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Macadamia nutshell particulates as sustainable fillers in epoxy- and cement-based polymer composites 夏威夷果壳颗粒在环氧树脂和水泥基聚合物复合材料中的可持续填料
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-03-10 DOI: 10.1016/j.rinma.2026.100923
Md Sefat Khan, Md Mainul Islam, Jayantha Epaarachchi
{"title":"Macadamia nutshell particulates as sustainable fillers in epoxy- and cement-based polymer composites","authors":"Md Sefat Khan,&nbsp;Md Mainul Islam,&nbsp;Jayantha Epaarachchi","doi":"10.1016/j.rinma.2026.100923","DOIUrl":"10.1016/j.rinma.2026.100923","url":null,"abstract":"<div><div>The growing global emphasis on sustainable materials has intensified interest in cellulosic resources for structural applications. Traditional high-performance materials, such as steel and glass fibers, have significant environmental drawbacks due to energy-intensive production and high carbon footprints. In this study, macadamia nutshell particulates (MNPs) were explored as a sustainable filler in synthetic polymer–natural fiber composites, aiming to address the limited compatibility between hydrophilic cellulose fibers and hydrophobic polymer matrices. The physical characteristics of the polymer–filler composites are influenced by intrinsic polymer structure (e.g., molecular weight, crystallinity, crosslinking) and external conditions (e.g., temperature, loading rate, and aging). Structural, physical and chemical characterization were performed. Various mixture ratios and processing conditions were investigated for both epoxy resin- and cement-based matrices. Results indicate that MNPs provided superior interfacial bonding and structural performance compared with other fillers, such as coconut shell and sawdust, particularly in epoxy resin systems, where improved adhesion and workability were observed. However, incorporating cellulosic fillers reduced stress and stiffness in epoxy-based composites. Interfacial strength was found significantly weaker among MNP and cement-based matrix. These findings demonstrate the potential of MNPs as an environmentally friendly filler, offering a viable pathway toward sustainable polymer composite development.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100923"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147448759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First principle studies of thermo-physical and optoelectronic properties of LiBP (B = Zn, Mg) Half-Heusler alloys for photovoltaic application 光伏用LiBP (B = Zn, Mg)半heusler合金热物理和光电子性能第一性原理研究
Results in Materials Pub Date : 2026-03-01 Epub Date: 2025-12-12 DOI: 10.1016/j.rinma.2025.100838
Kimurgor R. Justus , Madallah Yusuf , George S. Manyali , Felix O. Saouma
{"title":"First principle studies of thermo-physical and optoelectronic properties of LiBP (B = Zn, Mg) Half-Heusler alloys for photovoltaic application","authors":"Kimurgor R. Justus ,&nbsp;Madallah Yusuf ,&nbsp;George S. Manyali ,&nbsp;Felix O. Saouma","doi":"10.1016/j.rinma.2025.100838","DOIUrl":"10.1016/j.rinma.2025.100838","url":null,"abstract":"&lt;div&gt;&lt;div&gt;This study employs first-principles density functional theory (DFT) calculations to investigate the thermophysical and optoelectronic properties of LiBP (B = Zn, Mg) Half-Heusler (HH) alloys, with a focus on their potential photovoltaic and thermoelectric applications. The key findings are their semiconducting nature with direct band gaps of &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;E&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;g&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;34&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;eV&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; (LiZnP) and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;E&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;g&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;34&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;eV&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; (LiMgP), calculated using the PBE-GGA functional. Lithium Zinc Phosphide (LiZnP) demonstrates a higher refractive index (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;n&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;37&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;), and a larger dielectric constant, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;ɛ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;6&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, and stronger optical absorption and light interaction, making it a promising candidate for high absorption optoelectronic applications. In contrast, Lithium Magnesium Phosphide (LiMgP) offers advantages in transparency and lower thermal conductivity. It exhibits a slightly lower refractive index (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;n&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;29&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;), and a lower dielectric constant (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;ɛ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;27&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;). Both materials exhibit mechanical stability, with LiZnP displaying a higher Bulk modulus, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;B&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;637&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;408&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, and Shear modulus, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;507&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;533&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, making it more incompressible. Both alloys are dynamically stable, as indicated by the absence of imaginary frequencies in the Brillouin zone. LiZnP is particularly advantageous for high-absorption applications, while LiMgP excels in transparency and lower thermal conductivity, with a Debye temperature &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;Θ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;D&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;489&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;7&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; K and average sound velocity, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;V&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;m&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;4129&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;696&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;m/s&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;. Both materials are brittle, with Pugh’s modulus ratio, &lt;span&gt;&lt;math&gt;&lt;mi&gt;k&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;, less than 1.75, and negative Cauchy pressure, &lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mi&gt;C&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;′&lt;/mo&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt;. LiZnP exhibits greater hardness, with a Vickers hardness, &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;H&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;ν&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; of 97.27 compared to 88.46","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100838"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and corrosion resistance of Mg-Ti dissimilar joints fabricated via dual-beam laser welding 双光束激光焊接Mg-Ti异种接头的组织与耐蚀性
Results in Materials Pub Date : 2026-03-01 Epub Date: 2025-12-11 DOI: 10.1016/j.rinma.2025.100843
Chunxu Zhang , Chang Xu , Hongyang Wang , Min Qi , Xijing Zhuang , Xufeng Dong
{"title":"Microstructure and corrosion resistance of Mg-Ti dissimilar joints fabricated via dual-beam laser welding","authors":"Chunxu Zhang ,&nbsp;Chang Xu ,&nbsp;Hongyang Wang ,&nbsp;Min Qi ,&nbsp;Xijing Zhuang ,&nbsp;Xufeng Dong","doi":"10.1016/j.rinma.2025.100843","DOIUrl":"10.1016/j.rinma.2025.100843","url":null,"abstract":"<div><div>Current endovascular stents rely on homogeneous metallic materials lacking region-specific degradability, with non-degradable anchoring components posing risks of endothelial injury and distal stent graft-induced new entry (dSINE). This study introduces a coaxial continuous-pulse dual-beam laser system to weld NiTi alloy and WE43 Mg alloy. The weld appearance, microstructure and mechanical properties of joints obtained by single-beam and dual]-beam laser welding were compared and analyzed. The results showed that dual-beam laser welding (CPLW) produced superior WE43/NiTi joints with optimal tensile strength (141.6 MPa at 75 A) and enhanced interfacial bonding via elements diffuse into each other. However, corrosion resistance degraded significantly due to interfacial defects and Mg dissolution. Fracture modes differed: NiTi retained ductile fractures, while WE43 exhibited brittle-ductile mixed fractures from thermal cycling-induced grain coarsening in the heat-affected zone.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100843"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and evaluation of 3D-printed soft pneumatic actuators 3d打印软气动执行器的设计与评价
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-01-31 DOI: 10.1016/j.rinma.2026.100906
Ciro Moreno Garces , Gustavo Morales Pavez , Rafael Guerra Silva
{"title":"Design and evaluation of 3D-printed soft pneumatic actuators","authors":"Ciro Moreno Garces ,&nbsp;Gustavo Morales Pavez ,&nbsp;Rafael Guerra Silva","doi":"10.1016/j.rinma.2026.100906","DOIUrl":"10.1016/j.rinma.2026.100906","url":null,"abstract":"<div><div>Soft robotics enables safe and adaptive manipulation of delicate objects, with pneumatic actuators offering a flexible alternative to rigid systems. This study explores the design, simulation, fabrication, and testing of a pneumatic soft gripper manufactured via Fused Filament Fabrication using thermoplastic polyurethane. The response of four actuator designs, two chamber-based and two channel-based variants, was evaluated. The influence of geometric variations in chamber height, inter-chamber spacing, and number of chambers was analyzed using