Journal of Coordination Chemistry最新文献

Cu(II) complexes based on benzotriazole: structure-function relationship, synthesis, crystal structure and antidiabetic activity 基于苯并三唑的Cu（II）配合物：构效关系、合成、晶体结构及抗糖尿病活性

4区化学

Journal of Coordination Chemistry Pub Date : 2025-12-17 DOI: 10.1080/00958972.2025.2606841

Xia Wang, XINLING WANG, Mengmeng Cao, Tanpeng Zhou, Huaixia Yang

引用次数: 0

Highly selective ethylene oligomerization to high-carbon α-olefins over PNP chromium complex modified nano-SiO ₂ PNP铬配合物修饰纳米二氧化硅的高选择性乙烯低聚生成高碳α-烯烃

4区化学

Journal of Coordination Chemistry Pub Date : 2025-11-20 DOI: 10.1080/00958972.2025.2586681

Jinzhe Wang, Hongliang Huo, Lili Ma, Xue Zhai, Feng Li, Zhiqiu Zhang, Cuiqin Li

引用次数: 0

NHC–Pt(II) photosensitizers promote nuclear translocation and synergize with ROS bursts to trigger apoptosis NHC-Pt （II）光敏剂促进核易位并与ROS爆发协同触发细胞凋亡

4区化学

Journal of Coordination Chemistry Pub Date : 2025-11-12 DOI: 10.1080/00958972.2025.2584462

Jiaqi Geng, Zhongtang Yu, You‐Liang Zeng, Yupeng Zheng, Zong‐Wan Mao

引用次数: 0

Synthesis, structure and properties of lanthanoid(III) complexes based on N-heterocyclic dicarboxylic acid ligand 基于n -杂环二羧酸配体的类镧配合物的合成、结构与性能

4区化学

Journal of Coordination Chemistry Pub Date : 2025-09-02 DOI: 10.1080/00958972.2025.2475010

Xiaoling Luo, Zheng Liu, Xiaoqi Lan, Pintian Zou, Xiangfei Kong, Guo‐Cheng Han

引用次数: 0

Beyond BODIPY: dipyrrin complexes of P-block elements. Beyond BODIPY: p区元素的二吡啶配合物。

IF 2.1 4区化学

Journal of Coordination Chemistry Pub Date : 2025-08-05 DOI: 10.1080/00958972.2025.2539945

Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon

{"title":"Beyond BODIPY: dipyrrin complexes of P-block elements.","authors":"Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon","doi":"10.1080/00958972.2025.2539945","DOIUrl":"10.1080/00958972.2025.2539945","url":null,"abstract":"Dipyrrin has proven to be a versatile ligand platform for metals across the periodic table. Since much of the coordination chemistry has focused on transition metals, main-group dipyrrin chemistry has been underexplored, particularly in the case of heavy p-block elements. Boron dipyrrin complexes (also known as BODIPY) were initially reported in 1968, yet the first well-characterized example of a heavy p-block dipyrrin complex was in 2006. This nascent area of research has undergone a significant surge, where nearly half of the reports in this field have been published since 2019. Given this renewed interest and rapid development, we provide a focused review on heavy p-block dipyrrin complexes, describing the synthesis, structure, and spectroscopy of these molecules. One significant aspect of these complexes is their optical properties, which access red and near-infrared wavelengths with high quantum yields. While these main-group dipyrrins have been used as catalysts, they have also been leveraged for a variety of biological applications including photodynamic therapy, tumor imaging, and cytotoxic drugs. With the advent of synthetic methods for these novel p-block complexes, dipyrrins can begin to interface with recent advances and applications of main-group chemistry, potentially offering advantages over other ligand platforms.","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":" ","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12396737/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144955852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A type of binary composite catalyst CuTNPc/ZnO for synergistic photocatalytic degradation of dyes 一种用于染料协同光催化降解的二元复合催化剂CuTNPc/ZnO

4区化学

Journal of Coordination Chemistry Pub Date : 2025-05-07 DOI: 10.1080/00958972.2025.2497838

