International Journal of Chemical Kinetics最新文献

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Macrokinetics of ammonium sulfite oxidation inhibited by sodium thiosulfate in wet ammonium flue gas desulfurization 硫代硫酸钠抑制亚硫酸铵湿铵烟气脱硫的宏观动力学研究
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-10-18 DOI: 10.1002/kin.21764
Jian Peng, Wen Yao, Peichao Lian
{"title":"Macrokinetics of ammonium sulfite oxidation inhibited by sodium thiosulfate in wet ammonium flue gas desulfurization","authors":"Jian Peng,&nbsp;Wen Yao,&nbsp;Peichao Lian","doi":"10.1002/kin.21764","DOIUrl":"https://doi.org/10.1002/kin.21764","url":null,"abstract":"<p>The oxidation of ammonium sulfite must be inhibited to improve the economy and cycle performance of the ammonia flue gas desulfurization process. A stirred bubbling reactor was used to investigate the macrokinetics of oxidation inhibition of ammonium sulfite by sodium thiosulfate in wet ammonia desulfurization. The effects of initial <span></span><math>\u0000 <semantics>\u0000 <msubsup>\u0000 <mi>SO</mi>\u0000 <mn>3</mn>\u0000 <mrow>\u0000 <mn>2</mn>\u0000 <mo>−</mo>\u0000 </mrow>\u0000 </msubsup>\u0000 <annotation>${rm SO}^{2-}_{3}$</annotation>\u0000 </semantics></math> concentration, Na<sub>2</sub>S<sub>2</sub>O<sub>3</sub> concentration, pH value, gas flow rate, and temperature on the oxidation rate were discussed. The results show that the apparent activation energy of the reaction is 37.3 kJ/mol. The macrokinetics equation of sodium thiosulfate inhibiting sulfite oxidation in the ammonia desulfurization process was established. Combined with the kinetic model, it is inferred that the rate of sodium thiosulfate inhibiting ammonium sulfite oxidation is controlled by the intrinsic chemical reaction. The results can provide a reference for the regeneration of ammonium sulfite in the wet ammonia desulfurization process.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 2","pages":"117-124"},"PeriodicalIF":1.5,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143116437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Atmospheric chemistry of (Z)-CF2HCF=CHCl: Kinetics and products of reaction with Cl atoms and OH radicals (Z)-CF2HCF=CHCl的大气化学:与Cl原子和OH自由基反应的动力学和产物
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-10-07 DOI: 10.1002/kin.21763
Mads Peter Sulbaek Andersen, Josefine Ellerup Borcher, Ole John Nielsen
{"title":"Atmospheric chemistry of (Z)-CF2HCF=CHCl: Kinetics and products of reaction with Cl atoms and OH radicals","authors":"Mads Peter Sulbaek Andersen,&nbsp;Josefine Ellerup Borcher,&nbsp;Ole John Nielsen","doi":"10.1002/kin.21763","DOIUrl":"https://doi.org/10.1002/kin.21763","url":null,"abstract":"<p>Long path length FTIR-smog chamber techniques were used to study the title reactions in 650 Torr of N<sub>2</sub>, oxygen, or air diluent at 296 ± 3 K. Values of <i>k</i>(Cl + (<i>Z</i>)-CF<sub>2</sub>HCF = CHCl)═(6.6 ± 0.7) × 10<sup>−11</sup> and <i>k</i>(OH + (<i>Z</i>)-CF<sub>2</sub>HCF═CHCl)═(4.1 ± 0.7) × 10<sup>−12</sup> cm<sup>3</sup> molecule<sup>−1</sup> s<sup>−1</sup> were measured. The IR spectrum of (<i>Z</i>)-CF<sub>2</sub>HCF═CHCl is reported. The atmospheric lifetime of (<i>Z</i>)-CF<sub>2</sub>HCF═CHCl is determined by the reaction with OH and is approximately 2.8 days. Reaction of (<i>Z</i>)-CF<sub>2</sub>HCF═CHCl with Cl atoms gives HC(O)Cl and CF<sub>2</sub>HC(O)F as major primary products. Under environmental conditions, the OH radical initiated oxidation gives CF<sub>2</sub>HC(O)F and HC(O)Cl in yields of (98 ± 8)% and (100 ± 4)%, respectively. Accounting for non-uniform horizontal and vertical mixing leads to a 100-year time-horizon global warming potential value for (<i>Z</i>)-CF<sub>2</sub>HCF═CHCl of essentially zero.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 2","pages":"108-116"},"PeriodicalIF":1.5,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21763","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143113229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Species selection for automatic chemical kinetic mechanism generation 自动化学动力学机制生成的物种选择
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-09-24 DOI: 10.1002/kin.21762
Matthew S. Johnson, Hao-Wei Pang, Mengjie Liu, William H. Green
