Green Processing and Synthesis最新文献

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Synergism between lignite and high-sulfur petroleum coke in CO2 gasification 褐煤与高硫石油焦在CO2气化中的协同作用
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2022-8143
Lirui Mao, Tao Liu, Yanlin Zhao, Mingdong Zheng
{"title":"Synergism between lignite and high-sulfur petroleum coke in CO2 gasification","authors":"Lirui Mao, Tao Liu, Yanlin Zhao, Mingdong Zheng","doi":"10.1515/gps-2022-8143","DOIUrl":"https://doi.org/10.1515/gps-2022-8143","url":null,"abstract":"Abstract High-sulfur petroleum coke (PC) as solid waste has high treatment cost. Gasification technology can utilize PC and lignite for co-gasification. Organically combining the two is the key to expanding the adaptability of gasification raw materials. This work used thermal analysis technology to study the gasification reaction of PC and lignite systems in a CO2 atmosphere. The results show that the starting and end temperatures of the co-gasification of lignite/high-sulfur PC are lower than those of pure coke. The improved carbonization rate and gasification reaction index indicate that lignite improves the gasification performance. The gasification synergy factors are all greater than 1, indicating that the co-gasification process produces obvious synergism, and the synergism is more obvious in the gasification stage after 800°C. The lignite ash is gradually enriched on the surface of high-sulfur PC with the temperature increase, and the Ca and Fe elements have an obvious catalytic effect, but the catalytic effect has a saturation value. Ashes from lignite used as a multi-component gasification catalyst can increase the overall reactivity in the lignite/high-sulfur PC system, which can broaden the selection of gasification raw materials, and make efficient use of the resource characteristics of both.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45705006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Catalysts based on nickel salt heteropolytungstates for selective oxidation of diphenyl sulfide 镍盐杂多钨酸盐选择性氧化二苯基硫化物催化剂
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0026
M. Muñoz, Matthieu Greber, K. B. Tayeb, C. Lamonier, C. Cabello, G. Romanelli
{"title":"Catalysts based on nickel salt heteropolytungstates for selective oxidation of diphenyl sulfide","authors":"M. Muñoz, Matthieu Greber, K. B. Tayeb, C. Lamonier, C. Cabello, G. Romanelli","doi":"10.1515/gps-2023-0026","DOIUrl":"https://doi.org/10.1515/gps-2023-0026","url":null,"abstract":"Abstract Nickel salts of Keggin heteropolytungstates with the general formula Ni x A y W12−y O39or40 (A = Si/P) were synthesized and studied as bulk catalytic materials or supported ones by deposition on modified and functionalized clay minerals (pillared layered clay and porous clay heterostructure). Characterizations by Raman, 31P and 29Si-NMR, and ESEM-EDS techniques showed that pure and supported systems preserved the Ni/W ratio and the expected structural properties of heteropolyanions. These materials were evaluated as catalysts in the selective oxidation of sulfides to sulfoxides or sulfones, using aqueous hydrogen peroxide and mild reaction conditions. The bulk materials, with a higher content of Ni, displayed a remarkable catalytic behavior in the oxidation of diphenyl sulfide (Ni3PW11NiO40H, 90% conversion in 15 min at 75°C, 100% sulfone selectivity in 3 h). Supported catalysts, particularly the non-functionalized PCH (Ni2SW12O40/PCH), showed excellent activity, with also being selective in the oxidation of sulfide to sulfoxide (87% conversion, 88.9% sulfoxide selectivity). The reuse of these materials was studied in the optimum reaction conditions, resulting in similar activity and selectivity. Graphical abstract Selective oxidation reaction of DPS to DPSO2 with hydrogen peroxide as oxidant in presence of nickel salts of Keggin heteropolytungstates as catalysts","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48602740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile aqueous synthesis of ZnCuInS/ZnS–ZnS QDs with enhanced photoluminescence lifetime for selective detection of Cu(ii) ions 选择性检测Cu(ii)离子的ZnCuInS/ ZnS-ZnS量子点的水溶合成
