ChemElectroChem最新文献_第5页

Surface Nanostructuring of Copper Using Fluoride and Chloride 利用氟化物和氯化物对铜进行表面纳米结构处理

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-13 DOI: 10.1002/celc.202400414

Vicente Pascual-Llorens, Albert Serra Ramos, Pedro Mazaira-Couce, María Escudero-Escribano, Paula Sebastián-Pascual

{"title":"Surface Nanostructuring of Copper Using Fluoride and Chloride","authors":"Vicente Pascual-Llorens, Albert Serra Ramos, Pedro Mazaira-Couce, María Escudero-Escribano, Paula Sebastián-Pascual","doi":"10.1002/celc.202400414","DOIUrl":"10.1002/celc.202400414","url":null,"abstract":"Copper is an active electrocatalyst for various energy conversion reactions, but its performance depends on the structure of the active surface sites. In this work, we propose a simple strategy to tailor both the roughness and the active site's geometry of copper. To modify the surface of copper, we oxidize and reduce a copper polycrystalline electrode in 0.1 M solutions containing both sodium fluoride and sodium chloride with different chloride/fluoride molar ratios: (0.1-x) M NaF+x M NaCl. To address the anion effect on the changes in surface geometry, we recorded the voltammetric fingerprints of the modified electrodes using lead underpotential deposition (UPD). The voltammetric analysis suggested that while chloride induces (n10) sites, fluoride promotes an increase in the active surface area and the growth of low-coordinated sites with (110) or (111) geometry. Solutions containing both fluoride and chloride anions induced (n10) motifs covered by nanometric clusters, as observed by scanning electron microscopy, forming a highly defect-rich surface. Our work provides a direct link between electrochemical response and ex-situ structural characterization, and compares, in detail, the effect of chloride and fluoride on the surface nanostructuring of copper.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 20","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400414","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical Impedance Spectroscopy as a Characterization Method for Enzymatic Fuel Cell Bioanodes 作为酶燃料电池生物阳极表征方法的电化学阻抗光谱法

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-13 DOI: 10.1002/celc.202400329

Federica Torrigino, Marcel Nagel, Martin Hartmann, Katharina Herkendell

{"title":"Electrochemical Impedance Spectroscopy as a Characterization Method for Enzymatic Fuel Cell Bioanodes","authors":"Federica Torrigino, Marcel Nagel, Martin Hartmann, Katharina Herkendell","doi":"10.1002/celc.202400329","DOIUrl":"10.1002/celc.202400329","url":null,"abstract":"Enzymatic fuel cells (EFCs) offer renewable energy conversion via highly selective electrode reactions using enzymes as natural catalysts even under mild conditions. Electrochemical impedance spectroscopy (EIS) is a valuable tool for evaluating EFC performance, providing insights into substrate mass transport, enzyme kinetics, and electrode stability. Despite its acknowledged importance, the use of EIS coupled with distribution of relaxation times (DRT) analysis in EFCs research is limited. Our study addresses this gap by employing EIS and DRT analysis to investigate enzyme-based anodic processes, focusing on the bioelectrocatalytic oxidation of glucose catalyzed by glucose oxidase (GOx). Through careful variation of multiple parameters, it was possible to identify three distinct regions in the DRT plot. Each region has been subsequently associated with a key anodic process. The first region (R1) is associated with high-frequency phenomena occurring at the electrodes, primarily due to ionic conduction in the electrolyte. Intermediate-frequency processes are associated to charge transfer kinetics in region 2 (R2). Region 3 (R3) is linked to diffusion processes occurring at low frequencies. This thorough examination offers an insight into the functioning of enzymatic bioelectrodes, which in turn drives improvements in the design and components of biofuel cells to increase their power output.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400329","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancement of the Potential Window of Ppy Electrodes in the Presence of a Bis(Oxamato) Nickel(II) Complex for High-Performance Supercapacitor 在双(氧杂羰基)镍(II)络合物存在下增强铂电极的电位窗口以制造高性能超级电容器

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-12 DOI: 10.1002/celc.202400384

Camila Pesqueira, Bruna M. Hryniewicz, Vanessa Klobukoski, Saddam Weheabby, Olfa Kanoun, Tobias Rüffer, Igor A. Pašti, Marcio Vidotti

