{"title":"Identification of working conditions and prediction of FeO content in sintering process of iron ore fines","authors":"Xiao-ming Li, Bao-rong Wang, Zhi-heng Yu, Xiang-dong Xing","doi":"10.1007/s42243-024-01220-7","DOIUrl":"https://doi.org/10.1007/s42243-024-01220-7","url":null,"abstract":"<p>The iron oxide (FeO) content had a significant impact on both the metallurgical properties of sintered ores and the economic indicators of the sintering process. Precisely predicting FeO content possessed substantial potential for enhancing the quality of sintered ore and optimizing the sintering process. A multi-model integrated prediction framework for FeO content during the iron ore sintering process was presented. By applying the affinity propagation clustering algorithm, different working conditions were efficiently classified and the support vector machine algorithm was utilized to identify these conditions. Comparison of several models under different working conditions was carried out. The regression prediction model characterized by high precision and robust stability was selected. The model was integrated into the comprehensive multi-model framework. The precision, reliability and credibility of the model were validated through actual production data, yielding an impressive accuracy of 94.57% and a minimal absolute error of 0.13 in FeO content prediction. The real-time prediction of FeO content provided excellent guidance for on-site sinter production.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of TiO2 addition on microstructures and properties of MgO–CaO refractory aggregates","authors":"Shuai Zhang, Jing-ran Wang, Yuan-gao Li, Feng-you Li, Wen Yan, Hui-ying Shi","doi":"10.1007/s42243-024-01247-w","DOIUrl":"https://doi.org/10.1007/s42243-024-01247-w","url":null,"abstract":"<p>MgO–CaO (40 wt.% CaO) refractory aggregates were prepared using the calcined dolomite and light-burned magnesia fine powder as raw materials and TiO<sub>2</sub> as additive. The effect of TiO<sub>2</sub> on their phase composition, microstructures and properties was investigated by X-ray diffraction and scanning electron microscopy. The properties such as bulk density, apparent porosity, relative aggregate tube strength and hydration resistance were also investigated. The results showed that the CaTiO<sub>3</sub> generated by the reaction between CaO and TiO<sub>2</sub> was distributed around the CaO grain boundaries and intermittently distributed with MgO, which formed an isolation layer around CaO and greatly improved the hydration resistance. Meanwhile, the introduction of TiO<sub>2</sub> promoted sintering and increased the grain size, further improving the strengths and hydration resistance of the materials. In addition, the most significant enhancement in the hydration resistance and strengths of the samples was achieved when 1.0–2.0 wt.% TiO<sub>2</sub> was added. In this case, the relative strength of aggregate increased from 33.3% to 37.3%–43.1%, and the mass gain after the hydration test decreased from 3.13% to 1.26%–1.45%.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Fan, Tian-peng Qu, De-yong Wang, Cheng-jun Liu
{"title":"Quantitative characterization of reaction behavior between La-bearing FeCrAl melt and CaO–Al2O3–La2O3-based slags and its guidance for design of mold flux","authors":"Lei Fan, Tian-peng Qu, De-yong Wang, Cheng-jun Liu","doi":"10.1007/s42243-024-01233-2","DOIUrl":"https://doi.org/10.1007/s42243-024-01233-2","url":null,"abstract":"<p>The reaction behavior between CaO–Al<sub>2</sub>O<sub>3</sub>–La<sub>2</sub>O<sub>3</sub>-based slags and La-bearing FeCrAl melt was quantitatively characterized, which was further compared with the reaction behavior of CaO–SiO<sub>2</sub>-based slags. Based on this, the new type of mold flux for La-bearing FeCrAl alloy continuous casting was designed and its basic properties were evaluated. The results showed that the order of reaction degree of fluxing agents in CaO–Al<sub>2</sub>O<sub>3</sub>–La<sub>2</sub>O<sub>3</sub>-based slags is (Na<sub>2</sub>O) > (B<sub>2</sub>O<sub>3</sub>) > (Li<sub>2</sub>O), and the percentages of mass change of fluxing agents were 85.8, 54.29 and 42.35 wt.