International Journal of Materials Research最新文献

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Structure, dielectric and magnetic properties of hydrothermally synthesized Sn1−x Fe x O2 nanoparticles 水热合成 Sn1-x Fe x O2 纳米粒子的结构、介电和磁性能
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-29 DOI: 10.1515/ijmr-2022-0458
S. Saleh, Ihab A. Abdel Latif, A. A. Ibrahim, A. Al-Hajry, E. Ibrahim
{"title":"Structure, dielectric and magnetic properties of hydrothermally synthesized Sn1−x\u0000 Fe\u0000 x\u0000 O2 nanoparticles","authors":"S. Saleh, Ihab A. Abdel Latif, A. A. Ibrahim, A. Al-Hajry, E. Ibrahim","doi":"10.1515/ijmr-2022-0458","DOIUrl":"https://doi.org/10.1515/ijmr-2022-0458","url":null,"abstract":"\u0000 Sn1−x\u0000 Fe\u0000 x\u0000 O2 (x = 0, 1, 2, 3, and 4 %) of the diamagnetic/ferromagnetic phase were synthesized by the conventional hydrothermal method. X-ray diffraction spectra confirm that all the samples have a tetragonal structure. Electronic distribution over the unit cell of Sn1−x\u0000 Fe\u0000 x\u0000 O2 showed the dependence of electronic density on the x. The crystallite size of the obtained samples was in the range of 42–72 nm. Impedance spectroscopy was employed to investigate the variation of the electrical impedance and some related parameters as frequency functions in the range of 75 k Hz–10 MHz at room temperature. The dielectric behavior was explained using the Maxwell–Wagner model of interfacial polarization. The ac conductivity results were used to evaluate the maximum barrier height, the minimum hopping distance, and the density of the localized states at the Fermi level. The effect of adding the iron ion into the tin dioxide compound was apparent, as the electrical and magnetic properties as well as the morphology were affected, although the crystal structure phase still has the same tetragonal crystal system for the different iron concentration (Fe from x = 0 up to x = 0.04) with slight variation in the lattice constants. The magnetic measurements illustrated that the Fe-doped SnO2 nanoparticles exhibit ferromagnetic ordering at room temperature. Variation of the Fe content affects the ferromagnetic characteristics of the samples.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140408647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential of multifunctional electrospun nanofibers in cancer management 多功能电纺纳米纤维在癌症治疗中的潜力
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-29 DOI: 10.1515/ijmr-2023-0125
Abduladheem AL-Attabi, Mohanad Ali Abdulhadi, Lubna R. Al-Ameer, Mohammed Dohan Naeem Hussein, SadaJasim Abdulameer, R. Zabibah, A. Fadhil
{"title":"Potential of multifunctional electrospun nanofibers in cancer management","authors":"Abduladheem AL-Attabi, Mohanad Ali Abdulhadi, Lubna R. Al-Ameer, Mohammed Dohan Naeem Hussein, SadaJasim Abdulameer, R. Zabibah, A. Fadhil","doi":"10.1515/ijmr-2023-0125","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0125","url":null,"abstract":"\u0000 A controlled and sustained release of drugs is much more desirable and beneficial when dealing with cancer, as such drugs also harm normal cells. Available anticancer drugs used in chemotherapy are associated with severe side effects due to high dosage requirements. Electrospun nanofibers have an extensive surface area, controllable pore size, and tunable drug release profiles, which make these nanofibers promising candidates in the medical field. Electrospun fibrous matrices are increasingly used in cancer research as patches for drug delivery in living organisms and as scaffolds for cancer modeling in the lab. Towards these applications, nanofibers synthesized by electrospinning have exhibited great clinical potential as a biomimetic tumor microenvironment model for drug screening, a controllable platform for localized, prolonged drug release for cancer therapy, and a human cancer diagnostic tool for capture and isolation of circulating tumor cells in the bloodstream and detection of cancer-associated biomarkers. This review briefly describes most of the materials used in electrospinning. Then, we discuss two ways that electrospinning is used to fight cancer: first, as patches with anticancer agents for therapeutic cargo delivery, and second, as three-dimensional fiber for filtering and detecting cancers.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140413012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Memoriam Prof. Günter Petzow 悼念冈特-彼得佐夫教授
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-29 DOI: 10.1515/ijmr-2024-3003
{"title":"In Memoriam Prof. Günter Petzow","authors":"","doi":"10.1515/ijmr-2024-3003","DOIUrl":"https://doi.org/10.1515/ijmr-2024-3003","url":null,"abstract":"","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140411678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of graphene concentration on the properties of the composite prepared with poly(2-ethyl aniline) by mechanochemical method 石墨烯浓度对机械化学法制备的聚(2-乙基苯胺)复合材料性能的影响
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-28 DOI: 10.1515/ijmr-2023-0098
Duygu Anaklı
