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On the Radiation Resistance of Tetrafluoroethylene Telomers with Terminal Hydroxyl Groups 论带有末端羟基的四氟乙烯端聚物的抗辐射性
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-07-23 DOI: 10.1134/s0018143924700280
G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin, Yu. M. Shulga
{"title":"On the Radiation Resistance of Tetrafluoroethylene Telomers with Terminal Hydroxyl Groups","authors":"G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin, Yu. M. Shulga","doi":"10.1134/s0018143924700280","DOIUrl":"https://doi.org/10.1134/s0018143924700280","url":null,"abstract":"","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"246 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-Energy Excited Singlet States of para-Aminothiophenol in Methanol and n-Hexane Solutions 对氨基苯硫酚在甲醇和正己烷溶液中的低能激发单态
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-07-23 DOI: 10.1134/s001814392470036x
S. N. Tseplina, E. E. Tseplin
{"title":"Low-Energy Excited Singlet States of para-Aminothiophenol in Methanol and n-Hexane Solutions","authors":"S. N. Tseplina, E. E. Tseplin","doi":"10.1134/s001814392470036x","DOIUrl":"https://doi.org/10.1134/s001814392470036x","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Optical absorption spectra of <i>para</i>-aminothiophenol in <i>n</i>-hexane and methanol solutions have been obtained. The calculation has been carried out using the TDDFT B3LYP/6-311+G(d,p) method taking into account the polarizable continuum model of the electronic spectra of the <i>p</i>-aminothiophenol molecule in <i>n</i>-hexane and its hydrogen-bonded complex with two methanol molecules in a methanol solution. Based on these calculations, the main absorption bands are interpreted and it is shown that the second excited singlet state is formed by a π → σ* electronic transition, which makes a significant contribution to the first absorption band of <i>p</i>-aminothiophenol in these solutions.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"246 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141775618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Complexation of Styrylisoxazole Dye with Albumin 苯乙烯基异噁唑染料与白蛋白的络合
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700036
I. D. Burtsev, D. A. Vasilenko, N. E. Astakhova, E. B. Averina, A. V. Trofimov, V. A. Kuzmin
{"title":"Complexation of Styrylisoxazole Dye with Albumin","authors":"I. D. Burtsev, D. A. Vasilenko, N. E. Astakhova, E. B. Averina, A. V. Trofimov, V. A. Kuzmin","doi":"10.1134/s0018143924700036","DOIUrl":"https://doi.org/10.1134/s0018143924700036","url":null,"abstract":"","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"29 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Superhydrophilic UiO-66-NH2@PMAA Metal-Organic Framework Materials by Hydrothermal Reaction Coupled with Gamma Ray Irradiation Method 水热反应与伽马射线辐照法制备超亲水性 UiO-66-NH2@PMAA 金属有机框架材料
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700061
Kai Fan, Junwei Zhou, Chuanyang Gao, Jinshen Lei, Jinjie Qin, Xiaoying Liu
{"title":"Preparation of Superhydrophilic UiO-66-NH2@PMAA Metal-Organic Framework Materials by Hydrothermal Reaction Coupled with Gamma Ray Irradiation Method","authors":"Kai Fan, Junwei Zhou, Chuanyang Gao, Jinshen Lei, Jinjie Qin, Xiaoying Liu","doi":"10.1134/s0018143924700061","DOIUrl":"https://doi.org/10.1134/s0018143924700061","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>In this study, the UiO-66-NH<sub>2</sub>@PMAA metal-organic framework was prepared by using a hydrothermal reaction coupled with the gamma-ray irradiation method. The chemical structure of the product was studied using FTIR and XPS before and after irradiation, indicating the efficient development of the grafting reaction. The DSC results revealed a drop in the melting point of UiO-66-NH<sub>2</sub>@PMAA material, which might be attributed to PMAM grafting. Following that, different MOF materials were suction-filtered onto the surface of the membrane, and the alteration of their contact angle with time was recorded, indicating the enhancement of UiO-66-NH<sub>2</sub>@PMAA materials’ hydrophilicity. The modified MOF material has better dispersibility in aqueous solutions, providing reference significance for its application in related fields.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"22 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of PVDF-g-PSBA Membrane by Homogeneous Solution Gamma-Ray Co-Irradiation and Its Antibacterial Effects 利用均相溶液伽马射线共辐射制备 PVDF-g-PSBA 膜及其抗菌效果
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s001814392470005x