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2022-8155
Nande Mgedle, O. Aladesuyi, T. C. Lebepe, Vuyelwa Ncapayi, O. Oluwafemi
{"title":"Facile aqueous synthesis of ZnCuInS/ZnS–ZnS QDs with enhanced photoluminescence lifetime for selective detection of Cu(ii) ions","authors":"Nande Mgedle, O. Aladesuyi, T. C. Lebepe, Vuyelwa Ncapayi, O. Oluwafemi","doi":"10.1515/gps-2022-8155","DOIUrl":"https://doi.org/10.1515/gps-2022-8155","url":null,"abstract":"Abstract Quaternary quantum dots (QDs) have recently gained more attention due to their low toxicity, tunable wavelength, reduced or no blueshift emission upon overcoating, improved photoluminescence (PL) quantum yield, and PL lifetime when compared to their binary (II–VI) and ternary (I–III–VI) counterparts. In this work, the aqueous synthesis of ZnCuInS/ZnS–ZnS multi-shell quaternary QDs as a nanosensor for the selective detection of Cu2+ ions was reported. The as-synthesized QDs were spherical, with a particle diameter of 3.66 ± 0.81 nm, and emitted in the first near-infrared window (725 nm) with an average decay PL lifetime of 43.69 ns. The X-ray diffraction analysis showed that the QDs were of the wurtzite structure, while the Fourier transform infrared spectroscopy confirmed GSH capping through the sulphur–metal bond. Furthermore, the fluorometric study shows that the developed multi-shell QDs were selective towards Cu2+ ions compared to other metal ions via fluorescence quenching with a limit of detection of 1.4 µM, which is below the acceptable limit in drinking water.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47349888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phytocrystallization of silver nanoparticles using Cassia alata flower extract for effective control of fungal skin pathogens 利用决明花提取物对银纳米颗粒进行植物结晶,有效控制真菌性皮肤病原体
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0013
Moorthy Muruganandham, K. Sivasubramanian, P. Velmurugan, N. Arumugam, A. Almansour, Raju Suresh Kumar, S. Mahalingam, S. Sivakumar
{"title":"Phytocrystallization of silver nanoparticles using Cassia alata flower extract for effective control of fungal skin pathogens","authors":"Moorthy Muruganandham, K. Sivasubramanian, P. Velmurugan, N. Arumugam, A. Almansour, Raju Suresh Kumar, S. Mahalingam, S. Sivakumar","doi":"10.1515/gps-2023-0013","DOIUrl":"https://doi.org/10.1515/gps-2023-0013","url":null,"abstract":"Abstract A feasible alternative to classic chemical synthesis, the phyto-mediated production of silver nanoparticles (AgNPs) utilizing aqueous flower petal extract of Cassia alata as a reducing agent is reported for the first time. Characterization of synthesized AgNPs was carried out using various techniques viz., ultraviolet-visible spectroscopy (UV-Vis), X-ray powder diffraction (XRD), high-resolution transmission electron microscope (HRTEM), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The results of the FTIR research conducted in this study show different bond stretches with varying durations, which can be seen at various faraway points. AgNPs are mainly spherical and vary in size from 20 to 100 nm, according to TEM images. The highest X-ray energy surge, at 3 keV, is visible in the EDX spectrum. The XRD pattern showed that four diffraction peaks could be assigned to the 111, 200, 220, and 311 planes of the face-centered cubic crystalline silver, respectively, at 32.05, 46.27, 55.25, and 57.39°. Optimization of production parameters including pH, metal ion concentration, and substrate concentrations were studied. In addition, the bioactivity was evaluated against Trichophyton rubrum, Aspergillus fumigatus, Candida albicans, Epidermophyton floccosum, and Mucor sp. using the agar diffusion method. Furthermore, their antioxidant properties were assessed using 2,2-diphenyl-1-picryl-hydrazyl-hydrate assay and ferric ion reducing antioxidant power tests. MTT assay was performed using human fibroblast cell line (L929) to determine the cell viability and cytotoxicity through increased metabolism of the tetrazolium salt.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47453830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Photocatalytic properties of ZnFe-mixed oxides synthesized via a simple route for water remediation 复合氧化锌的光催化性能及其在水修复中的应用
