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Beyond BODIPY: dipyrrin complexes of P-block elements. Beyond BODIPY: p区元素的二吡啶配合物。
IF 2.1 4区 化学
Journal of Coordination Chemistry Pub Date : 2025-08-05 DOI: 10.1080/00958972.2025.2539945
Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon
{"title":"Beyond BODIPY: dipyrrin complexes of P-block elements.","authors":"Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon","doi":"10.1080/00958972.2025.2539945","DOIUrl":"10.1080/00958972.2025.2539945","url":null,"abstract":"<p><p>Dipyrrin has proven to be a versatile ligand platform for metals across the periodic table. Since much of the coordination chemistry has focused on transition metals, main-group dipyrrin chemistry has been underexplored, particularly in the case of heavy p-block elements. Boron dipyrrin complexes (also known as BODIPY) were initially reported in 1968, yet the first well-characterized example of a heavy p-block dipyrrin complex was in 2006. This nascent area of research has undergone a significant surge, where nearly half of the reports in this field have been published since 2019. Given this renewed interest and rapid development, we provide a focused review on heavy p-block dipyrrin complexes, describing the synthesis, structure, and spectroscopy of these molecules. One significant aspect of these complexes is their optical properties, which access red and near-infrared wavelengths with high quantum yields. While these main-group dipyrrins have been used as catalysts, they have also been leveraged for a variety of biological applications including photodynamic therapy, tumor imaging, and cytotoxic drugs. With the advent of synthetic methods for these novel p-block complexes, dipyrrins can begin to interface with recent advances and applications of main-group chemistry, potentially offering advantages over other ligand platforms.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":" ","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12396737/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144955852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I). 寻找天然存在的手性二烯{(R/S)-香芹酮}作为与铑(I)配位的双齿配体。
IF 2.2 4区 化学
Journal of Coordination Chemistry Pub Date : 2025-01-10 eCollection Date: 2025-01-01 DOI: 10.1080/00958972.2024.2448520
Zaskia Bezuidenhout, Andreas Roodt
{"title":"In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I).","authors":"Zaskia Bezuidenhout, Andreas Roodt","doi":"10.1080/00958972.2024.2448520","DOIUrl":"10.1080/00958972.2024.2448520","url":null,"abstract":"<p><p>Bis-rhodium-<i>mu</i>-chlorido dinuclear complexes with natural occurring limonene-type enantiomeric diene nucleophiles, (S)- and (R)-carvone [<b>S</b>Car and <b>R</b>Car], are presented and their single crystal structures reported. Utilizing the diolefinic bonds of the carvones, <i>mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IA/B</b>) and <i>mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIA/B</b>) were obtained in ca. 80% yields in clean reactions with reactant RhCl<sub>3</sub>(H<sub>2</sub>O)<sub>x</sub>. The \"structured\" chiral nanomaterials (<b>IA/B</b> and <b>IIA/<i>B</i> </b>><b> </b>1.1 nm) crystallize as two independent, dinuclear chiral molecules <i>Syn-mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IA</b>), <i>Anti-mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IB</b>), and <i>Syn-mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIA</b>, <i>Anti-mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIB</b>), respectively (based on the relative orientation of the carvone ring, oxo and methyl groups). Principal differences between the <b>IA/IIA</b> <i>vs</i> <b>IB/IIB</b> complexes in the solid state include the relative orientation of the two carvones, inducing a significant distortion in the <i>µ</i> <sup>2</sup>-Rh<sub>2</sub>Cl<sub>2</sub> core, with the dihedral angles of 49.7(1)°/49.73(6)° in <b>IA/IIA</b> (<i>Syn-mu</i> geometry), versus 23.8(1)°/24.00(6)° in <b>IB/IIB</b> (<i>Anti-mu</i> geometry), respectively. The presence of the two structurally independent complexes in the solid state is also inferred from <sup>1</sup>H NMR spectra.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"208-224"},"PeriodicalIF":2.2,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11854040/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143515779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of 4-Position Pyridine Ring Substitution on Zn(II) Complexes of 4-substituted Py2N2 Pyridinophane Macrocycles. 4位吡啶环取代对4取代Py2N2吡啶烷大环Zn（II）配合物的影响