{"title":"Species selection for automatic chemical kinetic mechanism generation","authors":"Matthew S. Johnson,&nbsp;Hao-Wei Pang,&nbsp;Mengjie Liu,&nbsp;William H. Green","doi":"10.1002/kin.21762","DOIUrl":"https://doi.org/10.1002/kin.21762","url":null,"abstract":"<p>Many important chemical kinetic systems require detailed chemical kinetic models to resolve. These detailed kinetic models can involve thousands of species and hundreds of thousands of chemical reactions, making them difficult to construct by hand. Modern automatic mechanism generation algorithms can mostly be divided into two classes: rule and rate based. Rule-based generators choose species based on user defined constraints on species and reaction classes. Rate-based generators generate a much larger set of potentially important species and reactions and then choose which ones to add based on running simulations of species and reactions deemed important and calculating the flux to potentially important species. In principle, the latter is preferable, as it requires the user to make far fewer assumptions about what is important in the system. However, while the effectiveness of the rate-based approach has been demonstrated in a wide variety of systems, it has also been demonstrated to have difficulty picking up important low-flux chemistries. Here we present a discussion of the challenges associated with rate-based mechanism generation and new algorithms that are able to efficiently mitigate these challenges improving species selection during mechanism generation in a set of case studies.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 2","pages":"93-107"},"PeriodicalIF":1.5,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21762","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143118913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decomposition of CH 3 NH 2 ${rm CH}_3{rm NH}_2$ : Implications for CH x / NH y ${rm CH}_{rm {it x}}/{rm NH}_{rm {it y}}$ radical–radical reactions CH 3 NH 2 ${rm CH}_3{rm NH}_2$ 的分解:对 CH x / NH y ${rm CH}_{rm {it x}}/{rm NH}_{rm {it y}}$ 自由基-自由基反应的影响
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-09-19 DOI: 10.1002/kin.21760
Peter Glarborg, Maria U. Alzueta
{"title":"Decomposition of \u0000 \u0000 \u0000 \u0000 CH\u0000 3\u0000 \u0000 \u0000 NH\u0000 2\u0000 \u0000 \u0000 ${rm CH}_3{rm NH}_2$\u0000 : Implications for \u0000 \u0000 \u0000 \u0000 CH\u0000 x\u0000 \u0000 /\u0000 \u0000 NH\u0000 y\u0000 \u0000 \u0000 ${rm CH}_{rm {it x}}/{rm NH}_{rm {it y}}$\u0000 radical–radical reactions","authors":"Peter Glarborg,&nbsp;Maria U. Alzueta","doi":"10.1002/kin.21760","DOIUrl":"https://doi.org/10.1002/kin.21760","url":null,"abstract":"&lt;p&gt;Experiments on methylamine (&lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;CH&lt;/mi&gt;\u0000 &lt;mn&gt;3&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;NH&lt;/mi&gt;\u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;annotation&gt;${rm CH}_3{rm NH}_2$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt;) decomposition in shock tubes, flow reactors, and batch reactors have been re-examined to improve the understanding of hydrocarbon/amine interactions and constrain rate constants for &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;CH&lt;/mi&gt;\u0000 &lt;mi&gt;x&lt;/mi&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm CH}_{ x}$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; + &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;NH&lt;/mi&gt;\u0000 &lt;mi&gt;y&lt;/mi&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm NH}_{ y}$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; reactions. In high-temperature shock tube experiments, the rapid thermal dissociation of &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;CH&lt;/mi&gt;\u0000 &lt;mn&gt;3&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;NH&lt;/mi&gt;\u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;/mrow&gt;\u0000 &lt;annotation&gt;${rm CH}_3{rm NH}_2$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; provides a fairly clean source of &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;CH&lt;/mi&gt;\u0000 &lt;mn&gt;3&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm CH}_3$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; and &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;NH&lt;/mi&gt;\u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm NH}_2$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; radicals, allowing an assessment of reactions of &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;CH&lt;/mi&gt;\u0000 &lt;mn&gt;3&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm CH}_3$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; with &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;msub&gt;\u0000 &lt;mi&gt;NH&lt;/mi&gt;\u0000 &lt;mn&gt;2&lt;/mn&gt;\u0000 &lt;/msub&gt;\u0000 &lt;annotation&gt;${rm NH}_2$&lt;/annotation&gt;\u0000 &lt;/semantics&gt;&lt;/math&gt; and NH. At the lower temperatures in batch and flow reactors, &lt;span&gt;&lt;/span&gt;&lt;math&gt;\u0000 &lt;semantics&gt;\u0000 &lt;mrow&gt;\u0000 &lt;msub&gt;\u0000 ","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 1","pages":"77-90"},"PeriodicalIF":1.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21760","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142707853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Force training neural network potential energy surface models 力训练神经网络势能面模型
