International Journal of Chemical Kinetics最新文献

{"title":"A Green and QbD-Optimized Rp-Hplc Method for Simultaneous Estimation of Linagliptin and Dapagliflozin","authors":"Sourabh Satapathy,&nbsp;Kuladip barman,&nbsp;Shivam Kumar,&nbsp;Neha Singh,&nbsp;Balak Das Kurmi,&nbsp;Preeti Patel","doi":"10.1002/kin.70032","DOIUrl":"https://doi.org/10.1002/kin.70032","url":null,"abstract":"<div>\u0000 \u0000 <p>The present study focuses on the development and optimization of a robust reversed-phase high-performance liquid chromatography (RP-HPLC) method for the simultaneous estimation of linagliptin and dapagliflozin in bulk and tablet dosage forms. A Quality by Design (QbD) approach was employed using the Box-Behnken design to systematically optimize critical chromatographic parameters, ensuring efficient separation with high sensitivity and reproducibility. The optimized conditions utilized a mobile phase of methanol: acetonitrile: buffer: triethylamine (80:10:10:0.1 v/v/v/v), with a pH adjusted to 5.0 using orthophosphoric acid and a flow rate of 1.0 mL/min. The method demonstrated excellent linearity (r² &gt; 0.998), precision (%RSD &lt; 2), and accuracy (98.9%–100.5%), complying with ICH guidelines. Additionally, a greenness evaluation was conducted using the AGREE analytical greenness metric tool, giving a score of 0.68, indicating an environmentally sustainable analytical approach. The developed method is rapid, reliable, and suitable for routine quality control analysis of linagliptin and dapagliflozin in pharmaceutical formulations.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"179-190"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147569969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kinetic Study of the Effect of C6H5-COONa as Corrosion Inhibitor on Concrete Properties","authors":"Latefa Sail,&nbsp;Bachir Boudjema","doi":"10.1002/kin.70037","DOIUrl":"https://doi.org/10.1002/kin.70037","url":null,"abstract":"<div>\u0000 \u0000 <p>This study tends to examine the use of sodium benzoate “C₆H₅-COONa” as a corrosion inhibitor added to the mixing water of concrete contaminated by chlorides, and test the mechanical performances of five types of concrete samples over several time periods, 7, 28, 56, and 90 days, in the absence and in the presence of limestone fillers and superplasticizing. Hence, the results confirm that the addition of “C₆H₅-COONa” increases the compressive resistance by 11.75%, 0.42%, 14.66%, and 20.63% comparing with the reference sample for the cited time periods, respectively. Also, the integration of limestone and superplasticizing significantly improves this resistance by 31.64%, 12.06%, 22.92%, and 21.88% respectively for 7, 28, 56, and 90 days. Tests were carried out on cement paste after the addition of sodium benzoate, results show that the start and the end setting time of cement shift out by 15.15% and 9.67% compared with reference cement. More than, after the addition of sodium benzoate and limestone fillers, the results indicate an increase in these parameters by 8.25% and 6.39% compared with reference cement, which indicates that sodium benzoate delays the start and end setting time of cement. In addition, Abrams cone slump tests were performed on fresh concrete for the different compositions in the absence and presence of superplasticizing “ORAFLOW THM 17200”. These results confirm that the addition of sodium benzoate to concrete does not negatively affect its properties in fresh or hard state, and then it can be used as a corrosion inhibitor for its reinforcements.