Energy & Environmental Materials最新文献

{"title":"Harnessing Nickel-Based Photocatalysts for CO2 Conversion and Hydrogen Production – A Review","authors":"Noura Zahir,&nbsp;Vinodh Rajangam,&nbsp;Shankara S. Kalanur,&nbsp;Sergey I. Nikitenko,&nbsp;Bruno G. Pollet","doi":"10.1002/eem2.70014","DOIUrl":"https://doi.org/10.1002/eem2.70014","url":null,"abstract":"<p>Photocatalysis offers a sustainable solution to two pressing global issues: greenhouse gas mitigation and clean energy generation. By harnessing light energy, photocatalytic processes enable water splitting for hydrogen production and CO₂ conversion into value-added products. Among the materials explored for photocatalysis, nickel-based photocatalysts have emerged as highly promising due to their low cost, abundance, stability, and efficiency. This review summarizes recent advancements in Ni-based photocatalysts, highlighting their role in improving photocatalytic performance by enhancing light absorption, charge separation, and reducing charge recombination. Key challenges and future directions for optimizing these materials are also discussed, offering insights into their potential for advancing clean energy technologies.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70014","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Review on High-Efficiency Transfer of Graphene Films Free from Defects and Contamination","authors":"Wenhao Yin,&nbsp;Chong Liu,&nbsp;Jingmin Li","doi":"10.1002/eem2.70009","DOIUrl":"https://doi.org/10.1002/eem2.70009","url":null,"abstract":"<p>Graphene, owing to its exceptional electronic, optical, thermal, and mechanical properties, has emerged as a highly promising material. Currently, the synthesis of large-area graphene films on metal substrates via chemical vapor deposition remains the predominant approach for producing high-quality graphene. To realize the potential applications of graphene, it is essential to transfer graphene films to target substrates in a manner that is non-destructive, clean, and efficient, as this significantly affects the performance of graphene devices. This review examines the current methods for graphene transfer from three perspectives: non-destructive transfer, clean transfer, and high-efficiency transfer. It analyzes and compares the advancements and limitations of various transfer techniques. Finally, the review identifies the key challenges faced by current graphene transfer methods and anticipates future developmental prospects.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring Novel Engineering Strategy to Tune Hydrogen Evolution by Lattice Impacted Carbon-Supported Rock Salt-Type NiCo2(O,F)3 Nanorods","authors":"Aslam Hossain,&nbsp;Zhengyou Li,&nbsp;Alexander V. Soldatov,&nbsp;A. K. M. Atique Ullah","doi":"10.1002/eem2.70020","DOIUrl":"https://doi.org/10.1002/eem2.70020","url":null,"abstract":"<p>This study explores a novel strategy to enhance the hydrogen evolution reaction (HER) activity of carbon-supported rock salt-type NiCo₂(O,F)₃ nanorods through lattice modifications induced by fluorine and excess amorphous carbon. X-ray absorption near-edge structure (XANES) analysis confirmed that Co and Ni predominantly exist in the +2 oxidation state, whereas extended X-ray absorption fine structure (EXAFS) analysis revealed shortened Co–O and Co–Co bond lengths, indicating lattice distortions. Rietveld refinement and electron microscopy confirmed the formation of a homogeneous solid solution (NixCo_2-x(O,F)₃) rather than a simple CoO/NiO composite. The optimized material (AH-2) exhibited the lowest overpotential (145 mV at 10 mA cm⁻¹) and the smallest Tafel slope (98 mV dec⁻¹), attributed to its balanced phase composition, enhanced electronic conductivity, and synergistic effects of carbon and fluorine incorporation. Electrochemical impedance spectroscopy (EIS) confirmed improved charge transfer efficiency, correlating with enhanced catalytic activity. These findings provide critical insights into the tunability of transition metal oxide catalysts via controlled lattice modifications, offering a promising avenue for developing cost-effective and efficient electrocatalysts for sustainable hydrogen production.