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Substrate temperature effect on the structural, morphological and optical properties of pyrolyzed bi-phase Cu2O–CuO thin films 基底温度对热解双相 Cu2O-CuO 薄膜的结构、形态和光学特性的影响
Results in Materials Pub Date : 2024-06-27 DOI: 10.1016/j.rinma.2024.100599
P.R. Jubu , J.D. Fanafa , A.B. Atsuwe , C. Mbakaan , Y. Yusof , O.S. Obaseki , M.B. Ochang , E. Danladi , V. Mbah , T. Mkanan
{"title":"Substrate temperature effect on the structural, morphological and optical properties of pyrolyzed bi-phase Cu2O–CuO thin films","authors":"P.R. Jubu ,&nbsp;J.D. Fanafa ,&nbsp;A.B. Atsuwe ,&nbsp;C. Mbakaan ,&nbsp;Y. Yusof ,&nbsp;O.S. Obaseki ,&nbsp;M.B. Ochang ,&nbsp;E. Danladi ,&nbsp;V. Mbah ,&nbsp;T. Mkanan","doi":"10.1016/j.rinma.2024.100599","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100599","url":null,"abstract":"<div><p>Multiphase nanomaterials are fascinating due to the synergistic effect between the crystalline phases that lead to improved device performance. Publications are available for the synthesis of monophasic copper oxides, such as Cu<sub>2</sub>O and CuO, and the mixed-phase Cu<sub>2</sub>O–CuO counterpart using different synthesis methods. However, literature report is scarce that focuses on the fabrication of bi-phase Cu<sub>2</sub>O–CuO thin films by the spray pyrolysis technique without phase transformation to form the monophasic counterparts. The present work attempts to prepare solely mixed-phase Cu<sub>2</sub>O–CuO films through small incremental change in substrate temperature, in steps of 20 <span><math><mrow><mo>°C</mo></mrow></math></span>. Structural analysis of the pyrolyzed films revealed the formation of a bi-phase Cu<sub>2</sub>O–CuO crystal system. The crystallite size increased from 18.64 to 23.94 nm, microstrain decreased from 7.134 <span><math><mrow><mo>×</mo><msup><mn>10</mn><mrow><mo>−</mo><mn>4</mn></mrow></msup></mrow></math></span> to 5.625 <span><math><mrow><mo>×</mo><msup><mn>10</mn><mrow><mo>−</mo><mn>4</mn></mrow></msup></mrow></math></span>, while stacking faults decreased from 3.753 <span><math><mrow><mo>×</mo><msup><mn>10</mn><mrow><mo>−</mo><mn>3</mn></mrow></msup></mrow></math></span> to 2.942 <span><math><mrow><mo>×</mo><msup><mn>10</mn><mrow><mo>−</mo><mn>3</mn></mrow></msup></mrow></math></span> with an increase in temperature. Microstructural analysis showed nanoaggregates with increased particle size at increasing temperature. The films exhibited a common optical bandgap of 2.61 eV. The values of the static refractive index and optical electronegativity were found to be 2.47 and 0.70, respectively. The surface roughness increased from 41.3 to 90.9 nm with substrate temperature.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100599"},"PeriodicalIF":0.0,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000736/pdfft?md5=28f60fbd7bc56e0339618ea46094df02&pid=1-s2.0-S2590048X24000736-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141485778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring uncommon Fe-oxides in non-metallic inclusions in ultra-high-strength steel 探索超高强度钢中非金属夹杂物中不常见的铁氧化物
Results in Materials Pub Date : 2024-06-22 DOI: 10.1016/j.rinma.2024.100598
Ekta Rani , Vandna K. Gupta , Francis Gyakwaa , Mourad Kharbach , Harishchandra Singh , Tuomas Alatarvas , Anna Martinelli , Timo Fabritius , Marko Huttula
{"title":"Exploring uncommon Fe-oxides in non-metallic inclusions in ultra-high-strength steel","authors":"Ekta Rani ,&nbsp;Vandna K. Gupta ,&nbsp;Francis Gyakwaa ,&nbsp;Mourad Kharbach ,&nbsp;Harishchandra Singh ,&nbsp;Tuomas Alatarvas ,&nbsp;Anna Martinelli ,&nbsp;Timo Fabritius ,&nbsp;Marko Huttula","doi":"10.1016/j.rinma.2024.100598","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100598","url":null,"abstract":"<div><p>Investigating non-metallic inclusions within ultra-high-strength-steel via conventional methods is a known: however, the challenge is to obtain chemical information of such inclusions at the sub-micrometer level. In this context, probing