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"219-229"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147565529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Antibacterial and Antibiofilm Potential of Two Palm Species (Syagrus romanzoffiana and Bismarckia nobilis, Arecaceae) against Drug-Resistant Escherichia coli and Bacillus subtilis","authors":"Fatima Riaz,&nbsp;Abdul Qadir Ahmad,&nbsp;Muhammad Junaid,&nbsp;Zubaria Ashraf,&nbsp; Umm-e-Habiba,&nbsp;Muhammad Amjad Riaz,&nbsp;Muhammad Hassnain,&nbsp;Muhammad Adil Karamat,&nbsp;Khalid Bilal","doi":"10.1002/kin.70034","DOIUrl":"https://doi.org/10.1002/kin.70034","url":null,"abstract":"<div>\u0000 \u0000 <p>The pathogenic microbes are becoming resistant to synthetic drugs, leading to a hazardous situation for human health and putting pressure on pharmaceutical giants to develop natural alternatives as herbal/plant-based medicines. The present in vitro study was therefore conducted to assess the therapeutic potential of two novel palm plants, <i>Syagrus romanzoffiana</i> and <i>Bismarckia nobilis</i>, of the family Arecaceae, against drug-resistant bacterial strains, <i>Escherichia coli</i> and <i>Bacillus subtilis</i>. The plant parts, such as the leaves, bark, and stems of both palms, were macerated in polar and nonpolar solvents (petroleum ether, chloroform, and methanol) to determine their antibacterial and antibiofilm potential. The % yield was comparatively more (6.42%) in the methanol crude extract of the stem of <i>S. romanzoffiana</i>, followed by the petroleum ether extract of the leaves of <i>B. nobilis</i> (6.24%). Overall, <i>S. romanzoffiana</i> has shown better results against these DR bacteria, with the highest antibacterial activity, as evidenced by a 26.3±0.33 mm zone of inhibition observed with the methanol stem extract against <i>E. coli</i>. On the contrary, <i>S. romanzoffiana</i> showed better biofilm inhibition activity, with a substantial value of 63.9±1.11% for the chloroform bark extract against the <i>E. coli</i> strain. The promising results suggest that these plants could represent a potential breakthrough against DR pathogens, pending further in vivo investigations.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"210-218"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147562744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Laser Absorption Shock Tube Study of C1 to C4 n-Alkyl Formate Pyrolysis","authors":"Malte Döntgen,&nbsp;Alina Wildenberg,&nbsp;Karl Alexander Heufer","doi":"10.1002/kin.70035","DOIUrl":"https://doi.org/10.1002/kin.70035","url":null,"abstract":"<p><span></span><math>\u0000 <semantics>\u0000 <mi>n</mi>\u0000 <annotation>$n$</annotation>\u0000 </semantics></math>-Alkyl formates are considered as potential alternative fuels or fuel additives. While their oxidation chemistry has been investigated intensely, their pyrolysis chemistry requires more experimental insights. The present work utilizes shock tube experiments in combination with infrared laser absorption measurements to obtain information about the <span></span><math>\u0000 <semantics>\u0000 <mi>n</mi>\u0000 <annotation>$n$</annotation>\u0000 </semantics></math>-alkyl formate dissociation and to derive rate coefficients. These experiments are complemented with kinetics predictions. Methyl formate is found to be less reactive than the longer <i>n</i>-alkyl formates, the latter of which have rather similar rate coefficients for dissociation towards <i>n</i>-alkene and formic acid, with <i>n</i>-butyl formate exhibiting the largest rate coefficient. The present experimental rate coefficients for <i>n</i>-alkyl formate decomposition are found to agree well with experimental results from the literature. The decomposition of formic acid formed via dissociation of the longer <i>n</i>-alkyl formates, the present experimental rate coefficient was initially assumed to deviate from theoretical predictions found in the literature. Yet when adjusting the collisional energy transfer parameters in the kinetics predictions, the present results can be reproduced through previous theoretical work. This indicates that formic acid might be very sensitive to the bath gas, which will be investigated in future work. With the present systematic investigation of <span></span><math>\u0000 <semantics>\u0000 <msub>\u0000 <mi>C</mi>\u0000 <mn>1</mn>\u0000 </msub>\u0000 <annotation>${rm C}_1$</annotation>\u0000 </semantics></math> to <span></span><math>\u0000 <semantics>\u0000 <msub>\u0000 <mi>C</mi>\u0000 <mn>4</mn>\u0000 </msub>\u0000 <annotation>${rm C}_4$</annotation>\u0000 </semantics></math> <i>n</i>-alkyl formates, detailed chemical kinetic modeling of <span></span><math>\u0000 <semantics>\u0000 <mi>n</mi>\u0000 <annotation>$n$</annotation>\u0000 </semantics></math>-alkyl formates will be aided in general. Moreover, the potential to gain insights at the elementary reaction level is revealed in the context of formic acid dissociation.