International Thermal Spray Conference最新文献

{"title":"Isothermal Oxidation Behavior of MCrAlY Bond Coats after Laser Microtexturing","authors":"T. Kiełczawa, P. Sokołowski, Hanna Myalska-Głowacka, G. Moskal, Hanna Myalska-Głowacka, Alberto Ion, A. Denoirjean, Alberto Ion","doi":"10.31399/asm.cp.itsc2023p0633","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0633","url":null,"abstract":"\u0000 The performance and applicability of thermal barrier coatings (TBCs) depend strongly on the top coat and bond coat interface integrity. The interlayer in TBC systems is often processed prior to top coat spraying to tailor its material properties or surface topography. Both, the bond coat spraying process and the further post-processing may significantly influence the thermally grown oxide (TGO) build-up which is crucial in terms of enhancing the TBC lifetime. In this work, NiCrAlY bond coats were sprayed by means of atmospheric plasma spraying. The as-sprayed bond coats were subjected to laser microtexturing which resulted in different bond coat topographies. Then, the samples were exposed to isothermal oxidation conditions under various oxidation dwell times to see the TGO evolution. The preliminary assessment of the oxidation mechanisms and oxide distribution was done by confocal laser scanning microscopy (CLSM). Scanning electron microscopy with energy dispersive X-Ray spectrometry (SEM/EDS) was used in order to analyze the evolution of bond coat structure and chemical composition during the high temperature oxidation.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"48 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123719246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anisotropy of Mechanical Properties of DMD Build Inconel 738","authors":"O. Kovárík, J. Čech, Egehan Kiziklioglu, J. Cizek, Tobias Stittgen","doi":"10.31399/asm.cp.itsc2023p0473","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0473","url":null,"abstract":"\u0000 Anisotropy of stress-strain behavior, fracture toughness, and fatigue crack growth rate was studied for Inconel 738LC alloy built by the Dynamic Metal Deposition technique (3DMD, a high-speed Directed Energy Deposition technique). The measured quasi-static properties, i.e. stress-strain and fracture toughness showed only subtle anisotropy, with no more than 10% differences found for different orientations. The fatigue crack growth rate was influenced by the specimen orientation more significantly (30% for fatigue crack growth threshold, up to 90% for Paris exponent and coefficient). This pilot study attributes the anisotropy of fatigue crack growth properties to material texture and the columnar grain geometry resulting from directional solidification. The obtained testing results indicate that 3DMD technology can produce materials with good mechanical and fracture properties even from materials considered as non-weldable such as In 738LC. The study provides a solid experimental base for further investigation of the fatigue crack growth mechanism relation to the material texture in 3DMD In 738LC.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"104 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123533028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Novel Fe- and Ni-Based HVOF-Sprayed Coatings Compared to APS-Sprayed TBC Systems for Improved Thermal Insulation Capabilities in Cryogenic Environments","authors":"M. Hauer, A. Gericke, Lukas Möhrke, W. Krömmer, K. Henkel","doi":"10.31399/asm.cp.itsc2023p0357","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0357","url":null,"abstract":"\u0000 In the current work, a NiCrAlY and Fe-based alloy are HVOF-sprayed due to the combination of high coating density and customizable coating properties. The oxygen to fuel gas ratio was varied to modify coating defects in a targeted manner. The results demonstrate material dependent defect mechanisms. Further investigations regarded residual stresses, hardness, and electrical conductivity. In particular, the thermal diffusivity proved to be very promising. Moreover, the coatings were compared with previous work on arc-sprayed coatings of similar chemical composition regarding insulation capability.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122454331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructural Evaluation of Tungsten Carbide-Cobalt (WC-17Co) Alloy Deposited by Cold Spraying, High Velocity Air Fuel, and High Velocity Oxygen Fuel Spraying Technologies","authors":"Theresa Grabowski, D. Gerner, F. Azarmi, Martin McDonnell, Uchechi Okeke","doi":"10.31399/asm.cp.itsc2023p0112","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0112","url":null,"abstract":"\u0000 In this study, microstructural characterization is conducted on WC-17Co coatings produced via High Velocity Oxygen Fuel (HVOF), High Velocity Air Fuel (HVAF), and Cold Spraying (CS). All coatings prepared were observed to be of good quality and with relatively low porosity content. SEM study showed important microstructural features and grain morphologies of each coating. While composition of feedstock material was approximately similar, elemental composition using EDS showed higher Co content and lower WC in the CS deposited coating. XRD experiment identified formation of more complex oxides and tungsten phases in coatings deposited technologies involving melting of powders such as HVOF and HVAF. These phases consisted mainly of cobalt oxides and brittle phases such as W3Co3C or W2C caused by decarburization of the tungsten carbide particles. Hardness of all coating samples were examined and CS deposited coating exhibited considerably lower hardness compared to the other two coating samples instead of having significantly lower porosity content. It could be contributed to dissociation and physical loss of hard carbide phase during high velocity impact of particles in CS process. It is in good agreement with detection of higher amount of cobalt in CS deposited coating material. It is strongly believed that results obtained from this study can be used for future investigation in thermo-mechanical properties of WC-Co coatings.