{"title":"Enhancement of the Potential Window of Ppy Electrodes in the Presence of a Bis(Oxamato) Nickel(II) Complex for High-Performance Supercapacitor","authors":"Camila Pesqueira, Bruna M. Hryniewicz, Vanessa Klobukoski, Saddam Weheabby, Olfa Kanoun, Tobias Rüffer, Igor A. Pašti, Marcio Vidotti","doi":"10.1002/celc.202400384","DOIUrl":"10.1002/celc.202400384","url":null,"abstract":"Enhancing the supercapacitors’ performance relies on the increased capacitance and voltage window, which are the current key challenges for developing new materials. In this study, the mononuclear NiII-bis(oxamato) complex ([nBu4N]2[Ni(opba)], 1) has been synthesized and used as a template in polypyrrole (PPy) based conductive polymer as a novel electrode material for supercapacitor applications. The surface and structural properties of PPy and PPy/1 electrodes were studied using SEM and TEM to elucidate their interactions. The results of characterization techniques revealed that complex 1 altered the morphology, creating a prominent three-dimensional globular structure in the PPy/1 hybrid material without significant chemical modification. The electrochemical properties of PPy and PPy/1 were investigated by CV, EIS, and GCD analyses. The PPy/1 electrode demonstrated intense pseudocapacitive behavior, showing a significantly widened potential window and increased current compared to the PPy electrode, resulting in enhanced energy storage capacity within the material. This improvement was evaluated by testing a symmetric supercapacitor in a coin cell architecture with an alginate-based gel acting as both electrolyte and separator. The maximum specific cell capacitance reached 41.6 F g−1 at a current density of 0.2 A g−1, with a remarkable capacity retention of 97 % after 1000 galvanostatic charge/discharge cycles.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400384","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

On the Challenges to Develop Hybrid Faradaic-Capacitive Electrodes Incorporating a Sacrificial Salt for Lithium-ion Capacitors: The Case of Li3V1.95Ni0.05(PO4)3-AC-Li2C4O4 为锂离子电容器开发包含牺牲盐的混合法拉第电容电极所面临的挑战：Li3V1.95Ni0.05(PO4)3-AC-Li2C4O4 的实例

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-10 DOI: 10.1002/celc.202400117

Miguel Granados-Moreno, Maria Arnaiz, Emanuele Gucciardi, Nahom Enkubahri Asres, Eider Goikolea, Jon Ajuria

{"title":"On the Challenges to Develop Hybrid Faradaic-Capacitive Electrodes Incorporating a Sacrificial Salt for Lithium-ion Capacitors: The Case of Li3V1.95Ni0.05(PO4)3-AC-Li2C4O4","authors":"Miguel Granados-Moreno, Maria Arnaiz, Emanuele Gucciardi, Nahom Enkubahri Asres, Eider Goikolea, Jon Ajuria","doi":"10.1002/celc.202400117","DOIUrl":"10.1002/celc.202400117","url":null,"abstract":"The low capacity of activated carbon (AC) electrodes remains as one of the major limiting factors for the development of high energy density lithium-ion capacitors (LICs). Hybridization of capacitive AC electrodes by incorporating faradaic materials into the electrode formulation could be performed to enhance the capacity of the overall device. However, this strategy requires an accurate electrode design to maximize the performance. In this work, Li3V1.95Ni0.05(PO4)3 (LVNP) was selected as faradaic material due to its compatibility with AC, showing high capacity, fast ionic diffusion, and relatively high conductivity. Various formulations and mass loadings have been studied to analyze the impact of incorporating LVNP into the positive electrode on the performance of the hybrid electrode. Moreover, for practical LIC applications, a sacrificial salt -dilithium squarate, Li2C4O4- was included in the hybrid electrode as a pre-lithiation additive, developing a ternary electrode. The sacrificial salt oxidized releasing lithium ions, while the electrochemical performance of the hybrid positive electrode remained almost unaltered. Finally, a cycle life test combined with a post-mortem analysis allows understanding the failure mechanisms of the electrode, suggesting the need of further improvements of the electrolyte and electrode-electrolyte interface to develop long lifetime hybrid faradaic-capacitive electrodes based on LVNP-AC active materials.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400117","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Corn Husk Derived Activated Carbon/Siloxene Composite Electrodes based Symmetric Supercapacitor with High Energy Density and Wide Temperature Tolerance 基于玉米芯衍生活性炭/硅氧烷复合电极的高能量密度和宽温度耐受性对称超级电容器

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-10 DOI: 10.1002/celc.202400230