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2022-8153
M. Hadnadjev-Kostic, Djurdjica Karanovic, T. Vulić, J. Dostanić, D. Lončarević
{"title":"Photocatalytic properties of ZnFe-mixed oxides synthesized via a simple route for water remediation","authors":"M. Hadnadjev-Kostic, Djurdjica Karanovic, T. Vulić, J. Dostanić, D. Lončarević","doi":"10.1515/gps-2022-8153","DOIUrl":"https://doi.org/10.1515/gps-2022-8153","url":null,"abstract":"Abstract ZnFe photocatalysts have been increasingly investigated for water remediation due to the high demands in this field, such as activity, toxicity, cost, and stability. The presented study was focused on the simple, safe, non-toxic, and eco-friendly synthesis and characterization of ZnFe-mixed metal oxides in correlation with their functional properties. Photocatalytic performance of these materials was evaluated by rhodamine B photodegradation under simulated solar light irradiation. The synthesized mixed oxides contained hexagonal wurtzite ZnO as the predominant phase, whereas, after thermal treatment, the formation of the spinel-structured ZnFe2O4 phase was observed. The photocatalysts with the additional spinel phase and thermally treated at 300°C and 500°C exhibited superior photocatalytic activity probably due to the highest amount of the ZnFe2O4 spinel phase, favourable mesoporous structure, and an optimal energy band gap of ∼2.30 eV that initiated higher light-harvesting efficiency. The rhodamine B photodegradation followed zero-order kinetics, indicating complete coverage of active sites by the pollutant substrate. Additionally, photocatalysts showed the highest efficiency at the natural pH (6.8), being in accordance with green synthesis principles. Simple, green route assembling synthesis method, high photodegradation efficiency, and good reusability make these ZnFe-mixed oxides great candidates for potential application in practical wastewater treatments.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66810140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
In vitro anti-cancer and antimicrobial effects of manganese oxide nanoparticles synthesized using the Glycyrrhiza uralensis leaf extract on breast cancer cell lines 甘草叶提取物合成的氧化锰纳米颗粒对乳腺癌细胞株的体外抗癌和抑菌作用
4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0063
Maryam Musleh Althobiti, Badr Alzahrani, Abozer Y. Elderdery, Nasser A. N. Alzerwi, Musaed Rayzah, Ahmed M. E. Elkhalifa, Bandar Idrees, Ebtisam Bakhsh, Abdulrahim A. Alabdulsalam, A. Mohamedain, Suresh S. Kumar, Pooi Ling Mok
{"title":"<i>In vitro</i> anti-cancer and antimicrobial effects of manganese oxide nanoparticles synthesized using the <i>Glycyrrhiza uralensis</i> leaf extract on breast cancer cell lines","authors":"Maryam Musleh Althobiti, Badr Alzahrani, Abozer Y. Elderdery, Nasser A. N. Alzerwi, Musaed Rayzah, Ahmed M. E. Elkhalifa, Bandar Idrees, Ebtisam Bakhsh, Abdulrahim A. Alabdulsalam, A. Mohamedain, Suresh S. Kumar, Pooi Ling Mok","doi":"10.1515/gps-2023-0063","DOIUrl":"https://doi.org/10.1515/gps-2023-0063","url":null,"abstract":"Abstract In this study, we evaluated the antiproliferative and apoptotic properties of Pluronic-F127-containing manganese oxide nanoparticles (PF-127-coated Mn 2 O 3 NPs) derived from the leaf extract of Glycyrrhiza uralensis (GU) on breast adenocarcinoma, MCF7, and MDA-MB-231 cell lines. The leaf extract of GU contains bioactive molecules that act as a reducing or capping agent to form Mn 2 O 3 NPs. Various analytical techniques were used to characterize the physiochemical properties of PF-127-coated Mn 2 O 3 NPs, including spectroscopy (ultralight-Vis, Fourier transform infrared, photoluminescence), electron microscopy (field emission scanning electron microscopy and transmission electron microscopy), X-ray diffraction (XRD), electron diffracted X-ray spectroscopy (EDAX), and dynamic light scattering. The average crystallite size of Mn 2 O 3 NPs was estimated to be 80 nm, and the NPs had a cubic crystalline structure. PF127-encapsulated Mn 2 O 3 NPs significantly reduce MDA-MB-231 and MCF-7 cell proliferation, while increasing endogenous ROS and lowering mitochondrial matrix protein levels. DAPI, EtBr/AO dual staining, and Annexin-V-FITC-based flow cytometry analysis revealed that PF127-coated Mn 2 O 3 NP-treated breast cancer cells exhibit nuclear damage and apoptotic cell death, resulting in cell cycle arrest in the S phase. Furthermore, PF127-encapsulated Mn 2 O 3 NPs show strong antimicrobial efficacy against various strains. As a result, we can conclude that PF127-coated Mn 2 O 3 NPs may be effective as future anticancer agents and treatment options for breast cancer.