{"title":"Study on the thermal stability and smoke suppressant effect of polyurethane foam modified by ammonium lignosulfonate","authors":"Xu Zhang, Dehe Yuan, Simiao Sun, Zhi Wang, Hua Xie, Zhanpeng Su","doi":"10.1515/ipp-2023-4378","DOIUrl":"https://doi.org/10.1515/ipp-2023-4378","url":null,"abstract":"Abstract The modified polyurethane foam (PUF) with ammonium lignosulfonate was prepared by one-step water foaming method. The effects of ammonium lignosulfonate on its thermal stability and smoke suppression were investigated by thermogravimetric analysis, pyrolysis kinetics analysis, smoke density (Ds) and smoke toxicity analysis. The results showed that the addition of 15 % ammonium lignosulfonate (PUFA15) had the lowest mass loss of PUFs and the highest integral programmed decomposition temperature (870.8 °C). Its activation energy was the highest according to the Flynn-Wall-Ozawa method (110.1 kJ/mol), Kissinger method (181.1 kJ/mol), Starnk method (106.3 kJ/mol) and Coats-Redfern method (149.7 kJ/mol). In addition, PUFA15 had the lowest Ds (34.43) and the highest transmittance (66.74). This indicated that PUFA15 had good thermal stability and smoke suppression properties. The research results had a reference value for exploring the production of environmentally friendly PUF by biomass modification.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49084679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Chicken feather protein for the thermal stability and combustion performance of rigid polyurethane foam","authors":"Xu Zhang, Simiao Sun, Dehe Yuan, Zhi Wang, Hua Xie, Zhanpeng Su","doi":"10.1515/ipp-2023-4364","DOIUrl":"https://doi.org/10.1515/ipp-2023-4364","url":null,"abstract":"Abstract Rigid polyurethane foams (RPUFs) were synthesized with chicken feather protein using the “one-step method” of all-water foaming. Thermogravimetry, pyrolysis kinetics analysis, Cone calorimetry and smoke density (Ds) were used to investigate the effects of chicken feather protein on thermal stability and combustion performance of RPUFs. The results showed that the modified RPUFs with 2.5 wt% chicken feather protein (RPUF-CF1) had the lowest mass loss, the highest integrated program pyrolysis temperature, the highest activation energy, the lowest Ds (13.3), the highest light transmittance (79.3 %), the lowest heat release rate (22.0 kW/m2 and 30.6 kW/m2) and total heat release (2.4 MJ/m2 and 2.8 MJ/m2), which indicated that RPUF-CF1 had better thermal stability and combustion performance. The current research results provide a useful reference for the preparation of RPUFs with good thermal stability by bio-based modification.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44937097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties","authors":"Zoulikha Khiati, L. Mrah","doi":"10.1515/ipp-2022-4302","DOIUrl":"https://doi.org/10.1515/ipp-2022-4302","url":null,"abstract":"Abstract An in-depth study of polyvinylidene fluoride (PVDF) based nanocomposite systems will be the focus of this research. This polymer being hydrophobic and apolar, it will be unlikely to generate strong interactions with clay leaves called organophilic maghnite. The challenge of this study will therefore be to manage the load/polymer interfaces by using montmorillonite with specific surface treatments by adding a surfactant Cetyltrimethylammonium bromide. Therefore, a significant improvement in mechanical and thermal properties was observed. The properties of PVDFNC nanocomposites were evaluated using various physico-chemical techniques (XRD, FTIR, TGA, DSC, TEM, SEM). The results of the structural and thermal measurements carried out on these products reveal that the structural concept of the surfactant influences both the morphological profile, the thermal and mechanical properties of the nanocomposites obtained. Accelerated crystallization is observed in PVDNC nanocomposites as an effective nucleation agent, the crystals formed are predominantly β shaped and have a small number of polar α crystals. Measurements by X-ray diffraction, as well as transmission and scanning electron microscopy indicated that modified maghnite was perfectly distributed 3 % by weight in the polyvinylidene fluoride matrix. The mechanical properties of the nanocomposites were evaluated according to the filler material used and the polyvinylidene fluoride matrix.