Kiran Kumar Reddy Reddygunta, Prof. Lidija Šiller, Dr. Aruna Ivaturi

{"title":"Corn Husk Derived Activated Carbon/Siloxene Composite Electrodes based Symmetric Supercapacitor with High Energy Density and Wide Temperature Tolerance","authors":"Kiran Kumar Reddy Reddygunta, Prof. Lidija Šiller, Dr. Aruna Ivaturi","doi":"10.1002/celc.202400230","DOIUrl":"10.1002/celc.202400230","url":null,"abstract":"In the present work, novel composite material comprising of corn husk derived activated carbon and siloxene nanosheets have been explored as new class of multicomponent electrode material for fabricating high energy density supercapacitors with wide temperature tolerance. The activated carbon obtained from corn husk (ACH–900) with high surface area and pore volume acts as an ideal framework for hosting siloxene nanosheets (S) that allows the overall siloxene–corn husk derived activated carbon (ACH–900/S) composite to deliver excellent electrochemical performance. The as-prepared ACH–900/S composite electrode exhibited a high specific capacitance of 415 F g−1 at 0.25 A g−1 and retained 73.4 % of its initial capacitance even at a high current density of 30 A g−1 in 1 M Na2SO4 electrolyte. In addition, the symmetric supercapacitor assembled with “acetonitrile/water-in-salt (AWIS)” electrolyte exhibited an energy density of 57.2 W h kg−1 at 338 W kg−1 with a cyclic stability of 92.8 % after 10000 cycles at 5 A g−1 current density. Besides, the fabricated ACH–900/S supercapacitor can operate over wide temperature range from 0 to 100 °C. This work opens up new frontiers to develop low-cost safe supercapacitors with wide temperature tolerance and excellent electrochemical performance.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400230","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achieving Complete Conversion from Nickel Foam to Nickel Sulfide Foam for a Freestanding Hybrid-Supercapacitor Electrode 实现独立式混合超级电容器电极从镍泡沫到硫化镍泡沫的完全转换

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-09 DOI: 10.1002/celc.202400383

Xuerui Yi, Caroline Kirk, Neil Robertson

{"title":"Achieving Complete Conversion from Nickel Foam to Nickel Sulfide Foam for a Freestanding Hybrid-Supercapacitor Electrode","authors":"Xuerui Yi, Caroline Kirk, Neil Robertson","doi":"10.1002/celc.202400383","DOIUrl":"10.1002/celc.202400383","url":null,"abstract":"We present a unique, one-step, hydrothermal process to prepare nickel sulfide (Ni3S2) foam by a simple and direct conversion from nickel foam, which contributes both as a scaffold for the reaction and as reactant. The Ni3S2 foam exhibits remarkable mechanical stability, retaining the structural integrity of the foam and excellent crystallinity even after ultrasonication at 200 W for 30 mins. We document the transformation of the nickel foam template into a Ni3S2 foam, highlighting the role of synthesis duration on the phase evolution and unique morphology of Ni3S2. PXRD and SEM analyses reveal a complete transformation after 24 hours from the nickel foam to a pure Ni3S2 foam, which has a highly porous and interconnected ultra-thin nanosheet architecture. This significantly enhances the surface area and provides many electrochemical reaction sites. In a three-electrode cell, the capacity of the Ni3S2 foam electrode is 3.9 C cm−2 at 8 mA cm−2, which is higher than previous reports for Ni3S2. In a hybrid supercapacitor device, the Ni3S2 foam demonstrates significant increase in capacitance through 500 cycles and the capacitance plateaus after 2000 cycles. Even after 8500 continued charge-discharge cycles, the device exhibits excellent cycle stability indicating improvement with age.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400383","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Mg Doping on the Performance of LiNi0.9Co0.1O2 Cathode for Lithium-Ion Batteries 掺杂镁对锂离子电池中 LiNi0.9Co0.1O2 阴极性能的影响

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-06 DOI: 10.1002/celc.202400320

Yang Su, Hai-lin Ren, Li-Zhong Dong, Shuai Zhao, Xiao-min Wang, Jia-Qi Li

{"title":"Effect of Mg Doping on the Performance of LiNi0.9Co0.1O2 Cathode for Lithium-Ion Batteries","authors":"Yang Su, Hai-lin Ren, Li-Zhong Dong, Shuai Zhao, Xiao-min Wang, Jia-Qi Li","doi":"10.1002/celc.202400320","DOIUrl":"10.1002/celc.202400320","url":null,"abstract":"High-nickel cathode materials are widely used in lithium-ion batteries because of their advantages of high energy density and high safety. High-nickel cathode materials need to further improve cycling stability because they are prone to structural changes and capacity degradation. This paper proposes a method to improve high-nickel cathode materials by Mg doping. XRD proves that Mg-doped high-nickel materials still have R-3 m spatial structural characteristics; Rietveld refinement confirms that the c-axis gradually increases with the increase of Mg content. Combined with DFT calculations, the presence of Mg can inhibit structural collapse during charge and discharge, reduce Li/Ni antisite defects, improve the electronic conductivity of the material, and improve the cyclic stability of the material. The 0.6 mol % Mg-doped sample has an initial discharge capacity of 233 mAh g−1 at 0.1 C in the range of 2.7–4.3 V, a capacity retention rate of 91.0 % after 50 cycles at 1 C, still retains 79.9 % after 100 cycles. The dQ/dV curves further indicate that the presence of Mg improves the structural stability of the material.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400320","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thienyl-Bridged Fused Porphyrin Tapes for Enhanced Heterogeneous Electrocatalytic Activity 用于增强异质电催化活性的噻吩基桥接融合卟啉带

