Indian Journal of Chemical Technology最新文献

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Synthesis, DFT and antioxidant studies of 2-(alkylamino)-4-(naphth-2-yl) thiazole 2-(烷基胺)-4-(萘-2-基)噻唑的合成、DFT及抗氧化研究
IF 0.5 4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.67293
{"title":"Synthesis, DFT and antioxidant studies of 2-(alkylamino)-4-(naphth-2-yl) thiazole","authors":"","doi":"10.56042/ijct.v30i2.67293","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.67293","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced sequestration of commercial Auramine O dye in a Fenton oxidative decolourization process Fenton氧化脱色法对工业金胺O染料的强化吸附
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5207
{"title":"Enhanced sequestration of commercial Auramine O dye in a Fenton oxidative decolourization process","authors":"","doi":"10.56042/ijct.v30i5.5207","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5207","url":null,"abstract":"The present work investigates the Fenton degradation of commercial Auramine O dye from a model solution through advanced oxidation process (AOP). The effects of initial pH, ferrous ion and H2O2 concentration have been evaluated with respect to the extent of decolourization of the feed solution. A maximum decolourization to the tune of 91.8% is accomplished at a pH of 3.0. The effect of various doses of Fe2+ and H2O2 on the percentage reduction in chemical oxygen demand (COD) is investigated at a constant pH. 84.9% reduction of COD is obtained using a combination of 48 mL/L H2O2 and 6 g/L Fe2+. The gas chromatography-mass spectrometry analysis reveals the presence of toxic non-biodegradable Auramine O dye in the model solution before the Fenton AOP, which is degraded into several compounds including CO2 after 30 min of Fenton AOP. The spectral output from FTIR analysis corroborates the molecular rearrangement during Fenton process with consequent degradation.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135444884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorptive removal of malachite green using ferromagnetic sterculia gum – graft- poly(n-isopropylacrylamide-co-acrylamide)/magnetite nanocomposite 铁磁固胶-接枝-聚(n-异丙烯酰胺-共丙烯酰胺)/磁铁矿纳米复合材料吸附去除孔雀石绿
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5193
{"title":"Adsorptive removal of malachite green using ferromagnetic sterculia gum – graft- poly(n-isopropylacrylamide-co-acrylamide)/magnetite nanocomposite","authors":"","doi":"10.56042/ijct.v30i5.5193","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5193","url":null,"abstract":"In present scenario, anthropogenic activities have degraded the quality of water bodies to an unbearable level. Discharge of untreated industrial and other effluents have made the water unconsumable. Present work is an attempt to fabricate new stimuli responsive adsorbent based on natural exudate gum sterculia, an indigenous natural gum for uptake of a cationic dye malachite green. Magnetic field responsive terculia gum–graft-poly(n-isopropylacrylamide-co-acrylamide) nanocomposite have been prepared and assessed it as adsorbents for enrichment of malachite green from aqueous solution. The nanocomposite is characterized by FTIR, TG-DTA, VSM and swelling studies. The VSM results have shown is superparamagnetic behaviour of nanocomposite with saturation magnetization of 1.5065 emu/g. The adsorption follows Temkin isotherm and results indicate maximum adsorption capacity of 19.977 (98.78%) malachite green. The desorption studies demonstrates excellent recovery ability of nanocomposite. The adsorption study confirms the prospective applications of polysaccharide based magnetic hydrogel for the fruitful and greener disposal of cationic dyes.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135446271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the thermal behaviour of a derivative based on a zirconium agent (modified montmorillonite) and determination of the physical characteristics 锆衍生物(改性蒙脱土)的热行为研究及物理特性测定
IF 0.5 4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.64537
{"title":"Study of the thermal behaviour of a derivative based on a zirconium agent (modified montmorillonite) and determination of the physical characteristics","authors":"","doi":"10.56042/ijct.v30i2.64537","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.64537","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Equilibrium, kinetic and thermodynamic study for the efficient removal of malachite green dye onto untreated Morus nigra L. (mulberry tree) leaves powder and its biochar 桑树叶粉及其生物炭高效脱除孔雀石绿染料的平衡、动力学和热力学研究
IF 0.5 4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.66355
{"title":"Equilibrium, kinetic and thermodynamic study for the efficient removal of malachite green dye onto untreated Morus nigra L. (mulberry tree) leaves powder and its biochar","authors":"","doi":"10.56042/ijct.v30i2.66355","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.66355","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasonication pretreatment of real-field pulping wastewater from bagasse-based paper mill 蔗渣造纸厂现场制浆废水的超声预处理
IF 0.5 4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.66923
{"title":"Ultrasonication pretreatment of real-field pulping wastewater from bagasse-based paper mill","authors":"","doi":"10.56042/ijct.v30i2.66923","DOIUrl":"https://doi.org/10.56042/ijct.v30i2.66923","url":null,"abstract":"","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"1 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70701868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mn3O4 and Ag2MnO4 nanoparticles loaded on g-C3N4 as magnetically catalysts for sonodegradation of dyes g-C3N4负载纳米Mn3O4和Ag2MnO4作为染料超声降解的磁性催化剂
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5210
{"title":"Mn3O4 and Ag2MnO4 nanoparticles loaded on g-C3N4 as magnetically catalysts for sonodegradation of dyes","authors":"","doi":"10.56042/ijct.v30i5.5210","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5210","url":null,"abstract":"New magnetic Mn3O4/g-C3N4 and Ag2MnO4/g-C3N4 nanocomposites have been synthesized based on Mn(II) Schiff base complex and used for sonodegradation of methylene blue (MB) and methyl orange (MO) dyes in aqueous solution. Ag2MnO4 nanoparticles (NPs) have been synthesized from Mn3O4 NPs and AgNO3 under ultrasonic irradiation for the first time. The results indicate that the sonodegradation method of dyes in the presence of Mn3O4/g-C3N4 and Ag2MnO4/g-C3N4 nanocomposites is better than solar degradation processes. The better photodegradation rates for MB and MO dyes observed in the presence of Ag2MnO4/g-C3N4 (k= 0.0916 min-1) and Mn3O4/g-C3N4 (k= 0.0381 min-1), as compared to pure Mn3O4 and Ag2MnO4 compounds The synthesized nanocomposites are good fluorescent materials.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135446268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal and mechanical properties of nanofilled poly(methyl methacrylate) nanocomposites produced by two ultrasonic methods 两种超声法制备纳米填充聚甲基丙烯酸甲酯纳米复合材料的热力学性能
