{"title":"Development of a prototype for the rubber latex industry to detect dry rubber content of fresh natural rubber latex using a novel measurement system with proton-electron transfer","authors":"Sittidet Chooduang, Korn Taksapattanakul","doi":"10.1515/ipp-2022-4304","DOIUrl":"https://doi.org/10.1515/ipp-2022-4304","url":null,"abstract":"Abstract Rubber latex industry has been looking for techniques to rapidly estimate the dry rubber content (DRC) of rubber latex with accuracy, at a low cost, and to be used by non-technical people in the field. The basis of electrical charge in terms of proton-electron transfer (P.E.TF) was used to develop a new prototype. The prototype was created with the P.E.TF system, two electrode probe detectors, and a new code program on Arduino board. The data was collected using the P.E.TF system of fresh natural rubber latex and presented as the P.E.TF number and the percentage of dry rubber content (%DRC). The standard method (ISO126:2005(E)) was used to calculate %DRC. The comparison of the %DRC measurement using the prototype and the standard method was studied. It was found that the new code program on Arduino board could evaluate the data. In real-time, it converted the P.E.TF number into %DRC on the LCD screen. The %DRC measurement using the prototype was close to that calculated using the standard method. The correlation between the two methods is 0.9814 of Rsqr. Therefore, the novel measurement system can replace the standard method for the %DRC measurement of fresh natural rubber latex. The prototype is simple, fast to detect, small, and low-cost without operator training.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"225 - 232"},"PeriodicalIF":1.3,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49454517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Notable electrical and mechanical properties of polyacrylamide (PAM) with graphene oxide (GO) and single-walled carbon nanotubes (SWCNTs)","authors":"Seema Awasthi, T. Yadav, K. Awasthi","doi":"10.1515/ipp-2022-4295","DOIUrl":"https://doi.org/10.1515/ipp-2022-4295","url":null,"abstract":"Abstract In the present investigation, a polyacrylamide (PAM) – graphene oxide (GO)-single-walled carbon nanotubes (SWNTs) composite has been prepared through a cost effective solution cast method and physical properties (electrical and mechanical) measurements have been carried out. The GO sheets contain oxygen functional groups which enhance the interfacial adhesion with the polymer matrix, while the SWNTs act as wires joining the GO together in the composite matrix. This interconnected network creates a conducting path, lowering film resistance and improving PAM films’ electrical, mechanical, and thermal properties. Raman study demonstrated that carbon nanofiller (SWNTs, GO) and polymer PAM have good interfacial bonding. The electrical conductivity and mechanical characteristics (hardness and elastic modulus) of these composite films were enhanced at a loading of 15 wt% GO and 15 wt% SWNTs in PAM matrix. Electrical conductivity of GO (15 wt%) – SWNTs (15 wt%)-PAM composite film was found to be 2.8 × 10−2 S/cm, which is five orders of magnitude higher than that of the PAM polymer. In comparison to pure PAM polymer, the elastic modulus and hardness are found to be 1.14 and 65 times higher, respectively.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"290 - 299"},"PeriodicalIF":1.3,"publicationDate":"2023-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45441677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Feasibility assessment of injection molding online monitoring based on oil pressure/nozzle pressure/cavity pressure","authors":"Hao-Hsuan Tsou, Chung-Ching Huang, Zhi-Hao Wang, Tingting Zhao","doi":"10.1515/ipp-2022-4281","DOIUrl":"https://doi.org/10.1515/ipp-2022-4281","url":null,"abstract":"Abstract This study produced a box-like product through injection molding, and pressure sensors were installed at the nozzle in the injection molding machine and mold cavity. Injection molding experiments were conducted with various process parameters to understand the correlations between the pressure of the cavity, nozzle, and oil pump. A high correlation (R > 0.95) between oil pressure and nozzle pressure could be found in the study. The oil pressure in the injection molding machine could fully describe the pressure variation of the molten plastic at the nozzle. However, the correlation between nozzle pressure and cavity pressure was slightly reduced due to changes in injection speed, melting temperature, and packing time. Thus, a suitable molding window can improve the correlation between oil pressure, nozzle pressure, and cavity pressure. This study provides a correlation between the three pressures and a reference for the future selection of process variables, an essential pretreatment for online monitoring.