Journal of Alloys and Metallurgical Systems最新文献

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Allotropic α→β transformation in diffusion-graded commercial-purity Ti–Zr multilayers: DSC overlapping peak deconvolution and kissinger kinetic analysis 扩散分级工业纯Ti-Zr多层膜的同素异形体α→β转变:DSC重叠峰反褶积和kissinger动力学分析
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-02-17 DOI: 10.1016/j.jalmes.2026.100238
Anas Jawabreh, Péter Barkóczy
{"title":"Allotropic α→β transformation in diffusion-graded commercial-purity Ti–Zr multilayers: DSC overlapping peak deconvolution and kissinger kinetic analysis","authors":"Anas Jawabreh,&nbsp;Péter Barkóczy","doi":"10.1016/j.jalmes.2026.100238","DOIUrl":"10.1016/j.jalmes.2026.100238","url":null,"abstract":"<div><div>Multilayered Ti–Zr mesostructures were produced from commercially pure Ti and Zr by subsequent hot compression and heat treatment then annealed at 740 °C and 770 °C for 120 h to generate a near-continuous Ti-rich to Zr-rich concentration gradient. Differential scanning calorimetry (DSC) was used to examine the α→β transformation at heating rates of 10–25 K/min, supported by optical microscopy and SEM–EDS to assess the extent of diffusion. The first endothermic reaction starts near the ∼50–50 at% Ti-Zr region where the transformation temperature is lowest according to the published and Thermo-calc calculated phase diagrams, while subsequent reactions occur in adjacent Ti- and Zr-rich compositions, producing strongly overlapping peaks in a small temperature range. The low-temperature peak ranges occur at 549.9 °C −562.1 °C and 570.4 °C −576.6 °C after 740 °C annealing, and at 543.5 °C −589.3 °C and 584.6 °C −645.3 °C after 770 °C annealing, followed by a high-temperature β-completion peak at 838 °C −867.6 °C (740 °C) or 915 °C −926.8 °C (770 °C). A Savitzky–Golay filtering, derivative-based segmentation, and Avrami-type deconvolution were used to isolate the overlapping reactions, and Kissinger analysis of the deconvoluted peaks provided apparent activation energies for each step. For the 740 °C samples, the first two low-temperature (onset) steps show higher apparent activation energies (225.7 and 474.7 kJ·mol⁻¹) than the β-completion step (163.145 kJ·mol⁻¹), while for the 770 °C samples the trend reverses (74.5 and 60.1 kJ·mol⁻¹ vs. 676.3 kJ·mol⁻¹). This change in trend indicates that diffusion heat treatment changes the gradient geometry, which controls peak overlap and shifts the apparent kinetics from deconvolution.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100238"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147384651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Er addition and thermomechanical processing on the in vitro corrosion and cytocompatibility of Mg–Zn–Y alloys Er的加入和热处理对Mg-Zn-Y合金体外腐蚀和细胞相容性的影响
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-01-27 DOI: 10.1016/j.jalmes.2026.100233
Raisa Tahsin Promy , Md. Walid Ahmed Nafiz , Syed Muhammad Al Amin , Chanchal Kumar Roy , Fahmida Gulshan
{"title":"Influence of Er addition and thermomechanical processing on the in vitro corrosion and cytocompatibility of Mg–Zn–Y alloys","authors":"Raisa Tahsin Promy ,&nbsp;Md. Walid Ahmed Nafiz ,&nbsp;Syed Muhammad Al Amin ,&nbsp;Chanchal Kumar Roy ,&nbsp;Fahmida Gulshan","doi":"10.1016/j.jalmes.2026.100233","DOIUrl":"10.1016/j.jalmes.2026.100233","url":null,"abstract":"<div><div>Controlling the corrosion rate of magnesium-based biodegradable alloys remains a key challenge for biomedical applications. This study investigates the effect of Er addition and thermomechanical processing (rolling and extrusion) on the cytocompatibility and corrosion behavior of Mg-1.88Zn-0.58Y alloys. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and optical microscopy (OM) identified the presence of secondary phases such as Mg<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>Zn and W-phases in both alloys and Mg<sub>24</sub>Er<sub>5</sub> only in the Mg-1.81Zn-0.8Y-0.33Er alloy. Corrosion behavior was evaluated by immersion tests in periodically replenished Kokubo’s simulated body fluid (SBF) for up to 21 days, with continuous pH monitoring. Hydrogen evolution tests, potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) supported the immersion findings, and post-corrosion SEM-EDS and Fourier-transform infrared spectroscopy (FTIR) analyses elucidated the underlying reasons. In both alloys, hot extrusion enhanced the formation of a protective Mg(OH)<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> layer and reduced the corrosion rate. The extruded Mg-1.88Zn-0.58Y alloy exhibited the lowest weight-loss rate (14.45 to 9.79 mm year<sup>−1</sup> from day 1 to day 21), hydrogen release (<span><math><mo>∼</mo></math></span>2.9 mL cm<span><math><msup><mrow></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></math></span> d<span><math><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></math></span>), and corrosion current density (<span><math><mrow><mn>31</mn><mo>.</mo><mn>58</mn><mspace></mspace><mi>μ</mi><mi>A</mi></mrow></math></span> cm<sup>−2</sup>). The Er-containing alloy showed poor corrosion resistance in the as-cast and rolled states (45.96 and 38.88 mm year<sup>−1</sup> after 21 days, respectively), but significant improvement in the extruded condition (10.04 mm year<sup>−1</sup>). Er containing quaternary alloys exhibited much higher H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> evolution rate of <span><math><mo>∼</mo></math></span>17.2 mL cm<span><math><msup><mrow></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></math></span> d<span><math><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></math></span> (after 24 h) for the as cast sample, considerably more than the acceptable limit for human body. Overall, the Er addition to the ternary alloy resulted in poor corrosion resistance. MTT cytotoxicity assays on Vero cells confirmed non-cytotoxic behavior (<span><math><mo>&gt;</mo></math></span>95% viability), while the Er-containing Mg-1.81Zn-0.8Y-0.33Er alloy extract produced strong selective toxicity against HeLa cells (<span><math><mo>&lt;</mo></math></span>5% viability).</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100233"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-temperature cyclic oxidation and microstructural behavior of CoMoCrSi-based composite coatings with Al2O3 and YSZ on T91 steel T91钢comocrsi基Al2O3和YSZ复合涂层高温循环氧化及显微组织行为
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-01-03 DOI: 10.1016/j.jalmes.2026.100232
Rakshith Kumar Shetty , Ajit M. Hebbale , T.V. Chandramouli , M.R. Ramesh , Jana Petru
{"title":"High-temperature cyclic oxidation and microstructural behavior of CoMoCrSi-based composite coatings with Al2O3 and YSZ on T91 steel","authors":"Rakshith Kumar Shetty ,&nbsp;Ajit M. Hebbale ,&nbsp;T.V. Chandramouli ,&nbsp;M.R. Ramesh ,&nbsp;Jana Petru","doi":"10.1016/j.jalmes.2026.100232","DOIUrl":"10.1016/j.jalmes.2026.100232","url":null,"abstract":"<div><div>This investigation focuses on the cyclic oxidation behaviour and microstructural evolution of Cobalt-Molybdenum-Chromium-Silicon coatings reinforced with alumina and yttria stabilised zirconia (YSZ) deposited on T91 steel by the atmospheric plasma spraying method. Characterization of the as-sprayed coatings was done to provide a consistent base line for comparison of the intercoatings. Cyclic oxidation experiments at 800 °C for 50 oxidation cycles was carried out with surface and cross section analyses using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) for the evaluation of oxidation scale formation, element distribution and phase stability. After cyclic oxidation, XRD showed an appearance of stable oxide constituents, which demonstrates the formation of protective scales on the coating surfaces. In comparison with unreinforced and alumina reinforced coatings, the YSZ reinforced coating displayed comparatively superior oxidation behavior as reflected in the more stable oxidation and less degradation during cyclic exposure. SEM examination of oxidized surfaces showed that the ceramic additions helped to increase coating integrity, improve scale adherence and reduce oxygen penetration. These effects were amplified for the YSZ-containing coating, showing a good response for high temperature oxidation. Overall, the addition of ceramic reinforcements, especially of YSZ, improved the phase stability and oxidation resistance of the CoMoCrSi-based coatings, which supports the suitability of the coatings for demanding boiler environments.