The large magnetic entropy change peak (−Δ<em>S_m^peak</em>, ∼ 4.69 J/(kg × <em>K</em>) near 272 K) and refrigeration capacity (&gt; 656.6 J/kg) under 5 T were observed in the amorphous Fe₈₈Pr₁₀Al₂ sample. The high −Δ<em>S_m^peak</em> near the ice point of the Fe₈₈Pr₁₀Al₂ amorphous alloy makes it possible to achieve higher −Δ<em>S_m^peak</em> from 272 K to 300 K in the micro-alloyed Fe₈₈Pr₁₀Al₂ metallic glasses, which is essential for constructing high-performance working materials in the domestic refrigerators.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"662 ","pages":"Article 123576"},"PeriodicalIF":3.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A molecular dynamics investigation into the ballistic impact resistance of CrFeCoNi crystalline-amorphous high-entropy nanocomposites","authors":"Weidong Song,&nbsp;Guoxin Zhao,&nbsp;Lijun Xiao","doi":"10.1016/j.jnoncrysol.2025.123575","DOIUrl":"10.1016/j.jnoncrysol.2025.123575","url":null,"abstract":"<div><div>Crystalline-amorphous (C-A) high-entropy nanocomposites with core-shell nanostructures have been demonstrated excellent mechanical properties at high strain rates due to their cooperative strengthening mechanism, which has great potential in the field of anti-ballistic impact. Nevertheless, limited research has been performed on the ballistic impact performance of C-A high-entropy nanocomposites, and their underlying ballistic impact resistance mechanism remains unclear. Herein, molecular dynamics (MD) simulations were conducted to investigate the dynamic response of CrFeCoNi C-A high-entropy nanocomposites subjected to ballistic impact. The effect of amorphous thickness on the deformation mechanisms of these nanocomposites was considered. The results revealed that an optimal amorphous thickness which could trigger a cooperative strengthening mechanism between dislocations and shear transformation zones (STZs) and minimize the penetration depth existed in the nanocomposites under various impact velocities. This work could provide valuable guidance for the optimization of C-A high-entropy nanocomposites with superior penetration resistance.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"662 ","pages":"Article 123575"},"PeriodicalIF":3.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Strength, thermally stable, and highly transparent glass shields for boron neutron capture therapy facilities","authors":"Dalal Abdullah Aloraini ,&nbsp;W.A. Abu‑Raia ,&nbsp;Aly Saeed","doi":"10.1016/j.jnoncrysol.2025.123555","DOIUrl":"10.1016/j.jnoncrysol.2025.123555","url":null,"abstract":"<div><div>Nuclear facilities, such as BNCT rooms, require shielding materials that can simultaneously attenuate neutrons and gamma rays. Accordingly, this study advances the development of dual-function gamma ray and thermal neutron glass shields reinforced with barium and boron, providing a practical solution for such nuclear environments. A glass composition of (30+x)B₂O₃-(50-3x)Na₂O-10ZnO-10K₂O-2xBaO was fabricated with varying B₂O₃ and BaO concentrations (<span><math><mrow><mi>x</mi><mo>=</mo><mn>0</mn><mo>,</mo><mspace></mspace><mn>5</mn><mo>,</mo><mspace></mspace><mn>10</mn><mo>,</mo></mrow></math></span> and 15 mol %, PZSBBa0, PZSBBa1, PZSBBa2, and PZSBBa3). The addition of B₂O₃ and BaO enhanced glass’s density, network connectivity, thermal stability, mechanical strength, and transparency. The half value layer of PZSBBa3 glass was minimized to 2.305, 2.665, 3.683, and 3.943 cm for gamma ray energies of 478, 661.64, 1173.23, and 1332.5 keV, respectively. Furthermore, adding 45 mol % of B₂O₃ (PZSBBa3) improved thermal neutron attenuation by 96.6 %. These findings position the fabricated PZSBBa3 glass as a promising radiation shield in nuclear facilities, particularly in BNCT, marking a significant progression in shielding material development.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"661 ","pages":"Article 123555"},"PeriodicalIF":3.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143878621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crystallization of YxZr1-xO2–0.5x nanocrystals induced structural and ion-exchange properties changes in lithium aluminosilicate glasses","authors":"Hao Li,&nbsp;Yunlan Guo,&nbsp;Jong Heo,&nbsp;Chao Liu","doi":"10.1016/j.jnoncrysol.2025.123570","DOIUrl":"10.1016/j.jnoncrysol.2025.123570","url":null,"abstract":"<div><div>Aluminosilicate glasses are well-suited for applications in the field of mobile phone screens due to their excellent optical and mechanical properties. The mechanical strength of glasses can be further improved by the crystallization and ion-exchange process. In this work, high transparent glass-ceramics with the precipitation of Y_xZr_1-xO_2–0.5x nanocrystals are prepared in the system of Li₂O-MgO-Al₂O₃-SiO₂. The introduction of MgO is beneficial for increasing the elastic modulus, which is a key factor in improving the mechanical strength of glass. Precipitation of Y_xZr_1-xO_2–0.5x crystalline phase has large effect on the structure and the subsequent ion-exchange properties of glass. With the precipitation of Y_xZr_1-xO_2–0.5x nanocrystals, there is a decrease in the content of Zr-O-Si band and a corresponding increase in the content of Q³ units. Structural changes in glass with the precipitation of Y_xZr_1-xO_2–0.5x nanocrystals leads to the increase of ion-exchange depth of layer. The Vickers hardness of glass-ceramics increases obviously after ion-exchange.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"661 ","pages":"Article 123570"},"PeriodicalIF":3.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143878623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tuning mechanics of metallic glasses via in silico microalloying","authors":"Heng Kang ,&nbsp;Nannan Ren ,&nbsp;Yunjiang Wang ,&nbsp;Pengfei Guan","doi":"10.1016/j.jnoncrysol.2025.123571","DOIUrl":"10.1016/j.jnoncrysol.2025.123571","url":null,"abstract":"<div><div>Ductilizing amorphous metals without sacrificing strength is challenging due to unclear plasticity carriers. This study attempts to mimic the microalloying strategy of physical metallurgy in computer simulations by selectively pinning a small fraction of typical atoms in metallic glass, which is targeted to efficiently optimize the mechanical properties. We found that pinning atoms with high participation in the low-frequency vibrational modes are more effective in strengthening, attributing to a mechanism of scale-dependent pinning effect. By pinning only 2 % atoms in the unstable glassy samples, one can achieve shear modulus comparable to samples prepared with cooling rates that are eight orders of magnitude slower, highlighting the validity of microalloying over thermal treatment. Moreover, this microalloying approach not only control elastic properties, but also mitigates the failure mode of metallic glass. It demonstrates that restricting the motion of atoms in regions external to the shear band plays a critical role in inhibiting the propagation of the shear band.</div></div>","PeriodicalId":16461,"journal":{"name":"Journal of Non-crystalline Solids","volume":"661 ","pages":"Article 123571"},"PeriodicalIF":3.2,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143874174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}