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Assembly of two-dimensional nanosheets of copper sulfide on nickel foam for high-efficiency energy storage applications: Exploring the effect of pH 在泡沫镍上组装二维硫化铜纳米片用于高效储能：探讨pH值的影响

Resources Chemicals and Materials Pub Date : 2025-09-01 Epub Date: 2025-06-02 DOI: 10.1016/j.recm.2025.100119

Akashdeep Dey, Mahendra S. Gaikwad, S. Noyel Victoria

{"title":"Assembly of two-dimensional nanosheets of copper sulfide on nickel foam for high-efficiency energy storage applications: Exploring the effect of pH","authors":"Akashdeep Dey, Mahendra S. Gaikwad, S. Noyel Victoria","doi":"10.1016/j.recm.2025.100119","DOIUrl":"10.1016/j.recm.2025.100119","url":null,"abstract":"<div><div>Two-dimensional (2D) CuS/Cu<sub>9</sub>S<sub>5</sub> nanostructures are quite popular owing to their intriguing electrochemical properties. In-situ hydrothermal deposition of 2D CuS/Cu<sub>9</sub>S<sub>5</sub> nanostructures on nickel foam at different pH was studied. The X-ray diffraction analysis confirmed two different stoichiometric forms, namely CuS and Cu<sub>9</sub>S<sub>5</sub>, in different proportions with a change in the synthesis pH. Morphological and compositional analysis exhibited a strong impact of pH on the CuS/Cu<sub>9</sub>S<sub>5</sub> deposits. The samples prepared at pH 6.5 presented less agglomerated and densely distributed 2D nanosheets. Transmission electron microscopic studies under high resolution for the deposits synthesized at pH 6.5 showed hexagonal CuS and rhombohedral Cu<sub>9</sub>S<sub>5</sub> particles of 32 nm average particle size. The electrochemical characterization of the samples for energy storage devices by cyclic voltammetry (CV) study revealed the specific capacitance from 1781 Fg<sup>−1</sup> to 1589 Fg<sup>−1</sup> at 10 mVs<sup>−1</sup>. The findings of CV and galvanostatic charge/discharge (GCD) analysis matched well. Rate capability studies showed the values between 72.9% and 50.24% at 7.5 Ag<sup>−1</sup> for various samples. The sample prepared at pH 6.5 exhibited 73.07% of its starting capacitance at 10 Ag<sup>−1</sup> after 2500 charging and discharging sequences. Electrochemical impedance spectroscopy runs (EIS) showed the existence of two constant phase elements (CPE) in series and the relaxation time constants from 0.01 to 0.5 seconds, which are preferred for energy storing purposes. Symmetric supercapacitor device prepared from sample deposited at pH 6.5 displayed 29.16 Wh energy per kg of material and a power density of 900 W kg<sup>−1</sup>, highlighting its suitability for high-efficiency energy storage applications.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 3","pages":"Article 100119"},"PeriodicalIF":0.0,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144231661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Outside Back Cover 外封底

Resources Chemicals and Materials Pub Date : 2025-09-01 Epub Date: 2025-10-09 DOI: 10.1016/S2772-4433(25)00052-2

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Progress in the development of self-healing polyurethane materials 自愈聚氨酯材料的研究进展

Resources Chemicals and Materials Pub Date : 2025-09-01 Epub Date: 2025-04-27 DOI: 10.1016/j.recm.2025.100114

Yongyin Zhu , Henghui Deng , Huizhou Luo , Ying Luo , Yu Chen , Zehong Chen , Chaoqun Zhang

{"title":"Progress in the development of self-healing polyurethane materials","authors":"Yongyin Zhu , Henghui Deng , Huizhou Luo , Ying Luo , Yu Chen , Zehong Chen , Chaoqun Zhang","doi":"10.1016/j.recm.2025.100114","DOIUrl":"10.1016/j.recm.2025.100114","url":null,"abstract":"<div><div>As a significant branch of smart materials, self-healing polyurethane materials mimic the biological damage repair mechanisms and have been widely applied in flexible electronics, functional coatings, biomedicine, and other fields. This review systematically summarizes the design principles and recent advancements in both extrinsic and intrinsic self-healing polyurethane materials, highlighting their respective self-healing mechanisms and characteristics. For extrinsic system, damage repair is primarily achieved through microcapsules, hollow fibers, nanoparticles, and microvascular networks. However, their healing efficiency remains limited by the stability of carriers and the release kinetics of healing agents. In contrast, intrinsic self-healing polyurethane materials achieve self-healing through the reversibility of dynamic covalent and non-covalent bonds, which confer excellent self-healing capabilities while necessitating a precise balance between mechanical performance and self-healing efficiency. Moreover, their healing behavior is highly dependent on environmental conditions, potentially restricting their practical applications. Recent studies have demonstrated that the synergistic design of dynamic bonding networks can significantly enhance the mechanical properties, self-healing efficiency, and environmental adaptability. These developments offer new insights and theoretical foundations for designing high-performance self-healing polyurethane materials and may broaden their industrial applications.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 3","pages":"Article 100114"},"PeriodicalIF":0.0,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143935841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Low-cost fabrication of high-performance anode-supported SOFCs with anti-carbon deposition capability 具有抗碳沉积能力的高性能阳极负载sofc的低成本制造