Kai Fan, Chuanyang Gao, Jinshen Lei, Junwei Zhou, Enmei Liu, Xiaoying Liu
{"title":"Preparation of PVDF-g-PSBA Membrane by Homogeneous Solution Gamma-Ray Co-Irradiation and Its Antibacterial Effects","authors":"Kai Fan, Chuanyang Gao, Jinshen Lei, Junwei Zhou, Enmei Liu, Xiaoying Liu","doi":"10.1134/s001814392470005x","DOIUrl":"https://doi.org/10.1134/s001814392470005x","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Poly(S-bioallethrin) (PSBA) was grafted onto the polyvinylidene fluoride (PVDF) molecular chain through a gamma-ray irradiation method to prepare the PVDF-g-PSBA membrane. Fourier transform infrared spectroscopy (FTIR) of different membranes confirmed the effective progress of the grafting reaction. The microstructure of the membrane before and after irradiation was analyzed by scanning electron microscope (SEM), illustrating that gamma-ray irradiation did not cause damage to the membrane structure. The original PVDF membrane and the modified PVDF-g-PSBA membrane were immersed in an Escherichia coli culture medium, and the antibacterial effects of membranes were tested, confirming the positive effect of the PVDF-g-PSBA membrane on inhibiting bacterial growth. This research could have market application value in terms of altering membrane materials and enhancing membrane performance.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"4 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modification of Membrane Based on Gamma-Ray Irradiation Method: Preparation of PVDF-g-PMAM Membrane and Its Anti-Fouling Performance 基于伽马射线辐照法的膜改性：PVDF-g-PMAM 膜的制备及其防污性能
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700048
Kai Fan, Jinshen Lei, Chuanyang Gao, Junwei Zhou, Yugang Yuan, Xiaoying Liu
{"title":"Modification of Membrane Based on Gamma-Ray Irradiation Method: Preparation of PVDF-g-PMAM Membrane and Its Anti-Fouling Performance","authors":"Kai Fan, Jinshen Lei, Chuanyang Gao, Junwei Zhou, Yugang Yuan, Xiaoying Liu","doi":"10.1134/s0018143924700048","DOIUrl":"https://doi.org/10.1134/s0018143924700048","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Polyvinylidene fluoride (PVDF) membranes were created utilizing the non-solvent-induced phase separation (NIPS) approach in this study, then gamma-ray irradiation was applied to form the PVDF-g-PMAM membrane. FTIR and XPS were used to examine the chemical structure of the membrane before and after irradiation. The DSC curves of membranes showed that grafting poly methylacrylamide (PMAM) caused a drop in the melting point of the modified PVDF-g-PMAM membrane. The SEM characterization showed that gamma-ray irradiation did not damage the microstructure of the membrane cross-section, and the distribution of micropores on the membrane surface was more dense and uniform. The insertion of hydrophilic PMAM greatly accelerates the initial contact angle and contact angle decline rate of the PVDF-g-PMAM membrane, illustrating that the membrane’s hydrophilicity has been effectively improved. Finally, after testing of permeability and rejection of different membranes, the result demonstrated good anti-fouling performance.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling of Acetylene Formation from Methane in a Plasma Jet 等离子射流中甲烷生成乙炔的模拟
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700127
I. V. Bilera, Yu. A. Lebedev, A. Yu. Titov, I. L. Epshtein
{"title":"Modeling of Acetylene Formation from Methane in a Plasma Jet","authors":"I. V. Bilera, Yu. A. Lebedev, A. Yu. Titov, I. L. Epshtein","doi":"10.1134/s0018143924700127","DOIUrl":"https://doi.org/10.1134/s0018143924700127","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>This work is devoted to numerical simulation of methane conversion to acetylene under plasma jet pyrolysis conditions and to comparison of simulation results with available experimental data. Calculations have been carried out in terms of the plug-flow reactor model for atmospheric pressure. The main processes of methane decomposition and acetylene formation have been analyzed for the case of using either hydrogen or methane as a plasma-forming gas. The results of calculations on the main products of methane decomposition (hydrogen and acetylene) are in good agreement with experimental data.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"5 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct One-Step Plasma-Chemical Synthesis of Nanostructured β-Ga2O3–GaN Thin Films of Various Compositions 等离子体-化学一步法直接合成各种成分的纳米结构 β-Ga2O3-GaN 薄膜
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700139