%, respectively. Moreover, the addition of (Li<sub>2</sub>O) and (Na<sub>2</sub>O) promoted the reaction between (CaO) and [Al], and the reaction degree of the former was weaker than that of the latter, which was due to the greater effect of (Na<sub>2</sub>O) on the activity of (CaO) and (Al<sub>2</sub>O<sub>3</sub>) than (Li<sub>2</sub>O). Compared with the reactivity of CaO–SiO<sub>2</sub>-based slags, the percentages of mass change of Al and La caused by slag–steel reaction decreased by 10.63–14.36 and 39.78–50.49 wt.%, respectively. The percentages of mass change of (Al<sub>2</sub>O<sub>3</sub>), (La<sub>2</sub>O<sub>3</sub>) and (CaO) in slags highest increased by 17.71, 17.98, and 7.81 wt.%, respectively. The reactivity of CaO–Al<sub>2</sub>O<sub>3</sub>–La<sub>2</sub>O<sub>3</sub>-based slags was significantly weakened. Ultimately, the new type of mold flux was designed and the composition range was determined. The fundamental properties of new mold flux basically meet the theoretical requirements for La-bearing FeCrAl alloy continuous casting.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of TiO2 and BaO on viscosity and potassium removal capacity of blast furnace slag","authors":"Jian-tao Ju, Xin-yi Li, Liu-le Wei, Xiang-dong Xing","doi":"10.1007/s42243-024-01222-5","DOIUrl":"https://doi.org/10.1007/s42243-024-01222-5","url":null,"abstract":"<p>In order to increase the utilization rate of vanadium–titanium magnetite in blast furnace smelting, the viscosity and potassium removal capacity of CaO–SiO<sub>2</sub>–Al<sub>2</sub>O<sub>3</sub>–MgO–BaO–TiO<sub>2</sub> slag (CaO/SiO<sub>2</sub> = 1.05, 1–5 wt.% BaO, 2–20 wt.% TiO<sub>2</sub>) were studied for slag optimization using the cylinder method and slag–metal equilibrium technique, respectively. Also, the structural properties of the slag were characterized by Fourier transform infrared spectroscopy. The concept of “a ring structure of Ti–O–Si” was proposed to express the change in the viscosity of the blast furnace slag. The results showed that the viscosity of slag increased with the increase in BaO content while the potassium removal capacity decreased. Furthermore, an increase in TiO<sub>2</sub> content from 2 to 20 wt.% resulted in a decrease in viscosity and an increase in potassium removal capacity. The Fourier transform infrared spectroscopy results showed that the charge compensation of Ba<sup>2+</sup> can form complex aluminosilicate structure and increase the viscosity of slag. Meanwhile, with the increase in TiO<sub>2</sub> content, Ti<sup>4+</sup> ions replace Si<sup>4+</sup> in the silicon-oxygen tetrahedral structure, thereby reducing the degree of polymerization of the silicate network and decreasing the viscosity.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ya-ru Wang, Zi-yong Hou, He Yang, Jun Zhao, Zhi-yuan Chang, Fan-mao Meng, Ling Zhang, Gui-lin Wu, Xiao-xu Huang
{"title":"Effect of initial microstructure on microstructure evolution and mechanical properties of 0.12C martensitic steels during quenching and tempering","authors":"Ya-ru Wang, Zi-yong Hou, He Yang, Jun Zhao, Zhi-yuan Chang, Fan-mao Meng, Ling Zhang, Gui-lin Wu, Xiao-xu Huang","doi":"10.1007/s42243-024-01226-1","DOIUrl":"https://doi.org/10.1007/s42243-024-01226-1","url":null,"abstract":"<p>The microstructure evolution and mechanical properties of a Fe–0.12C–0.2Si–1.6Mn–0.3Cr–0.0025B (wt.%) steel with different initial microstructures, i.e., hot rolled (HR) and cold rolled–annealed (CRA), were studied through optical microscopy, scanning electron microscopy, electron channeling contrast imaging, microhardness and room temperature uniaxial tensile tests. After water quenching from 930 °C to room temperature, a fully martensitic microstructure was obtained in both as-quenched HR and CRA specimens, which shows a microhardness of 480 ± 5 HV, and no significant difference in microstructure and microhardness was observed. Tensile test results show that the product of tensile strength and total elongation (UTS × TE) of the as-quenched HR specimen, i.e., 24.1 GPa%, is higher than that of the as-quenched CRA specimen, i.e., 18.9 GPa%. While, after being tempered at 300 °C, the martensitic microstructures and mechanical properties of the two as-quenched specimens change significantly due to the synergy role of the matrix phase softening and the precipitation strengthening. Concerning the maximum UTS × TE, it is 18.9 GPa% obtained in the as-quenched CRA one, while that is 24.4 GPa% obtained in the HR specimen after tempered at 300 °C for 5 min.