Resources Chemicals and Materials Pub Date : 2025-09-01 Epub Date: 2025-04-24 DOI: 10.1016/j.recm.2025.100117

Shang Peng , Zhao Liu , Pairuzha Xiaokaiti , Tiancheng Fang , Jiwei Wang , Guoqing Guan , Abuliti Abudula

{"title":"Low-cost fabrication of high-performance anode-supported SOFCs with anti-carbon deposition capability","authors":"Shang Peng , Zhao Liu , Pairuzha Xiaokaiti , Tiancheng Fang , Jiwei Wang , Guoqing Guan , Abuliti Abudula","doi":"10.1016/j.recm.2025.100117","DOIUrl":"10.1016/j.recm.2025.100117","url":null,"abstract":"<div><div>The development of cost-effective solid oxide fuel cells (SOFCs) is crucial for the large-scale application. In this study, anode-supported SOFC single cells were fabricated using a combination of slurry spraying and spin-coating technique to achieve a dense Yttria Stabilized Zirconia (YSZ) electrolyte layer while maintaining low production cost. The electrochemical performance of the fabricated SOFC was evaluated using hydrogen and dry methane as fuels. Microstructural analysis confirmed that the YSZ electrolyte exhibited high densification with a thickness of approximately 10 μm, ensuring excellent gas-tightness and preventing fuel crossover. The NiO-YSZ anode demonstrated favorable porosity, with well-sintered NiO particles forming a robust framework to facilitate electrochemical reactions. Performance evaluations revealed that under hydrogen operation, the SOFC achieved a peak power density of 1.408 W/cm² at 1000 °C, with open-circuit voltages (OCVs) closely matching theoretical predictions. When operated with dry methane, the SOFC maintained stable performance, reaching a peak power density of 0.96 W/cm² at 1000 °C, highlighting its potential for direct hydrocarbon utilization. Gas composition analysis of the anode exhaust confirmed the absence of excessive carbon deposition, indicating the effectiveness of the anode microstructure in mitigating coking during methane oxidation. These findings demonstrate that the spray-coated and spin-coated SOFC design offers a promising approach to improving fuel cell efficiency and cost-effectiveness. Future research should focus on optimizing electrolyte fabrication methods and enhancing anode stability in hydrocarbon-fueled operation to further advance the commercialization of SOFC technology.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 3","pages":"Article 100117"},"PeriodicalIF":0.0,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Facilitated hydrogenation of furfural into furfuryl alcohol over catalyst CuSiAlOx made with infrared-heating calcination 红外加热煅烧催化剂CuSiAlOx催化糠醛加氢生成糠醇

Resources Chemicals and Materials Pub Date : 2025-09-01 Epub Date: 2025-06-14 DOI: 10.1016/j.recm.2025.100122

Mengjuan Zhang , Xiaoyu Wu , Chao Wang , Jiarui He , Guoguo Liu , Peng Zheng , Zhennan Han , Jinggang Zhao , Kangjun Wang