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70020","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Sustainable Direct Recycling Method for LMO/NMC Cathode Mixture from Retired Lithium-Ion Batteries in EV","authors":"Yu Wang,&nbsp;Kang Shen,&nbsp;Chris Yuan","doi":"10.1002/eem2.12863","DOIUrl":"https://doi.org/10.1002/eem2.12863","url":null,"abstract":"<p>Direct recycling methods offer a non-destructive way to regenerate degraded cathode material. The materials to be recycled in the industry typically constitute a mixture of various cathode materials extracted from a wide variety of retired lithium-ion batteries. Bridging the gap, a direct recycling method using a low-temperature sintering process is reported. The degraded cathode mixture of LMO (LiMn₂O₄) and NMC (LiNiCoMnO₂) extracted from retired LIBs was successfully regenerated by the proposed method with a low sintering temperature of 300°C for 4 h. Advanced characterization tools were utilized to validate the full recovery of the crystal structure in the degraded cathode mixture. After regeneration, LMO/NMC cathode mixture shows an initial capacity of 144.0 mAh g⁻¹ and a capacity retention of 95.1% at 0.5 C for 250 cycles. The regenerated cathode mixture also shows a capacity of 83 mAh g⁻¹ at 2 C, which is slightly higher compared to the pristine material. As a result of the direct recycling process, the electrochemical performance of degraded cathode mixture is recovered to the same level as the pristine material. Life-cycle assessment results emphasized a 90.4% reduction in energy consumption and a 51% reduction in PM2.5 emissions for lithium-ion battery packs using a direct recycled cathode mixture compared to the pristine material.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.12863","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the Impact of Microstructure Alterations on Photocatalytic Hydrogen Peroxide Preparation via DFT Prediction and Analysis","authors":"Hong Tu,&nbsp;Zhichao Zhao,&nbsp;Shunshun Chen,&nbsp;Ya Wang,&nbsp;Shunhong Chen,&nbsp;Jian Zhang,&nbsp;Jian Wu","doi":"10.1002/eem2.70016","DOIUrl":"https://doi.org/10.1002/eem2.70016","url":null,"abstract":"<p>Photocatalytic technology has attracted much attention in the fields of clean energy and environmental governance. However, how to design and develop highly efficient photocatalytic materials remains an urgent scientific problem to be solved. This study focuses on enhancing photocatalytic activity through microstructure modification. Among them, ToRed-4 showed the most prominent performance. Under the illumination condition of 420 nm, its value was 13 506 μmol g⁻¹ h⁻¹, which was approximately 18 times that of CN550 (bulk g-C₃N₄) (719 μmol g⁻¹ h⁻¹). By using DFT calculations, the photocatalytic performance was deeply analyzed, revealing the significant advantages of the ToRed series in key performance indicators and the underlying synergy mechanisms, including the reduction of the HOMO-LUMO energy gap, the efficient separation of electron holes, the expansion of the electronic transition range, the transformation of the electrostatic potential distribution, the increase in dipole moment, and the optimization of the Coulomb attractive energy. The research results of this study provide a key basis for opening up new avenues for the design and development of highly efficient photocatalytic materials and are expected to play an important role in related fields.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70016","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photocatalytic Membrane Filtration: Materials, System Optimization, and External Field Enhancement","authors":"Xianyuan Sun,&nbsp;Jie Tian,&nbsp;Jiayang Cai,&nbsp;Yanjie Wang,&nbsp;Tao He,&nbsp;Xiaoqing Qiu,&nbsp;Zibiao Li,&nbsp;Zuofang Yao,&nbsp;Detlef W. Bahnemann,&nbsp;Jiahong Pan","doi":"10.1002/eem2.70012","DOIUrl":"https://doi.org/10.1002/eem2.70012","url":null,"abstract":"<p>Photocatalytic membranes hold significant potential for promoting pollutant degradation and reducing membrane fouling in filtration systems. Although extensive research has been conducted on the independent design of photocatalysts or membrane materials to improve their catalytic and filtration performance, the complex structures and interface mechanisms, as well as insufficient light utilization, are still often overlooked, limiting the overall performance improvement of photocatalytic membranes. This work provides an overview of enhancement strategies involving restricted area effects, external fields, such as mechanical, magnetic, thermal, and electrical fields, as well as coupling techniques with advanced oxidation processes (e.g., O₃, Fenton, and persulfate oxidation) for dual enhancement of photocatalysts and membranes. In addition, the synthesis method of photocatalytic membranes and the influence of factors, such as light source type, frequency, and relative position on photocatalytic membrane performance were also studied. Finally, economic feasibility and pollutant removal performance were further evaluated to determine the promising enhancement strategies, paving the way for more efficient and scalable applications of photocatalytic membranes.