X. Ni, W. Chow, Shaogang Zhang, Mei Zhao, Zhongkui Zheng, Xishi Wang
{"title":"Combining Bromofluoropropene with Water Mist for Suppressing Deep Seated Wood Crib Fires","authors":"X. Ni, W. Chow, Shaogang Zhang, Mei Zhao, Zhongkui Zheng, Xishi Wang","doi":"10.3801/iafss.fss.11-1236","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-1236","url":null,"abstract":"Application of 2-bromo-3,3,3-trifluoropropene (BTP) with water mist in suppressing deep seated wood crib fires was reported in this paper. Performance of the combination of the two clean fire suppressants was examined by laboratory scale experiments and compared with water mist and BTP used alone. Results showed that coupling of water mist with BTP could extinguish the wood crib fires with high efficiency, in which BTP discharged first could fast extinguish the flame, and the following water mist could cool the wood surface and stop glowing combustion. As a result, a complete fire extinguishment without re-strike was achieved in short time. Furthermore, hydrogen fluoride (HF) acid gas produced in the suppression process was acceptable for the use of water mist in conjunction with BTP.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"59 1","pages":"1236-1246"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75582020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Ukleja, M. Delichatsios, Jianping Zhang, M. Suzanne
{"title":"Carbon monoxide production during underventilated fires in corridors","authors":"S. Ukleja, M. Delichatsios, Jianping Zhang, M. Suzanne","doi":"10.3801/IAFSS.FSS.11-316","DOIUrl":"https://doi.org/10.3801/IAFSS.FSS.11-316","url":null,"abstract":"This work presents experimental results and non-dimensional correlations of factors and conditions affecting carbon monoxide (CO) production in corridor-like enclosure fires. Thirty eight experiments were performed in a three metre long corridor-like enclosure having a cross section 0.5 m x 0.5 m, door-like openings in the front panel and a propane gas burner located near the closed end being flushed with the floor. Measurements of carbon monoxide concentrations were performed at locations inside the enclosure and also in the exhaust duct of a hood collecting the combustion products for direct comparison. Visual observations through the opening revealed that flames were detaching from the burner for tests with global equivalence ratios (GERs) greater than one for the burning inside the enclosure (underventilated fires). After detachment, flames were travelling towards the opening then finally stayed anchored in the vicinity of the opening and emerged outside. After flames were visible outside, the concentration of CO inside the corridor increases to much higher levels owing to the recirculation of gases inside the enclosure behind the flames. A correlation between CO concentration inside the enclosure and GER was found with CO increasing initially but then decreasing for high global equivalence ratios. An additional correlation was found between the CO yield and the GER in the enclosure before the flames reached and then, anchored at the opening of the enclosure. Finally, it was found that the ratio of CO to smoke yield, yco/ys, is not constant but increases for global equivalence ratios of the enclosure greater than one in contrast to its value being constant for over ventilated conditions.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"66 1","pages":"316-330"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74008999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jan C. Thomas, A. Simeoni, Michael R. Gallagher, N. Skowronski
{"title":"An Experimental Study Evaluating the Burning Dynamics of Pitch Pine Needle Beds Using the FPA","authors":"Jan C. Thomas, A. Simeoni, Michael R. Gallagher, N. Skowronski","doi":"10.3801/iafss.fss.11-1406","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-1406","url":null,"abstract":"Pine needle litters, a key fuel in coniferous forest systems, are highly porous fuel beds. They provide a source of continuous fuel medium that can be easily ignited and will sustain flame spread on the ground during forest fires. This work represents an experimental study that is focused on the influence of the fuel moisture content on the burning dynamics and the flammability characteristics of forest fuel beds. The FM Global Fire Propagation Apparatus was utilized to obtain time to ignition, heat release rate, total heat released and CO/CO2 concentration data. The methodologies applied in previous studies were improved with new modifications. The results were analyzed with respect to the sample’s fuel moisture content as well as other test conditions, such as airflow condition (wind), sample holder openness and external heat flux. The importance of the fuel moisture content is critical to understand as the majority of fuels present in the natural environment have elevated moisture content compared to dead dry fuel. Samples studied are representative of wet ground fuels as well as live fuels which do burn when crowning conditions develop. The results presented here are a building block for developing an experimental database that can be used to understand the influence of environmental conditions on the flammability of porous forest fuels and assess the risks that comes with a wildfire. Furthermore, the data can also be used for fire behavior model validation.