{"title":"Facilitated hydrogenation of furfural into furfuryl alcohol over catalyst CuSiAlOx made with infrared-heating calcination","authors":"Mengjuan Zhang , Xiaoyu Wu , Chao Wang , Jiarui He , Guoguo Liu , Peng Zheng , Zhennan Han , Jinggang Zhao , Kangjun Wang","doi":"10.1016/j.recm.2025.100122","DOIUrl":"10.1016/j.recm.2025.100122","url":null,"abstract":"<div><div>A CuSiAlO<sub>x</sub> catalyst was prepared through infrared-heating calcination and employed to catalyze vapor furfural (FFR) hydrogenation in a fixed-bed reactor. Its catalytic performance was systematically evaluated and compared to that of a catalyst derived from the same precursor but calcined using an electric oven. The hydrogenation tests were performed at temperatures varying in 140 ∼ 180 °C, H<sub>2</sub>/FFR (mol/mol) ratios in 4:1 ∼ 8:1, and liquid hourly space velocity (LHSVs) in 0.6 ∼ 1.0 h<sup>-1</sup>. The catalyst CuSiAlO<sub>x</sub>-IH (prepared by infrared-heating calcination) demonstrated higher FFR conversion than CuSiAlO<sub>x</sub>-EH (prepared by electric-oven heating) did. Under the conditions of a H<sub>2</sub>/FFR ratio of 6:1, a temperature of 140 °C, and an LHSV of 0.6 h<sup>-1</sup>, the CuSiAlO<sub>x</sub>-IH catalyst achieved a 99.70 % FFR conversion and 95.72 % selectivity to furfur alcohol (FOL) in a continuous test for 18 h. This time duration with good stability was twice longer than that enabled by CuSiAlO<sub>x</sub>-EH. Characterization of the fresh, reduced, and spent catalysts revealed that the catalyst CuSiAlO<sub>x</sub>-IH, compared to CuSiAlO<sub>x</sub>-EH, possessed more Cu defects, a higher BET surface area, a smaller average size, and the narrower size distribution of active-species particles. These structural advantages thus rendered the CuSiAlO<sub>x</sub>-IH catalyst superior in its catalysis of the FFR hydrogenation reactions.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 3","pages":"Article 100122"},"PeriodicalIF":0.0,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144331304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Essential strategies for efficient low–tar biomass gasification: in-bed intensification and interactive two–stage reactions 有效的低焦油生物质气化的基本策略：床内强化和相互作用的两阶段反应

Resources Chemicals and Materials Pub Date : 2025-06-01 Epub Date: 2024-11-19 DOI: 10.1016/j.recm.2024.11.002

Chao Wang , Xinyu Wang , Zhennan Han , Mengjuan Zhang , Lianfeng Zhu , Xin Jia , Ping An , Dingrong Bai , Fang Wang , Guoqing Guan , Guangwen Xu

{"title":"Essential strategies for efficient low–tar biomass gasification: in-bed intensification and interactive two–stage reactions","authors":"Chao Wang , Xinyu Wang , Zhennan Han , Mengjuan Zhang , Lianfeng Zhu , Xin Jia , Ping An , Dingrong Bai , Fang Wang , Guoqing Guan , Guangwen Xu","doi":"10.1016/j.recm.2024.11.002","DOIUrl":"10.1016/j.recm.2024.11.002","url":null,"abstract":"<div><div>Gasification is a highly effective technology for converting biomass into fuel gas or syngas. While various gasifiers have been commercialized for fuel gas production, mitigating tar formation in gasifiers remains challenging. This review is devoted to summarizing the general strategies adopted in various gasifiers to reduce tar formation for high-efficiency clean gasification. For single-bed and staged-gasification processes, their low-tar strategies are typically different. In the single-bed processes, the low-tar strategies involve in-bed intensification achieved by controlling flow directions of gas and particles inside the gasifier. During the gasification, these two components often have different temperatures to facilitate thermochemical interactions between them. Meanwhile, the two-stage gasifiers are generally designed to decouple pyrolysis, gasification and tar cracking reactions for maximizing the benefits (such as yield and efficiency) realized from the interactions among these reactions. In addition to minimizing tar formation, the approach of reaction decoupling can also raise the calorific value of product gas, even without use of oxygen, and/or improve the adaptability of gasification technology to the feedstocks with various moisture contents and particle sizes. The reanalysis based on those essential low-tar strategies is expected to gain alternative insights into the reaction principles implicated in most advanced biomass gasification technologies.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 2","pages":"Article 100087"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144713517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Catalytic steam reforming of aqueous products derived from hydrothermal conversion of biomass for hydrogen production 生物质水热转化水产物的催化蒸汽重整制氢

Resources Chemicals and Materials Pub Date : 2025-06-01 Epub Date: 2025-06-14 DOI: 10.1016/j.recm.2025.100121