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5216
{"title":"Thermal and mechanical properties of nanofilled poly(methyl methacrylate) nanocomposites produced by two ultrasonic methods","authors":"","doi":"10.56042/ijct.v30i5.5216","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5216","url":null,"abstract":"PPMANC1 and PMMANC2 nanocomposites have been fabricated using two reactive clays by two methods and characterized in order to estimate the impact of the different dispersion states on the mechanical properties. A simple and economical process of polymerisation is adopted to develop PMMANC nanocomposites using an Algerian clay, trying to optimize the distribution of PMMA in the clay layers. Two distinct types of organic clays have been mined, labelled as (i) benzyltrimethyl ammonium chloride (BTBA-Mag (1CEC)) and (ii) hexadecyltrimethylammonium bromide (HDTAB-MagCTA (2.5CEC)). Evaluation of the properties of the PMMANC1 and PMMANC2 nanocomposites are carried out using different physicochemical techniques. The results obtained by XRD, transmission electron microscopy reveal that the modified maghnite are well dispersed in the matrix and significant improvements in thermal properties are observed from thermal analysis. The Young module, impact resistance and tensile strength of the nanocomposites incorporating 5% organoargile are the most effective compared to the two synthesis processes.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135446281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive analysis and process simulation of biodiesel production from biomass sources 生物质生产生物柴油的综合分析与过程模拟
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5203
{"title":"Comprehensive analysis and process simulation of biodiesel production from biomass sources","authors":"","doi":"10.56042/ijct.v30i5.5203","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5203","url":null,"abstract":"The present research work entails the process simulation of biodiesel production on a large scale using the ASPEN process simulator. Catalytic transesterification and non-catalytic supercritical mode of transesterification are simulated with experimental results and compared to determine the efficient mode of transesterification under different initial feedstock raw material conditions. It is found that the supercritical method (280℃; 276.4 atm; 42:1 for alcohol and oil ratio) is efficient in terms of cost and product quality for the feedstocks with high Free Fatty Acid (FFA) content. For feedstocks with a negligible amount of FFA, alkali-catalyzed homogeneous transesterification (60-65℃; 4atm; 6:1- alcohol: oil ratio) is efficient in terms of product quality and yield although the cost is similar to that of the supercritical mode of transesterification. Pre-treatment steps like simple esterification and glycerolysis for high FFA-contained feedstocks are studied using the ASPEN simulation to understand better the overall process by which the pre-treatment is carried out. Finally, the combustion characteristics of the biodiesel blend along with n-heptane (a surrogate for Petro-diesel) are studied using the Python scripted Cantera combustion chamber and it is found that the amount of soot and carbon monoxide emission is very less indicating complete and efficient combustion. This simulation study is carried out with the help of DWSIM simulation software.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"269 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135444883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magneto-hybrid nanofluid (〖Al〗_2 O_3 / Cu-Oil) flow in a porous square enclosure with Cattaneo-Christov heat flow model-sensitivity analysis 用Cattaneo-Christov热流模型敏感性分析了磁杂化纳米流体(〖Al〗_2 O_3 / Cu-Oil)在多孔方框中的流动
4区 工程技术
Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5194
{"title":"Magneto-hybrid nanofluid (〖Al〗_2 O_3 / Cu-Oil) flow in a porous square enclosure with Cattaneo-Christov heat flow model-sensitivity analysis","authors":"","doi":"10.56042/ijct.v30i5.5194","DOIUrl":"https://doi.org/10.56042/ijct.v30i5.5194","url":null,"abstract":"The rheological behaviour of nanofluids is an important specification that has a substantial impact on the system performance. The effect of an inclined magnetic field on mixed convection in a square cavity through a porous medium has been numerically investigated in the current paper. Various levels of thermal conductivity have been maintained on each wall throughout the system. Additionally, the Cattaneo-Christov heat flow model is influenced in the energy equation. The conservation equations for primary, secondary, and mass momentum, energy, and nanoparticles with wall boundary conditions are dimensionless and coupled to proper scaling transformations. To address the dimensionless nonlinear coupled boundary value problem, a finite-difference computing methodology known as the Harlow-Welch Marker and Cell (MAC) method is used. The fundamental goal of this research is to look at the rheological behaviour of nanoparticles as base fluids in the aforementioned effects. The influence of factors on the physical framework such as Richardson number (Ri), Hartmann number (Ha), Darcy number (Da), Reynolds number (Re), and Prandtl number (Pr) is investigated graphically. The MATLAB software is used to obtain streamlined and isothermal contours. The findings indicate an enhancement in the average Nusselt number with an increase in the parameters. Furthermore, the presence of nanoparticles raises the average Nusselt number for low values of the Reynolds number. The system is analyzed with three convection stages of Richardson number, and it is also found that for mixed convection, the system holds better results. The obtained outcomes are compared with well-known existing findings to validate the present work.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":"47 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135446280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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