Journal of Metallurgy最新文献

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Columnar-to-Equiaxed Transition in Metal-Matrix Composites Reinforced with Silicon Carbide Particles 碳化硅增强金属基复合材料的柱状向等轴转变
Journal of Metallurgy Pub Date : 2013-12-30 DOI: 10.1155/2013/628495
A. Ares, C. Schvezov
{"title":"Columnar-to-Equiaxed Transition in Metal-Matrix Composites Reinforced with Silicon Carbide Particles","authors":"A. Ares, C. Schvezov","doi":"10.1155/2013/628495","DOIUrl":"https://doi.org/10.1155/2013/628495","url":null,"abstract":"The present work is focused on the study of the effect of directional heat extraction on the silicon-carbide (SiC) distribution in zinc-aluminum matrix composites (MMCs) and on the columnar-to-equiaxed (CET) position in directionally solidified samples. To this end, a ZA-27 alloy matrix was reinforced with ceramic particles of SiC and vertically directionally solidified. The cooling rates, temperature gradients, and interphase velocities were then measured, and their influence on the solidification microstructure of the MMCs was analyzed. The recalescence detected and measured during the equiaxed transition was of the order of 3.5°C to 1.1°C. The values of the temperature gradients reached a minimum during the CET and were even negative in most cases (between −3.89 K and 0.06 K). The interphase velocities varied between 0.07 mm/s and 0.44 mm/s at the transition. Also, the presence of ceramic particles in ZA-27 alloys affected the thermodynamic local conditions and the kinetics of nucleation, producing a finer microstructure.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"10 1","pages":"1-12"},"PeriodicalIF":0.0,"publicationDate":"2013-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86036866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Factorial Analysis of Welding Current Influence on Heat Affected Zone Hardness of Cast Iron, Aluminium, and Mild Steel Weldments Cooled in Palm Oil 焊接电流对棕榈油冷却铸铁、铝和低碳钢焊接件热影响区硬度影响的析因分析
Journal of Metallurgy Pub Date : 2013-11-20 DOI: 10.1155/2013/245312
C. Nwoye, J. Odō, E. Ameh, S. Nwakpa
{"title":"Factorial Analysis of Welding Current Influence on Heat Affected Zone Hardness of Cast Iron, Aluminium, and Mild Steel Weldments Cooled in Palm Oil","authors":"C. Nwoye, J. Odō, E. Ameh, S. Nwakpa","doi":"10.1155/2013/245312","DOIUrl":"https://doi.org/10.1155/2013/245312","url":null,"abstract":"Factorial analysis of heat affected zone hardness of some metals was evaluated. Three models were derived and used as tools for evaluating the welding current influence on the predictability of HAZ hardness in aluminium, cast iron, and mild steel weldments similarly cooled in palm oil. It was discovered that on welding these materials, and similarly cooling their respective weldments in palm oil, the model predicts aluminium weldment HAZ hardness by multiplying the determined general current product rule (GCPR) with the ratio: HAZ hardness product of cast iron and mild steel/HAZ hardness sum of cast iron and mild steel . Computational analysis of experimental and model-predicted results indicates that aluminium, cast iron, and mild steel weldment HAZ hardness per unit welding current as evaluated from experiment and derived model are 3.3917, 4.8333, and 2.7944 and 3.3915, 4.8335, and 2.7946 (VHN) A−1, respectively. Deviational analysis shows that the maximum deviation of model-predicted HAZ hardness from the experimental results is less than 0.007%. This invariably implies over 99.99 % confidence level for the derived models.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"41 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2013-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91255611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Preparation of Niobium Metal Powder by Two-Stage Magnesium Vapor Reduction of Niobium Pentoxide 五氧化二铌两段镁气还原法制备金属铌粉
Journal of Metallurgy Pub Date : 2013-08-19 DOI: 10.1155/2013/629341
T. Kumar, S. R. Kumar, M. L. Rao, T. Prakash
{"title":"Preparation of Niobium Metal Powder by Two-Stage Magnesium Vapor Reduction of Niobium Pentoxide","authors":"T. Kumar, S. R. Kumar, M. L. Rao, T. Prakash","doi":"10.1155/2013/629341","DOIUrl":"https://doi.org/10.1155/2013/629341","url":null,"abstract":"Magnesium vapor reduction of niobium pentoxide was studied using a laboratory system. Niobium powder was prepared by the magnesium vapor reduction at 1123 K for 5 hours and it contained about 8 mass % oxygen. However, the oxygen concentration could be decreased to 0.65% when it was prepared by double-step reduction by magnesium vapor and a chemical treatment. Controlled and diluted supply of magnesium vapor to the reaction front has averted excess heat generation at the reaction front and thereby fine particles were produced. Effects of various factors on the vapor reduction process were studied and discussed.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"52 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86761723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution 取代噻二唑对N80钢在HCl溶液中腐蚀活性的缓蚀作用
Journal of Metallurgy Pub Date : 2013-04-18 DOI: 10.1155/2013/256403
M. Yadav, Sumit Kumar, D. Behera