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-09-06 DOI: 10.1002/kin.21759
Christian Devereux, Yoona Yang, Carles Martí, Judit Zádor, Michael S. Eldred, Habib N. Najm
{"title":"Force training neural network potential energy surface models","authors":"Christian Devereux,&nbsp;Yoona Yang,&nbsp;Carles Martí,&nbsp;Judit Zádor,&nbsp;Michael S. Eldred,&nbsp;Habib N. Najm","doi":"10.1002/kin.21759","DOIUrl":"10.1002/kin.21759","url":null,"abstract":"<p>Machine learned chemical potentials have shown great promise as alternatives to conventional computational chemistry methods to represent the potential energy of a given atomic or molecular system as a function of its geometry. However, such potentials are only as good as the data they are trained on, and building a comprehensive training set can be a costly process. Therefore, it is important to extract as much information from training data as possible without further increasing the computational cost. One way to accomplish this is by training on molecular forces in addition to energies. This allows for three additional labels per atom within the molecule. Here we develop a neural network potential energy surface for studying a hydrogen transfer reaction between two isomers of <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>C</mi>\u0000 <mn>5</mn>\u0000 </msub>\u0000 <msub>\u0000 <mi>H</mi>\u0000 <mn>5</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation>${mathrm{C}}_5{mathrm{H}}_5$</annotation>\u0000 </semantics></math>. We show that, for a much smaller training set, force training not only improves the accuracy of the model compared to only training on energies, but also provides more accurate and smoother first and second derivatives that are crucial to run dynamics and extract vibrational frequencies in the context of transition-state theory. We also demonstrate the importance of choosing the proper force to energy weight ratio for the loss function to minimize the model test error.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 1","pages":"59-76"},"PeriodicalIF":1.5,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Folic acid as a green inhibitor for corrosion protection of Q235 carbon steel in 3.5 wt% NaCl solution 叶酸作为绿色缓蚀剂在 3.5 wt% 氯化钠溶液中保护 Q235 碳钢
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-07-31 DOI: 10.1002/kin.21758
Peng Han, Zebang Liu, Zhichao Ren, Yue Li, Zhenwei Sun, Chenyang Xu
{"title":"Folic acid as a green inhibitor for corrosion protection of Q235 carbon steel in 3.5 wt% NaCl solution","authors":"Peng Han,&nbsp;Zebang Liu,&nbsp;Zhichao Ren,&nbsp;Yue Li,&nbsp;Zhenwei Sun,&nbsp;Chenyang Xu","doi":"10.1002/kin.21758","DOIUrl":"10.1002/kin.21758","url":null,"abstract":"<p>This study combines experimental and theoretical explorations. The corrosion inhibition performance of different concentrations (50, 100, 250, and 500 ppm) of folic acid in 3.5 wt% NaCl solution on Q235 steel was tested by weight loss and electrochemical test. The corrosion inhibition efficiency increased with the gradual increase of folic acid concentration and reached a maximum of 87% at 500 ppm folic acid. The experimental results for electrochemistry and weight loss are in good agreement with the simulation calculations. The adsorption of folic acid on the steel surface obeyed the Langmuir isotherm, and the adsorption process was a combination of chemisorption and physisorption. The contact angle test also yielded the maximum increase in hydrophobicity of the specimen surface at the added folic acid concentration of 500 ppm. The corrosion morphology after the addition of corrosion inhibitor was relatively flat. The adsorption orientation of folic acid molecules on the steel surface in an aqueous environment was investigated using density functional theory (DFT)/molecular dynamics (MD) simulations. The microscopic mechanism of action of folic acid corrosion inhibitors is clarified.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 1","pages":"40-58"},"PeriodicalIF":1.5,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141871282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Remembrance of Prof Dr Horst Hippler 纪念霍斯特-希普勒教授博士
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-07-18 DOI: 10.1002/kin.21748
Hartmut Herrmann, Craig Taatjes, Jeff Manion