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70012","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Scalable Nickel-Chelated Polydopamine Conformal Coatings for Enhanced Long-term Photostability of BiVO4 Photoanodes","authors":"Weilong Qin,&nbsp;Qitao Liu,&nbsp;Na An,&nbsp;Ruiyuan Sun,&nbsp;Haorui Gong,&nbsp;Neway Belachew,&nbsp;Muhammad Bilal Akbar,&nbsp;Hao Wang,&nbsp;Yang Zhou,&nbsp;Qinglu Liu,&nbsp;Yunzhi Tang,&nbsp;Jianming Li,&nbsp;Jiabo Le,&nbsp;Yongbo Kuang","doi":"10.1002/eem2.70008","DOIUrl":"https://doi.org/10.1002/eem2.70008","url":null,"abstract":"<p>Large-scale bismuth vanadate (BiVO₄) photoanodes are critical to the practical application of photoelectrochemical water splitting devices. However, the lack of interface-modified coatings with simultaneous low cost, scalability, high hole transport efficiency, low impedance, and photocorrosion resistance is a major challenge that prevents the practical application of large-size photoanodes. Here, we present a scalable nickel-chelated polydopamine conformal coating for modifying BiVO₄ (BiVO₄@PDA-Ni, BPNi), achieving over 500 h of stable water oxidation at 0.6 V_RHE. The excellent stability is attributed to the chelated Ni acting as hole oxidation sites for PDA, thereby suppressing the accumulated-holes-induced PDA decomposition. Additionally, the in situ generation of Ni(IV) facilitates the structural reorganization of PDA in the photoelectrochemical system, further enhancing the stability of the PDA matrix. The findings of PDA photodegradation, its autonomous metal ion capture within photoelectrochemical systems, and the rapid deactivation of BPNi photoanodes caused by vanadium (V) ions have all provided significant guidance for the enhancement of PDA. Our study demonstrates that nickel-chelated polydopamine can be applied to large-scale BiVO₄ photoanodes to facilitate oxygen evolution. This will promote the development of large-scale photoanodes suitable for photoelectrochemical devices.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Regulating Reconstruction-Engineered Active Sites of CoP Electrocatalyst by Br Ions During the Oxygen and Hydrogen Evolution Reaction","authors":"Jing Yao,&nbsp;Yuanyuan Zhang,&nbsp;Feng Gao,&nbsp;Qi Jin,&nbsp;Lirong Zhang,&nbsp;Lingling Xu,&nbsp;Mingyi Zhang,&nbsp;Hong Gao,&nbsp;Peng Yu","doi":"10.1002/eem2.70013","DOIUrl":"https://doi.org/10.1002/eem2.70013","url":null,"abstract":"<p>An in-depth understanding of the catalyst surface evolution is crucial for precise control of active sites, yet this aspect has often been overlooked. This study reveals the spontaneous anion regulation mechanism of Br-doped CoP electrocatalysts in the alkaline hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The introduction of Br modulates the electronic structure of the Co site, endowing Br-CoP with a more metallic character. In addition, P ion leaching promotes the in situ reconstruction of Br-CoOOH, which is the real active site for the OER reaction. Meanwhile, the HER situation is different. On the basis of P ion leaching, the leaching of Br ions promotes the formation of CoP-Co(OH)₂ active species. In addition, Br doping enhances the adsorption of *H, showing excellent H adsorption free energy, thereby greatly improving the HER activity. Simultaneously, it also enhances the adsorption of OOH*, effectively facilitating the occurrence of OER reactions. Br-CoP only needs 261 and 76 mV overpotential to drive the current density of 20 mA cm⁻² and 10 mA⁻², which can be maintained unchanged for 100 h. This study provides new insights into anion doping strategies and catalyst reconstruction mechanisms.