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48434928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Free vibration behaviour and some mechanical properties of micro particle reinforced epoxy composites","authors":"Meltem Ürer, Aydin Demir","doi":"10.1515/ipp-2023-4379","DOIUrl":"https://doi.org/10.1515/ipp-2023-4379","url":null,"abstract":"Abstract The epoxy composite specimens of certain sizes were produced by adding graphite, silicon carbide and boron carbide microparticles separately at the rates of 5, 10 and 15 wt% to the epoxy resin. Free vibrations of these composite samples were investigated experimentally in a simple supported vibration test setup. Frequency spectrums were obtained by modal analysis method in this experimental setup. The damping ratios were calculated using the half power bandwidth method. The mechanical properties of these composite specimens were also determined by applying the tensile test. By controlling the obtained vibration values theoretically, the effects of microparticle contributions to these specimens at certain rates on natural frequency and damping properties were investigated in detail. The maximum reduction in natural frequency was observed at 5 wt% of each reinforcement. Only the first natural frequency of the 15 wt% boron carbide reinforced epoxy composite was slightly increased. The damping ratio was increased at 10 wt% graphite added and 5 wt% boron carbide added epoxy composites compared to pure epoxy, but decreased in other composite specimens.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47020167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ponnusamy Natarajan, Ponnusamy Rajasekaran, M. Mohanraj, Shanmugam Devi
{"title":"Mechanical and tribological properties of snake grass fibers reinforced epoxy composites: effect of Java plum seed filler weight fraction","authors":"Ponnusamy Natarajan, Ponnusamy Rajasekaran, M. Mohanraj, Shanmugam Devi","doi":"10.1515/ipp-2023-4376","DOIUrl":"https://doi.org/10.1515/ipp-2023-4376","url":null,"abstract":"Abstract Natural fiber composite materials are able to compete with common synthetic materials in situations where the strength-to-weight ratio is important. In this study, we aim to analyze the mechanical, tribological, and surface morphology of composites fabricated from randomly oriented snake grass natural fiber with java plum seed filler. Different weight ratios of fiber to seed filler are chosen: 30:0, 28:2, 26:4, 24:6, 22:8, and 20:10. A 70 % epoxy resin was kept constant in all compositions. The fabricated hybrid composite samples were subjected to tensile, flexural, shear, Shore D hardness, water absorption, and wear tests as per ASTM standards, and the results were compared with those of snake grass mono fiber composites. The 20:10 composite has the maximum tensile strength, impact resistance, flexural strength, hardness, water absorption, and wear resistance compared to other composites. The fiber/matrix adhesion was explored using a scanning electron microscope (SEM). The 20:10 composite shows predominant mechanical and tribological characteristics, making it easier to utilize in structural and automotive applications.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44352030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj, Chithambara Thanu
{"title":"Mechanical characterization of randomly oriented short Sansevieria Trifasciata natural fibre composites","authors":"Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj, Chithambara Thanu","doi":"10.1515/ipp-2023-4377","DOIUrl":"https://doi.org/10.1515/ipp-2023-4377","url":null,"abstract":"Abstract The present work investigates the mechanical characteristics of randomly oriented short Sansevieria Trifasciata Fibre Polyester (STFP) composites. The STFP composites are fabricated using compression moulding methods with varying fibre weight percentages (5 %–50 %) and fibre lengths (5 mm–50 mm). It has been observed that the impact, flexural, and tensile strength of STFPs improve as the length of the fibre increases, up to a maximum of 40 mm. After that, these properties start to decrease as the length of the fibre further increases. Further, the analysis revealed that STFPs exhibited an increase in properties when the fibre weight percentage was less than 40 %, followed by a decrease in properties as the fibre percentage increased beyond that point. The impact strength of STFP is around 8.2 J/cm2. Similarly, the STFP has a flexural modulus and strength of about 3.4 GPa and 82.6 MPa, respectively. Lastly, the tensile strength of STFP is around 78.26 MPa, the elongation at break is between 6.25 % and 9.36 %, and the Young’s modulus is 11.8 GPa. The matrix and fibre interaction were examined by Scanning Electron Microscopy (SEM). Furthermore, Thermogravimetric (TGA) and Differential Scanning Calorimeter (DSC) analyses are carried out. From these analyses, the thermal stability of STFP is 200 °C and its activation energy is 65.48 kJ/mol. After a thorough comparison with other well-known natural fibres, the proposed properties of STFP demonstrate its superiority as a practical and effective natural fibre composite.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":"0 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41338098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Chithambara Thanu, Appadurai M, E. Fantin Irudaya Raj, T. Lurthu Pushparaj