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"199-209"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.70035","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147562271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on Mass Transfer and Thermodynamics Parameters of Alkaline Hydrolysis of Methyl Benzoate Under Arbitrary Temperatures","authors":"Huiqiang Jia,&nbsp;Tianyu Ge,&nbsp;Wenshuai Bai,&nbsp;Yan Liu","doi":"10.1002/kin.70040","DOIUrl":"https://doi.org/10.1002/kin.70040","url":null,"abstract":"<div>\u0000 \u0000 <p>Sodium benzoate, a food preservative, can be synthesized through alkaline hydrolysis of excess methyl benzoate, enabling resource utilization. This reaction is quite complex because the produced sodium benzoate acts as a surfactant and methanol as a co-solvent, both of which will affect mass transfer characteristics. In this paper, a mathematical model of the heterogeneous liquid-liquid reaction at arbitrary temperatures was developed firstly. Then, process conditions were determined through preliminary screening experiments. The interfacial tensions of two phases were measured, and the relationship of total interfacial tension with sodium benzoate concentration and temperature was established through regression analysis. Lastly, mass transfer and thermodynamic parameters of the reaction were determined using a combination of calorimetric experiments, genetic algorithm, and local convergence algorithm. This model enables rapid prediction of thermal power, as well as conversion rate, temperature, and provides theoretical support for scaling up from laboratorial scale to pilot, and even industrial production.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"230-245"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147568548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Selective and Catalyst-Free Oxidation of Benzyl Alcohol With Nitric Acid Under Mild Conditions","authors":"Shuo Ai,&nbsp;Kaili Gao,&nbsp;Linghui Liu,&nbsp;Wanguo Yu","doi":"10.1002/kin.70033","DOIUrl":"https://doi.org/10.1002/kin.70033","url":null,"abstract":"<div>\u0000 \u0000 <p>Benzaldehyde is a useful starting material of pharmaceuticals and spice. Benzaldehyde was synthesized via the oxidation of benzyl alcohol with concentrated nitric acid at 10°C–39°C, and the selectivity and yield were up to 99.7% and 98.9%, respectively. The selectivity was reduced at higher reaction temperatures. This is an intensely exothermic reaction in the absence of catalyst and organic solvent, and the composition of products was very simple. Most of benzyl alcohol was transformed into benzaldehyde within 2 min, showing high production efficiency. The oxidation reaction of benzaldehyde followed pseudo-zeroth-order kinetics with activation energy of 30.5 kJ/mol, so the accumulation of benzaldehyde would not accelerate its oxidation reaction. The high selectivity to benzaldehyde at low temperatures was attributed to the higher activation energy of oxidation of benzaldehyde compared to oxidation of benzyl alcohol. The reaction process was monitored by in-situ UV-Vis. The oxidation rate with concentrated HNO₃ was much higher than that with dilute HNO₃. NO₂ and NO were the dominant product in the presence of concentrated and dilute HNO₃, respectively. This paper presents a feasible scheme to selectively transform benzyl alcohol into benzaldehyde with a new oxidant instead of catalyst.