finite element analysis. The three-parameter Mooney–Rivlin model was used to predict the material's response across operating pressures. Actuators with rectangular chambers achieved the highest blocking force, whereas the channel-based modification increased flexion for about 20–33% relative to the base design. One actuator from each model was additively manufactured with thermoplastic polyurethane filament to validate the numerical results, with a relative error in the 8–19% range. Finally, a gripper built using one of the designs successfully handled various objects (e.g., tomatoes, bananas) weighing up to 254g, although it struggled with smooth cylindrical items (e.g., spray cans). These findings demonstrate the feasibility of FFF pneumatic actuators and highlight key design trade-offs for soft robotic applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100906"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146188427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation for short glass fiber reinforced magnetically loaded polymer composites by compression molding on morphology and mechanical-magnetic properties 短玻纤增强磁载高分子复合材料压缩成型的形貌和机械磁性能实验研究
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-03-07 DOI: 10.1016/j.rinma.2026.100924
Yingnan Wang, Pierre Mertiny
{"title":"Experimental investigation for short glass fiber reinforced magnetically loaded polymer composites by compression molding on morphology and mechanical-magnetic properties","authors":"Yingnan Wang,&nbsp;Pierre Mertiny","doi":"10.1016/j.rinma.2026.100924","DOIUrl":"10.1016/j.rinma.2026.100924","url":null,"abstract":"<div><div>Polymer composites incorporating magnetic fillers offer great potential for applications in energy storage, biomedical devices, and electromechanical systems. To facilitate the design of such components, it is critical to understand the morphology, thermal, mechanical, and magnetic behavior of short glass fiber reinforced, magnetically loaded polymer (SFRMP) composites, which are inherently heterogeneous and potentially anisotropic. In this study, ternary composites consisting short glass fibers (SGFs), isotropic NdFeB magnetic particles, and a modified low-viscosity thermoset matrix were fabricated via compression molding at a total filler volume fraction of 50%, with magnetic particle contents ranging from 27.5 to 47.0% by volume. Microstructural characterization revealed preferential in-plane alignment of magnetic particles and partial planar orientation of SGFs. The elastic modulus increased with magnetic particles content, reaching 17.04 GPa for the highest particle loading, while thermal conductivity increased nonlinearly to 1.71 W/(m·K), approximately 7.6 times higher than the neat matrix. Magnetic characterization confirmed directional dependence in remanence-to-saturation ratios, consistent with XRD analysis indicating slight preferential crystallographic orientation. This study demonstrates a scalable fabrication strategy for producing low-porosity, high-filler-density SFRMP composites with enhanced multifunctional performance.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100924"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cement conformity to physical and mechanical specifications: An introductive case study on CEM II 32.5 R and CEM II 42.5 R to standard NBF 02-013 :2009, revised 2012 水泥符合物理和机械规范:CEM II 32.5 R和CEM II 42.5 R对标准NBF 02-013:2009的介绍性案例研究,2012年修订
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-03-07 DOI: 10.1016/j.rinma.2026.100921
Etienne Malbila , Emmanuel Ouedraogo , Kadigué Rabdo , Bernard Zouma , Sié Kam
{"title":"Cement conformity to physical and mechanical specifications: An introductive case study on CEM II 32.5 R and CEM II 42.5 R to standard NBF 02-013 :2009, revised 2012","authors":"Etienne Malbila ,&nbsp;Emmanuel Ouedraogo ,&nbsp;Kadigué Rabdo ,&nbsp;Bernard Zouma ,&nbsp;Sié Kam","doi":"10.1016/j.rinma.2026.100921","DOIUrl":"10.1016/j.rinma.2026.100921","url":null,"abstract":"<div><div>Cement has been widely used as a binder in construction materials. The present work deals with a conformity study of cement brands produced in Burkina Faso. The study mainly concerned the 32.5R and 42.5R strength class sets of CEM II cements. The conformity criteria used were physical and mechanical properties requirements defined in standard NBF 02-013: 2009, revised 2012. One hundred fifty (150) samples of cement type CEMII were prepared from five cement factories, and several tests were applied on cement, fresh, and hardened mortars. Physical tests enabled us to determine the setting time of cement, the specific surface, and the stability of samples of cement mortar. Mechanical strength of cement mortar was measured at 2 and 28 days of age. Both physical and mechanical properties are compared with standard properties as specified in the relevant standard. The results showed the conformity ratio of 93% for compressive strength, 100% and 96% respectively for setting time and expansion, and for specific surface. Finally, all cement samples meet the specifications of standard NBF 02-013:2009, revised 2012. However, it's necessary to improve the production process in order to improve the quality, especially of cement plants represented by Brands CBF4 and CBF5 produced in Burkina Faso.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100921"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Agricultural waste-derived additives for high-performance cement: A novel approach using bagasse pulp and rice husk ash 农业废弃物衍生的高性能水泥添加剂:使用甘蔗渣纸浆和稻壳灰的新方法