Fe-based oxide in inclusions is a vital aspect for guiding steel’ performance. The vibrational properties of sub micrometer size Fe-based oxides were investigated by Raman mapping along with chemometric analysis with the aim of probing their chemical composition. Highly contrasted Raman spectra were recorded from several inclusions embedded at different spatial locations. The observed spectral features were identified as specific markers of hematite (α-Fe<sub>2</sub>O<sub>3</sub>) and magnetite (Fe<sub>3</sub>O<sub>4</sub>). Principal Component Analysis was used to confirm the presence of these markers and potentially revealing additional patterns. Their unambiguous assignment has been inferred by comparing our experimental findings with the literature data recorded either in single crystals of iron oxides or oxyhydroxides. Micro-Raman spectroscopy is proven to be a reliable, cost-effective, and non-invasive tool for the unambiguous identification of subsurface regions of steel.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100598"},"PeriodicalIF":0.0,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000724/pdfft?md5=581c5eb214900c55f760d22dbf6e8972&pid=1-s2.0-S2590048X24000724-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141485773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improved thermoelectric properties in solid state microwave of Zn1-xYbxSb compound by Yb for Zn substitution 以镱代锌改善 Zn1-xYbxSb 化合物在固态微波中的热电性能
Results in Materials Pub Date : 2024-06-21 DOI: 10.1016/j.rinma.2024.100597
Arej Kadhim
{"title":"Improved thermoelectric properties in solid state microwave of Zn1-xYbxSb compound by Yb for Zn substitution","authors":"Arej Kadhim","doi":"10.1016/j.rinma.2024.100597","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100597","url":null,"abstract":"<div><p>In this research, the Zn-Yb-Sb materials in the form Zn<sub>1-x</sub>Yb<sub>x</sub>Sb; x = 0.02 to 0.8, were composed by a solid-state microwave method. These samples were examined to determine the crystal structure by XRD analysis, which indexed to the orthorhombic phase. The dominant peak (112) had a clearly shift in Bragg angle from 28.536° to 28.784° with increasing Yb content. The Yb content (x) effects on the thermoelectric properties (TE) was measured at the temperature reach to 500 K. Increased the Yb content (the sample with x = 0.8) in Zn<sub>1-x</sub>Yb<sub>x</sub>Sb caused an increase in the Seebeck coefficient (486 μV/K at 433 K) and a decrease in each of the hole concentration (3.02 × 10<sup>21</sup> cm<sup>−3</sup>) and the electrical conductivity (5320 S/m). Ascribing to the increased Seebeck coefficient, the higher value of the power factor measured in this research was 1257 μW/mK<sup>2</sup> at 473K for the sample of Zn<sub>0.92</sub>Yb<sub>0.08</sub>Sb (x = 0.08).). These experimental results suggest that a clear idea of the application of the Zn<sub>1-x</sub>Yb<sub>x</sub>Sb for TE modules.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100597"},"PeriodicalIF":0.0,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000712/pdfft?md5=cc610f455aee429a029dcbdf7ae38526&pid=1-s2.0-S2590048X24000712-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141485772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced room temperature ferromagnetism and versatile optical properties in MgFe2O4 spinel ferrite prepared under different calcination temperatures 不同煅烧温度下制备的 MgFe2O4 尖晶石铁氧体增强的室温铁磁性和多功能光学特性
Results in Materials Pub Date : 2024-06-20 DOI: 10.1016/j.rinma.2024.100596
Thanit Tangcharoen