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 5","pages":"191-198"},"PeriodicalIF":1.6,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147569970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pyrolysis of Neopentane in a Single Pulse Shock Tube: The Pressure Dependence of the Rate Constant for the C─C Bond Cleavage of Neopentane","authors":"Kenji Yasunaga,&nbsp;Hiroto Moriyama,&nbsp;Nobutaka Yamanaka,&nbsp;Hiroshi Yamada","doi":"10.1002/kin.70027","DOIUrl":"10.1002/kin.70027","url":null,"abstract":"<div>\u0000 \u0000 <p>The pyrolysis of neopentane (2,2-dimethylpropane) has been the subject of investigation at two pressures, approximately 2 and 10 atm, and a range of temperatures from 1000 to 1300 K. A single pulse shock tube was employed to measure the species concentration profiles of the reactant, intermediates, and products by means of gas chromatography (GC) sampling at a reaction time of 1.4 ms. The estimated reaction rate constants for C─C bond cleavage in neopentane (R1), derived from the fitting of a reaction model simulation to the concentration profiles of neopentane, can be represented by the following equations: <i>k</i>_R1 = 5.0 × 10¹³ exp(−64,100 cal mol⁻¹/<i>RT</i>) s⁻¹ and <i>k</i>_R1 = 1.0 × 10¹⁴ exp(−63,300 cal mol⁻¹/<i>RT</i>) s⁻¹ at 2 and 10 atm, respectively. The rate constants obtained, together with comparisons with literature values, indicate that the rate of C─C bond cleavage of neopentane is in the fall-off region under the present experimental conditions. It is important to note that the estimated rate constants may be overestimated at low temperatures. This is due to the assumption of a linear relationship between the logarithm of the rate constant and the inverse of the temperature, as is evident from the fitting to the Arrhenius equation <i>A </i>exp(−<i>E_a</i>/<i>RT</i>). A rate-of-consumption/production analysis was performed for neopentane and isobutene at 2 and 10 atm to investigate the influence of secondary reactions. Assuming a 50% uncertainty in the hydrogen abstraction reactions by both methyl radicals and hydrogen atoms from the C─H bond, <i>k</i>_R1 was estimated to have 38% and 43% uncertainties at 2 and 10 atm, respectively.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 4","pages":"138-145"},"PeriodicalIF":1.6,"publicationDate":"2026-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147567820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biogenic Synthesis of Silver and Iron Nanoparticles Derived From Grewia Optiva Leaf Extract: A Novel Approach for Antidiabetic, Anticoagulant and Anti-Inflammatory Therapies","authors":"Muhammad Salman Khan,&nbsp;Khushbakht Asad,&nbsp;Sehrish Asad,&nbsp;Aulia Kanwal,&nbsp;Abdur Rahim,&nbsp;Mina Ziarati,&nbsp;Muhammad Bilal,&nbsp;Nolubabalo Matinise,&nbsp;Farhad Badshah","doi":"10.1002/kin.70031","DOIUrl":"10.1002/kin.70031","url":null,"abstract":"<p>This study presents the green synthesis of silver (Ag-NPs) and iron nanoparticles (Fe-NPs) using aqueous leaf extract of <i>Grewia optiva</i> as a natural reducing and stabilizing agent. The extract was prepared using a Kjeldahl apparatus under controlled heating. Nanoparticle synthesis was optimized by varying pH, temperature, and salt concentration, and the products were characterized by Ultraviolet-visible (UV–vis) spectroscopy, Fourier Transform Infrared (FTIR) spectroscopy, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). The biosynthesized nanoparticles were crystalline, stable, and predominantly sized between 10 and 30 nm. Biological evaluations demonstrated that both Ag-NPs and Fe-NPs exhibited significant antidiabetic, anti-inflammatory, and anticoagulant effects, with Ag-NPs showing slightly higher activity. These results highlight <i>G. optiva</i> as a sustainable source for developing therapeutic nanoparticles with biomedical potential.</p>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 4","pages":"159-174"},"PeriodicalIF":1.6,"publicationDate":"2026-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.70031","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147568917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption Congo Red Dye on SnZnFeO Nanocomposite: Statistical Modeling and Interpretation","authors":"Mahesh R. Sonawane,&nbsp;Tarulata N. Chhowala,&nbsp;Kiran E. Suryawanshi,&nbsp;Umesh Fegade,&nbsp;Ren-Jang Wu,&nbsp;Tariq Altalhi","doi":"10.1002/kin.70030","DOIUrl":"10.1002/kin.70030","url":null,"abstract":"<div>\u0000 \u0000 <p>This study investigates the removal of Congo red (CR) dye from aqueous solutions using synthetically prepared SnO₂/ZnO/Fe₂O₃ nanocomposite (SnZnFeONPs). The structural properties of