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of distance between heat sources on droplet transfer behavior and weld formation of AH36 during laser and CWW GMAW arc hybrid welding","authors":"Yun-tao Chen, Zhi-dong Yang, Zheng-xuan Ni, Jiang-min Xu, Shan-wen Dong, Guo-xiang Xu, Shu-jin Chen","doi":"10.1007/s42243-024-01224-3","DOIUrl":"https://doi.org/10.1007/s42243-024-01224-3","url":null,"abstract":"","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141272151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of silica on crystallization process of calcium ferrite: thermodynamic and kinetic analysis","authors":"Xu-chao Wang, Cheng-yi Ding, Xue-wei Lv, Hong-ming Long, Yu-xi Wu, Feng Jiang, Ren-de Chang, Sheng Xue, Qing-lin Chen","doi":"10.1007/s42243-024-01242-1","DOIUrl":"https://doi.org/10.1007/s42243-024-01242-1","url":null,"abstract":"<p>SiO<sub>2</sub> is the main component of gangue in sinters and a crucial constituent in the formation of the SiO<sub>2</sub>–Fe<sub>2</sub>O<sub>3</sub>–CaO (SFC) system. The non-isothermal crystallization kinetics of the SFC system were investigated using differential scanning calorimetry. The crystallization process of SFC was studied under different cooling rates (5, 10, 15, and 20 K/min), and the crystalline phases and microstructures of the SFC crystals were verified through X-ray diffraction and scanning electron microscopy. The results indicate that when the SiO<sub>2</sub> content is 2 wt.%, increasing the cooling rate promotes the precipitation of CaFe<sub>2</sub>O<sub>4</sub> (CF) in the SFC system, thereby inhibiting the precipitation of Ca<sub>2</sub>Fe<sub>2</sub>O<sub>5</sub> (C<sub>2</sub>F). In contrast to the CaO–Fe<sub>2</sub>O<sub>3</sub> (C–F) system, the addition of SiO<sub>2</sub> does not alter the precipitation mechanisms of C<sub>2</sub>F and CF. By further adding SiO<sub>2</sub>, the precipitation of Ca<sub>2</sub>SiO<sub>4</sub> (C<sub>2</sub>S) significantly increases. Simultaneously, the CaO content in the liquid phase decreases. This leads to the crystallization process of the CF<sub>4</sub>S (4 wt.% SiO<sub>2</sub>) system bypassing the precipitation of C<sub>2</sub>F and directly forming CF and CaFe<sub>4</sub>O<sub>7</sub> (CF<sub>2</sub>). In the case of the CF<sub>8</sub>S (8 wt.% SiO<sub>2</sub>) system, the crystallization process skips the precipitation of C<sub>2</sub>F and CF, directly yielding CF<sub>2</sub>. The crystallization process of both CF<sub>2</sub>S (2 wt.% SiO<sub>2</sub>) and CF is similar, comprising two reaction stages. The Ozawa method was used to calculate the activation energy for the crystallization of C<sub>2</sub>F and CF as − 329 and − 419 kJ/mol, respectively. Analysis using the Malek method reveals model functions for both stages.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141196968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of cooling method on TiN precipitation behavior of high-titanium high-strength steel during solidification","authors":"Xue-jian Zhang, Guang-wei Yang, Yong Wan, Yong-hong Wen, Chuan-sheng Tang, Ming-qi Liu, Li-jie Tian","doi":"10.1007/s42243-024-01184-8","DOIUrl":"https://doi.org/10.1007/s42243-024-01184-8","url":null,"abstract":"<p>Metallographic microscopy, scanning electron microscopy and TiN growth thermodynamic and kinetic equations were used to investigate the morphology, quantity, and size of TiN in the center of high-titanium high-strength steels under different solidification cooling rates. The results showed that TiN in the center of the experimental steels mainly existed in three forms: single, composite (Al<sub>2</sub>O<sub>3</sub>–TiN), and multi-particle aggregation. TiN began precipitating at around 1497 °C (solidification fraction of 0.74). From the end of melting to solidification for 180 s, the cooling rates in the center of the experimental steels for furnace cooling, air cooling, refractory mold cooling, and cast iron mold cooling tended to stabilize at 0.17, 0.93, 1.65, and 2.15 °C/s, respectively. The size of TiN in the center of the experimental steel cooled using furnace cooling was mainly concentrated in the 5–15 µm range. In contrast, the size of TiN in the center of the experimental steels cooled using air cooling, refractory mold cooling, and cast iron mold cooling were mainly concentrated in the 1–5 µm range. In addition, their density of TiN in the center of the experimental steels is significantly higher than that of the furnace-cooled experimental steel. Thermodynamic and kinetic precipitation models of TiN established predicted the growth size of TiN in a high-titanium high-strength steel when the solidification cooling rates are not below 0.93 °C/s.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fang Liu, Yi-chi Zhang, Wang Zeng, Jun Ni, Yun-peng Si, Heng Zhou, Tian-xiang Zhang, Sheng-li Wu, Ming-yin Kou