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-02-20 DOI: 10.1016/j.rinma.2026.100914
Atefeh Halili , Davood Mostofinejad , Hadi Bahmani , Jafar Sobhani
{"title":"Agricultural waste-derived additives for high-performance cement: A novel approach using bagasse pulp and rice husk ash","authors":"Atefeh Halili ,&nbsp;Davood Mostofinejad ,&nbsp;Hadi Bahmani ,&nbsp;Jafar Sobhani","doi":"10.1016/j.rinma.2026.100914","DOIUrl":"10.1016/j.rinma.2026.100914","url":null,"abstract":"<div><div>Agricultural residues such as rice husk and sugarcane bagasse pulp, often discarded as waste, hold untapped potential for advancing sustainable construction materials. This study introduces a novel approach to valorizing these abundant by-products by incorporating bleached bagasse pulp and rice husk ash into cement composites. The innovative blend not only addresses environmental concerns but also significantly enhances the performance of cementitious materials.</div><div>Experimental results revealed a remarkable 59% increase in hydration when 8% bleached bagasse pulp and 20% rice husk ash were added to cement mortar. Mechanical properties also saw substantial gains, with compressive and flexural strengths improving by 13% and 19%, respectively. Furthermore, the addition of bleached bagasse pulp resulted in a significant increase in deflection at flexural failure, ranging from 49% to 222%, indicating improved ductility and toughness.</div><div>A comprehensive life cycle assessment (LCA) underscored the environmental benefits of this approach, showing 11%-19% reductions in impact when 20% rice husk ash was used as a partial replacement for cement. By demonstrating both enhanced performance and a reduced environmental footprint, these findings underscore the significance of agricultural–residue–based composites as a high-performance, environmentally conscious alternative for modern civil engineering applications. This work strengthens the link between agricultural waste management and sustainable infrastructure development, positioning such composites as a viable pathway toward greener construction practices.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100914"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic tri-modal reinforcement of chitosan–gelatin hydrogels with hydroxyapatite, functionalized carbon nanotubes, and zinc oxide for superior mechanical and biological performance 壳聚糖-明胶水凝胶与羟基磷灰石、功能化碳纳米管和氧化锌的协同三模强化,具有优异的机械和生物性能
Results in Materials Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.rinma.2026.100907
Samaneh Nikpar, Hamid Reza Rezaie, Alireza Khavandi, Jafar Javadpour
{"title":"Synergistic tri-modal reinforcement of chitosan–gelatin hydrogels with hydroxyapatite, functionalized carbon nanotubes, and zinc oxide for superior mechanical and biological performance","authors":"Samaneh Nikpar,&nbsp;Hamid Reza Rezaie,&nbsp;Alireza Khavandi,&nbsp;Jafar Javadpour","doi":"10.1016/j.rinma.2026.100907","DOIUrl":"10.1016/j.rinma.2026.100907","url":null,"abstract":"<div><div>The clinical translation of hydrogel-based scaffolds for tissue engineering is often limited by the inherent trade-off between biocompatibility, mechanical integrity, and resistance to post-implantation infections. While natural polymer hydrogels closely mimic the extracellular matrix (ECM), they typically exhibit insufficient load-bearing capacity and inadequate antibacterial performance, restricting their application in mechanically demanding and infection-prone environments. The objective of this study was to develop and systematically evaluate a multifunctional chitosan–gelatin (CS–Gel) nanocomposite hydrogel capable of simultaneously addressing these limitations through a tri-modal reinforcement strategy. The hydrogels were fabricated via glutaraldehyde-mediated chemical cross-linking and reinforced with hydroxyapatite (HA, 1 wt%), carboxyl-functionalized multi-walled carbon nanotubes (f-MWCNTs, 0.3 wt%), and zinc oxide nanoparticles (ZnO, 1–3 wt.