{"title":"Evaluation of antibacterial and osteogenic properties of a novel Poly (acrylic acid)-calcium-zinc biomineralized hydrogel","authors":"Xiaobin Xie, Xiaoxiao Feng, Lihui Hong, Xinke Yu, Hongye Li, Hao Zhang, Mingming Liu, Yimeng Wang","doi":"10.3389/fmats.2024.1444750","DOIUrl":"https://doi.org/10.3389/fmats.2024.1444750","url":null,"abstract":"Infectious bone defects are one of the thorny problems faced by orthopedists. Developing prosthetic materials with antimicrobial osteogenic features is a key solution. Biodegradable Polyacrylic acid (PAA)-based hydrogels have gained attention for their exceptional qualities. However, the influence of zinc ions on PAA-based mineralized hydrogels remains understudied. In this paper, Poly (acrylic acid)-calcium-zinc (PA-CZ) biomineralized hydrogel was prepared through ionic cross-linking and biomineralization. In vitro bacterial and cell tests demonstrated the hydrogel’s exceptional biocompatibility, antibacterial, and osteogenic traits, along with good mechanical strength. The PA-CZ mineralized hydrogel lays the foundation for developing orthopedic implants with antimicrobial osteogenic features and offers a promising approach for treating infected bone defects.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141923167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qingming Zhao, Li Chen, Xiaoyu Wang, Shengru Zhang, Fan Li
{"title":"Study on the modification effect and mechanism of composite solid waste and steel fiber on the mechanical properties of concrete","authors":"Qingming Zhao, Li Chen, Xiaoyu Wang, Shengru Zhang, Fan Li","doi":"10.3389/fmats.2024.1431648","DOIUrl":"https://doi.org/10.3389/fmats.2024.1431648","url":null,"abstract":"To promote the use of solid waste in concrete production and solve the problem of secondary pollution caused by a large amount of solid waste, the four-factor and four-level orthogonal test method was used to investigate the different replacement rates of coal gangue (CG) ceramics (15%, 20%, 25%, and 30%), coal gangue ceramic sand (CGS) (10%, 15%, 20%, and 25%), fly ash (FA) (10%, 15%, 20%, and 25%), and steel fiber (SF) content (0.30%, 0.60%, 0.90%, and 1.2). By using range analysis, variance analysis, matrix analysis, and regression analysis, the prediction models of primary and secondary factors, optimal dosage, and strength under different factor levels were obtained. The microstructure and strengthening mechanisms of different materials were analyzed by scanning electron microscopy (SEM). The results show that the optimal combination of the CG substitution rate is 30%, CGS substitution rate is 15%, SF content is 1.2%, and FA substitution rate is 10% for cube compressive strength. For the splitting tensile strength, the optimal combination is a CG substitution rate of 30%, CGS substitution rate of 25%, SF content of 1.2%, and FA substitution rate of 10%. The resulting strength prediction model has high accuracy, which can predict the strength within the range selected by the orthogonal test in this paper and provide a reference for the application of steel fibers and solid waste in concrete, which contributes to the energy conservation and emission reduction in the construction industry.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141923538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junhan Song, Jie Zhang, Jing Peng, Xinhua Song, Long Liang, Hui Feng
{"title":"Mechanical properties and deformation behavior of a high entropy alloy with precipitate under cycle loading","authors":"Junhan Song, Jie Zhang, Jing Peng, Xinhua Song, Long Liang, Hui Feng","doi":"10.3389/fmats.2024.1436577","DOIUrl":"https://doi.org/10.3389/fmats.2024.1436577","url":null,"abstract":"Compared to the traditional alloys, high entropy alloys exhibit exceptional strength and outstanding ductility, making them highly attractive for use in demanding engineering applications. However, the atomic-scale deformation behavior of HEAs with precipitate under the low-cycle loading conditions has not been well studied. Here, we utilize molecular dynamics simulations to investigate the low cycle fatigue behavior of AlCoCrFeNi HEAs with AlNi-rich phase, in order to better understand the cyclic deformation, work hardening, and damage mechanisms. In the stress-strain hysteresis loops, the stress in the elastic stage exhibits a gradual linear increase, followed by fluctuations at yielding and plastic deformation. The strain hardening depends on the cycle number after the yielding stage. With an increase in the number of cycles, the activation mode of stacking faults gradually transitions from a multi-slip system to a single-slip system, attributed to the gradual phase transformation. A thorough examination of dislocation evolution is crucial in understanding the strengthening and plastic behavior of materials under cyclic loading. The generation of more stair-rod dislocations further suppresses the movement of dislocations. The combined effects of element diffusion, structural transformation, and incoherent precipitation play a critical role in enhancing the mechanical properties of AlCoCrFeNi HEAs. The strength of high entropy alloys is improved through interface strengthening caused by element diffusion and structural transformation, along with dispersion induced by incoherent precipitation. This work provides a detailed atomic-level understanding of the cyclic deformation-induced strengthening mechanism, in order to design high-strength and ductile HEAs with specific desired properties.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141925515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Samia Elattar, Umair Khan, A. Zaib, Anuar Ishak, Norah Alwadai, Hind Albalawi
