Preparation of Superhydrophilic UiO-66-NH2@PMAA Metal-Organic Framework Materials by Hydrothermal Reaction Coupled with Gamma Ray Irradiation Method

IF 0.9 4区 化学 Q4 CHEMISTRY, PHYSICAL
Kai Fan, Junwei Zhou, Chuanyang Gao, Jinshen Lei, Jinjie Qin, Xiaoying Liu
{"title":"Preparation of Superhydrophilic UiO-66-NH2@PMAA Metal-Organic Framework Materials by Hydrothermal Reaction Coupled with Gamma Ray Irradiation Method","authors":"Kai Fan, Junwei Zhou, Chuanyang Gao, Jinshen Lei, Jinjie Qin, Xiaoying Liu","doi":"10.1134/s0018143924700061","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>In this study, the UiO-66-NH<sub>2</sub>@PMAA metal-organic framework was prepared by using a hydrothermal reaction coupled with the gamma-ray irradiation method. The chemical structure of the product was studied using FTIR and XPS before and after irradiation, indicating the efficient development of the grafting reaction. The DSC results revealed a drop in the melting point of UiO-66-NH<sub>2</sub>@PMAA material, which might be attributed to PMAM grafting. Following that, different MOF materials were suction-filtered onto the surface of the membrane, and the alteration of their contact angle with time was recorded, indicating the enhancement of UiO-66-NH<sub>2</sub>@PMAA materials’ hydrophilicity. The modified MOF material has better dispersibility in aqueous solutions, providing reference significance for its application in related fields.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"22 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0018143924700061","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

In this study, the UiO-66-NH2@PMAA metal-organic framework was prepared by using a hydrothermal reaction coupled with the gamma-ray irradiation method. The chemical structure of the product was studied using FTIR and XPS before and after irradiation, indicating the efficient development of the grafting reaction. The DSC results revealed a drop in the melting point of UiO-66-NH2@PMAA material, which might be attributed to PMAM grafting. Following that, different MOF materials were suction-filtered onto the surface of the membrane, and the alteration of their contact angle with time was recorded, indicating the enhancement of UiO-66-NH2@PMAA materials’ hydrophilicity. The modified MOF material has better dispersibility in aqueous solutions, providing reference significance for its application in related fields.

Abstract Image

水热反应与伽马射线辐照法制备超亲水性 UiO-66-NH2@PMAA 金属有机框架材料
摘要 本研究采用水热反应结合伽马射线辐照法制备了UiO-66-NH2@PMAA金属有机框架。利用傅立叶变换红外光谱和 XPS 对辐照前后的产物化学结构进行了研究,结果表明接枝反应进行得很顺利。DSC 结果显示 UiO-66-NH2@PMAA 材料的熔点下降,这可能是 PMAM 接枝的结果。随后,将不同的 MOF 材料吸滤到膜表面,记录其接触角随时间的变化,表明 UiO-66-NH2@PMAA 材料的亲水性增强。改性后的 MOF 材料在水溶液中具有更好的分散性,为其在相关领域的应用提供了参考意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
High Energy Chemistry
High Energy Chemistry 化学-物理化学
CiteScore
1.50
自引率
28.60%
发文量
62
审稿时长
6-12 weeks
期刊介绍: High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信