Notable electrical and mechanical properties of polyacrylamide (PAM) with graphene oxide (GO) and single-walled carbon nanotubes (SWCNTs)

IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL
Seema Awasthi, T. Yadav, K. Awasthi
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引用次数: 0

Abstract

Abstract In the present investigation, a polyacrylamide (PAM) – graphene oxide (GO)-single-walled carbon nanotubes (SWNTs) composite has been prepared through a cost effective solution cast method and physical properties (electrical and mechanical) measurements have been carried out. The GO sheets contain oxygen functional groups which enhance the interfacial adhesion with the polymer matrix, while the SWNTs act as wires joining the GO together in the composite matrix. This interconnected network creates a conducting path, lowering film resistance and improving PAM films’ electrical, mechanical, and thermal properties. Raman study demonstrated that carbon nanofiller (SWNTs, GO) and polymer PAM have good interfacial bonding. The electrical conductivity and mechanical characteristics (hardness and elastic modulus) of these composite films were enhanced at a loading of 15 wt% GO and 15 wt% SWNTs in PAM matrix. Electrical conductivity of GO (15 wt%) – SWNTs (15 wt%)-PAM composite film was found to be 2.8 × 10−2 S/cm, which is five orders of magnitude higher than that of the PAM polymer. In comparison to pure PAM polymer, the elastic modulus and hardness are found to be 1.14 and 65 times higher, respectively.
氧化石墨烯(GO)和单壁碳纳米管(SWCNTs)对聚丙烯酰胺(PAM)电学和力学性能的影响
摘要:本研究通过低成本的溶液浇铸法制备了聚丙烯酰胺(PAM) -氧化石墨烯(GO)-单壁碳纳米管(SWNTs)复合材料,并对其物理性能(电学和力学)进行了测量。氧化石墨烯片含有氧官能团,增强了与聚合物基体的界面附着力,而单壁碳纳米管则充当了将氧化石墨烯连接在复合基体中的导线。这种相互连接的网络创造了导电路径,降低了薄膜电阻,改善了PAM薄膜的电学、机械和热性能。拉曼研究表明,碳纳米填料(SWNTs、GO)与聚合物PAM具有良好的界面键合。在PAM基体中添加15wt %的氧化石墨烯和15wt %的单壁碳纳米管时,复合薄膜的电导率和力学特性(硬度和弹性模量)得到了增强。氧化石墨烯(15wt %)- SWNTs (15wt %)-PAM复合膜的电导率为2.8 × 10−2 S/cm,比PAM聚合物的电导率高5个数量级。与纯PAM聚合物相比,其弹性模量和硬度分别提高1.14倍和65倍。
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来源期刊
International Polymer Processing
International Polymer Processing 工程技术-高分子科学
CiteScore
2.20
自引率
7.70%
发文量
62
审稿时长
6 months
期刊介绍: International Polymer Processing offers original research contributions, invited review papers and recent technological developments in processing thermoplastics, thermosets, elastomers and fibers as well as polymer reaction engineering. For more than 25 years International Polymer Processing, the journal of the Polymer Processing Society, provides strictly peer-reviewed, high-quality articles and rapid communications from the leading experts around the world.
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