{"title":"Irreversible mechanism and thermal cross-radiative flow in nanofluids driven along a stretching/shrinking sheet with the existence of possible turning/critical points","authors":"Samia Elattar, Umair Khan, A. Zaib, Anuar Ishak, Norah Alwadai, Hind Albalawi","doi":"10.3389/fmats.2024.1391066","DOIUrl":"https://doi.org/10.3389/fmats.2024.1391066","url":null,"abstract":"The significant increase in thermal efficiency and the rate of energy exchange used in fuel dynamics and automobile coolants are leading to a better understanding of nanofluids. This computational analysis explores the thermal conductivity performance for radiative cross-flow of a nanofluid across an expanding/constricting sheet with a suction effect as a result of its application. To compute or calculate the magnificent point of nanofluid flow, the entropy, and asymmetrical heat source/sink effects are also elicited. The boundary layers traverse a stream-wise procedure for expanding and contracting sheets. Additionally, the study examines the features of heat transfer and cross-flow of nanofluids using numerical simulations. By employing similarity variables, the basic PDE equations of the current model are transformed into ODEs, and they are subsequently evaluated using the bvp4c method. Therefore, the effects of embedded flow variables on drag force, heat transfer rate, and entropy generation profiles have been framed using parametric research. Multiple solutions are offered for a specific range of the contracting parameter as well as the mass suction parameter. In addition, the heat transfer rate accelerates due to the heat source and decelerates due to the heat sink. The literature that is already published has been compared favorably, and it reveals many commonalities.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yunlin Liu, Shangwei Huo, Zhixin Wu, Dingguo Yang, Ke Ren, Jianhua Liu, Riguang Wang
{"title":"Research on axial compression performance test and bearing capacity calculation method of newly assembled hollow lattice wallboard","authors":"Yunlin Liu, Shangwei Huo, Zhixin Wu, Dingguo Yang, Ke Ren, Jianhua Liu, Riguang Wang","doi":"10.3389/fmats.2024.1424911","DOIUrl":"https://doi.org/10.3389/fmats.2024.1424911","url":null,"abstract":"With the great development of the construction industry, prefabricated building components have been greatly developed. To study the compressive performance of the new wallboard, the axial compression performance test of six full-scale new lattice wallboards was carried out in this paper. The failure mode, axial pressure-displacement relationship curve, axial compression bearing capacity, and axial pressure-strain relationship of the wallboard were obtained through the experiments. This reveals the influence of the thickness of the concrete surface and the number of ribs on the performance of the wallboard. The test results show that the ultimate bearing capacity of the specimen increases with the increase of the thickness of the concrete surface layer with the same number of ribs. Specimen DW -30 increased by 4% over DW -20 and DW -50 increased by 41.6% over DW -30. The ultimate bearing capacity of the three-ribbed specimens was higher than that of the two-ribbed specimens for the same concrete face thickness, about 1.11 times that of the two-ribbed specimens. The concrete facing thickness and the number of ribs have a restraining effect on the deformation of the wallboard. Additionally, the calculation formula of axial bearing capacity of type latticed wallboard considering the influence of eccentric compression was proposed, which can provide a reference for engineering calculation.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141925873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on the auxetic mechanical metamaterials and their applications in the field of applied engineering","authors":"Volha Siniauskaya, Hao Wang, Yadong Liu, Yuhang Chen, Michael Zhuravkov, Yongtao Lyu","doi":"10.3389/fmats.2024.1453905","DOIUrl":"https://doi.org/10.3389/fmats.2024.1453905","url":null,"abstract":"Metamaterials are artificially created materials or structures with properties not found in nature. They encompass electromagnetic, acoustic, and mechanical metamaterials, which are particularly significant in applied engineering. Mechanical metamaterials exhibit unique mechanical properties such as vanishing shear modulus, negative Poisson’s ratio, negative compressibility, etc. This paper reviews the most commonly used mechanical metamaterials and discusses their applications in the field of applied engineering, specifically in vibration isolation, energy absorption, and vibration reduction. The prospects for future developments in this field are also presented.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":3.2,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research on mechanical properties of steel-polypropylene fiber concrete and application of beam structure","authors":"Jiuyang Li, Jingwei Luo, Li Chen, Xinmei Fan, Yuepeng Zhu, Xiaoyu Wang, Jingpeng Guo","doi":"10.3389/fmats.2024.1440466","DOIUrl":"https://doi.org/10.3389/fmats.2024.1440466","url":null,"abstract":"Concrete faces the difficulties of low tensile strength and poor crack resistance in building structures. In order to remedy this deficiency. In this paper, steel-polypropylene hybrid fiber reinforced concrete (SPFRC) was prepared by adding steel fiber (SF) and three kinds of polypropylene fiber (PF) to C50-grade concrete. The mechanical properties and microstructure of SPFRC were studied with different fiber combinations and content, obtaining the best hybrid combination. Based on this, the bending resistance and cracking of SPFRC beam members were investigated. The results demonstrate that the addition of fiber improves the compressive strength of ordinary concrete by 0.16% ∼ 17.69%, the splitting tensile strength by 15.18% ∼ 47.45%, and the bending strength by 3.54% ∼ 26.77%. Compared with single-fiber concrete, the hybrid fiber can achieve better internal microstructure, which further enhances the mechanical properties of the material. Hybrid fibers overlap within concrete beams, effectively redistributing stress and inhibiting the formation and propagation of cracks. For the three types of SPFRC beams, the cracking load is increased by 14.29% ∼ 28.57% compared with PC beam, the ultimate bearing capacity is increased by 9.68% ∼ 19.35%. The optimal dosage is determined as 1.0% SF, 0.6% Embossed polypropylene fiber (PBF). It provides reference for the application of SPFRC in flexural members.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":3.2,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu Cheng, Jiatao Liu, Wentong Wang, Lu Jin, Shiying Yan