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"145 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121252655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Carbon Fiber Orientation when Cold Spraying Metallic Powders onto Carbon Fiber Reinforced Polymers","authors":"A. Liberati, Payank Patel, A. Roy, P. Vo, Chunzhou Pan, C. Moreau, R. Chromik, S. Yue, P. Stoyanov","doi":"10.31399/asm.cp.itsc2023p0280","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0280","url":null,"abstract":"\u0000 A previous study on the pull-off testing of metallized carbon fiber reinforced polymers (CFRPs) via cold spray showed that better adhesion strengths could be obtained when features such as carbon fibers or surfacing elements were present, by providing potential mechanical interlocking features. In this work, the effect of the fiber orientation on the deposition and bonding of the metallic coating to the thermoplastic composite substrate is explored. Pure Sn powder was cold sprayed onto two thermoplastic Polyether-Ether- Ketone (PEEK) CFRP substrates, containing carbon fibers with different orientations: one had fibers in the plane of the substrate (uni-directional tape), while the other had fibers mostly perpendicular to the substrate (ZRT film). Characterization of the coatings was performed via scanning electron microscopy (SEM) and confocal microscopy, and some aspects of mechanical testing (namely wear and scratch testing) were carried out to assess the effect of the substrate on the properties of the coatings.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125258173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effects of Thermal Exposure on Microstructure of Thermal Barriers Deposited by Hybrid Plasma Spraying","authors":"JRadek Musalek, T. Tesar, J. Medricky, F. Lukáč, J. Dudik","doi":"10.31399/asm.cp.itsc2023p0422","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0422","url":null,"abstract":"\u0000 Hybrid plasma spraying combines plasma spraying of dry powders and liquids (suspensions and solutions). Combination of these two approaches allows deposition of microstructures consisting of both conventional coarse and ultrafine splats. Moreover, splats with dissimilar size may have also different chemistry. Such combination is potentially interesting for many fields of thermal spraying, including thermal barrier coatings (TBCs), as novel microstructures may be economically and relatively easily obtained. The technology has recently reached a level, where coatings with interesting hybrid microstructures may be reliably deposited, so that their potential for practical applications may be evaluated. In this study, first experimental TBCs with YSZ-based hybrid topcoat were deposited by hybrid water/argon stabilized plasma (WSP-H) technology. Al2O3 and YAG were selected as secondary phase deposited from suspension as both provide strong materials contrast in scanning electron microscope (SEM) so they can be used as “markers” in the coating microstructure. Samples were exposed to thermal cycling simulating in-service TBC conditions in order to test their thermal shock resistance. Changes of the coating microstructure were studied by SEM analysis and X-ray diffraction.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125301356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Study on the Powder Manufacturing Effect on Flowability and Deformability of Pure Cu Powders in Cold Spray Application","authors":"N. Eftekhari, D. Saha, H. Jahed","doi":"10.31399/asm.cp.itsc2023p0560","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0560","url":null,"abstract":"\u0000 The quality of feedstock powder is a critical factor in determining the properties of coatings deposited using cold spray (CS). However, most commercially available powders are not designed or optimized for CS applications, making it challenging to tailor powders to desired quality. In this research, we investigated and compared the cold-sprayability of four different Cu powders produced by electrolysis and gasatomization methods. We assessed the powders' microstructure, particle morphology and size distribution to understand the effect of manufacturing methods on Cu powder characteristics. We also studied the flowability of the powders using the shear cell method and evaluated their mechanical properties and deformability for CS using nano-indentation. Our results showed that gas-atomized powders with equiaxed grains exhibited promising flowability and deformability for CS applications, outperforming the other powders tested. Specifically, the spherical morphology of gas-atomized powders provided less surface area than the irregular-shaped electrolytic powder, reducing the interaction of surface forces and contributing to smooth powder flow. Additionally, the gasatomized powder with small dendrites in the microstructure exhibited the highest nano-hardness value (HIT= 1.6±0.1 GPa), while the porous electrolytic Cu powder had the lowest value (HIT= 0.7±0.2 GPa). In conclusion, we found that gas-atomized Cu powders with equiaxed grains may hold promise as the optimised feedstock for CS application, considering both effective metrics of flowability and deformability.