{"title":"Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution","authors":"M. Yadav, Sumit Kumar, D. Behera","doi":"10.1155/2013/256403","DOIUrl":"https://doi.org/10.1155/2013/256403","url":null,"abstract":"The inhibition effect of some prepared compounds, namely, thiadiazole derivatives, on N80 steel corrosion in 15% HCl solutions has been studied by using the weight loss, electrochemical polarization, and electrochemical impedance spectroscopy techniques. It was found that the inhibition efficiency of the thiadiazole derivatives, namely, 2-amino-5-(4-methoxyphenyl)-1,3,4-thiazole (AMPT), 2-amino-5-phenyl-1,3,4-thiazole (APT), and 2-amino-5-(4-chlorophenyl)-1,3,4-thiazole (ACPT), increases with the increase in concentration. Inhibition efficiency follows the order AMPT > APT > ACPT. The effect of temperature on the corrosion was investigated by the weight loss method, and some thermodynamic parameters were calculated. The inhibitive action may be attributed to the adsorption of inhibitor molecules on the active sites of the metal surface following Langmuir adsorption isotherm. Polarization measurements indicated that thiadiazole derivatives act as mixed-type corrosion inhibitor. The adsorption of thiadiazole derivatives on N80 surface exposed to inhibitor-containing solutions was confirmed using SEM and FT-IR spectra.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"16 1","pages":"1-14"},"PeriodicalIF":0.0,"publicationDate":"2013-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79227026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Mathematical Models for the Novel Cathode Convexes in a Reduction Cell 还原电池中新型阴极凸的数学模型
Journal of Metallurgy Pub Date : 2013-03-31 DOI: 10.1155/2013/196891
Z. He, T. Xia, W. Xiong, Q. Shen, B. Li
{"title":"Mathematical Models for the Novel Cathode Convexes in a Reduction Cell","authors":"Z. He, T. Xia, W. Xiong, Q. Shen, B. Li","doi":"10.1155/2013/196891","DOIUrl":"https://doi.org/10.1155/2013/196891","url":null,"abstract":"A less magnitude of liquid aluminum deformation is required to shorten the anode-cathode distance so as to lower the electric energy consumption of the aluminum reduction cell. A mathematical model aimed to describe the electrolyte/aluminum two-phase flow in reduction cells, based on the computational fluid dynamics method, was developed to study the impacts of the cathode convexes on the electrolyte/aluminum interface deformation. The results showed that the magnitude of the two-phase interface deformation was reduced for about 17.2% with the novel cathode convexes; while at the same time, the washout of the melt on the ledge was also enhanced.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"26 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2013-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91029562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
XRD and DTA Analysis of Developed Agglomerated Fluxes for Submerged Arc Welding 埋弧焊烧结焊剂的XRD和DTA分析
Journal of Metallurgy Pub Date : 2013-03-11 DOI: 10.1155/2013/827491
Ajay Kumar, H. Singh, S. Maheshwari
{"title":"XRD and DTA Analysis of Developed Agglomerated Fluxes for Submerged Arc Welding","authors":"Ajay Kumar, H. Singh, S. Maheshwari","doi":"10.1155/2013/827491","DOIUrl":"https://doi.org/10.1155/2013/827491","url":null,"abstract":"A unique study of structural and chemical analysis of crystalline phases in developed agglomerated fluxes was carried out. Thirty-two fluxes were developed by using a mixture of oxides, halides, carbonates, silicates, and ferroalloys for submerged arc welding. The present paper focuses on only ten (out of thirty-two) fluxes which were analyzed by X-ray diffraction (XRD) to know the different types of oxides formed and changed in oxidation number of metallic centers after sintering process at around 850∘C. To know the effect of temperature over phase transformation and melting of different compounds, differential thermal analysis (DTA) was carried out from 1000 to 1400∘C. This study aims to know the quantity of ions present (percentage) and melting behavior of developed agglomerated fluxes for submerged arc welding process.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"1 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2013-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86519544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Fabrication of Single-Phase NiTi by Combustion Synthesis of Mechanically Activated Powders 燃烧合成机械活化粉末制备单相NiTi
Journal of Metallurgy Pub Date : 2012-12-30 DOI: 10.1155/2012/153841
S. M. Nasab, M. Aboutalebi, S. H. Seyedein, A. M. Kakhki, J. V. Khaki