{"title":"Enhanced room temperature ferromagnetism and versatile optical properties in MgFe2O4 spinel ferrite prepared under different calcination temperatures","authors":"Thanit Tangcharoen","doi":"10.1016/j.rinma.2024.100596","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100596","url":null,"abstract":"<div><p>This study employs the sol-gel auto combustion technique fueled by diethanolamine (DEA) to synthesize nanocrystalline magnesium ferrite (MgFe<sub>2</sub>O<sub>4</sub>) powders. During the study, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–visible diffuse reflectance spectroscopy (UV-DRS), photoluminescence spectroscopy (PL), and vibrating sample magnetometry (VSM) were then used in order to determine how differing calcination temperatures influence the structure, chemical bonding, surface texture, morphology, optical, fluorescence, and magnetic properties of the resulting MgFe<sub>2</sub>O<sub>4</sub> powders. The findings from the XRD and FT-IR analysis indicate that a single-phase spinel structure is formed in each of the MgFe<sub>2</sub>O<sub>4</sub> samples. According to UV-DRS analysis, optimal calcination improved sample reflection levels in comparison to the visible and infrared spectral findings for the as-synthesized sample. The calcined samples exhibited bandgap energy (<em>E</em><sub><em>g</em></sub>) ranging from 2.11 eV to 2.14 eV, which was greater than the 2.02 eV of the as-synthesized sample. Examination of the PL spectra in the range of 380–700 nm revealed various light emission bands for the samples, which increased significantly in intensity at higher calcination temperatures. Furthermore, higher calcination temperatures also increased the magnetization of the MgFe<sub>2</sub>O<sub>4</sub> spinel powders, while coercivity dropped significantly.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100596"},"PeriodicalIF":0.0,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000700/pdfft?md5=5408b74b8ad6fc2d4271203a2fc4f0dc&pid=1-s2.0-S2590048X24000700-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141438790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Heat of hydration of Portland cement containing coal-derived char at different temperatures 不同温度下含煤焦的硅酸盐水泥的水化热
Results in Materials Pub Date : 2024-06-18 DOI: 10.1016/j.rinma.2024.100595
Hua Yu, Prayush Jonchhe, Chooikim Lau, Kam Ng
{"title":"Heat of hydration of Portland cement containing coal-derived char at different temperatures","authors":"Hua Yu,&nbsp;Prayush Jonchhe,&nbsp;Chooikim Lau,&nbsp;Kam Ng","doi":"10.1016/j.rinma.2024.100595","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100595","url":null,"abstract":"<div><p>The heat of hydration is fundamental in understanding the hydration mechanism of cementitious materials, and temperature can significantly affect the heat of hydration. A recent study has shown that coal-derived char can be used as a green additive for improving the engineering properties of conventional cement grout. However, the impact of temperature on heat of hydration of char-cement grout is currently unknown. In this study, the heat of hydration (with degree of hydration) of cement and char-cement grouts at 5, 23, and 35 °C are investigated. This study reveals that incorporating char into the cement grout enhances its degree of hydration at temperatures ranging from 5 to 35 °C, highlighting the potential advantages of using coal char in grouting applications, especially at low temperature.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100595"},"PeriodicalIF":0.0,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000694/pdfft?md5=f9199c0821ef7bd862f65a5f36e57147&pid=1-s2.0-S2590048X24000694-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141429452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of preheating before rolling on the microstructural and mechanical properties of lamellar Al/Ti/Al composite produced by roll bonding 轧制前预热对轧制粘接法生产的片状铝/钛/铝复合材料微观结构和机械性能的影响
Results in Materials Pub Date : 2024-06-18 DOI: 10.1016/j.rinma.2024.100594
Hamid Partoyar, Hamed roghani, Hamid Reza jafarian, Mehrad Roshani