{"title":"Experimental analysis of localized hybridization by means of adding woven polyester strip","authors":"M. Chithambara Thanu, Appadurai M, E. Fantin Irudaya Raj, T. Lurthu Pushparaj","doi":"10.1515/ipp-2023-4339","DOIUrl":"https://doi.org/10.1515/ipp-2023-4339","url":null,"abstract":"Abstract Natural fiber-reinforced composites must be hybridized with synthetic fibers to enhance their mechanical strength. They are appropriate for structural applications after hybridizing with more than 40 % of synthetic fibers. The hybrid composite becomes a partly biodegradable material due to the blend of natural fibers. The localized hybridization approach has been used to minimize the quantity of synthetic fiber used in hybridization. The region around the drilled hole of a composite has been identified as stress concentrated region. In that stress-concentrated region, a polyester strip of different widths is deployed to reinforce it to reduce the delamination occurrence. The present work deals with Jute Fiber reinforced unsaturated polyester resin with local hybridization of woven polyester made up of Perma Core T-18 polyester fiber strands. The interfacial shear and tensile strengths are evaluated for the proposed composite. The results revealed that the yield strength of the proposed composite increased from 18.32 MPa to 29.62 MPa due to local hybridization. The increment of 69.24 % in yield strength is more significant for structural applications.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47343278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Manickaraj, R. Ramamoorthi, S. Sathish, A. Johnson Santhosh
{"title":"A comparative study on the mechanical properties of African teff and snake grass fiber-reinforced hybrid composites: effect of bio castor seed shell/glass/SiC fillers","authors":"K. Manickaraj, R. Ramamoorthi, S. Sathish, A. Johnson Santhosh","doi":"10.1515/ipp-2023-4343","DOIUrl":"https://doi.org/10.1515/ipp-2023-4343","url":null,"abstract":"Abstract The environmental awareness and sustainable nature of plant-based fibers have forced material researchers and automakers to use natural fibers instead of petroleum-based fibers for various industrial applications. The need for environmentally and biodegradable fibers has created a demand in the transportation industry. In this study, bio castor seed shell (C), glass fiber (G), and SiC (SC) fillers in a constant weight fraction (10 %) were reinforced separately with varying weight fractions (5–25 %) of African teff and snake grass fibers to improve the mechanical properties of the hybrid composites. Both African teff and snake grass fibers were subjected to alkaline treatment to remove amorphous elements such as hemicellulose, lignin, and wax, resulting in high surface roughness. The hybrid composites were fabricated by the compression molding technique and their mechanical properties were characterized as per ASTM standards. The fractured surface of the treated fiber was examined by scanning electron microscopy. From the results, it was found that SC10SG20AT showed maximum mechanical properties compared to C10SG20AT and G10SG20AT due to higher load-bearing capacity of SiC filler. Therefore, SC10SG20AT can be recommended for lightweight applications.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42172837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chithambara Thanu, Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj
{"title":"Mechanical strength enhancement of natural fibre composites via localized hybridization with stitch reinforcement","authors":"Chithambara Thanu, Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj","doi":"10.1515/ipp-2023-4371","DOIUrl":"https://doi.org/10.1515/ipp-2023-4371","url":null,"abstract":"Abstract Stress concentration is an unavoidable phenomenon during the fabrication of composite structures. This research focuses on reducing stress concentration. Circular holes made on the composite structural member induce stress-concentrated regions. These stress-concentrated regions around the circular hole (considered as a weak section) were strengthened by adding synthetic fibre (local hybridization) in the form of fibre stitches (locked loop stitch). Through conducting a single fibre pull-out test, the present study analysed the impact of incorporating synthetic fibres in stitch form and the enhancement of Interfacial Shear Strength (IFSS). The load acting on the broken warp fibres is distributed to the broken weft fibres when the number of concentric stitches increases. The increment of concentric stitches resulted in the increase of IFSS due to localized hybridization. The tensile test results also show a significant improvement with 110 Nmm axial fastening force, from 6.749 MPa (for the natural fibre composite) to 76.91 MPa (for locally hybridized with eight concentric stitches). A simple bolted lap joint with local hybridization around the hole has been evaluated for different clamp-up forces. The best combinations of the clamp-up force and the extent of hybridization have been identified. SEM images illustrate the reduced voids and the reduced fibre pull-out due to the local hybridization around delamination-prone areas.","PeriodicalId":14410,"journal":{"name":"International Polymer Processing","volume":" ","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42744069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}