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117001575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hybrid Aerosol Deposition of Dense Al2O3 Coatings and Evaluation of the Through-Thickness Effect","authors":"M. Shahien, K. Shinoda","doi":"10.31399/asm.cp.itsc2023p0443","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0443","url":null,"abstract":"\u0000 Hybrid aerosol deposition (HAD) has been proposed recently as a new coating regime to deposit homogeneous ceramic coatings via the utilization of mesoplasma and solid particle deposition. This study will discuss the implementation of HAD for the deposition of alumina (Al2O3) coatings on 304 stainless steel and aluminum substrates, and evaluation of the hardness and Young’s modulus using a nanoindentation method to clarify the through-thickness properties. Dense and uniform coatings with a nanocrystalline structure were fabricated on both substrate materials. The fabricated HAD coatings consisted of α-Al2O3 phase. The hardness and Young’s modulus distributions along the through-thickness direction showed a significant difference across the coating-substrate interface and tended to show a slight decrease by 10-15% as the measured position went close the surface. Increasing the hardness and Young’s modulus on the substrate side near the interface is presumably related to the peeing effect of the substrate as well as the increase of interface roughness during the room temperature impact consolidation (RTIC) and deformation of the hard ceramic particles on the substrate. The decrease in the coating’s mechanical properties along the through-thickness direction is considered to be related to the particle deformation tendency during the coating build-up. At the beginning stage of the deposition, initial particles are impacting on a metallic substrate which is ductile enough to facile plastic deformation and the deposited layer can have an enough hammering effect by the subsequent impacting particles. The hardness and Young’s modulus in this location are 15.6 GPa and 246 GPa, respectively, and the highest through the thickness in case of the stainless steel substrate. However, the later particles are impacting on a hard ceramic surface (initially formed HAD Al2O3 layers), which hardly undergo plastic deformation or led to less particle deformation. In addition, through-thickness measurements revealed that the deposited coatings on the stainless steel substrate showed higher hardness than deposited coatings on aluminum substrates. Thus, the stainless steel enhances the degree of deformation of the deposited particles, and the resulted smaller crystallite size and strain lead to increased hardness and modulus.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"128 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128213273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advanced Techniques for Evaluation of Thermal Shock Durability of Thermal Barrier Coating","authors":"Kazuma Takeno, Y. Okajima, T. Torigoe, S. Kuroda, K. Ito","doi":"10.31399/asm.cp.itsc2023p0683","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0683","url":null,"abstract":"\u0000 Although increasing the thickness of thermal barrier coating (TBC) enhances its thermal protection capability, it generally decreases its thermal shock durability. This is caused by an increase of thermal stress due to the increase of the temperature differential between the TBC surface and the metal surface. In order to realize the optimum TBC thickness, the thermal shock durability of TBC should be evaluated precisely and quantitatively. This study focused on two advanced techniques to evaluate the durability of TBC that were developed through joint research with the National Institute for Materials Science (NIMS). The first technique utilizes a new acoustic emission (AE) measurement system called continuous wave memory (CWM), which can analyze AE events more precisely than conventional AE systems. The second technique is a noncontact strain measurement method using laser speckles, which can measure the strain on the TBC surface at high temperature. These techniques were combined with a laser thermal cycle test to establish the “𝜖H-N diagram”, which shows the relationships between the hot shock strain 𝜖H in the laser thermal cycle test and the cycle number N to failure for different TBC thicknesses. In these experiments, CWM was used to determine the TBC failure more precisely, while the laser speckle method was used to measure the thermal shock strain 𝜖H. The obtained 𝜖H-N diagram revealed the durability of TBC for various thicknesses and was transformed to an evaluation map to predict the TBC thickness limitation. For real parts, this evaluation map is useful to estimate if a thicker TBC will fail or not by comparing the maximum strain it is predicted to undergo by numerical analysis.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129002586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Laser Texturing as Interfacial Treatment for Enhancing the Material Behaviors—The Real Influence of the Laser Treatment","authors":"S. Costil, Laura Convert, E. Bourillot, Nicolas Pocholle, M. François","doi":"10.31399/asm.cp.itsc2023p0428","DOIUrl":"https://doi.org/10.31399/asm.cp.itsc2023p0428","url":null,"abstract":"\u0000 Surface texturing is one of the most technologically appropriate laser surface treatment applications. Over the past few decades, texturing has emerged as an attractive surface engineering option and has been used by researchers to generate micro/nanopatterns on operating surfaces. This technique can create simple or complex patterns on component surfaces depending on their aesthetic or functional goals and without altering the overall properties. In addition, this non-contact process can be applied to hard-to-reach areas. Recently, laser surface texturing has been applied to improve the adhesion of contact surfaces. Several authors have demonstrated the impact and benefits of textured surfaces to achieve optimal adhesion of coatings and increase in-service behavior. Nevertheless, based on the laser-matter interaction phenomena, chemical and mechanical transformations of the surfaces can be noticed but are difficult to characterize. Indeed, the affected layers are of the order of a few hundred nanometers. Then, analyses must be performed with variable levels of resolution in order to analyze the structural, chemical and mechanical characteristics of the matter. To develop new applications of unconventional assemblies and improved adhesion of new materials, a control of these local modifications is required.","PeriodicalId":114755,"journal":{"name":"International Thermal Spray Conference","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123872724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}