ChemSusChem最新文献_第7页

Bombyx Mori Silk Fibroin as a Sustainable Organocatalyst for Diastereoselective Michael Additions. 家蚕丝素蛋白作为非对映选择性Michael添加物的可持续有机催化剂。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-27 DOI: 10.1002/cssc.202500584

Carola Ricciardelli, Giorgio Rizzo, Pietro Cotugno, Antonio Salomone, Daniela Trisciuzzi, Orazio Nicolotti, Erica Colaprico, Cosimo D Altomare, Gianluca M Farinola

引用次数: 0

Recyclable Ligand-free Cobalt Catalyst for Alkoxycarbonylation of Chloroacetates. 氯乙酸烷氧羰基化可回收无配体钴催化剂。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-27 DOI: 10.1002/cssc.202500949

Wenyu Wang, Zhusong Cao, Yuya Hu, Rui Sang, Qingshan Kong, Qicai Xue, Baoxin Zhang

{"title":"Recyclable Ligand-free Cobalt Catalyst for Alkoxycarbonylation of Chloroacetates.","authors":"Wenyu Wang, Zhusong Cao, Yuya Hu, Rui Sang, Qingshan Kong, Qicai Xue, Baoxin Zhang","doi":"10.1002/cssc.202500949","DOIUrl":"https://doi.org/10.1002/cssc.202500949","url":null,"abstract":"Direct carbonylation of the C(sp3)-Cl bond remains a challenging transformation in the chemical industry. The usual use of precious metals, the high cost of ligands and the lack of recyclability of catalysts make their industrial application on a large scale impossible. We report here a ligand-free cobalt-based catalyst for the alkoxycarbonylation of chloroacetates to dialkyl malonates, which are important industrial intermediates. This catalyst uses an extremely inexpensive precursor, CoCO3, with a very low catalyst loading (0.5 mol%) to achieve product yields of up to 99% with nearly 100% chemoselectivity. Solvents and previously essential phase transfer agents are not needed. Most importantly, the catalyst can be easily recycled without losing its activity and selectivity. Over 95% product yield was achieved even after 8 recycles. The feasibility of this system was demonstrated through 14 examples of the alkoxycarbonylation reaction. FTIR investigations identified the active cobalt species as [Co(CO)4]-. As the first recyclable cobalt-based catalyst, this ligand-free system has great potential for large-scale industrial transfer.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500949"},"PeriodicalIF":7.5,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144504291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Beyond Simple Grinding: Methylammonium Chloride Promotes Sustainable, Cylinder-Free Mechanochemical Synthesis of Deferiprone. 超越简单的研磨：甲基氯化铵促进可持续的，无圆柱体的机械化学合成去铁素。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-26 DOI: 10.1002/cssc.202500457

Francesco Basoccu, Sara Piermarini, Tommaso Angelini, Massimiliano Mari, Edoardo Mariani, Alessandro Falchi, Andrea Porcheddu

引用次数: 0

(ODA)₂CuBr₄ Perovskite Quantum Dots/C₃N₄ as Visible-Light-Driven Heterogeneous Photocatalyst for Chemoselective Aerobic Oxidation of Alcohols to Aldehydes. （ODA）2CuBr4钙钛矿量子点/C3N4作为可见光驱动的非均相光催化剂用于醇类化学选择性好氧氧化制醛。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-25 DOI: 10.1002/cssc.202500596

