Alexander A Grechnikov, Alexey S Borodkov, Yaroslav O Simanovsky, Sergey M Nikiforov
{"title":"Silicon surface assisted laser desorption ionization mass spectrometry for quantitative analysis.","authors":"Alexander A Grechnikov, Alexey S Borodkov, Yaroslav O Simanovsky, Sergey M Nikiforov","doi":"10.1177/14690667211006017","DOIUrl":"https://doi.org/10.1177/14690667211006017","url":null,"abstract":"<p><p>The approach to quantitative analysis by silicon Surface Assisted Laser Desorption Ionization Mass Spectrometry (Si-SALDI) is proposed. The approach is based on the new method for forming an active surface layer on a silicon substrate by exposing to laser radiation directly in the ion source of a mass spectrometer. The method can be used repeatedly on the same substrate, providing high reproducibility of its surface ionization properties and high ionization efficiency of organic compounds. Within the proposed approach, the methods of improvement of signal reproducibility are also considered, including continuous monitoring of the silicon surface ionization properties using a Knudsen effusion cell; scanning the surface of a silicon substrate with a laser beam; selecting the optimal value of laser fluence and using a reproducible sample introduction technique. It is demonstrated that this approach can be successfully applied to quantify clinically relevant concentrations of pharmaceutical drugs in extracts of blood.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"27 2-4","pages":"84-93"},"PeriodicalIF":1.3,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/14690667211006017","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"25561984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A simulation study of excitation contour of a linear trap with spatial harmonics.","authors":"N V Konenkov","doi":"10.1177/14690667211020153","DOIUrl":"https://doi.org/10.1177/14690667211020153","url":null,"abstract":"<p><p>The process of nonlinear resonant excitation of ion oscillations in a linear trap is studied. There is still no detailed simulation of the resonance peak in the literature. We propose to use the excitation contour to describe the collective ion resonance. The excitation contour is a resonant mass peak obtained by the trajectory method with the Gaussian distribution of the initial coordinates and velocities. The following factors are considered: excitation time, low order hexapole and octopole harmonics with amplitudes A<sub>3</sub> and A<sub>4</sub>, the depth of the initial ion cloud position. These multipoles are used for selective ion ejection from linear ion trap. All these factors affect the ion yield and the shape of the contours. Obtained data can be useful for control of such processes as ion fragmentation, ion isolation, ion activation, and ion ejection. Simulated resonance peaks are important for the theoretical description of the ion collective nonlinear resonances.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"27 2-4","pages":"94-100"},"PeriodicalIF":1.3,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/14690667211020153","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"38952117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Theoretical fractional formulation of a three-dimensional radio frequency ion trap (Paul-trap) for optimum mass separation.","authors":"Sarkhosh Seddighi Chaharborj, Shahriar Seddighi Chaharborj, Zahra Seddighi Chaharborj, Pei See Phang","doi":"10.1177/14690667211026790","DOIUrl":"https://doi.org/10.1177/14690667211026790","url":null,"abstract":"<p><p>We investigate the dynamics of an ion confined in a Paul-trap supplied by a fractional periodic impulsional potential. The Cantor-type cylindrical coordinate method is a powerful tool to convert differential equations on Cantor sets from cantorian-coordinate systems to Cantor-type cylindrical coordinate systems. By applying this method to the classical Laplace equation, a fractional Laplace equation in the Cantor-type cylindrical coordinate is obtained. The fractional Laplace equation is solved in the Cantor-type cylindrical coordinate, then the ions is modelled and studied for confined ions inside a Paul-trap characterized by a fractional potential. In addition, the effect of the fractional parameter on the stability regions, ion trajectories, phase space, maximum trapping voltage, spacing between two signals and fractional resolution is investigated and discussed.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"27 2-4","pages":"73-83"},"PeriodicalIF":1.3,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/14690667211026790","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"39147654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of anthocyanin from red sorghum (<i>Sorghum bicolor</i>) bran by liquid chromatography-electron spray ionization mass spectrometry analysis.","authors":"P Suganyadevi, M Saravanakumar, S Mohandas","doi":"10.1177/14690667211035720","DOIUrl":"https://doi.org/10.1177/14690667211035720","url":null,"abstract":"<p><p>In the present study, anthocyanin pigments from red sorghum (<i>Sorghum bicolor</i>) bran were identified and characterized by Liquid Chromatography-Electron Spray Ionization Mass Spectrometry. The individual anthocyanins were identified by comparing their mass spectrometric data and retention times, published data. 3-deoxyanthocyanidins and methyl 3-deoxyanthocyanidins were identified in red sorghum bran. This paper presents complete LCMS profile and MS spectrometric data of red sorghum bran.