Yanbing Yin, Chunxin Li, Zhou Wang, Yongming Feng, Bei Jiang, Yifei Li, Wei Yang

引用次数: 0

Synthesis, crystal structures, and anticancer studies of Ni(II), Co(III), and Zn(II) complexes derived from chlorinated-2-(2-aminophenyl)-1H-benzimidazole Schiff base 氯化-2-（2-氨基苯基）- 1h -苯并咪唑席夫碱衍生的Ni（II）、Co（III）和Zn（II）配合物的合成、晶体结构和抗癌研究

4区化学

Journal of Coordination Chemistry Pub Date : 2025-02-04 DOI: 10.1080/00958972.2025.2456700

Hou Cong Li, Ming Wang, Y. Zheng, Ning An, Min Hou, Jing Hu, Wen Ge Li

引用次数: 0

Synthesis, characterization, and crystal structures of 4-hydroxy- N’ -(2-hydroxy-5-methylbenzylidene)benzohydrazide and its copper(II) complexes with antibacterial activity 具有抗菌活性的4-羟基- N ' -（2-羟基-5-甲基苄基）苯并肼及其铜（II）配合物的合成、表征和晶体结构

4区化学

Journal of Coordination Chemistry Pub Date : 2025-01-31 DOI: 10.1080/00958972.2025.2456217

Ruojing Song, Yu‐Xi Sun

引用次数: 1

Catalytic synthesis of vitamin E acetate using metal organic framework material ZIF-8 金属有机骨架材料ZIF-8催化合成维生素E醋酸酯

4区化学

Journal of Coordination Chemistry Pub Date : 2025-01-31 DOI: 10.1080/00958972.2025.2458650

Mingzhe Li, Yuyang Zhou, Hua Zhou, Dingqiang Lu

引用次数: 0

In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I). 寻找天然存在的手性二烯{(R/S)-香芹酮}作为与铑(I)配位的双齿配体。

IF 2.2 4区化学

Journal of Coordination Chemistry Pub Date : 2025-01-10 eCollection Date: 2025-01-01 DOI: 10.1080/00958972.2024.2448520

Zaskia Bezuidenhout, Andreas Roodt

{"title":"In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I).","authors":"Zaskia Bezuidenhout, Andreas Roodt","doi":"10.1080/00958972.2024.2448520","DOIUrl":"10.1080/00958972.2024.2448520","url":null,"abstract":"Bis-rhodium-mu-chlorido dinuclear complexes with natural occurring limonene-type enantiomeric diene nucleophiles, (S)- and (R)-carvone [SCar and RCar], are presented and their single crystal structures reported. Utilizing the diolefinic bonds of the carvones, mu-[RhI(SCar)Cl]2 (IA/B) and mu-[RhI(RCar)Cl]2 (IIA/B) were obtained in ca. 80% yields in clean reactions with reactant RhCl3(H2O)x. The \"structured\" chiral nanomaterials (IA/B and IIA/B > 1.1 nm) crystallize as two independent, dinuclear chiral molecules Syn-mu-[RhI(SCar)Cl]2 (IA), Anti-mu-[RhI(SCar)Cl]2 (IB), and Syn-mu-[RhI(RCar)Cl]2 (IIA, Anti-mu-[RhI(RCar)Cl]2 (IIB), respectively (based on the relative orientation of the carvone ring, oxo and methyl groups). Principal differences between the IA/IIA vs IB/IIB complexes in the solid state include the relative orientation of the two carvones, inducing a significant distortion in the µ 2-Rh2Cl2 core, with the dihedral angles of 49.7(1)°/49.73(6)° in IA/IIA (Syn-mu geometry), versus 23.8(1)°/24.00(6)° in IB/IIB (Anti-mu geometry), respectively. The presence of the two structurally independent complexes in the solid state is also inferred from 1H NMR spectra.","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"208-224"},"PeriodicalIF":2.2,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11854040/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143515779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0