{"title":"Fabrication of Single-Phase NiTi by Combustion Synthesis of Mechanically Activated Powders","authors":"S. M. Nasab, M. Aboutalebi, S. H. Seyedein, A. M. Kakhki, J. V. Khaki","doi":"10.1155/2012/153841","DOIUrl":"https://doi.org/10.1155/2012/153841","url":null,"abstract":"Single-phase NiTi was fabricated through the thermal explosion mode of combustion synthesis of mechanically activated powders. Combustion and ignition temperatures of combustion synthesis were investigated in different milling times. In this process, equiatomic powder mixtures of nickel and titanium were activated by planetary ball mill and pressed into disk-shaped pellets then heated in a tube furnace, while temperature-time profile was recorded. X-ray diffraction analysis (XRD) was performed on milled powders as well as synthesized samples. Scanning electron microscopy (SEM) was also used to study the microstructural evolution during milling. The results showed that there was a threshold milling time to obtain single-phase NiTi. It was also seen that the ignition temperature and combustion temperature were reduced significantly by increasing milling time.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"14 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2012-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75663733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of Diacetyl Monoxime Thiosemicarbazone on the Corrosion of Aged 18 Ni 250 Grade Maraging Steel in Sulphuric Acid Solution 二乙酰单胺硫代氨基脲对时效18ni250级马氏体时效钢在硫酸溶液中的腐蚀影响
Journal of Metallurgy Pub Date : 2012-12-17 DOI: 10.1155/2012/723687
T. Poornima, J. Nayak, A. Shetty
{"title":"Effect of Diacetyl Monoxime Thiosemicarbazone on the Corrosion of Aged 18 Ni 250 Grade Maraging Steel in Sulphuric Acid Solution","authors":"T. Poornima, J. Nayak, A. Shetty","doi":"10.1155/2012/723687","DOIUrl":"https://doi.org/10.1155/2012/723687","url":null,"abstract":"The corrosion inhibition of the aged 18 Ni 250 grade maraging steel in 0.5 M sulphuric acid by diacetyl monoxime thiosemicarbazone (DAMTSC) at 303–323 K has been investigated by potentiodynamic polarization, EIS, and SEM techniques. Good inhibition efficiency of DAMTSC was revealed even at low concentrations, which increased with the increase in DAMTSC concentration and decreased with the increase in temperature. The activation energies, , as well as other thermodynamic parameters (; ; ), were evaluated and discussed. The adsorption of DAMTSC on the aged maraging steel surface was found to obey the Langmuir adsorption isotherm model and shows mixed type inhibition behavior.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"65 1","pages":"1-13"},"PeriodicalIF":0.0,"publicationDate":"2012-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87607932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Mechanical Response of Al-1.09Mg2Si Alloy under Varying Mould and Thermal Ageing Conditions Al-1.09Mg2Si合金在不同模具和热时效条件下的力学响应
Journal of Metallurgy Pub Date : 2012-12-11 DOI: 10.1155/2012/921235
O. Sekunowo, G. Lawal, S. Adeosun
{"title":"Mechanical Response of Al-1.09Mg2Si Alloy under Varying Mould and Thermal Ageing Conditions","authors":"O. Sekunowo, G. Lawal, S. Adeosun","doi":"10.1155/2012/921235","DOIUrl":"https://doi.org/10.1155/2012/921235","url":null,"abstract":"Samples of the 6063 (Al-1.09Mg2Si) alloy ingot were melted in a crucible furnace and cast in metal and sand moulds, respectively. Standard tensile, hardness, and microstructural test specimens were prepared from cast samples, solution treated at 520∘C, soaked for 6 hrs, and immediately quenched at ambient temperature in a trough containing water to assume a supersaturated structure. The quenched specimens were then thermally aged at 175∘C for 3–7 hrs. Results show that at different ageing time, varied fractions of precipitates and intermetallics evolved in the specimens’ matrices which affect the resulting mechanical properties. The metal mould specimens aged for four hours (MTA-4) exhibited superior ultimate tensile strength of 247.8 MPa; microhardness, 68.5 HV; elongation, 28.2% . It is concluded that the extent of improvement in mechanical properties depends on the fractions, coherence, and distribution of precipitates along with the type of intermetallics developed in the alloy during ageing process.","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"46 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2012-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82909186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Precipitation of Phase Using General Diffusion Equation with Comparison to Vitek Diffusion Model in Dissimilar Stainless Steels 用一般扩散方程分析相的析出,并与Vitek扩散模型比较
Journal of Metallurgy Pub Date : 2012-11-22 DOI: 10.1155/2012/154617
Chih-Chun Hsieh, Weite Wu
{"title":"Precipitation of Phase Using General Diffusion Equation with Comparison to Vitek Diffusion Model in Dissimilar Stainless Steels","authors":"Chih-Chun Hsieh, Weite Wu","doi":"10.1155/2012/154617","DOIUrl":"https://doi.org/10.1155/2012/154617","url":null,"abstract":"This study performs a precipitation examination of the phase using the general diffusion equation with comparison to the Vitek model in dissimilar stainless steels during multipass welding. Experimental results demonstrate that the diffusivities (, , and ) of Cr, Ni, and Si are higher in -ferrite than (, , and ) in the phase, and that they facilitate the precipitation of the σ phase in the third pass fusion zone. The Vitek diffusion equation can be modified as follows: .","PeriodicalId":16342,"journal":{"name":"Journal of Metallurgy","volume":"246 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2012-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86696395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
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