{"title":"Preparation and property study of sawdust-modified cement mortar","authors":"Yu Cheng, Jiatao Liu, Wentong Wang, Lu Jin, Shiying Yan","doi":"10.3389/fmats.2024.1457167","DOIUrl":"https://doi.org/10.3389/fmats.2024.1457167","url":null,"abstract":"Sawdust, a solid waste generated during stone processing, poses a serious threat to the environment with its untreated accumulation. This paper first analyzes the chemical composition and physical properties of sawdust, and discusses its mechanism of action in cement mortar. By systematically optimizing the blending ratio and modification method of sawdust, the sawdust-modified cement mortar with excellent performance was prepared. This study evaluates the key performance indicators of sawdust-modified cement mortar, such as compressive strength, flexural strength, and durability, through a series of experiments. The experimental results indicate that the incorporation of an appropriate amount of sawdust significantly enhances the mechanical properties of cement mortar, while also improving its durability, particularly in terms of freeze-thaw resistance. Microstructural analysis reveals the mechanism by which sawdust improves the pore structure of cement mortar; the active components in the sawdust react with the hydration products of cement, resulting in the formation of crystalline structures with higher strength.Therefore, the use of sawdust as a modifier in cement mortar can improve its mechanical properties and durability, while simultaneously reducing the accumulation of solid waste and promoting the sustainable development of building materials.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":3.2,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuefu Yang, Chaohe Chen, Yifeng Zhuang, Zhijia Suo
{"title":"Reviewing the progress of corrosion fatigue research on marine structures","authors":"Yuefu Yang, Chaohe Chen, Yifeng Zhuang, Zhijia Suo","doi":"10.3389/fmats.2024.1399292","DOIUrl":"https://doi.org/10.3389/fmats.2024.1399292","url":null,"abstract":"This paper reviews the state-of-the-art progress of research into corrosion fatigue on marine structures, both theoretical and experimental. This includes corrosion fatigue life prediction models/methods, load–environment interaction/coupling test methods, accelerated corrosion methods in corrosion fatigue testing, fatigue crack measurement, and corrosion fatigue life assessment in the whole life period. To date, some theoretical models and methods for predicting the corrosion fatigue life of metallic materials or structures have been proposed and applied. Meanwhile, load–environment interaction/coupling testing on metallic material specimens has been maturely developed and widely applied. Some newly developed corrosion fatigue theoretical and experimental methods, based on data-driven machine learning and at-sea monitoring, have received preliminary application. This review of accelerated corrosion methods, fatigue crack measurement methods, and corrosion fatigue life assessment for marine structures in the whole-life period has been undertaken by extensive reference to relevant studies conducted worldwide. Challenges and recommendations for further developing and improving corrosion fatigue assessment methods and test techniques are also reported and discussed.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":3.2,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mesoscopic numerical simulation of chloride diffusion behavior in cracked recycled aggregate concrete","authors":"Jing Liu","doi":"10.3389/fmats.2024.1441220","DOIUrl":"https://doi.org/10.3389/fmats.2024.1441220","url":null,"abstract":"The cracking of recycled aggregate concrete (RAC) is well known to promotes the chloride diffusion, accelerates the corrosion of reinforcement embedded in RAC. To reveal the mechanism of chloride diffusion in RAC under cracking, a multiphase mesoscopic model for chloride diffusion in RAC was proposed. It should be noted that RAC is regarded as eight-phase composite materials consisting of coarse aggregate, reinforcement, new and old mortar, new and old interface transition zones (ITZ), cracks, and damage zones. The effects of the width and depth of cracks and damage zones on chloride diffusion behavior in RAC after cracking were further investigated. The numerical simulation results show that the damage zones accelerate the chloride diffusion and exacerbates the accumulation effect of chloride at the crack tip. Compared to the crack depth, the crack width of RAC has a small effect on chloride diffusion behavior, especially, the crack width is less than 50 µm. More importantly, the chloride diffusion streamline generated by numerical simulation reveals the mechanism of cracks promoting chloride diffusion. The research in this paper provides new insights into the durability design of RAC by revealing the diffusion behavior of chloride ions in RAC.","PeriodicalId":12524,"journal":{"name":"Frontiers in Materials","volume":null,"pages":null},"PeriodicalIF":3.2,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}