Hongcai Su , Tian Li , Lingjun Zhu , Guangwen Xu , Shurong Wang

{"title":"Catalytic steam reforming of aqueous products derived from hydrothermal conversion of biomass for hydrogen production","authors":"Hongcai Su , Tian Li , Lingjun Zhu , Guangwen Xu , Shurong Wang","doi":"10.1016/j.recm.2025.100121","DOIUrl":"10.1016/j.recm.2025.100121","url":null,"abstract":"<div><div>The catalytic steam reforming (SR) of biomass-derived organic compounds could be considered as a promising route to generate H<sub>2</sub> fuel. This work aimed to achieve efficient H<sub>2</sub> production by the SR of aqueous products obtained from the hydrothermal conversion process of lignocellulosic biomass. The catalytic SR was studied over 15Ni/NiAl<sub>2</sub>O<sub>4</sub> for model compound mixtures composed of furfural, levulinic acid, and formic acid. At a reaction temperature of 800 °C, the high H<sub>2</sub> yield of 93.8 % was achieved. Bimetallic Ni–Cu and Ni–Co catalysts supported by NiAl<sub>2</sub>O<sub>4</sub> were synthesized to optimize the SR performance in the presence of H<sub>2</sub>SO<sub>4</sub> as impurity. The Ni–Co and Cu–Ni alloys formed on the bimetallic catalysts during calcination and reduction were verified. The results revealed that the alloys formation improved the resistance of catalysts to oxidation and H<sub>2</sub>SO<sub>4</sub>, thus weakening the catalyst deactivation during the SR process. Importantly, the catalytic SR was successfully applied to convert aqueous products from the hydrothermal conversion of pine sawdust. This study provides an encouraging route for upgrading biomass into high-value fuels.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 2","pages":"Article 100121"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144330034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis and characterization of carbonaceous materials for lead adsorption 用于铅吸附的碳质材料的合成与表征

Resources Chemicals and Materials Pub Date : 2025-06-01 Epub Date: 2025-03-28 DOI: 10.1016/j.recm.2025.100103

Benyapha Glingasorn , Yang Wei , Sarute Ummartyotin

{"title":"Synthesis and characterization of carbonaceous materials for lead adsorption","authors":"Benyapha Glingasorn , Yang Wei , Sarute Ummartyotin","doi":"10.1016/j.recm.2025.100103","DOIUrl":"10.1016/j.recm.2025.100103","url":null,"abstract":"<div><div>Protein fibers derived from silk fibroin (SF) were chemically extracted and purified from cocoons. It was used as a reinforced fiber for hydrogel formation with collagen (Col) and hyaluronic acid (HA). Calcium chloride (8 wt. %) was employed as a crosslinking reagent to synthesize the SF/Col/HA-based hydrogel composite. FTIR spectroscopy confirmed the presence of N–H stretching due to the plane bending of amide II in the β-sheet structure. XRD analysis confirmed the crystallinity of the SF/Col/HA-based hydrogel composite. Scanning electron microscopy revealed three-dimensional porous structures with interconnected pores. These porous structures can serve as reservoirs for storing adsorbent media. The hydrogel composite was thermally stable at 250 °C. The low-boiling bound solvent evaporation temperature, glass transition temperature, and degradation temperature were 102 °C–105 °C, 298 °C–300 °C, and 524 °C–545 °C, respectively. The ranges of porosity and gel fraction were 60 %–80 % and 90 %–95 %, respectively. The hydrogel composite was rapidly swollen within 1 h, reaching a plateau afterward. The compressive strength was 4–6 MPa. As absorbent media, hydrogels can easily adhere to lead ions via electrostatic interactions. They can be used as reservoirs for the adsorption of heavy metals.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 2","pages":"Article 100103"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Recent advances of sustainable and recyclable polymer materials from renewable resources 利用可再生资源制备可持续可循环高分子材料的研究进展

Resources Chemicals and Materials Pub Date : 2025-06-01 Epub Date: 2024-10-29 DOI: 10.1016/j.recm.2024.10.004

Ting Luo , Yun Hu , Meng Zhang, Puyou Jia, Yonghong Zhou

{"title":"Recent advances of sustainable and recyclable polymer materials from renewable resources","authors":"Ting Luo , Yun Hu , Meng Zhang, Puyou Jia, Yonghong Zhou","doi":"10.1016/j.recm.2024.10.004","DOIUrl":"10.1016/j.recm.2024.10.004","url":null,"abstract":"<div><div>With the increasing consumption of non renewable resources such as oil, the traditional polymer manufacturing industry that relies on fossil resources is facing unprecedented challenges. The design, synthesis, and recycling of renewable and environmentally friendly bio-based polymers as alternatives to petroleum based polymers have become hot topics in research and industrial fields. Biomass has been used as a raw material to design and synthesize closed-loop recyclable polymers, which is of great significance in addressing the waste of resources and negative impact on the environment in the traditional polymer preparation process. This review summarized recent advances in the design, synthesis, and properties of closed-loop recyclable bio-based polymers, focusing on the sustainability and recyclability of bio-based materials, followed by a brief discussion of the potential applications of closed-loop recyclable bio-based polymers in emerging applications such as 3D printing and friction electric nanogenerators. In addition, perspectives and recommendations for future research on closed-loop recyclable bio-based polymers were presented.</div></div>","PeriodicalId":101081,"journal":{"name":"Resources Chemicals and Materials","volume":"4 2","pages":"Article 100085"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144713515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Outside Back Cover 外封底

Resources Chemicals and Materials Pub Date : 2025-06-01 Epub Date: 2025-07-28 DOI: 10.1016/S2772-4433(25)00023-6

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