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reducing Critical Raw Material Use in Commercial Solid Oxide Fuel Cells Using Vertically Aligned Thin-Film Cathodes with Enhanced Long-Term Stability","authors":"Matthew P. Wells,&nbsp;Kosova Kreka,&nbsp;Mohana V. Kante,&nbsp;Miriam Botros,&nbsp;Ozden Celikbilek,&nbsp;Jan Pieter Ouweltjes,&nbsp;Federico Baiutti,&nbsp;Simon M. Fairclough,&nbsp;Caterina Ducati,&nbsp;Albert Tarancón,&nbsp;Judith L. MacManus-Driscoll","doi":"10.1002/eem2.70011","DOIUrl":"https://doi.org/10.1002/eem2.70011","url":null,"abstract":"<p>Solid oxide fuel cells (SOFCs) are widely presented as a sustainable solution to future energy challenges. Nevertheless, solid oxide fuel cells presently rely on significant use of several critical raw materials to enable optimized electrode reaction kinetics. This challenge can be addressed by using thin-film electrode materials; however, this is typically accompanied by complex device fabrication procedures as well as poor mechanical/chemical stability. In this work, we conduct a systematic study of a range of promising thin-film electrode materials based on vertically aligned nanocomposite (VAN) thin films. We demonstrate low area specific resistance (ASR) values of 0.44 cm² at 650 °C can be achieved using (La_0.60Sr_0.40)_0.95Co_0.20Fe_0.80O₃-(Sm₂O₃)_0.20(CeO₂)_0.80 (LSCF-SDC) thin films, which are also characterized by a low degradation rate, approximately half that of planar LSCF thin films. We then integrate these (La_0.60Sr_0.40)_0.95Co_0.20Fe_0.80O₃-(Sm₂O₃)_0.20(CeO₂)_0.80 vertically aligned nanocomposite films directly with commercial anode supported half cells through a single-step deposition process. The resulting cells exhibit peak power density of 0.47 W cm⁻² at 750 °C, competitive with 0.64 W cm⁻² achieved for the same cells operating with a bulk (La_0.60Sr_0.40)_0.95Co_0.20Fe_0.80O₃ cathode, despite 99.5% reduction in cathode critical raw material use. By demonstrating such competitive performance using thin-film cathode functional layers, this work also paves the way for further cost reductions in solid oxide fuel cells, which could be achieved by likewise applying thin-film architectures to the anode functional layer and/or current collecting layers, which typically account for the greatest materials cost in solid oxide fuel cell stacks. Therefore, the present work marks a valuable step towards the sustainable proliferation of solid oxide fuel cells.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70011","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Elevating Lithium and Sodium Storage Performance Through the Synergistic Integration of ZnS and Sulfurized Polyacrylonitrile Hybrid Anode Materials","authors":"Ying Liu,&nbsp;Mingxu Li,&nbsp;Dirfan Zabrian,&nbsp;Dong-Ho Baek,&nbsp;Hyun Woo Kim,&nbsp;Jae-Kwang Kim,&nbsp;Jou-Hyeon Ahn","doi":"10.1002/eem2.70001","DOIUrl":"https://doi.org/10.1002/eem2.70001","url":null,"abstract":"<p>High-performance lithium-ion batteries and sodium-ion batteries have been developed utilizing a hybrid anode material composed of zinc sulfide/sulfurized polyacrylonitrile. The <i>in situ-</i>generated zinc sulfide nanoparticles serve as catalytic agents, significantly enhancing conductivity, shortening diffusion paths, and accelerating reaction kinetics. Simultaneously, the sulfurized polyacrylonitrile fibers form a three-dimensional matrix that not only provides a continuous network for rapid electron transfer but also prevents zinc sulfide nanoparticle aggregation and mitigates volume changes during charge–discharge cycles. Moreover, the heterointerface structure at the junction of zinc sulfide nanoparticles and the sulfurized polyacrylonitrile matrix increases the availability of active sites and facilitates both ion adsorption and electron transfer. As an anode material for lithium-ion batteries, the zinc sulfide/sulfurized polyacrylonitrile hybrid demonstrates a high reversible capacity of 1178 mAh g⁻¹ after 100 cycles at a current density of 0.2 A g⁻¹, maintaining a capacity of 788 mAh g⁻¹ after 200 cycles at 1 A g⁻¹. It also exhibits excellent sodium storage capabilities, retaining a capacity of 625 mAh g⁻¹ after 150 cycles at 0.2 A g⁻¹. Furthermore, <i>ex-situ</i> X-ray photoelectron spectroscopy, X-ray diffraction, ⁷Li solid-state magic angle spinning nuclear magnetic resonance, and <i>in situ</i> Raman are employed to investigate the reaction mechanisms of the zinc sulfide/sulfurized polyacrylonitrile hybrid anode, providing valuable insights that pave the way for the advancement of hybrid anode materials in lithium-ion batteries and sodium-ion batteries.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 4","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.70001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}