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135700025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Clean preparation of rutile from Ti-containing mixed molten slag by CO2 oxidation 含钛混合熔渣CO2氧化法清洁制备金红石
4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0083
Jiqing Han, Qiuping Feng, Li Zhang
{"title":"Clean preparation of rutile from Ti-containing mixed molten slag by CO<sub>2</sub> oxidation","authors":"Jiqing Han, Qiuping Feng, Li Zhang","doi":"10.1515/gps-2023-0083","DOIUrl":"https://doi.org/10.1515/gps-2023-0083","url":null,"abstract":"Abstract The effects of SiO2 and CO2 on the crystallization action of Ti-containing mixed molten slag (molten Ti-containing blast furnace slag and molten Ti slag) were discussed by thermodynamic calculation and specific experiments. The results of thermodynamic calculation indicated that the increase of SiO2 addition mass and CO2 oxidation time can promote the transformation of anosovite and sphene to rutile. The experiment results showed that the phase composition of modification slag was only rutile under the SiO2 addition mass of 110 g and the CO2 oxidation time of 180 s. Moreover, the formation theory of rutile was investigated. Using CO2 as an oxidizing gas can not only prepare rutile but also achieve carbon neutrality, which is a clean preparation method.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136207657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Algae-based green AgNPs, AuNPs, and FeNPs as potential nanoremediators 基于藻类的绿色AgNPs、AuNPs和FeNPs作为潜在的纳米修复剂
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0008
F. Tonelli, Christopher Santos Silva, Vinicius Marx Silva Delgado, F. Tonelli
{"title":"Algae-based green AgNPs, AuNPs, and FeNPs as potential nanoremediators","authors":"F. Tonelli, Christopher Santos Silva, Vinicius Marx Silva Delgado, F. Tonelli","doi":"10.1515/gps-2023-0008","DOIUrl":"https://doi.org/10.1515/gps-2023-0008","url":null,"abstract":"Abstract This review addresses green algae-based gold (Au), iron (Fe), and silver (Ag) nanoparticles (NPs) as eco-friendly nanomaterials to deal with biological, organic, and inorganic environmental contaminants. Among nanotechnological tools that can fully degrade, adsorb, and/or convert pollutants into less harmful structures, AgNPs, AuNPs, and FeNPs deserve highlight for their efficiency and low cost. However, green protocols are preferable to produce them in an eco-friendly manner. Although phycosynthesis is still in its infancy, algae present various advantages as green raw materials to NPs’ synthesis; fast growth rate, low-energy input requirement, low costs, easy and eco-friendly cultivation, and high tolerance to metals are examples. To allow their large-scale application, however, challenges regarding obtaining sufficient biomaterial with good reproducibility, designing protocols to achieve desirable features on NPs, and recovering the biocompatible nanomaterial after use still need attention. Perspectives for the field involve surpassing these limitations, broadening knowledge on synthesis mechanisms, protocols, and new species useful to offer, in the future, commercial eco-friendly, and low-cost phycosynthesized AuNPs, AgNPs, and FeNPs to nanoremediation. The potential of these NPs to deal with environmental contaminants, their advantageous characteristics and biocompatibility, the main limitations associated with their large-scale application, and future prospects for the field will receive attention.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43263717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Development of a fuzzy logic model for the prediction of spark-ignition engine performance and emission for gasoline–ethanol blends 用于预测汽油-乙醇混合燃料火花点火发动机性能和排放的模糊逻辑模型的建立