{"title":"Influence of graphene concentration on the properties of the composite prepared with poly(2-ethyl aniline) by mechanochemical method","authors":"Duygu Anaklı","doi":"10.1515/ijmr-2023-0098","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0098","url":null,"abstract":"\u0000 In this study, poly(2-ethyl aniline)/graphene composites were prepared by a mechanochemical method, through in-situ polymerization of 2-ethyl aniline in the presence of graphene at different concentrations. Vickers microhardness, elastic modulus and electrical conductivity measurements were carried out as a function of the graphene concentration in the composite. Increasing the graphene content of the composite resulted in an increase in the conjugation length and carrier mobility of the polymer, and thus in the electrical conductivity of the composites. However, thermogravimetric analysis showed that the thermal stability of poly(2-ethyl aniline) increased with increasing graphene concentration. This study suggests the potential of graphene concentration to efficiently modify the morphological, electrical, mechanical, and thermal properties of poly(2-ethyl aniline).","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140418293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly palm oil directed synthesis of mesoporous titania for photocatalytic application 生态友好型棕榈油定向合成用于光催化应用的介孔二氧化钛
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-28 DOI: 10.1515/ijmr-2022-0403
Preethi Thangaraj, Abarna Balachandran, Rajarajeswari G. Ramamurthy
{"title":"Eco-friendly palm oil directed synthesis of mesoporous titania for photocatalytic application","authors":"Preethi Thangaraj, Abarna Balachandran, Rajarajeswari G. Ramamurthy","doi":"10.1515/ijmr-2022-0403","DOIUrl":"https://doi.org/10.1515/ijmr-2022-0403","url":null,"abstract":"\u0000 Utilisation of templates facilitates the synthesis of titania samples with improved physico-chemical properties. When biomaterials are utilised as templates in the creation of inorganic materials, they can lead to constructed mesostructures via cost-effective and environmentally friendly synthetic pathways. Based on this context, the goal of this study was to assess the impact of palm oil on the surface properties and crystallite characteristics of titania nanoparticles. In this work, the various physico-chemical parameters such as thermal, surface area, porosity, crystallinity, chemical composition, textural and morphological characteristics of the palm oil (PO) templated titania were studied using various analysis techniques. Palm oil templated titania samples were synthesised using various amounts of palm oil as templates. The sample generated with a molar ratio of PO over titania precursor of 0.07 possessed large surface area (74.5 m2 g−1), small particle size (13.4 nm), uniformly dispersed spherical particles with good morphology and porosity among the various templated titania produced in this work. In addition, it was found to possess maximum photocatalytic efficiency in degrading the target 4-chlorophenol under UV irradiation.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140419946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strontium and copper co-doped nanohydroxyapatite for bone augmentation 用于骨质增生的锶和铜共掺纳米羟基磷灰石
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-26 DOI: 10.1515/ijmr-2023-0089
Shivani Sathyanarayanan, S. Kannan
{"title":"Strontium and copper co-doped nanohydroxyapatite for bone augmentation","authors":"Shivani Sathyanarayanan, S. Kannan","doi":"10.1515/ijmr-2023-0089","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0089","url":null,"abstract":"\u0000 Bone disorders and conditions have been increasing at an alarming rate all over the world, especially in niches where increased obesity and poor physical activity have been prevailing. Synthetic nanohydroxyapatite (HAp) is one of the remedies to reconstruct bone formation. Its rate of dissolution and compatibility is in the moderately acceptable range. The doping of HAp with bone-forming ions can make them highly biologically compatible materials. In the present work, we formulated HAp doped with essential micronutrients of strontium and copper. Nanoglobular Sr and Cu doped HAp (SC-HAp) with an average size of 30 nm was prepared. The SC-HAp was partially crystalline and amorphous, which could influence the dissolution rate of the material. The biomineralization ability of the SC-HAp seemed to be effective in apatite formation. The calcium, collagen and alkaline phosphatase secretion levels after the addition of SC-HAp on MG63 cells indicate the bone-forming capacity of the material. Further, the cell proliferation rate was enhanced compared to the control with SC-HAp.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140428451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of hydroxyapatite matrix Ag and CNT particle reinforced hybrid biocomposites with improved mechanical and antibacterial properties 合成具有更好机械性能和抗菌性能的羟基磷灰石基质银和 CNT 粒子增强混合生物复合材料
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-14 DOI: 10.1515/ijmr-2023-0120
Serdar Özkaya, A. Çanakçı, A. H. Karabacak, Müslim Çelebi, Sabriye Canakcı, Esma Ceylan
{"title":"Synthesis of hydroxyapatite matrix Ag and CNT particle reinforced hybrid biocomposites with improved mechanical and antibacterial properties","authors":"Serdar Özkaya, A. Çanakçı, A. H. Karabacak, Müslim Çelebi, Sabriye Canakcı, Esma Ceylan","doi":"10.1515/ijmr-2023-0120","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0120","url":null,"abstract":"\u0000 Hydroxyapatite is an important biomaterial for orthopaedic applications due to its high structural similarity to human bone. However, weak mechanical and antibacterial properties limit the use of hydroxyapatite compared to metallic implants such as Ti and 316L alloys for direct use in the human skeleton. To overcome these shortcomings, we have prepared hydroxyapatite matrix silver and carbon nanotube reinforced biocomposites. Silver particles have beneficial effects on biomaterials due to their effective