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"375 - 386"},"PeriodicalIF":1.3,"publicationDate":"2023-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46378316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental investigation and simulation of 3D printed sandwich structures with novel core topologies under bending loads","authors":"M. Eryildiz","doi":"10.1515/ipp-2022-4311","DOIUrl":"https://doi.org/10.1515/ipp-2022-4311","url":null,"abstract":"Abstract In a range of applications, such as the automotive, aerospace, and shipbuilding sectors, where weight reduction is essential, sandwich structures are getting more popular. The performance of sandwich structures in bending can be enhanced by using lightweight core topologies. In this study, six different novel and new core topologies were designed with CATIA V5. Polylactic acid (PLA) sandwich structures with new core designs were produced using the fused deposition modeling (FDM) additive manufacturing method. In order to determine the mechanical characteristics of these six designed core topologies, three-point bending tests on sandwich structures were performed. The influence of core topology on the flexural characteristics of lightweight sandwich structures was investigated to appropriately choose and design the core topology of the sandwich structures to meet desired structural requirements. To evaluate the flexural behavior of sandwich structures, finite element simulation using ANSYS Workbench 2021 R2 was also performed. Both the experimental data and simulation were in good agreement and clearly showed that the sandwich structure with the triple bow core exhibited the highest mechanical properties. These results provide new perspectives on the investigation of the mechanical response of sandwich structures, which can be beneficial for many other industries and applications.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"277 - 289"},"PeriodicalIF":1.3,"publicationDate":"2023-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48559302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comparative analysis of the effect of post production treatments and layer thickness on tensile and impact properties of additively manufactured polymers","authors":"Çağın Bolat, Berkay Ergene, Hasan Ispartalı","doi":"10.1515/ipp-2022-4267","DOIUrl":"https://doi.org/10.1515/ipp-2022-4267","url":null,"abstract":"Abstract In recent years, additive manufacturing (AM) technologies have become greatly popular in the polymer, metal, and composite industries because of the capability for rapid prototyping, and appropriateness for the production of complex shapes. In this study, a comprehensive comparative analysis focusing on the influence of post-processing types (heat treatment and water absorption) on tensile and impact responses was carried out on 3D printed PETG, PLA, and ABS. In addition, layer thickness levels (0.2, 0.3, and 0.4 mm) were selected as a major production parameter and their effect on mechanical properties was combined with post-processing type for the first time. The results showed that both tensile and impact resistance of the printed polymers increased thanks to the heat treatment. The highest tensile strength was measured for heat-treated PLA, while the peak impact endurance level was reached for heat-treated PETG. Also, water absorption caused a mass increment in all samples and induced higher tensile elongation values. Decreasing layer thickness had a positive effect on tensile features, but impact strength values dropped. On the other hand, all samples were subjected to macro and micro failure analyses to understand the deformation mechanism. These inspections indicated that for impact samples straight crack lines converted to zigzag style separation lines after the heat treatment. As for the tensile samples, the exact location of the main damage zone altered with the production stability, the water absorption capacity of the polymer, and the thermal diffusion ability of the filament.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"244 - 256"},"PeriodicalIF":1.3,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41413529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kousaku Tao, K. Yamada, S. Higashi, K. Kago, Shiho Kuwashiro, H. Hirano, Hiroki Takeshita, K. Tokumitsu
{"title":"Effect of molding history on molecular orientation relaxation during physical aging of polystyrene injection moldings","authors":"Kousaku Tao, K. Yamada, S. Higashi, K. Kago, Shiho Kuwashiro, H. Hirano, Hiroki Takeshita, K. Tokumitsu","doi":"10.1515/ipp-2022-4264","DOIUrl":"https://doi.org/10.1515/ipp-2022-4264","url":null,"abstract":"Abstract This work examined the effect of changing molding conditions on the physical aging of polystyrene injection moldings. First, we investigated the relationship between the molecular orientation and the molding conditions. The molecular orientation near the surface changed with changing injection rate, so we hypothesized that this molecular orientation might form during the filling stage. Because this molecular orientation did not relax under heat treatment below the glass transition temperature (Tg), the oriented molecules near the surface were thought to be elongated owing to the high strain rate during the filling stage. On the other hand, the molecular orientation in the core layer changed with changing holding pressure and relaxed under heat treatment below Tg. Thus, the molecules in the core layer might become oriented during the holding stage and not be elongated owing to the slow strain rate. Furthermore, the molecular orientation in the core layer decreased with increasing mold temperature, and the physical heat resistance improved with increasing mold temperature. Meanwhile, the excess enthalpy did not change with changing molding conditions. Therefore, the improvement in physical heat resistance with increasing mold temperature was likely caused by the decrease in the molecular orientation in the core layer. Analyzing the relaxation behavior of the molecular orientation suggested that increasing mold temperature reduced the number of oriented molecules with large deformation in the core layer.