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"30 1","pages":"1406-1419"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73229221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Basic Experiment on the Heat Release Property of a Tsunami Fire Fueled by Debris and Fuel Oil Spilled on the Sea Surface Following Tsunami","authors":"Tomoaki Nishino, Hidekazu Suzuki, T. Tsuchihashi","doi":"10.3801/iafss.fss.11-758","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-758","url":null,"abstract":"This paper describes an effort to model the heat release rate curve of a tsunami fire. A tsunami fire is defined as a fire that breaks out in coastal areas inundated by a tsunami following an earthquake. Tsunami fires may result in the ignition of tsunami refuge buildings. One type of tsunami fire is a fire where fuel oil spilled from tanks and an enormous amount of debris such as timber, broken houses and expanded polystyrene are burning together on the sea surface. We conducted basic combustion experiments for this type of fire using a pool with a size of 600 mm square where heat release rates were measured by varying the types of debris and the exposed surface areas of fuel oil. Furthermore, a model for heat release rate at the fully developed phase and time to the beginning of fire decay was proposed. The predictions of the proposed model are shown to be more conservative in comparison with the experimental data.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"24 1","pages":"758-768"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87553745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermal degradation and flame-retardant properties of epoxy acrylate resins modified with a novel flame retardant containing phosphorous and nitrogen","authors":"X. Qian, Q. Tai, Yuan Hu, R. Yuen, T. Chee","doi":"10.3801/iafss.fss.11-883","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-883","url":null,"abstract":"A novel monomer containing phosphorus and nitrogen (EBAPP) has been synthesized by allowing phenyl dichlorophosphate to react with ethylenediamine and 2-hydroxyethyl acrylate (HEA). The structure of EBAPP was characterized by FTIR, 1 H NMR and 31 P NMR. A series of flame-retardant resins was obtained by blending EBAPP with epoxy acrylate (EA) in different ratios and exposing to the UV-light. The flame-retardant properties of the resins were characterized by the limiting oxygen index (LOI) and microscale combustion calorimeter (MCC). The results showed that the incorporation of EBAPP into EA could improve the flame retardancy of EA. The thermal properties of the resins were investigated by thermogravimetric analysis (TGA) in air atmosphere, indicating that EBAPP could improve the char residues at high temperature. Moreover, the thermal degradation of EA/EBAPP resins were investigated by the real-time fourier transform infrared spectra (RTIR) and thermogravimetric analysis/infrared spectrometry (TGA-IR) analysis. The morphologies of the formed chars were observed by scanning electron microscopy (SEM), demonstrating that 20 wt% of EBAPP in EA exhibited the most effective flame retardancy due to the dense char layers formed during combustion.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"27 1","pages":"883-894"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85490058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fire Testing a New Fluorine-free AFFF Based on a Novel Class of Environmentally Sound High Performance Siloxane Surfactants","authors":"Ralf Hetzer, F. Kümmerlen, K. Wirz, D. Blunk","doi":"10.3801/iafss.fss.11-1261","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-1261","url":null,"abstract":"The most effective fire extinguishing agents for pool fires are Aqueous Film Forming Foams (AFFF). Today, all available AFFF contain polyfluorinated compounds (PFC), i.e. polyfluorinated tensides (PFT), to establish the aqueous film on the surface of a burning liquid. These fluorinated compounds are persistent, potentially bio-accumulative and toxic. Therefore it is essential to find environmentally sound substitutes for these problematic surfactants. Commercially available fluorine-free foams (FfreeF) lack the ability of aqueous film formation. Although FfreeF are performing well in many situations [1,2], there are numerous scenarios where an aqueous film forming component is mandatory for fast fire extinguishing, e.g. in case of burning liquids. To achieve a well performing AFFF, a new approach is to replace the film forming PFC/PFT by siloxane surfactants. Today, siloxane surfactants are typically used in plant protective agents, in textile surface treatment and as lubricants. As the properties of commercially available siloxane surfactants are not suitable for AFFF, new siloxane surfactants were designed, synthesized and tested for their suitability as film forming ingredients in AFFF formulations. The surface activity and foaming behaviour of model formulations have been determined. Finally, one experimentally fluorine-free AFFF formulation has been subjected to fire tests. In this context a new fire test for scarcely available chemicals is presented.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"29 1","pages":"1261-1270"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85277238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental Study on Suppression of Methane Explosion Containing Obstacles with Ultra-fine Water Mist","authors":"H. Xue, Y. Li, P. Zhu, W. Qin, Xishi Wang","doi":"10.3801/iafss.fss.11-1247","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-1247","url":null,"abstract":"The effects of obstacles on methane explosion inside a narrow space and its suppression by ultra-fine water mist are investigated experimentally. Two PCB pressure transducers and two E12-1-C-U fast response thermocouples are used to obtain the explosion pressure and temperature, respectively. A Fastcam Ultima APX high speed video camera is used to visualize the process of methane explosion with the influence of obstacles and ultra-fine water mist. The results show that the explosion would be strengthened by the obstacles, while the further strengthening occurs to the cases where the obstacles are farther from the ignition electrode. In addition, the more the obstacles are, the stronger the explosion strengthening will be. The reinforcement effect on gas explosion of the square ring is a little stronger than the column one. The suppression of methane gas explosion containing obstacles with ultra-fine water mist is very effective.