antibacterial activity. In addition, CNT particles are known for their high strength and their ability to improve the mechanical properties of composite materials. To prepare the hydroxyapatite-based composites, the powder blends with different reinforcement types (Ag, CNT) and ratios were ground using a planetary ball mill. The biocomposite powders were then cold pressed under 500 MPa pressure to obtain green samples. The sintering process was carried out at 1200 °C for 4 h. The microstructural and structural investigations were carried out by scanning electron microscopy and X-ray diffraction, respectively. In order to better evaluate the mechanical properties of the samples, hardness measurements, compression and fracture tests were carried out. Antibacterial tests were also carried out against various micro-organisms. Both types of reinforcement were found to be effective in improving the mechanical properties. In addition, it was observed that CNT reinforcement slightly increased the antibacterial resistance, but silver-reinforced samples provided excellent antibacterial resistance.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139839008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of hydroxyapatite matrix Ag and CNT particle reinforced hybrid biocomposites with improved mechanical and antibacterial properties 合成具有更好机械性能和抗菌性能的羟基磷灰石基质银和 CNT 粒子增强混合生物复合材料
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-14 DOI: 10.1515/ijmr-2023-0120
Serdar Özkaya, A. Çanakçı, A. H. Karabacak, Müslim Çelebi, Sabriye Canakcı, Esma Ceylan
{"title":"Synthesis of hydroxyapatite matrix Ag and CNT particle reinforced hybrid biocomposites with improved mechanical and antibacterial properties","authors":"Serdar Özkaya, A. Çanakçı, A. H. Karabacak, Müslim Çelebi, Sabriye Canakcı, Esma Ceylan","doi":"10.1515/ijmr-2023-0120","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0120","url":null,"abstract":"\u0000 Hydroxyapatite is an important biomaterial for orthopaedic applications due to its high structural similarity to human bone. However, weak mechanical and antibacterial properties limit the use of hydroxyapatite compared to metallic implants such as Ti and 316L alloys for direct use in the human skeleton. To overcome these shortcomings, we have prepared hydroxyapatite matrix silver and carbon nanotube reinforced biocomposites. Silver particles have beneficial effects on biomaterials due to their effective antibacterial activity. In addition, CNT particles are known for their high strength and their ability to improve the mechanical properties of composite materials. To prepare the hydroxyapatite-based composites, the powder blends with different reinforcement types (Ag, CNT) and ratios were ground using a planetary ball mill. The biocomposite powders were then cold pressed under 500 MPa pressure to obtain green samples. The sintering process was carried out at 1200 °C for 4 h. The microstructural and structural investigations were carried out by scanning electron microscopy and X-ray diffraction, respectively. In order to better evaluate the mechanical properties of the samples, hardness measurements, compression and fracture tests were carried out. Antibacterial tests were also carried out against various micro-organisms. Both types of reinforcement were found to be effective in improving the mechanical properties. In addition, it was observed that CNT reinforcement slightly increased the antibacterial resistance, but silver-reinforced samples provided excellent antibacterial resistance.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139779124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Special issue in memory of Prof. Wolfgang Gust 纪念沃尔夫冈-古斯特教授特刊
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-01 DOI: 10.1515/ijmr-2024-3002
{"title":"Special issue in memory of Prof. Wolfgang Gust","authors":"","doi":"10.1515/ijmr-2024-3002","DOIUrl":"https://doi.org/10.1515/ijmr-2024-3002","url":null,"abstract":"","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139687423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic modelling application for prediction of diffusion formation of supersaturation solution 热力学模型在预测过饱和溶液扩散形成中的应用
IF 0.8 4区 材料科学
International Journal of Materials Research Pub Date : 2024-02-01 DOI: 10.1515/ijmr-2023-0234
Alexey Rodin, Bright Mween, Alexandra Khvan, Tatiana Lepkova, Natali Goreslavetz
{"title":"Thermodynamic modelling application for prediction of diffusion formation of supersaturation solution","authors":"Alexey Rodin, Bright Mween, Alexandra Khvan, Tatiana Lepkova, Natali Goreslavetz","doi":"10.1515/ijmr-2023-0234","DOIUrl":"https://doi.org/10.1515/ijmr-2023-0234","url":null,"abstract":"\u0000 In this paper the effect of diffusion formation of supersaturated solid solution in the Al–Ge system is discussed. It was shown that at relatively low temperatures of diffusion annealing, Ge concentration in Al-based solid solution became higher than the solubility limit at given temperatures. The maximal concentration of Ge was determined by extrapolation of the diffusion profile on the Ge/Al interface. Analysis of diffusivity of Al in Ge allowed to suggest that slow diffusion in Ge restricts the formation of Ge-based solid solution. Qualitative approach confirmed this suggestion.","PeriodicalId":14079,"journal":{"name":"International Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":0.8,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139813896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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