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100232"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145926083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Sn addition on the microstructure, mechanical properties, and corrosion behaviour of AZ31 magnesium alloy Sn添加对AZ31镁合金组织、力学性能和腐蚀行为的影响
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-01-29 DOI: 10.1016/j.jalmes.2026.100234
Md. Rakibul Islam , Istiak Mahmood Rahi , Md. Noushad Hossain , H.M.M. A. Rashed
{"title":"Effect of Sn addition on the microstructure, mechanical properties, and corrosion behaviour of AZ31 magnesium alloy","authors":"Md. Rakibul Islam ,&nbsp;Istiak Mahmood Rahi ,&nbsp;Md. Noushad Hossain ,&nbsp;H.M.M. A. Rashed","doi":"10.1016/j.jalmes.2026.100234","DOIUrl":"10.1016/j.jalmes.2026.100234","url":null,"abstract":"<div><div>This study systematically investigates the effect of adding tin (Sn) to AZ31 magnesium alloy on its microstructure, mechanical strength, and corrosion behaviour. Alloys with 0, 2, and 4 wt% Sn were processed and characterized using microscopy, X-ray diffraction, hardness testing, hot compression (at 300 °C), and electrochemical impedance spectroscopy (EIS). Quantitative analysis revealed that Sn addition significantly refined the grain size from 137.8 µm to 23.7 µm and promoted the formation of Mg<sub>2</sub>Sn precipitates. Calculations determined that the total strength gain in the AZ31–2 %Sn alloy was overwhelmingly dominated by grain refinement and solid solution effects. In the AZ31–4 %Sn alloy, while grain refinement remained the largest component, the sharp increase in overall strength was substantially augmented by the presence of Mg<sub>2</sub>Sn Orowan precipitates. Constitutive analysis of hot deformation yielded strain rate sensitivity exponents (m) between 0.17 and 0.20, identifying dislocation climb as the governing deformation mechanism, with a minor contribution from grain boundary sliding in the fine-grained 4 % Sn alloy. Equivalent circuit modeling of EIS data demonstrated a trade-off in corrosion performance: the 2 % Sn alloy achieved the highest charge-transfer resistance (R<sub>ct</sub> ≈ 1.7 ×10^5 Ω). This improvement is specifically attributed to Sn4 + -induced modification of the MgO/Mg(OH)<sub>2</sub> passive film, resulting in a denser and more stable barrier. Conversely, the 4 % Sn alloy suffered from accelerated degradation (R<sub>ct</sub> ≈ 2.05 ×10^4 Ω) because excessive Sn forms coarse Mg<sub>2</sub>Sn intermetallics, which act as cathodic sites and drive micro-galvanic corrosion. These findings highlight that moderate Sn alloying (2 wt%) optimizes the property balance by enhancing strength without compromising corrosion resistance.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100234"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146173429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An attempt toward machine learning-driven optimization of manufacturing processes for metal-supported solid oxide fuel cells using nickel and iron oxides as raw support materials 利用镍和铁氧化物作为原材料,对金属支撑固体氧化物燃料电池的制造工艺进行机器学习驱动优化的尝试
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2025-12-08 DOI: 10.1016/j.jalmes.2025.100230
Hirofumi Sumi , Mizuki Momai , Yuki Yamaguchi