{"title":"Iron recovery and dephosphorization behaviors from high-phosphorus oolitic hematite by gas-based direct reduction and magnetic separation","authors":"Fang Liu, Yi-chi Zhang, Wang Zeng, Jun Ni, Yun-peng Si, Heng Zhou, Tian-xiang Zhang, Sheng-li Wu, Ming-yin Kou","doi":"10.1007/s42243-024-01249-8","DOIUrl":"https://doi.org/10.1007/s42243-024-01249-8","url":null,"abstract":"<p>With the depletion of high-quality iron ore resources, high-phosphorus oolitic hematite (HPOH) has attracted great attention due to its large reserve and relatively high iron content. However, HPOH is very difficult to be used in ironmaking process due to its special structure. A two-step method of gas-based direct reduction and magnetic separation was thus proposed to recover iron and reduce phosphorus. The results showed that the powdery reduced iron produced contained 92.31% iron and 0.1% phosphorus, and the iron recovery was 92.65% under optimum reduction condition, which is suitable for following steelmaking. The apatite will be reduced under long reduction time and a large reducing gas flow rate, resulting in more phosphorus found in the metallic iron. Increasing the hydrogen–carbon ratio will inhibit the formation and growth of iron particles and prevent the breakage of oolitic structure. Careful adjustment of reduction temperature is recommended as it affects the oolitic structure and reduction.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhao Zhang, Cheng Zhou, Fang-zhou Jin, Yong-feng Cai, Yi-fan Ni, Cheng-hao Fan, Dan Song
{"title":"High-temperature corrosion resistance of Fe–Cr–Mo amorphous coating for water wall protection of USC boiler","authors":"Zhao Zhang, Cheng Zhou, Fang-zhou Jin, Yong-feng Cai, Yi-fan Ni, Cheng-hao Fan, Dan Song","doi":"10.1007/s42243-024-01237-y","DOIUrl":"https://doi.org/10.1007/s42243-024-01237-y","url":null,"abstract":"<p>A novel Fe–Cr–Mo amorphous coating, a high-temperature corrosion-resistant material for water wall protection of power plant ultra-supercritical boilers, has been prepared via arc spraying. A systematic study was conducted to evaluate the high-temperature corrosion behavior of this coating, and its resistance to corrosion at high temperatures was scientifically assessed. The results indicate that the thickness of Fe–Cr–Mo amorphous coating is approximately 350 μm, exhibiting typical amorphous characteristics as confirmed by X-ray diffraction and transmission electron microscope characterization. During each stage of the 750 °C corrosion test, the oxygen content of the amorphous coating was significantly lower than that of the contrast coating (PS45 alloy coating), indicating a superior corrosion protection effect at high temperature. After 100 h of continuous testing, the corrosion mass gain of the amorphous coating was only 28.62% that of PS45 coating and 3.89% that of T12 steel substrate, indicating significantly depressed high-temperature corrosion kinetics. The excellent high-temperature corrosion resistance of Fe–Cr–Mo amorphous coating is primarily attributed to the stable Fe/Cr oxide film generated by the metastable state of the amorphous state, which serves as an excellent barrier. Furthermore, under the influence of heat in a high-temperature environment, the amorphous structure gradually transforms into a nanocrystalline structure. In contrast, the oxide film of the amorphous/nanocrystalline coating has low thermal stress, leading to better adhesion with the coating and resistance to cracking and peeling, thus providing excellent sustained protection.</p>","PeriodicalId":16151,"journal":{"name":"Journal of Iron and Steel Research International","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141197328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}