{"title":"Remembrance of Prof Dr Horst Hippler","authors":"Hartmut Herrmann,&nbsp;Craig Taatjes,&nbsp;Jeff Manion","doi":"10.1002/kin.21748","DOIUrl":"10.1002/kin.21748","url":null,"abstract":"","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 12","pages":"689-690"},"PeriodicalIF":1.5,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141740416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Remediation of cationic dye from wastewater using a new environmentally friendly adsorbent: A response surface methodology and artificial neural network modeling study 使用新型环保吸附剂修复废水中的阳离子染料:响应面方法和人工神经网络建模研究
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-07-12 DOI: 10.1002/kin.21756
Samiya Telli, Houria Ghodbane, Aissa Laouissi, Meriem Zamouche, Yassine Kadmi
{"title":"Remediation of cationic dye from wastewater using a new environmentally friendly adsorbent: A response surface methodology and artificial neural network modeling study","authors":"Samiya Telli,&nbsp;Houria Ghodbane,&nbsp;Aissa Laouissi,&nbsp;Meriem Zamouche,&nbsp;Yassine Kadmi","doi":"10.1002/kin.21756","DOIUrl":"10.1002/kin.21756","url":null,"abstract":"<p>In the current report, both response surface methodology (RSM) and artificial neural network (ANN) were employed to develop an innovative way for removing crystal violet (CV) from aqueous media using <i>Haloxylon salicornicum</i> (HS) as a cost-effective, eco-friendly adsorbent. HS was characterized using scanning electron microscopy (SEM) and Fourier-transform infrared (FTIR) spectroscopy. The effects of operational parameters such as adsorbent dosage, initial dye concentration, and pH on HS were studied using a central composite design (CCD). A comparative analysis of the model findings and experimental measurements revealed high correlation coefficients (R2ANN = 0.994, R2RSM = 0.971), indicating both models accurately predicted HS. The predictive performance of the ANN and RSM models was evaluated using metrics such as mean absolute deviation (MAD), mean absolute percentage error (MAPE), root mean square error (RMSE), mean square error (MSE), and the correlation coefficient (<i>R</i><sup>2</sup>). The results indicate that the ANN model provides greater accuracy compared to the RSM model. The experimental data were analyzed using both linear and nonlinear forms of pseudo-first and pseudo-second order kinetic models (LPFO, NLPFO, LPSO, and NLPSO). Statistical error analysis was conducted to identify the best-fitting kinetic or isotherm models for the adsorption data. The adsorption process of CV/HS was best described by NLPSO and LPSO. Additionally, the adsorption isotherms were analyzed using linear and nonlinear regression methods. The findings indicated that the linear Langmuir and Freundlich isotherms provided a more accurate fit compared to the nonlinear models, demonstrating greater effectiveness in accounting for the adsorption parameters. Thermodynamic investigations clearly demonstrate that the biosorption of CV is spontaneous and exothermic. This cost-effective adsorbent is highly promising for treating textile wastewater.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"57 1","pages":"16-39"},"PeriodicalIF":1.5,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to “Rate constants and conversion ratios for aqueous-phase reactions of SO4− with CnF2n+1C(O)O− (n = 4–7) at 298 K” 对 "298 K 时 SO4- 与 CnF2n+1C(O)O- (n = 4-7)水相反应的速率常数和转化率 "的更正
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-07-10 DOI: 10.1002/kin.21757
Shuzo Kutsuna, Kazuhide Koike, Hisao Hori
{"title":"Erratum to “Rate constants and conversion ratios for aqueous-phase reactions of SO4− with CnF2n+1C(O)O− (n = 4–7) at 298 K”","authors":"Shuzo Kutsuna,&nbsp;Kazuhide Koike,&nbsp;Hisao Hori","doi":"10.1002/kin.21757","DOIUrl":"10.1002/kin.21757","url":null,"abstract":"<p>In the original article published in 2009, Equation (3) after correction was used to determine values of <i>β<sub>n</sub></i>; hence, there are no corrections to values of <i>β<sub>n</sub></i> in Table V.</p><p>We apologize for this error.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"56 9","pages":"568"},"PeriodicalIF":1.5,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21757","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141588482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Theoretical study on gas-phase reactions during chemical vapor deposition of TixAl1–xN from TiCl4, AlCl3, and NH3 关于 TiCl4、AlCl3 和 NH3 化学气相沉积 TixAl1-xN 过程中气相反应的理论研究
IF 1.5 4区 化学
International Journal of Chemical Kinetics Pub Date : 2024-07-09 DOI: 10.1002/kin.21750
Noboru Sato, Jun Yamaguchi, Masahiro Koto, Hayato Kubo, Takanori Sugiyama, Takahito Tanibuchi, Momoko Deura, Takeshi Momose, Yukihiro Shimogaki
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