IF 2.1 4区 化学
Journal of Coordination Chemistry Pub Date : 2025-01-01 Epub Date: 2025-02-03 DOI: 10.1080/00958972.2025.2453062
Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green
{"title":"Effect of 4-Position Pyridine Ring Substitution on Zn(II) Complexes of 4-substituted Py<sub>2</sub>N<sub>2</sub> Pyridinophane Macrocycles.","authors":"Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green","doi":"10.1080/00958972.2025.2453062","DOIUrl":"10.1080/00958972.2025.2453062","url":null,"abstract":"<p><p>The metal binding properties of macrocyclic small molecules is a key property that drives what applications for which these ligands can be used. Pyridine modified Py<sub>2</sub>N<sub>2</sub> pyridinophane small molecules are a new class of macrocyclic small molecules, whose properties have not been explored. As a result, Zn(II) metal binding of a library of six pyridine modified Py<sub>2</sub>N<sub>2</sub> complexes are reported here. These results include <sup>1</sup>H NMR, log β<sub>Zn(II)</sub>, and X-ray diffraction, which are compared to PyN<sub>3</sub> congeners to show that the differences in each scaffold yield markedly different metal binding properties that can be exploited in future applications.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"225-232"},"PeriodicalIF":2.1,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12492988/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145232785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction and characterization of Fe3O4@SiO2-Dop/Amide-BTA-pd(0) nanocomposite as a novel and efficient nanomagnetic recoverable catalyst for synthesis of 5-substituted 1h-tetrazoles in water Fe3O4@SiO2-Dop/Amide-BTA-pd(0)纳米复合材料作为新型高效纳米磁性可回收催化剂在水中合成 5-取代的 1h-tetrazoles 的构建与表征
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-09-17 DOI: 10.1080/00958972.2024.2404071
Yajing Zhang
{"title":"Construction and characterization of Fe3O4@SiO2-Dop/Amide-BTA-pd(0) nanocomposite as a novel and efficient nanomagnetic recoverable catalyst for synthesis of 5-substituted 1h-tetrazoles in water","authors":"Yajing Zhang","doi":"10.1080/00958972.2024.2404071","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404071","url":null,"abstract":"The development of efficient, and environmentally friendly catalytic systems for synthesis of 5-substituted 1H-tetrazoles is an important challenge in organic synthesis because tetrazole derivative...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"34 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on advanced counter electrode materials for high-efficiency dye sensitized solar cells 高效染料敏化太阳能电池用先进对电极材料综述
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-09-14 DOI: 10.1080/00958972.2024.2404070
Kirandeep Kaur Dhillon, Meenakshi Patyal, Shikha Bhogal, Nidhi Gupta
{"title":"A review on advanced counter electrode materials for high-efficiency dye sensitized solar cells","authors":"Kirandeep Kaur Dhillon, Meenakshi Patyal, Shikha Bhogal, Nidhi Gupta","doi":"10.1080/00958972.2024.2404070","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404070","url":null,"abstract":"Dye-sensitized solar cells offer a promising alternative to conventional photovoltaics due to their low production costs and high power conversion efficiencies. A crucial component in DSSCs is the ...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"11 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Copper(II) complexes of hindered diazines: methylquinoxalines 受阻重氮：甲基喹喔啉的铜(II)配合物
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-09-10 DOI: 10.1080/00958972.2024.2400713
Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira