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0009
Manikandan Kaliyaperumal, R. Sundaresan, Balu Pandian, S. Rajendran
{"title":"Development of a fuzzy logic model for the prediction of spark-ignition engine performance and emission for gasoline–ethanol blends","authors":"Manikandan Kaliyaperumal, R. Sundaresan, Balu Pandian, S. Rajendran","doi":"10.1515/gps-2023-0009","DOIUrl":"https://doi.org/10.1515/gps-2023-0009","url":null,"abstract":"Abstract Due to the enormous of fossil fuels and the ensuing increase in automobiles, an unprecedented scenario has arisen with pollution levels that are out of human control. In this study, a fuzzy logic model is developed to predict how well a spark-ignition engine running on gasoline and ethanol mixes would operate. A test engine was operated on pure gasoline and gasoline–ethanol fuel mixtures in a range of ratios at varying engine speeds. In order to estimate outputs such as brake-specific fuel consumption (BSFC), brake thermal efficiency, nitrogen oxides (NOx), hydrocarbon emissions, and carbon monoxide, a fuzzy logic model, a sort of logic model application, has been developed using experimental data. The developed fuzzy logic model’s output was compared to the results of the trials to see how well it performed. The output parameters were indicated, including braking power, thermal, volumetric, and mechanical efficiency. The input parameters were engine speed and ethanol mixes. Regression coefficients were nearly equal for training and testing data. According to the study, a superior method for accurately forecasting engine performance is the fuzzy logic model. To eliminate proportionality signs from equations, regression analysis is used. It is accurate to develop mathematical relations based on dimensional analysis. Based on the root mean square errors, BSFC is a minimum of 6.12 and brake power is a maximum of 8.16; lower than 2% of errors occur on average.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47969503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The mechanisms of inhibition and lubrication of clean fracturing flowback fluids in water-based drilling fluids 清洁压裂返排液在水基钻井液中的抑制和润滑机理
IF 4.3 4区 工程技术
Green Processing and Synthesis Pub Date : 2023-01-01 DOI: 10.1515/gps-2023-0062
Huaizhu Liu, Dong-lan Chen, Kangning Zhao, Binbin Hu, Jianjia Zhang, Yang Ning, Tong Shan, J. Zhang, Wan Zhang, Fan Zhang
{"title":"The mechanisms of inhibition and lubrication of clean fracturing flowback fluids in water-based drilling fluids","authors":"Huaizhu Liu, Dong-lan Chen, Kangning Zhao, Binbin Hu, Jianjia Zhang, Yang Ning, Tong Shan, J. Zhang, Wan Zhang, Fan Zhang","doi":"10.1515/gps-2023-0062","DOIUrl":"https://doi.org/10.1515/gps-2023-0062","url":null,"abstract":"Abstract This study presents a novel approach for the reuse of uncontaminated fracturing flowback fluids to improve the inhibitory and lubricating properties of water-based drilling fluids (WBFs), curb environmental pollution arising from flowback fluids, and substantially mitigate the expenses associated with WBFs. The experimental design was optimized using orthogonal experiments and range analyses, whereby the modified rubber powder was set at 2.0%, xanthan gum at 0.15%, and a plant phenol to modified complexing agent ratio of 1:0.01. The assessment of the performance evaluation tests indicated that the use of uncontaminated fracturing flowback fluids as the base water can remarkably enhance the inhibitory and lubricating properties of WBFs. Precisely, this approach reduces the linear expansion rate from 62.31% to 21.25%, the reduction rate of extreme pressure lubrication coefficient by 87.98%, and the reduction rate of mud cake sticking factor by 59.86%. This investigation has established the potential environmental and economic benefits of reusing clean fracturing flowback fluids in WBFs.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44387072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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