Jia-Qi Di, Shuai-Zheng Zhang, Dan-Dan Su, Ming-Ming Li, Zhan-Hui Zhang

{"title":"(ODA)2CuBr4 Perovskite Quantum Dots/C3N4 as Visible-Light-Driven Heterogeneous Photocatalyst for Chemoselective Aerobic Oxidation of Alcohols to Aldehydes.","authors":"Jia-Qi Di, Shuai-Zheng Zhang, Dan-Dan Su, Ming-Ming Li, Zhan-Hui Zhang","doi":"10.1002/cssc.202500596","DOIUrl":"10.1002/cssc.202500596","url":null,"abstract":"The direct oxidation of alcohols to aldehydes using molecular oxygen (O2) as the terminal oxidant under mild conditions is a highly desirable transformation in organic synthesis due to its atom economy and environmental sustainability. Herein, a nanostructured composite consisting of (ODA)2CuBr4 perovskite quantum dots and graphitic carbon nitride (C3N4) is fabricated and characterized to evaluate its catalytic performance. Under visible-light irradiation, the (ODA)2CuBr4/C3N4 hybrid demonstrates excellent chemoselectivity in converting various alcohols to the corresponding aldehydes with high to excellent yields. Notably, the reaction is performed at ambient temperature without the need for additional reagents or harsh conditions. The catalyst system efficiently utilizes O2 from air as the oxidant, offering a green and sustainable synthetic approach. Furthermore, the (ODA)2CuBr4/C3N4 catalyst exhibits remarkable stability and recyclability, maintaining its catalytic activity with negligible degradation after ten consecutive reaction cycles, highlighting its potential for practical applications.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2500596"},"PeriodicalIF":7.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144493270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fully Realizing the Bipolar Energy Storage Capability of Radical Polymer-Grafted Graphene Sheets for Zinc-Organic Battery Cathodes. 充分实现自由基聚合物接枝石墨烯片用于锌有机电池负极的双极储能能力。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-25 DOI: 10.1002/cssc.202500733

Weize Jin, Haoran Liu, Xia Wu, Patrick Théato, Xiaoyu Huang, Yongjun Li

{"title":"Fully Realizing the Bipolar Energy Storage Capability of Radical Polymer-Grafted Graphene Sheets for Zinc-Organic Battery Cathodes.","authors":"Weize Jin, Haoran Liu, Xia Wu, Patrick Théato, Xiaoyu Huang, Yongjun Li","doi":"10.1002/cssc.202500733","DOIUrl":"10.1002/cssc.202500733","url":null,"abstract":"Radical polymers, containing stable nitroxyl radical, 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), within their repeating units, are considered as bipolar cathode materials capable of undergoing both oxidation and reduction in the redox process. However, in most cases, TEMPOcontaining radical polymers are exclusively employed as p-type cathode materials, initially oxidized to a positively charged state, with only one electron being stored or released in the redox process of TEMPO units. Here, a kind of composite material, poly(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl methacrylate) (PTMA) grafted to reduced graphene oxide, rGO-g-PTMA, is applied as cathode material for zinc-organic battery. Its high specific capacity (>220 mAh g-1) and two well-resolved voltage plateaus confirmed the participation of TEMPO reduction in energy storage, as well as the bipolar energy storage capability of PTMA. Its electrochemical reaction mechanism and energy storage performance are also investigated in detail. This first full and distinct utilization of its p- and n-type redox reaction of PTMA opens a new avenue for nitroxyl radicals as high-performance cathode materials for zinc-organic batteries.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2500733"},"PeriodicalIF":7.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144482697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Crystallized Poly(Triazine Imide) Decorated with Dynamically Coordinated Pd^II Complex for Efficient Photocatalytic Overall Water Splitting. 动态配位PdII修饰的聚（三嗪亚胺）晶体光催化整体水分解研究。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-25 DOI: 10.1002/cssc.202500987

