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Degradation Mechanism of Rubbers :Part II 橡胶的降解机理:第二部分
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.92.263
S. Otomo
{"title":"Degradation Mechanism of Rubbers :Part II","authors":"S. Otomo","doi":"10.2324/gomu.92.263","DOIUrl":"https://doi.org/10.2324/gomu.92.263","url":null,"abstract":"2. 1 各種ゴムの劣化機構 各種ゴムの劣化機構の説明に際し,一部のゴムについて は酸化劣化に伴うモジュラスと硬さの変化の平均値と標準 偏差値が記載された表を本文中に示している.これらの表 に記載されたデータは,NOC技術ノートに紹介された老化 防止剤が添加されていない加硫物の耐熱酸化性の評価結果 である.モジュラスと硬さは加硫密度と比例関係にあるこ とから,主鎖切断反応やゲル化反応からなるゴムの劣化挙 動の特徴を表すものと考えられ,前報と同様に劣化機構 考察の一助とした. 2. 1. 1 高飽和ニトリルゴム(HNBR)の劣化機構 HNBRは,NBRのC=Cを選択的に水素添加して製造さ れる.その際,1,2-ブタジエンユニットが優先的に水素添 加されるため,HNBRは図1に示すように,一部水素添加 されなかった1,4-構造を加硫点として有するミクロ化学構 造を有し,またニトリル基による耐油性も維持されてい る.さらにHNBRの耐酸化性と耐オゾン劣化性は,C=C Degradation Mechanism of Rubbers :Part II","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"48 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"120903772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Technology of Rubber Molding (Part3) 橡胶成型工艺(三)
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.94.372
Koichi Yamaguchi
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引用次数: 0
「超先端材料超高速開発基盤技術プロジェクト」特集号の専門用語の解説 “超尖端材料超高速开发基础技术项目”专刊术语解读
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.95.30
裕史 森田
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引用次数: 0
The Current State of Waste Plastic and Waste Rubber Tasks for the Sustainable Society 可持续发展社会中废塑料和废橡胶的现状和任务
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.93.129
T. Kamo
{"title":"The Current State of Waste Plastic and Waste Rubber Tasks for the Sustainable Society","authors":"T. Kamo","doi":"10.2324/gomu.93.129","DOIUrl":"https://doi.org/10.2324/gomu.93.129","url":null,"abstract":"19世紀に発明されたプラスチックは軽くて丈夫で安価 で,鮮やかな色や多様なデザインに対応できるため20世紀 後半の石油化学の勃興に伴って大量生産された.特にプラ スチック容器の発明により食品を常温で長期間保存するこ とが可能となり,食料の流通を一変させわれわれのライフ スタイルに大きな影響を与えた.一方,安価な雑貨やファ ストフードの包装に大量に使用されたため,プラスチック は20世紀の大量生産・大量消費を代表するシンボルとなっ た. 野外や海洋に投棄されたプラスチックはこれまでごみ処 理や景観の問題と考えられてきたが,2017 年に Ellen MacArthur財団が海洋中に蓄積されるプラスチックの総 量が2050年には魚類よりも多くなると発表した.また5 mm以下の小さなプラスチックの小片(マイクロプラス チック)が生態系へ深刻な影響を与え,食物連鎖による生 物濃縮によって人の健康へも脅威になる可能性が指摘され, マイクロプラスチックは世界の最重要な環境問題の1つと","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125718842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
「ImPACT しなやかなタフポリマー」特集号の専門用語の解説 “ImPACT柔软的坚韧聚合物”专号的专业术语的解说
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.92.318
恵造 芥川
{"title":"「ImPACT しなやかなタフポリマー」特集号の専門用語の解説","authors":"恵造 芥川","doi":"10.2324/gomu.92.318","DOIUrl":"https://doi.org/10.2324/gomu.92.318","url":null,"abstract":"","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123799195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance Technologies of Biodegradable Plastics to Solve the Ocean Contamination by Plastics 生物降解塑料高性能技术解决海洋塑料污染
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.93.141
M. Mochizuki
{"title":"High-performance Technologies of Biodegradable Plastics to Solve the Ocean Contamination by Plastics","authors":"M. Mochizuki","doi":"10.2324/gomu.93.141","DOIUrl":"https://doi.org/10.2324/gomu.93.141","url":null,"abstract":"","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"171 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124374993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
アクリルゴムの加硫について（16）［金属石鹸/硫黄架橋系のスコーチ防止］ 丙烯酸橡胶的硫化(16)[金属肥皂/硫磺交联系的防滑轮]
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.95.annc2_83
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引用次数: 0
バルノックPMについて（29）［EPDM用架橋助剤（15）］ 关于巴诺克PM (29) [EPDM架桥助剂(15)]
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.94.annc11_423
{"title":"バルノックPMについて（29）［EPDM用架橋助剤（15）］","authors":"","doi":"10.2324/gomu.94.annc11_423","DOIUrl":"https://doi.org/10.2324/gomu.94.annc11_423","url":null,"abstract":"","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127744374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-resolution Measurement of the Mechanocaloric Properties of Natural Rubber 天然橡胶机械热性能的高分辨率测量
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.95.212
T. Matsuo, Hal Suzuki, D. Takajo
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引用次数: 1
アクリルゴムの加硫について（14） 丙烯酸橡胶的硫化(14)
NIPPON GOMU KYOKAISHI Pub Date : 1900-01-01 DOI: 10.2324/gomu.92.annc8_347
{"title":"アクリルゴムの加硫について（14）","authors":"","doi":"10.2324/gomu.92.annc8_347","DOIUrl":"https://doi.org/10.2324/gomu.92.annc8_347","url":null,"abstract":"","PeriodicalId":158600,"journal":{"name":"NIPPON GOMU KYOKAISHI","volume":"306 5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132650080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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