{"title":"Effect of preheating before rolling on the microstructural and mechanical properties of lamellar Al/Ti/Al composite produced by roll bonding","authors":"Hamid Partoyar,&nbsp;Hamed roghani,&nbsp;Hamid Reza jafarian,&nbsp;Mehrad Roshani","doi":"10.1016/j.rinma.2024.100594","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100594","url":null,"abstract":"<div><p>This study explores the effect of preheating before rolling on the microstructural and mechanical properties of an AA5052/Ti/AA5052 lamellar composite fabricated by roll bonding. The roll bonding was done in two ways: conventional rolling and preheating before rolling. Preheating was done before rolling for 7 min at 350 °C. Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), microhardness, and tensile tests were used for microstructural and mechanical investigations. By performing preheating, the strength increased from 468 MPa to 511 MPa, elongation changes were insignificant, and hardness decreased in aluminum and titanium layers from 108 to 100 HV and 234 to 212 HV, respectively. By preheating, aluminum diffusion in titanium and metallurgical connection occurred. Therefore, SEM showed better bonding in preheated specimens.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100594"},"PeriodicalIF":0.0,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000682/pdfft?md5=0c61ef17c79311d9681416928c4606d6&pid=1-s2.0-S2590048X24000682-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141428878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bio responsive block: The performance of bio waste material with reduced environmental impact 生物反应块:生物废料的性能,减少对环境的影响
Results in Materials Pub Date : 2024-06-18 DOI: 10.1016/j.rinma.2024.100589
Runda Aduldejcharas
{"title":"Bio responsive block: The performance of bio waste material with reduced environmental impact","authors":"Runda Aduldejcharas","doi":"10.1016/j.rinma.2024.100589","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100589","url":null,"abstract":"<div><p>The key purpose of this research is to establish guidelines on how to manage Bio Waste Material. A field study was performed to examine the environmental problems caused by Bio Waste Material that is made up of Perna Viridis (PV) shells, the latter of which is a common type of mussel found in Bang Ja Kreng Community, Samut Songkhram Province. This area is a fishery location and experiences vast quantities of shell waste, which ultimately impacts community pollution. It is not possible to dispose of this waste in a traditional manner and there are no specific locations where the shells can be dumped. Consequently, most people secretly dispose of them in mangrove forests or along public roadsides. Thus, in order to facilitate future use, the researcher conducted an analytical investigation to examine material performance. The temperatures at which mussel shells were burned were 400, 800, and 1200 °C. An X-ray diffractometer (XRD), a device that examines X-ray diffraction through layers of atoms or molecules in materials or sample substances, was Utilised to Analyse their elements. Furthermore, this analytical investigation also included X-ray fluorescence (XRF) as a tool to examine the elemental compositions. It was discovered that burning altered the chemical structure at different temperatures. Portland cement contained the same components. It was revealed that CaO constituted as much as 80.14 % of the weight below 1200 °C. In general, CaO was discovered to constitute up to 64.73 % of the weight when comparing cement. It is a substance that is used to research cement reduction when manufacturing Bio-Responsive Blocks. In order to compare lower costs and larger profits, the compound was divided into different ratios. An ANSYS simulation was used to Analyse the material properties and create three models: one for a single concrete Block and another for an 80 × 80 cm wall. The experiments did not involve the use of columns or beams. Instead of using the wall as a load-bearing wall, the goal was to add value to the product processing of mussel shell waste and determine how it can be recycled and reused beneficially (i.e., to improve sustainability or create a pleasant community environment.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100589"},"PeriodicalIF":0.0,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000633/pdfft?md5=5af0b120c0537325876b8de3ec14d680&pid=1-s2.0-S2590048X24000633-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141435123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
