Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green
{"title":"Effect of 4-Position Pyridine Ring Substitution on Zn(II) Complexes of 4-substituted Py<sub>2</sub>N<sub>2</sub> Pyridinophane Macrocycles.","authors":"Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green","doi":"10.1080/00958972.2025.2453062","DOIUrl":"10.1080/00958972.2025.2453062","url":null,"abstract":"<p><p>The metal binding properties of macrocyclic small molecules is a key property that drives what applications for which these ligands can be used. Pyridine modified Py<sub>2</sub>N<sub>2</sub> pyridinophane small molecules are a new class of macrocyclic small molecules, whose properties have not been explored. As a result, Zn(II) metal binding of a library of six pyridine modified Py<sub>2</sub>N<sub>2</sub> complexes are reported here. These results include <sup>1</sup>H NMR, log β<sub>Zn(II)</sub>, and X-ray diffraction, which are compared to PyN<sub>3</sub> congeners to show that the differences in each scaffold yield markedly different metal binding properties that can be exploited in future applications.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"225-232"},"PeriodicalIF":1.6,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12492988/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145232785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Spyros Perontsis, Vladimiros Chrysoulidis, Antonios G. Hatzidimitriou, George Psomas
{"title":"A hexanuclear cerium(IV) complex with the non–steroidal anti–inflammatory drug mefenamic acid","authors":"Spyros Perontsis, Vladimiros Chrysoulidis, Antonios G. Hatzidimitriou, George Psomas","doi":"10.1080/00958972.2024.2445210","DOIUrl":"https://doi.org/10.1080/00958972.2024.2445210","url":null,"abstract":"A hexanuclear cerium(IV) complex with a non–steroidal anti–inflammatory drug mefenamic acid (Hmef) as a ligand has been synthesized and characterized by diverse techniques. The molecular structure of the complex was determined by single–crystal X–ray crystallography revealing the formula [Ce<sub>6</sub>(O)<sub>4</sub>(OH)<sub>4</sub>(mef)<sub>12</sub>(DMF)<sub>2</sub>]. The antioxidant activity of the complex was evaluated for its ability to scavenge free radicals. The interaction of the complex with calf–thymus DNA was studied by diverse techniques showing its potency to intercalate to DNA. The interaction of the complex for human and bovine serum albumins was studied by fluorescence emission spectroscopy and revealed its tight and reversible binding to the albumins.","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"1 1","pages":"1-16"},"PeriodicalIF":0.0,"publicationDate":"2024-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147882409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Construction and characterization of Fe3O4@SiO2-Dop/Amide-BTA-pd(0) nanocomposite as a novel and efficient nanomagnetic recoverable catalyst for synthesis of 5-substituted 1h-tetrazoles in water","authors":"Yajing Zhang","doi":"10.1080/00958972.2024.2404071","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404071","url":null,"abstract":"The development of efficient, and environmentally friendly catalytic systems for synthesis of 5-substituted 1H-tetrazoles is an important challenge in organic synthesis because tetrazole derivative...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"34 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on advanced counter electrode materials for high-efficiency dye sensitized solar cells","authors":"Kirandeep Kaur Dhillon, Meenakshi Patyal, Shikha Bhogal, Nidhi Gupta","doi":"10.1080/00958972.2024.2404070","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404070","url":null,"abstract":"Dye-sensitized solar cells offer a promising alternative to conventional photovoltaics due to their low production costs and high power conversion efficiencies. A crucial component in DSSCs is the ...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"11 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira
{"title":"Copper(II) complexes of hindered diazines: methylquinoxalines","authors":"Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira","doi":"10.1080/00958972.2024.2400713","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400713","url":null,"abstract":"Five new copper(II) complexes of substituted quinoxaline ligands have been prepared and characterized via single crystal X-ray diffraction, including [Cu(5-Mequinox)2(NO3)2] (2), [Cu(5-Mequinox)(NO...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"3 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of phthalocyanine/C3N4 structures and investigation of photocatalytic activities in the oxidation reaction of 4-nitrophenol","authors":"Ece Tugba Saka, Ahmet Senocak, Cagla Akkol","doi":"10.1080/00958972.2024.2400573","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400573","url":null,"abstract":"Photocatalytic oxidation is an advanced oxidation technique widely preferred for the removal of pollutants in wastewater. In this work, paramagnetic metallo-phthalocyanines EB2 and EB3 (Co(II)phtha...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"37 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Design, structure and antivirus molecular docking of chloridobis(1,10-phenanthroline)-(thiocyanato)-copper(II)","authors":"Simranjeet Singh, Mukesh Choudhary","doi":"10.1080/00958972.2024.2398216","DOIUrl":"https://doi.org/10.1080/00958972.2024.2398216","url":null,"abstract":"The reaction of sodium thiocyanate with CuCl2·2H2O salt using 1,10-phenanthtroline as a co-ligand led to chloridobis(1,10-phenanthroline)-(thiocyanato) copper(II), [Cu(Phen)2(Cl)(NCS)] (1). The str...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"2 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta
{"title":"2-Propyl-1H-imidazole-4,5-dicarboxylate acid supported cu/ni/fe/co complexes: synthesis, biological and catalytic evaluation","authors":"Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta","doi":"10.1080/00958972.2024.2395894","DOIUrl":"https://doi.org/10.1080/00958972.2024.2395894","url":null,"abstract":"Herein, we report 2-propyl-1H-imidazole-4,5-dicarboxylate complexes of Cu/Co/Fe/Ni metal ions. The complexes have been characterized using powder X-ray diffraction, FTIR, and mass spectrometry. The...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"98 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kgaugelo C. Tapala, Garland K. More, Hadley S. Clayton
{"title":"Synthesis, crystal structure, Hirshfeld surface analysis, DFT studies and biological evaluation of bis(acetonitrile)bromido(η6-1-isopropyl-4-methylbenzene)osmium(II) hexafluoroantimonate","authors":"Kgaugelo C. Tapala, Garland K. More, Hadley S. Clayton","doi":"10.1080/00958972.2024.2396979","DOIUrl":"https://doi.org/10.1080/00958972.2024.2396979","url":null,"abstract":"The complex bis(acetonitrile)bromido(η6-1-isopropyl-4-methylbenzene)osmium(II) hexafluoroantimonate, [OsBr(C10H14)(CH3CN)2]SbF6 (1) crystallizes as a triclinic system in space group P1 (no. 2), con...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"48 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}