Jiapeng Xu, Dengyang Lu, Xinming Li, Renjie Li, Jing Zhang, Tianyou Peng

{"title":"Crystallized Poly(Triazine Imide) Decorated with Dynamically Coordinated PdII Complex for Efficient Photocatalytic Overall Water Splitting.","authors":"Jiapeng Xu, Dengyang Lu, Xinming Li, Renjie Li, Jing Zhang, Tianyou Peng","doi":"10.1002/cssc.202500987","DOIUrl":"10.1002/cssc.202500987","url":null,"abstract":"Exploring photocatalysts capable of overall water splitting without the need of sacrificial agents or external bias holds significant practical importance. Herein, crystallized poly(triazine imide) (cPTI) loaded with CoOx as oxygen evolution photocatalyst is decorated with (FFV)2PdCl2 complex (FFV = Fluoflavin) for constructing a novel Z-scheme heterojunction. The dynamic coordination between the PdII ion and FFV ligands in (FFV)2PdCl2 results in unsaturated PdII active sites as the excellent hydrogen evolution photocatalyst. The resultant (FFV)2PdCl2/cPTI-CoOx heterojunction delivers excellent overall water splitting activity with H2/O2 yields up to 201/101 μmol h-1 under the illumination of Xe-lamp and an apparent quantum yield of 19.8% at 365 nm. Mechanistic studies reveal that the Z-scheme charge transfer mechanism in (FFV)2PdCl2/cPTI-CoOx effectively promotes the photoinduced charge separation, while maintaining high redox capacity for overall water splitting. This work presents the first instance of integrating crystallized poly(triazine imide) with dynamically coordinated complex, paving a new way for manufacturing highly efficient overall water splitting system.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2500987"},"PeriodicalIF":7.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144482696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ultrathin 2D Ni/Co Hydroxide Heterostructures for High Energy Density Flexible Microsupercapacitor. 高能量密度柔性微型超级电容器的超薄二维Ni/Co氢氧化物异质结构。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-24 DOI: 10.1002/cssc.202500850

Sayali Ashok Patil, Pallavi Bhaktapralhad Jagdale, Narad Barman, Amanda Sfeir, Mansi Pathak, Sébastien Royer, Ranjit Thapa, Akshaya Kumar Samal, Manav Saxena

{"title":"Ultrathin 2D Ni/Co Hydroxide Heterostructures for High Energy Density Flexible Microsupercapacitor.","authors":"Sayali Ashok Patil, Pallavi Bhaktapralhad Jagdale, Narad Barman, Amanda Sfeir, Mansi Pathak, Sébastien Royer, Ranjit Thapa, Akshaya Kumar Samal, Manav Saxena","doi":"10.1002/cssc.202500850","DOIUrl":"10.1002/cssc.202500850","url":null,"abstract":"Assembling 2D ultrathin nanosheets into vertical heterostructures offers significant potential for advanced energy storage due to enhanced active sites, improved ion diffusion, and increased electrical conductivity, leading to superior ion/electron transport, higher energy density, and improved rate performance. In case of transition-metal hydroxides, to overcome with challenges such as random assembly, complex synthesis, instability, and poor interfacial contact is critical. This study synthesizes large area, ultrathin, 2D Nickel/Cobalt hydroxide vertical heterostructures (nickel as the top layer) using a wet chemical process, achieving 32% higher areal charge storage compared to cobalt/nickel hydroxide vertical heterostructures, 57% higher than Ni(OH)2 and 330% higher than individual Co(OH)2. The synergistic interaction between nickel and cobalt hydroxides contributes to a high volumetric capacity (710 mAh cm-3) and energy density (285 mAh cm-3) in symmetric devices. The flexible microsupercapacitor retains 75% capacitance after 15,000 cycles and demonstrates stability under bending up to 135°, with a volumetric capacity of 393 mAh cm-3. Density functional theory simulations complement experiments, revealing interaction energy and electronic state redistribution near the Fermi level. This integrated approach serves as a guide for enhancing electrochemical properties in 2D heterostructures, aiding in the development of next-generation, high-performance energy storage materials.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2500850"},"PeriodicalIF":7.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144473525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From Turpentine to (-)-Menthol: A New Approach. 从松节油到(-)-薄荷醇的新途径。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-24 DOI: 10.1002/cssc.202500515

Dominik Dylong, Johannes Panten, Bernhard Rußbüldt, Peter J C Hausoul, Regina Palkovits, Matthias Eisenacher

引用次数: 0

Advances in Lignin Chemistry, Bonding Performance, and Formaldehyde Emission Reduction in Lignin-Based Urea-Formaldehyde Adhesives: A Review. 木质素基脲醛胶粘剂的木质素化学、粘接性能及甲醛减排研究进展

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-23 DOI: 10.1002/cssc.202500491