UV-heat dually curable epoxy resin composites with low filler contents and high curing speed 具有低填料含量和高固化速度的紫外线加热双固化环氧树脂复合材料
Results in Materials Pub Date : 2024-06-17 DOI: 10.1016/j.rinma.2024.100586
Zheqin Liu, Peng Li, Suibin Luo, Zheng Liu, Rong Sun, Shuhui Yu
{"title":"UV-heat dually curable epoxy resin composites with low filler contents and high curing speed","authors":"Zheqin Liu,&nbsp;Peng Li,&nbsp;Suibin Luo,&nbsp;Zheng Liu,&nbsp;Rong Sun,&nbsp;Shuhui Yu","doi":"10.1016/j.rinma.2024.100586","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100586","url":null,"abstract":"<div><p>Epoxy resin composites are a type of polymer-based materials with wide application scopes. A mass of fillers was added to improve thermal properties which may degrades mechanical properties at the same time. In addition, the common heat-curing process takes several hours to completely cure. To improve the performance of epoxy resin composites of low-content fillers, we prepare UV-heat dually curable epoxy resin with silicate ester. The overall curing time of UV-heat curing process is about half of the traditional thermal-curing process. The breakdown voltage of epoxy resin modified by silicate ester is up to 181 MV/m, which is increased by 50 % compared to pure epoxy resin. The silicate ester curing agent can react with both epoxy resin and silica fillers and can thus improve the dispersion of the fillers in the matrix and enhance the interaction between fillers and the resin. As a result, the coefficient of thermal expansion (CTE) of the composites was greatly reduced. The CTE of silicate ester-modified epoxy resin composites is 93 ppm/K and 137 ppm/K over the temperature range below and above its T<sub>g</sub>, respectively, which is 25 % lower than those of normal epoxy resin composites.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100586"},"PeriodicalIF":0.0,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000608/pdfft?md5=2f8aee3aa248c0493fa6e617a70434f0&pid=1-s2.0-S2590048X24000608-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141423998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of machine parameters and wall thickness on microstructural characteristics and microhardness of laser powder bed fusion Inconel 718 parts following heat-treatment 机器参数和壁厚对热处理后激光粉末床熔融 Inconel 718 零件的微观结构特征和显微硬度的影响
Results in Materials Pub Date : 2024-06-13 DOI: 10.1016/j.rinma.2024.100585
A. Doris , L. Trujillo , E. Arrieta , L.E. Murr , P. Gradl , C.C. Katsarelis , V. Hafiychuk , K.R. Wheeler , R.B. Wicker , F. Medina
{"title":"Impact of machine parameters and wall thickness on microstructural characteristics and microhardness of laser powder bed fusion Inconel 718 parts following heat-treatment","authors":"A. Doris ,&nbsp;L. Trujillo ,&nbsp;E. Arrieta ,&nbsp;L.E. Murr ,&nbsp;P. Gradl ,&nbsp;C.C. Katsarelis ,&nbsp;V. Hafiychuk ,&nbsp;K.R. Wheeler ,&nbsp;R.B. Wicker ,&nbsp;F. Medina","doi":"10.1016/j.rinma.2024.100585","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100585","url":null,"abstract":"<div><p>This study investigates a series of geometric feature build plates manufactured by multiple laser powder bed fusion (L-PBF) machine configurations, examining seven different wall thicknesses ranging from 0.1 to 2.0 mm. These build plates and thin wall specimens completed a full heat treatment cycle: stress relief (SR), HIP, solution, and aging per standards. The fully heat-treated (FHT) Inconel 718 wall specimens were sectioned from sixteen different geometric feature build plates built across fifteen different L-PBF machines. They were characterized by optical microscopy and EBSD image mapping. The microstructural evolution from the As-built sample, SR, HIP to FHT wall specimens from a single machine configuration was also obtained along with cooling rate simulations for 0.1 mm, 0.2 mm, 0.5 mm, and 0.8 mm wall thicknesses. The difference in cooling