the nanocomposites were characterized using SEM, EDX, FTIR, and XRD techniques. The effects of key parameters, including initial CR dye concentration, pH, ultrasound duration, and adsorbent dosage, on dye removal efficiency were systematically evaluated. Under optimized conditions, an adsorption efficiency exceeding 97% was achieved. Equilibrium data fitted the Langmuir model best (<i>R</i>² = 0.996) with a <i>Q</i>_max of 344.82 mg g⁻¹, indicating monolayer adsorption of CR molecules. However, the Freundlich model (<i>R</i>² = 0.968) also suggested some degree of surface heterogeneity and possible multilayer interactions. Kinetic studies indicated that the adsorption process followed a pseudo-second-order (PSO) model. Computational simulations revealed that CR molecules adsorbed in a parallel orientation on the nanocomposite surface. Thermodynamic analysis indicated that the adsorption process is exothermic and primarily governed by physical interactions. The adsorption intensity values (n) at 25°C, 35°C, and 45°C were 0.599, 0.593, and 0.563, respectively, all less than 1, confirming favorable adsorption. Furthermore, the saturation adsorption capacity (Q_s_a_t) decreased from 438.465 mg g⁻¹ at 298 K to 34.633 mg g⁻¹ at 318 K, indicating reduced interaction at higher temperatures. These findings suggest that SnZnFeONPs exhibit excellent potential for efficient CR dye removal from industrial effluents through adsorption.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 4","pages":"146-158"},"PeriodicalIF":1.6,"publicationDate":"2026-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147562448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Liquid-Based High Entropy Electrolyte for Li-ion and Li-metal Batteries","authors":"Yang Tan,&nbsp;Yin Hu,&nbsp;Handong Li,&nbsp;Ziwen Tang,&nbsp;Shiyu Chen","doi":"10.1002/kin.70025","DOIUrl":"10.1002/kin.70025","url":null,"abstract":"<div>\u0000 \u0000 <p>Lithium-ion batteries have permeated every aspect of modern production and daily life due to their outstanding performance. However, in the face of continuously rising performance demands and emerging application scenarios, existing commercial lithium-ion batteries can no longer meet current demands. As a novel battery system, lithium metal batteries demonstrate higher energy density compared to traditional lithium-ion batteries, yet still face challenges such as lithium dendrite growth, unstable SEI formation, electrolyte consumption, and high safety risks. Although strategies like electrolyte modification, artificial solid electrolyte interphase (SEI) formation, and current collector modification have improved the performance of Li-ion and Li metal batteries, they still struggle to balance characteristics like energy density, rate capability, cycle life, wide temperature range, and safety. In recent years, the high-entropy concept has been introduced into liquid electrolyte-based lithium-ion and lithium metal batteries, achieving preliminary progress. This mini-review focuses on the application of high-entropy effects in liquid electrolytes for lithium-ion and lithium metal batteries. In this review, we summarize methods for modulating electrolyte mixing entropy and configuration entropy. Furthermore, the structure-property relationships between entropy-driven lithium-ion solvation environments and battery performances such as high rate capability, wide voltage window, and temperature range adaptability are discussed. Through a series of characterization studies and theoretical simulations, the regulatory mechanisms are elucidated. Finally, based on existing researches, this review proposes perspectives for future studies and practical development of liquid high-entropy electrolytes, aiming to accelerate technological iteration in novel lithium-ion batteries and high-energy-density lithium metal batteries.</p>\u0000 </div>","PeriodicalId":13894,"journal":{"name":"International Journal of Chemical Kinetics","volume":"58 4","pages":"123-137"},"PeriodicalIF":1.6,"publicationDate":"2026-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147567546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}