{"title":"Copper(II) complexes of hindered diazines: methylquinoxalines","authors":"Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira","doi":"10.1080/00958972.2024.2400713","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400713","url":null,"abstract":"Five new copper(II) complexes of substituted quinoxaline ligands have been prepared and characterized via single crystal X-ray diffraction, including [Cu(5-Mequinox)2(NO3)2] (2), [Cu(5-Mequinox)(NO...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"3 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design, Synthesis, and biological evaluation of copper(II) complexes with phenanthroline-based ligands as potential anticancer agents 作为潜在抗癌剂的菲罗啉基配体铜（II）配合物的设计、合成和生物学评价
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-09-10 DOI: 10.1080/00958972.2024.2400169
Dongdong Li, Hui Wang, Cheng Tan, Linlin Dai, Shuang Zhi, Zibo Yang
{"title":"Design, Synthesis, and biological evaluation of copper(II) complexes with phenanthroline-based ligands as potential anticancer agents","authors":"Dongdong Li, Hui Wang, Cheng Tan, Linlin Dai, Shuang Zhi, Zibo Yang","doi":"10.1080/00958972.2024.2400169","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400169","url":null,"abstract":"We have synthesized and characterized five copper(II) complexes, [Cu(L1)(alanine)(NO3)]·2H2O (1), [Cu(L1)(methionine)(H2O)]NO3·4H2O (2), [Cu(L2)(glycine)] NO3·3H2O (3), [Cu(L2)(alanine)Cl]·2H2O (4)...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"22 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of phthalocyanine/C3N4 structures and investigation of photocatalytic activities in the oxidation reaction of 4-nitrophenol 酞菁/C3N4 结构的合成及其在 4-硝基苯酚氧化反应中的光催化活性研究
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-09-10 DOI: 10.1080/00958972.2024.2400573
Ece Tugba Saka, Ahmet Senocak, Cagla Akkol
{"title":"Synthesis of phthalocyanine/C3N4 structures and investigation of photocatalytic activities in the oxidation reaction of 4-nitrophenol","authors":"Ece Tugba Saka, Ahmet Senocak, Cagla Akkol","doi":"10.1080/00958972.2024.2400573","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400573","url":null,"abstract":"Photocatalytic oxidation is an advanced oxidation technique widely preferred for the removal of pollutants in wastewater. In this work, paramagnetic metallo-phthalocyanines EB2 and EB3 (Co(II)phtha...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"37 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design, structure and antivirus molecular docking of chloridobis(1,10-phenanthroline)-(thiocyanato)-copper(II) 氯双(1,10-菲罗啉)-(硫氰基)-铜(II)的设计、结构和抗病毒分子对接
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-08-31 DOI: 10.1080/00958972.2024.2398216
Simranjeet Singh, Mukesh Choudhary
{"title":"Design, structure and antivirus molecular docking of chloridobis(1,10-phenanthroline)-(thiocyanato)-copper(II)","authors":"Simranjeet Singh, Mukesh Choudhary","doi":"10.1080/00958972.2024.2398216","DOIUrl":"https://doi.org/10.1080/00958972.2024.2398216","url":null,"abstract":"The reaction of sodium thiocyanate with CuCl2·2H2O salt using 1,10-phenanthtroline as a co-ligand led to chloridobis(1,10-phenanthroline)-(thiocyanato) copper(II), [Cu(Phen)2(Cl)(NCS)] (1). The str...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"2 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2-Propyl-1H-imidazole-4,5-dicarboxylate acid supported cu/ni/fe/co complexes: synthesis, biological and catalytic evaluation 2-Propyl-1H-imidazole-4,5-dicarboxylate acid supported cu/ni/fe/co complexes: synthesis, biological and catalytic evaluation
IF 1.9 4区 化学
Journal of Coordination Chemistry Pub Date : 2024-08-28 DOI: 10.1080/00958972.2024.2395894
Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta
{"title":"2-Propyl-1H-imidazole-4,5-dicarboxylate acid supported cu/ni/fe/co complexes: synthesis, biological and catalytic evaluation","authors":"Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta","doi":"10.1080/00958972.2024.2395894","DOIUrl":"https://doi.org/10.1080/00958972.2024.2395894","url":null,"abstract":"Herein, we report 2-propyl-1H-imidazole-4,5-dicarboxylate complexes of Cu/Co/Fe/Ni metal ions. The complexes have been characterized using powder X-ray diffraction, FTIR, and mass spectrometry. The...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"98 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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