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-06 DOI: 10.1002/celc.202400258

Hadi Ghahramanzadehasl, Deepak Bansal, Drialys Cardenas Morcoso, Nicolas D. Boscher

引用次数: 0

Oxygen In The Mix: Is Oxic Microbial Electrosynthesis A Potential Alternative For Biomass Production? 混合中的氧气：氧微生物电合成是生物质生产的潜在替代方案吗？

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-06 DOI: 10.1002/celc.202400397

Johannes Eberhard Reiner, Benjamin Korth, Miriam Edel

{"title":"Oxygen In The Mix: Is Oxic Microbial Electrosynthesis A Potential Alternative For Biomass Production?","authors":"Johannes Eberhard Reiner, Benjamin Korth, Miriam Edel","doi":"10.1002/celc.202400397","DOIUrl":"10.1002/celc.202400397","url":null,"abstract":"Oxic microbial electrosynthesis (oMES) allows the utilization of renewable electricity and industrial gas streams containing CO2 and O2 for biomass production by cultivating aerobic, autotrophic, hydrogen-oxidizing bacteria, commonly known as Knallgas bacteria. oMES is likely not a direct competitor to conventional anoxic microbial electrosynthesis as harnessing aerobic hydrogen-oxidizing bacteria depends on energetically inefficient assimilatory CO2 reduction pathways. However, it might be a complementary approach to classical biomass production from the perspective of limited land use and the availability of cheap renewable energy. The best characterized Knallgas bacterium is Cupriavidus necator. Extensively studied as lithoautotrophic production host, C. necator already offers a broad arsenal of genetic tools. In contrast, mechanistical knowledge about the recently discovered Kyrpidia spormannii is limited, but this species shows remarkable growth when cultivated as cathodic biofilm in bioelectrochemical systems. In addition, first experiments indicate a low energy demand for biomass production, which is in the order of magnitude of gas fermentation with C. necator or heterotrophic and methanotrophic technologies. Still, many aspects of the electrochemical cultivation of K. spormannii need to be better understood and rigorously improved to be a competitive technology in the making, including electron transfer and microbial kinetics, cultivation conditions, mass and energy balances, and reactor design.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 20","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400397","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Impedance Spectroscopy of Lithium Intercalation into Cathode Materials in Coin Cells 硬币电池中锂离子与阴极材料互溶的阻抗光谱学

IF 3.5 4区化学

ChemElectroChem Pub Date : 2024-09-06 DOI: 10.1002/celc.202400390

Göktug Yesilbas, Daniel Grieve, David Rettmann, Kivanc Gülderen, Aliaksandr S. Bandarenka, Jeongsik Yun

{"title":"Impedance Spectroscopy of Lithium Intercalation into Cathode Materials in Coin Cells","authors":"Göktug Yesilbas, Daniel Grieve, David Rettmann, Kivanc Gülderen, Aliaksandr S. Bandarenka, Jeongsik Yun","doi":"10.1002/celc.202400390","DOIUrl":"10.1002/celc.202400390","url":null,"abstract":"Understanding the internal reactions in Li-ion batteries is crucial to analyze them more accurately and improve their efficiency since they are involved in almost every aspect of everyday life. Electrochemical impedance spectroscopy is a valuable research technique to investigate such batteries, as it reveals sensitive properties and essential information about cell reaction mechanisms and kinetics. Physical understanding of the electrochemical process and system of a battery can be analyzed using equivalent electric circuits (EECs) with rational selection of electric circuit elements and their combination. However, impedance analysis of a battery is often conducted using oversimplified EEC models in practice due to the complexity and difficulty of the physics and mathematics of the modeling. This study proposes and verifies an EEC model that represents a three-stage mechanism for intercalation-type materials. For the systematic model study and verifications, we investigated cathode half cells using four different layered structured cathode materials, namely, LiCoO2, LiNi1/3Mn1/3Co1/3O2, LiNi0.9Mn0.05Co0.05O2, and Ni0.815Co0.15Al0.035O2. Parametric analysis of the impedance fittings for the four different cathode materials showed similar behavior depending on the states of charge. We also provided the complete set of parameters of the four systems: charge transfer resistance, double-layer capacitance, and solid-electrolyte interphase (SEI) resistance and capacitance. Lastly, we explain how different electrochemical processes, such as intercalation and alloying, can be analyzed and modeled in EEC models.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 19","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202400390","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0