Anass Ait Benhamou, Liza Abid, Ingrid Calvez, Alain Cloutier, Mojgan Nejad, Tatjana Stevanovic, Véronic Landry

{"title":"Advances in Lignin Chemistry, Bonding Performance, and Formaldehyde Emission Reduction in Lignin-Based Urea-Formaldehyde Adhesives: A Review.","authors":"Anass Ait Benhamou, Liza Abid, Ingrid Calvez, Alain Cloutier, Mojgan Nejad, Tatjana Stevanovic, Véronic Landry","doi":"10.1002/cssc.202500491","DOIUrl":"10.1002/cssc.202500491","url":null,"abstract":"Lignin, a complex biopolymer derived from plant biomass, has attracted significant attention in both academic research and industry due to its potential to revolutionize formaldehyde-based adhesives by reducing their emissions, a critical concern in the wood industry. In the realm of wood adhesives, the integration of lignin has seen significant progress in recent years, where it is utilized either as a partial replacement for traditional synthetic resins or as a modifier to enhance adhesive properties. This has led to notable improvements in both environmental impact and adhesive performance, contributing to developing more sustainable and ecofriendly wood composite materials. This review provides an in-depth exploration of the recent advancements in the rapidly growing field of lignin-based urea-formaldehyde (UF) adhesives, spanning from fundamental research to practical applications. The initial sections of this article offer an updated overview of lignin, covering its chemical structure, properties, extraction methods, and various chemical modifications, with a focus on its potential in adhesive applications. The review concludes with a detailed discussion of the economic and environmental advantages, alongside the challenges and future directions for integrating lignin into UF adhesive technology. This review play a key resource for understanding the evolving field of sustainable wood adhesives.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2500491"},"PeriodicalIF":7.5,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biobased Poly(dodecylene Furanoate) with Inherent Advantages in Performance and Circularity. 生物基聚呋喃酸十二烯在性能和圆度方面具有固有优势。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-06-23 DOI: 10.1002/cssc.202501080

Hesham Aboukeila, Eswara Rao Chokkapu, Hang-Fei Tu, Onkar Singh, Wilfred T Diment, Shu Xu, Meltem Urgun-Demirtas, John Klier, George W Huber, Brian P Grady, Eugene Y-X Chen

{"title":"Biobased Poly(dodecylene Furanoate) with Inherent Advantages in Performance and Circularity.","authors":"Hesham Aboukeila, Eswara Rao Chokkapu, Hang-Fei Tu, Onkar Singh, Wilfred T Diment, Shu Xu, Meltem Urgun-Demirtas, John Klier, George W Huber, Brian P Grady, Eugene Y-X Chen","doi":"10.1002/cssc.202501080","DOIUrl":"10.1002/cssc.202501080","url":null,"abstract":"Biobased polymers are gaining traction toward more sustainable flexible-film packaging, yet overcoming trade-offs between their performance properties and end-of-life (EoL) options still remains a challenge. Here, it is shown that biobased poly(dodecylene 2,5-furanoate) (PDDF), synthesized via both step-growth polycondensation and chain-growth ring-opening polymerization methods, exhibits advantages not only in gas barrier properties but also in EoL options due to its biodegradability and closed-loop chemical circularity. Specifically, PDDF displays significantly lower oxygen and carbon dioxide permeability than commercial poly(butylene adipate-co-terephthalate) (PBAT) and linear low-density polyethylene , alongside a markedly higher modulus (by ≈3 ×) and reduced water vapor transmission rate compared to PBAT. This superior performance is attributed to the inherently rigid, polar, H-bonding furan rings that enhance chain interaction, packing and crystallinity and thus reduce free volume impeding gas diffusion, while the long hydrophobic dodecylene segments inhibit water permeation. Furthermore, PDDF can be recycled back to its cyclic monomer by base-catalyzed depolymerization or diester and diol monomers by simple methanolysis. These superior barrier properties, coupled with biodegradation and closed-loop circularity, highlight the potential of the biobased PDDF as a more sustainable alternative for packaging.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e2501080"},"PeriodicalIF":7.5,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144473466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0