L. A. Mochalov, M. A. Kudryashov, M. A. Vshivtsev, Yu. P. Kudryashova, I. O. Prokhorov, A. V. Knyazev, A. V. Almaev, N. N. Yakovlev, E. V. Chernikov, N. N. Erzakova
{"title":"Direct One-Step Plasma-Chemical Synthesis of Nanostructured β-Ga2O3–GaN Thin Films of Various Compositions","authors":"L. A. Mochalov, M. A. Kudryashov, M. A. Vshivtsev, Yu. P. Kudryashova, I. O. Prokhorov, A. V. Knyazev, A. V. Almaev, N. N. Yakovlev, E. V. Chernikov, N. N. Erzakova","doi":"10.1134/s0018143924700139","DOIUrl":"https://doi.org/10.1134/s0018143924700139","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>For the first time, nanostructured thin films of the β-Ga<sub>2</sub>O<sub>3</sub>−GaN system have been obtained by plasma-enhanced chemical vapor deposition (PECVD) on c-plane sapphire substrates. High-purity gallium metal, as well as high-purity gaseous nitrogen and oxygen, were used as sources of macrocomponents. Low-temperature nonequilibrium plasma of an inductively coupled RF (40.68 MHz) discharge at reduced pressure (0.01 torr) was the initiator of chemical transformations between the reactants. A mixture of oxygen and nitrogen was used as a plasma-forming gas. The plasma-chemical process was studied using optical emission spectroscopy (OES). The resulting β-Ga<sub>2</sub>O<sub>3</sub>−GaN thin films with a GaN content of 2 to 7% were characterized by various analytical methods.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"39 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Increase in the Two-Photon Absorption Cross Section of Styryl Dye in Supramolecular Complexes with Cucurbiturils 增加苯乙烯基染料与葫芦素的超分子复合物的双光子吸收截面
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700140
N. Kh. Petrov, A. A. Ivanov, D. A. Ivanov, A. B. Fedotov, A. A. Lanin, A. S. Chebotarev
{"title":"Increase in the Two-Photon Absorption Cross Section of Styryl Dye in Supramolecular Complexes with Cucurbiturils","authors":"N. Kh. Petrov, A. A. Ivanov, D. A. Ivanov, A. B. Fedotov, A. A. Lanin, A. S. Chebotarev","doi":"10.1134/s0018143924700140","DOIUrl":"https://doi.org/10.1134/s0018143924700140","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Using fluorescence spectroscopy, the two-photon absorption cross sections of aqueous solutions of the styryl dye <i>trans</i>-4-[4-(dimethylamino)styryl]-1-methylpyridinium iodide (DASPI) and its inclusion complexes with cucurbit[n]urils (CB[<i>n</i>] <i>n</i> = 6–8) have been measured. A nonmonotonic dependence of the cross section on the excitation wavelength and on the cavitand cavity size has been revealed. Compared to the free dye, a sevenfold increase in the two-photon absorption cross section has been observed in DASPI inclusion complexes with CB[8] at an excitation wavelength of 980 nm.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"28 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Methacrylate-Сontaining Para-Derivatives of N,N-Diethyl-4-(phenyldiazenyl)aniline as Initiators in Two-Photon Polymerization 作为双光子聚合引发剂的 N,N-二乙基-4-(苯基二氮)苯胺的甲基丙烯酸酯-С-含对衍生物
IF 0.7 4区 化学
High Energy Chemistry Pub Date : 2024-05-13 DOI: 10.1134/s0018143924700115
M. V. Arsenyev, E. R. Zhiganshina, D. A. Kolymagin, V. A. Ilyichev, R. S. Kovylin, A. G. Vitukhnovsky, S. A. Chesnokov
{"title":"Methacrylate-Сontaining Para-Derivatives of N,N-Diethyl-4-(phenyldiazenyl)aniline as Initiators in Two-Photon Polymerization","authors":"M. V. Arsenyev, E. R. Zhiganshina, D. A. Kolymagin, V. A. Ilyichev, R. S. Kovylin, A. G. Vitukhnovsky, S. A. Chesnokov","doi":"10.1134/s0018143924700115","DOIUrl":"https://doi.org/10.1134/s0018143924700115","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The possibility of using a series of methacrylate-containing <i>N</i>,<i>N</i>-diethyl-4-(phenyldiazenyl)anilines with various <i>para</i>-substituents (–H, –Br, –NO<sub>2</sub>) relative to the azo group as photoinitiators of radical polymerization is considered. The electrochemical and photoluminescent properties of these compounds have been studied. In the presence of azo dyes, two-photon photopolymerization of pentaerythritol triacrylate was carried out using focused 780-nm radiation from a femtosecond laser. Structures with minimal dimensions of linear elements of 94 ± 5 nm were obtained by means of the DLW nanolithography technique, and 3D microstructures of complex architecture were fabricated.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"33 1","pages":""},"PeriodicalIF":0.7,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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