rates between the thick and thin walls was simulated to provide an understanding of microstructural evolution and evaluate the computer simulation as a tool to predict microstructural features. For FHT wall specimens, results indicate mostly equiaxed grain structures containing annealing twins, ranging in size from ∼21 μm to 93 μm parallel and perpendicular to the build direction. For most of the samples, the grain size was shown to increase with the increasing wall thickness due to slower solidification rates. The double aging composing the fully heat-treated thin walls also fully age-hardened the grain structures with gamma double-prime precipitates. This precipitation produced a median Vickers (HV) hardness for nominal section thicknesses &gt;0.6 mm of ∼ HV 472; consistent with commercially heat-treated and optimized Inconel 718 products. Feature sizes &gt;0.6 mm were reproducible for all L-PBF machine configurations.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100585"},"PeriodicalIF":0.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X24000591/pdfft?md5=cb9b5c2c55c6b795f37c76c8e8f58a9e&pid=1-s2.0-S2590048X24000591-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141325049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quartz and feldspar-blended clay composites for thermal and structural applications 用于热能和结构应用的石英和长石混合粘土复合材料
Results in Materials Pub Date : 2024-06-05 DOI: 10.1016/j.rinma.2024.100584
Chijioke P. Egole , Rasaq O. Medupin , Gaius C. Nzebuka , Nnamdi A. Nnodum , Ugochukwu P. Ochieze , Orevaoghene Eterigho-Ikelegbe , Uwemedimo N. Wilson , Kelvin O. Yoro
{"title":"Quartz and feldspar-blended clay composites for thermal and structural applications","authors":"Chijioke P. Egole ,&nbsp;Rasaq O. Medupin ,&nbsp;Gaius C. Nzebuka ,&nbsp;Nnamdi A. Nnodum ,&nbsp;Ugochukwu P. Ochieze ,&nbsp;Orevaoghene Eterigho-Ikelegbe ,&nbsp;Uwemedimo N. Wilson ,&nbsp;Kelvin O. Yoro","doi":"10.1016/j.rinma.2024.100584","DOIUrl":"https://doi.org/10.1016/j.rinma.2024.100584","url":null,"abstract":"<div><p>In this study, some selected clay samples were beneficiated and blended with quartz and feldspar in various proportions to develop composites with good thermal and structural performance for sustainable development. X-ray fluorescence <strong>(</strong>XRF) analysis affirms the aluminosilicate nature of the clay samples and other trace oxides. The pore volume of the fired bulk composites disappears at 1200 °C leading to a decline in apparent density, apparent porosity, and water absorption. Furthermore, this study revealed that at the same temperature, the bulk density (1.69, g/cm<sup>3</sup>, 1.78, g/cm<sup>3</sup>, 1.78 g/cm<sup>3</sup>), modulus of rupture (33.2 kg/cm<sup>3</sup>, 39.34 kg/cm<sup>3</sup>, 38.88 kg/cm<sup>3</sup>), and total shrinkage (23.6 %, 22.3 %, 20.6 %) were maximum. Additionally, the results showed that the relative plasticity of the clay samples improved with the addition of feldspar and quartz from 1.27 to 1.33 and 1.35 for the fired composites (BO1: 50 % clay, 30 % feldspar, 20 % quartz, and CO1: 50 % clay, 25 % feldspar, 25 % quartz), respectively. Results obtained from thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis confirmed the clay samples to be thermally stable. The X-ray diffraction (XRD) patterns of all the fired composites showed major peaks, with quartz content being the highest at 27.5° (2θ) angle, albite presenting the lowest non-clay mineral content. Based on the analyses conducted in this study, it could be inferred that the clay sample is suitable for thermal insulation and structural applications.</p></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"23 ","pages":"Article 100584"},"PeriodicalIF":0.0,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590048X2400058X/pdfft?md5=ba21a17a09047678efa80ba0bd0f12ea&pid=1-s2.0-S2590048X2400058X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141325048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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