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"233 - 243"},"PeriodicalIF":1.3,"publicationDate":"2023-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49641527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Statistical research on the mixing properties of wave based screws by numerical simulations","authors":"Tian Liu, Yaoxue Du, Xiangdong He","doi":"10.1515/ipp-2022-4253","DOIUrl":"https://doi.org/10.1515/ipp-2022-4253","url":null,"abstract":"Abstract Research based on numerical simulation with the CFD software ANSYS POLYFLOW is conducted on the mixing properties for the wave screw elements, as well as barrier screw elements, by using statistical tools. Then, the investigation is conducted in detail on the relationship between pressure, maximum shear rate, mixing index and other flow field characteristics of the two above screws under the same simulation conditions. It is found that polymer melt flow in the wave screw possesses various advantages compared with the normal barrier screw, such as acquiring larger pressure, stronger shearing and stretching action, better mixing and efficiency, which mainly result from the periodic depth change design in the screw groove. On the other hand, the increased wave bulge in the wave screw lessens the space for the polymer melt to be conveyed forward, which can greatly reduce the original function of the secondary flight. Also, the convergent and divergent zones in the wave screw groove produce a much stronger stress favoring the shear and elongation rates, and also lead to a sharp increase of the axial force load on the wave screw. Consequently, for the optimization of the wave screw configuration it is suggested to reduce the axial force without decreasing the effect of the excellent distributive and dispersive mixing.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"200 - 213"},"PeriodicalIF":1.3,"publicationDate":"2023-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44314103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study on flame retardancy and thermal stability of rigid polyurethane foams modified by amino trimethylphosphonate cobalt and expandable graphite","authors":"Bing Liu, Xu Zhang, Dehe Yuan, Zhi Wang, Hua Xie","doi":"10.1515/ipp-2022-4250","DOIUrl":"https://doi.org/10.1515/ipp-2022-4250","url":null,"abstract":"Abstract Amino trimethylphosphonate cobalt (Co2+-ATMP) flame retardant was prepared by ion exchange method, and rigid polyurethane foam (RPUF) modified by Co2+-ATMP and expandable graphite (EG) was prepared by one-pot and free-rise method. The flame retardancy, thermal stability and smoke toxicity of modified RPUF were studied by limiting oxygen index (LOI), cone calorimeter (Cone), thermogravimetric analysis (TG) and smoke toxicity characterization. The results showed that the flame retardancy, thermal stability and smoke toxicity of RPUF modified by Co2+-ATMP and EG are significantly improved. When the ratio of Co2+-ATMP to EG is 1:5, the LOI value is the highest, and the toxicity of flue gas was the lowest. The peak heat release rate (PHRR) and total heat release rate (THR) were both the lowest, 138 kW/m2 and 15.9 MJ/m2, respectively. Compared with RPUF-0, it decreased by 39.2% and 16.8% respectively. The research results can provide reference for the subsequent flame retardant modification of RPUF.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"267 - 276"},"PeriodicalIF":1.3,"publicationDate":"2023-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49212613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fabrication of flame-retardant and smoke-suppressant rigid polyurethane foam modified by hydrolyzed keratin","authors":"Xu Zhang, Chen Xu, Zhi Wang, Hua Xie","doi":"10.1515/ipp-2022-4303","DOIUrl":"https://doi.org/10.1515/ipp-2022-4303","url":null,"abstract":"Abstract Rigid polyurethane foam (RPUF) has been fabricated and modified by hydrolyzed keratin to improve its flame retardancy and smoke suppression. Then, the limiting oxygen index (LOI), cone calorimeter (CONE), thermogravimetric analyzer and scanning electron microscope (SEM) were used to characterize the modified RPUFs. It was found that the LOI of the modified RPUFs increased with the presence of hydrolyzed keratin. In addition, the peak heat release rate (PHRR) and total heat release (THR) of the modified RPUF tended to decrease. The HRR of RPUF-HK5 reduced 28.8 kW/m2 compared with RPUF-0, and the THR of RPUF-HK5 was 0.74 MJ/m2 lower than that of RPUF-0. RPUF-HK5 had the most obvious smoke suppression effect. Compared with RPUF-0, the smoke density (Ds) and light transmittance (T) of RPUF-HK5 decreased by 8.88 and increased by 11.26%, respectively. The current research results showed that hydrolyzed keratin can improve the flame-retardant and smoke-suppression performances of RPUFs and that 5 wt% hydrolyzed keratin was the most suitable ratio for the modified RPUF.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"38 1","pages":"257 - 266"},"PeriodicalIF":1.3,"publicationDate":"2023-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49222874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}