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"21 1","pages":"1247-1260"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83293383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ignition temperature and surface emissivity of heterogeneous loosely packed materials from pyrometric measurements","authors":"B. Dlugogorski, S. Hirunpraditkoon, E. Kennedy","doi":"10.3801/IAFSS.FSS.11-262","DOIUrl":"https://doi.org/10.3801/IAFSS.FSS.11-262","url":null,"abstract":"This paper reports the ignition temperature and emissivity of heterogeneous materials characterised by high void fraction of between 0.92 and 0.94 and composed of loose particles of shredded grass and paper, planed wood, shredded plastic bags, as well as sugar and bread, with about 95 % of the particles (by mass) of less than 50 mm in size. These materials reflect a typical composition and void fraction of so-called refusederived fuels (RDF), which are obtained from municipal solid waste, then densified and combusted for energy recovery. An infrared pyrometer, with a spectral response range of 8 to 14 µm, recorded the surface temperature of the surrogate RDF, prior to the onset of the flaming combustion, in a stand alone mass loss calorimeter operated at 20 and 45 kW m -2 . The overlapping spectral ranges of the pyrometer and the radiator heater necessitated the development of a practical methodology to obtain the actual surface temperature from the apparent measurements, which included the effect of the reflected radiation. In addition to surface temperatures (292 ‐ 325 °C for 20 kW m -2 and 250 ‐ 294 °C for 45 kW m -2 ), in this contribution, we estimate the actual emissivities (0.95 ‐ 0.98) of the materials from the intensity of the reflected radiation.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"66 1","pages":"262-275"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87755749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. Shi, J. Ji, Jinhua Sun, S. Lo, Linjie Li, X. Yuan
{"title":"Experimental Study on the Characteristics of Temperature Field of Fire Room under Stack Effect in a Scaled High-rise Building Model","authors":"W. Shi, J. Ji, Jinhua Sun, S. Lo, Linjie Li, X. Yuan","doi":"10.3801/iafss.fss.11-419","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-419","url":null,"abstract":"A set of experiments were conducted in a scaled building model with 12 floors to study on the temperatures of fire room under stack effect in a high-rise building. The fuel mass loss rate, radiant flux, heat flux and temperatures in the atria and fire room at the first floor were experimentally investigated. The flames of pool fires in room are tilted towards the staircase under the air flow induced by the stack effect. The mass loss rate of fuel is influenced slightly by the position of window opened in the staircase, while the temperature distribution in the atria and fire room is different in the opened and closed staircases. The hot smoke temperatures in the atria and fire room at the first floor increase with an increasing pool size. The upper hot smoke temperatures in the atria are higher than those in the fire room in cases with an opened staircase. Compared different positions of the window opened in the staircase, it can be found that the upper hot smoke temperatures in the atria in cases with the 3 rd floor window opened are the highest due to the weaker stack effect. In the closed staircases, the upper hot smoke temperatures in the fire room are great higher than these in the atria at the first floor. Besides, the radiant flux and heat flux of the left sidewalls of staircase in an opened staircase are higher than those in a closed staircase, due to the tilted flame. The results obtained in this paper may be used for the safety design of the room in high-rise buildings.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"66 1","pages":"419-431"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83810245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Finding the Probability of Doors Being Open Using a Continuous Position Logger","authors":"K. Frank, M. Spearpoint, S. Weddell","doi":"10.3801/iafss.fss.11-969","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-969","url":null,"abstract":"Data for the probability that a doors are open or closed in the event of a fire is sparse. The literature only presents a snap-shot rather than how the position of the door has changed over time. This paper describes the development of a low-cost, unobtrusive logging device that can continuously monitor the position of a door for extended periods. The devices were used to record 180 days of data from 52 doors located in different types of sleeping occupancies: hotels, apartments, dormitories and rest homes. Results were obtained for the probability that doors were open during day-time and night-time; and also during weekdays and weekends. Overall a probability distribution for the fraction of time that a door was found to be open is an inverse Gaussian function with mean µ = 0.104 and shape factor l = 0.0117.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":"37 1","pages":"969-982"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89200683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}