{"title":"An attempt toward machine learning-driven optimization of manufacturing processes for metal-supported solid oxide fuel cells using nickel and iron oxides as raw support materials","authors":"Hirofumi Sumi ,&nbsp;Mizuki Momai ,&nbsp;Yuki Yamaguchi","doi":"10.1016/j.jalmes.2025.100230","DOIUrl":"10.1016/j.jalmes.2025.100230","url":null,"abstract":"<div><div>A novel fabrication method for metal-supported solid oxide fuel cells (SOFCs) is proposed using nickel and iron oxides as raw support materials. This approach enables the co-sintering of all components in their oxide states via conventional ceramic processing. To minimize cell warpage, which is a critical issue in mechanical integrity, machine learning models, including random forest and linear regression, are employed to optimize the manufacturing process parameters. The random forest regression model demonstrated superior predictive accuracy (RMSE = 0.01454 and <em>R</em><sup>2</sup> = 0.7310) than the linear regression model (RMSE = 0.02253 and <em>R</em><sup>2</sup> = 0.4642), effectively capturing the non-linear relationships between the manufacturing process parameters and cell warpage. The electrolyte thickness, presintering temperature, and Ni/(Fe+Ni) atomic ratio are identified as key factors influencing cell warpage. Material characterizations using X-ray diffraction and coefficient of thermal expansion measurements validate these predictions. Although the open circuit voltage remains below the theoretical electromotive force owing to residual microstructural defects in the electrolyte, the cell warpage successfully reduced from 0.07578 to 0.03825 by increasing the presintering temperature from 1150 to 1250 °C. These results demonstrate the potential of machine learning for guiding manufacturing process optimization of mechanically robust and high-performance metal-supported SOFCs.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100230"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145738965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive comparison of dynamic strain localisation and mechanical behaviour in traditional and additively manufactured Ti6Al4V 传统和增材制造Ti6Al4V的动态应变局部化和力学行为的综合比较
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2025-12-06 DOI: 10.1016/j.jalmes.2025.100228
Govind Gour , Antonio Pellegrino
{"title":"A comprehensive comparison of dynamic strain localisation and mechanical behaviour in traditional and additively manufactured Ti6Al4V","authors":"Govind Gour ,&nbsp;Antonio Pellegrino","doi":"10.1016/j.jalmes.2025.100228","DOIUrl":"10.1016/j.jalmes.2025.100228","url":null,"abstract":"<div><div>Titanium alloys are widely used in aerospace, defence, automotive, and biomedical engineering owing to their high specific strength and excellent corrosion resistance. Additive manufacturing has emerged as a promising alternative to conventional production methods, offering the capability to fabricate complex geometries while reducing processing time and material waste. In this study, the high strain rate deformation behaviour of Ti6Al4V produced by selective laser melting is investigated using a Split Hopkinson Tension Bar system equipped with a multi-camera high-speed imaging setup. A comprehensive experimental programme is conducted on specimens manufactured in three different build orientations to assess the influence of processing direction on dynamic strain localisation and true stress–strain response. The post-necking behaviour is examined and compared with that of conventionally forged Ti6Al4V, revealing notable differences in ductility and strain localisation mechanisms. In addition, the high strain rate compressive behaviour of both material variants and their temperature dependence are investigated using a Split Hopkinson Compression Bar system equipped with thermal conditioning. The deformation and failure mechanisms of additively manufactured specimens produced in different orientations are further examined through post-mortem analysis of the fracture surfaces.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100228"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145698156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hot corrosion behavior of La₂Ce₂O₇ thermal barrier coatings under high-temperature molten salt environments La₂Ce₂O₇热障涂料在高温熔盐环境下的热腐蚀行为
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-02-23 DOI: 10.1016/j.jalmes.2026.100239