%). Comprehensive structural characterization using FTIR, XRD, and SEM confirmed homogeneous nanofiller dispersion and the formation of an interconnected porous microarchitecture. Progressive incorporation of ZnO resulted in microstructural densification, reduced pore size, enhanced compressive strength and Young's modulus, and suppressed swelling and hydrolytic degradation compared with the ZnO-free control. In vitro cytocompatibility assays using MC3T3-E1 pre-osteoblastic cells demonstrated sustained cell viability exceeding 70% for all formulations. Furthermore, antibacterial evaluations revealed a strong, concentration-dependent inhibitory effect, with more than 80% bacterial inhibition against <em>Staphylococcus aureus</em> (<em>S. aureus</em>, Gram-positive) and <em>Escherichia coli</em> (<em>E. coli</em>, Gram-negative) at 3 wt% ZnO. This systematic study demonstrates that tri-modal reinforcement effectively overcomes the mechanical, biological, and antibacterial limitations of conventional CS–Gel hydrogels, establishing a robust and rational design framework for next-generation multifunctional scaffolds suitable for load-bearing and infection-sensitive tissue engineering applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100907"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147396263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Leveraging nanopolymer bio-coatings for biodegradable implant systems: An overview 利用纳米聚合物生物涂层的可生物降解植入系统:概述
Results in Materials Pub Date : 2026-03-01 Epub Date: 2025-12-15 DOI: 10.1016/j.rinma.2025.100868
Victor U. Agbogo , Emmanuel R. Sadiku , Lucey Mavhungu , Williams K. Kupolati , Moipone L. Teffo , Oryina M. Injor
{"title":"Leveraging nanopolymer bio-coatings for biodegradable implant systems: An overview","authors":"Victor U. Agbogo ,&nbsp;Emmanuel R. Sadiku ,&nbsp;Lucey Mavhungu ,&nbsp;Williams K. Kupolati ,&nbsp;Moipone L. Teffo ,&nbsp;Oryina M. Injor","doi":"10.1016/j.rinma.2025.100868","DOIUrl":"10.1016/j.rinma.2025.100868","url":null,"abstract":"<div><div>Biodegradable magnesium (Mg) alloys hold great promise as temporary implant materials due to their biocompatibility and mechanical similarity to bone; however, their rapid corrosion in physiological environments limits clinical use. This paper reviews recent advances in nano-polymer bio-coatings designed to enhance the corrosion resistance and functionality of Mg-based implants. A systematic approach was adopted, examining bio-derived polymers reinforced with nanofillers such as carbon nanotubes, nanoclays, and hydroxyapatite. Quantitative findings from selected studies indicate that polymer–nanofiller hybrid coatings can reduce corrosion rates of Mg alloys by up to 65–80 % and improve adhesion strength by approximately 30–40 % compared with conventional coatings. Furthermore, hybrid bio-coatings demonstrated enhanced apatite formation, contributing to improved osseointegration. Conceptual and experimental insights are provided into electrochemical surface modification, bio-macromolecule integration, and the role of functionally graded coatings. The review concludes that nano-polymer coatings represent a sustainable and effective pathway for improving Mg-alloy implants, with future directions pointing toward 3D-printed coating systems, AI-driven coating design, and multifunctional biomedical platforms.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100868"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Functionalized Cocos nucifera L shell particulate enhancement on the nanocrystalline and anticorrosion performance of Zn-Al2O3-CSP on mild steel for extended application 功能化椰壳L颗粒增强Zn-Al2O3-CSP在低碳钢上的纳米晶化和防腐性能
Results in Materials Pub Date : 2026-03-01 Epub Date: 2025-12-09 DOI: 10.1016/j.rinma.2025.100841
Ojo S.I. Fayomi , Omaji Adakole , Ho Soon Min , Kunle M. Oluwasegun
{"title":"Functionalized Cocos nucifera L shell particulate enhancement on the nanocrystalline and anticorrosion performance of Zn-Al2O3-CSP on mild steel for extended application","authors":"Ojo S.I. Fayomi ,&nbsp;Omaji Adakole ,&nbsp;Ho Soon Min ,&nbsp;Kunle M. Oluwasegun","doi":"10.1016/j.rinma.2025.100841","DOIUrl":"10.1016/j.rinma.2025.100841","url":null,"abstract":"<div><div>The degradation of mild steel in corrosive environments necessitates innovative, eco-friendly protective coatings. This study aims to enhance the corrosion resistance and mechanical properties of mild steel by developing a Zn-Al<sub>2</sub>O<sub>3</sub> nanocomposite coating reinforced with functionalized coconut shell particulates (CSP: 0, 2, 4, 6 g) constant-current electrodeposition (1.5 A/cm<sup>2</sup>). The coatings were characterized for corrosion behavior in 3.65 % NaCl using linear polarization resistance (LPR) and open circuit potential (OCP), while hardness, microstructure, and phase composition were assessed via Brinell hardness testing, scanning electron microscopy (SEM), and X-ray diffraction (XRD). Results revealed that Zn-20Al<sub>2</sub>O<sub>3</sub>-6CSP significantly outperformed uncoated steel, with polarization resistance increasing from 23.5 Ω cm<sup>2</sup> to 97.2 Ω cm<sup>2</sup> and corrosion rate decreasing from 9.98 mm/year to 1.16 mm/year. Hardness improved by 92 % (to 261.8 kgf/mm<sup>2</sup>) due to reduced voids and intermetallic phases (ZnO, Al<sub>2</sub>O<sub>3</sub>, MgO, FeO). These findings position CSP as a promising sustainable additive for advanced anti-corrosion coatings, warranting further exploration in marine applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100841"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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