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"27 2-4","pages":"107-114"},"PeriodicalIF":1.3,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/14690667211035720","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"39257485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Applications of Beta Negative Binomial Distribution Series on Holomorphic Functions","authors":"A. Wanas, Najah Ali Jiben Al-Ziadi","doi":"10.34198/EJMS.6221.271292","DOIUrl":"https://doi.org/10.34198/EJMS.6221.271292","url":null,"abstract":"The purpose of this article is to derive the necessary and sufficient conditions for the power series ℘ג, whose coefficients are probabilities of the beta negative binomial distribution to be in the family F , , , , , ג, of holomorphic functions which are defined in the open unit disk. We establish a number of important geometric properties, such as, coefficient estimates, extreme points, neighborhood property, integral representation, radii of starlikeness and convexity and Hadamard product properties for functions belongs to this family. Also we determinate some differential subordination properties of the power series ℘ג, .","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"271-292"},"PeriodicalIF":1.3,"publicationDate":"2021-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42505033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Coupled Anti Q-Fuzzy Subgroups using t-Conorms","authors":"C. Ampadu","doi":"10.34198/EJMS.6221.239251","DOIUrl":"https://doi.org/10.34198/EJMS.6221.239251","url":null,"abstract":"In this paper we study coupled anti Q-fuzzy subgroups of G with respect to t-conorm C. We also discuss the union, normal and direct product of them. Moreover, the homomorphic image and pre-image of them is investigated under group homomorphisms and anti homomorphisms. 1 Some Old and New Notions and Notations Remark 1.1. (a) In this paper we assume G is a group as defined in [1]. (b) We assume the notions of homomorphism and anti-homomorphism as defined in [1]. (c) We assume C : [0, 1]× [0, 1] 7→ [0, 1] is a t-conorm as defined in [1]. (d) By idempotent, we refer to t-conorm C as defined in [1]. Definition 1.2. Let G be an arbitrary group with multiplicative binary operation and identity e. By a fuzzy subset of G×G we mean a function from G×G into [0, 1]. The set of all fuzzy subsets of G×G will be called the [0, 1]-power set of G×G, and will be denoted by [0, 1]G×G. Received: February 1, 2021; Accepted: March 7, 2021 2010 Mathematics Subject Classification: 08A72, 20-XX, 47A30, 20N25, 20K27, 20K30.","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"239-251"},"PeriodicalIF":1.3,"publicationDate":"2021-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46883360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Special Subfamilies of Holomorphic and Bi-univalent Functions related to Quasi-subordination","authors":"S. R. Swamy, Y. Sailaja","doi":"10.34198/EJMS.6221.225237","DOIUrl":"https://doi.org/10.34198/EJMS.6221.225237","url":null,"abstract":"In the current work, special subfamilies of holomorphic bi-univalent functions based on quasi-subordination are introduced. Initial coefficient estimates for functions belonging to these subfamilies are established. Several consequences of our results and connections to known families are indicated. 1 Preliminaries Let A be the set of normalized holomorphic functions that have the form","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"225-237"},"PeriodicalIF":1.3,"publicationDate":"2021-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69827211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Coefficient Estimates for Certain Subclasses of m-Fold Symmetric Bi-univalent Functions Associated with Pseudo-Starlike Functions","authors":"T. G. Shaba, A. Patil","doi":"10.34198/EJMS.6221.209223","DOIUrl":"https://doi.org/10.34198/EJMS.6221.209223","url":null,"abstract":"In the present investigation, we introduce the subclasses ΛΣ (η,h, φ) and ΛΣ (η,h, δ) of m-fold symmetric bi-univalent function class Σm, which are associated with the pseudo-starlike functions and defined in the open unit disk U. Moreover, we obtain estimates on the initial coefficients |bm+1| and |b2m+1| for the functions belong to these subclasses and identified correlations with some of the earlier known classes.","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"209-223"},"PeriodicalIF":1.3,"publicationDate":"2021-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46974343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Anticommutativity and n-schemes","authors":"Brice Réné Amougou Mbarga","doi":"10.34198/EJMS.6121.175186","DOIUrl":"https://doi.org/10.34198/EJMS.6121.175186","url":null,"abstract":"Abstract The purpose of this paper is two-fold. A first and more concrete aim is to give new characterizations of equivalence distributive Goursat categories (which extend 3-permutable varieties) through variations of the little Pappian Theorem involving reflexive and positive relations. A second and more abstract aim is to show that every finitely complete category E satisfying the n-scheme is locally anticommutative.","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"175-186"},"PeriodicalIF":1.3,"publicationDate":"2021-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41403273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Gull Alpha Power of the Ampadu-Type: Properties and Applications","authors":"C. Ampadu","doi":"10.34198/EJMS.6121.187207","DOIUrl":"https://doi.org/10.34198/EJMS.6121.187207","url":null,"abstract":"This paper introduces a new statistical distribution called Gull Alpha Power of the Ampadu Type (GAPA-G for short). The new distribution is inspired by the Gull Alpha Power of [1] and the Ampadu-G of [2]. Some properties with application are investigated.","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":"1 1","pages":"187-207"},"PeriodicalIF":1.3,"publicationDate":"2021-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43615933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}