Banothu Ramesh, S.P. Kumaresh Babu
{"title":"Hot corrosion behavior of La₂Ce₂O₇ thermal barrier coatings under high-temperature molten salt environments","authors":"Banothu Ramesh,&nbsp;S.P. Kumaresh Babu","doi":"10.1016/j.jalmes.2026.100239","DOIUrl":"10.1016/j.jalmes.2026.100239","url":null,"abstract":"<div><div>In this study, La₂Ce₂O₇ (LC) powders synthesized via a molten-salt process were deposited as a thermal barrier coating on Hastelloy-X substrates by atmospheric plasma spraying (APS), with a NiCrAlY bond coat as an interlayer. The APS-deposited LC coating exhibited phase stability up to 1600 °C for 100 h while retaining its fluorite structure. The thermal conductivity of the coating remained low, ranging from 0.64 to 0.82 W·m⁻¹ ·K⁻¹ over the temperature range of 30–1000 °C. The coating was further subjected to thermal cycling tests to evaluate its thermal cycling lifetime and failure behavior, during which chipping-type spallation developed within the ceramic topcoat near the bond-coat interface due to thermally induced stresses. Hot-corrosion tests were performed in Na₂SO₄, V₂O₅, and a eutectic mixture consisting of 32 wt% Na₂SO₄–68 wt% V₂O₅ at 900 °C for 30 h. The coating exhibits high stability in pure Na₂SO₄ and moderate degradation in V₂O₅. In contrast, severe degradation is observed in the Na₂SO₄–V₂O₅ eutectic mixture, where LaVO₄ forms as the dominant corrosion product, accompanied by CeVO₄, LaCeVO₄, and CeO₂. This study presents a coating-level evaluation of the high-temperature phase stability of APS-deposited La₂Ce₂O₇ coatings, together with a systematic assessment of their hot-corrosion behavior in sulfate- and vanadate-containing service environments.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100239"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147384652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructural and corrosion rate evolution of Mg-Nd-Zr alloy during multiaxial forging processing Mg-Nd-Zr合金在多轴锻造过程中的组织与腐蚀速率演变
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-02-26 DOI: 10.1016/j.jalmes.2026.100240
V. Greshta, D. Pavlenko, D. Tkach, O. Voskoboynik
{"title":"Microstructural and corrosion rate evolution of Mg-Nd-Zr alloy during multiaxial forging processing","authors":"V. Greshta,&nbsp;D. Pavlenko,&nbsp;D. Tkach,&nbsp;O. Voskoboynik","doi":"10.1016/j.jalmes.2026.100240","DOIUrl":"10.1016/j.jalmes.2026.100240","url":null,"abstract":"<div><div>Bioresorbable magnesium alloys represent a promising class of materials for temporary osteosynthesis implants; however, their clinical application is limited by excessively rapid degradation rates. This study investigates the effect of severe plastic deformation via multiaxial forging («abc»-pressing) on the microstructure, microhardness, and corrosion behaviour of an Mg-Nd-Zr system alloy (Nd–3.0 wt%, Zr–0.4 wt%, Zn–0.2 wt%) for biomedical applications. Deformation processing was performed at 350 °C with up to 9 cycles. Microstructural characterisation was conducted using optical microscopy and scanning electron microscopy with energy-dispersive spectroscopy. Corrosion behaviour was evaluated by potentiodynamic polarisation in 0.9% NaCl solution simulating physiological conditions. Multiaxial forging induced grain refinement from 56 ± 21 μm to 48 ± 18 μm after 5 deformation cycles, accompanied by transformation of the continuous intergranular Mg₁₂Nd β-phase network into uniformly distributed spheroidised particles. Decomposition of the supersaturated α−Mg solid solution resulted in Nd depletion of the matrix (from 2.2 to &lt;0.6 wt%) and concurrent β-phase enrichment (up to 30.6 wt% Nd). Microhardness measurements revealed an increase in mean values across all specimen faces following deformation processing, with a significant reduction in data scatter, indicating improved structural homogeneity attributable to increased dislocation density and uniform distribution of secondary phases. Electrochemical testing demonstrated a 30% reduction in corrosion current density (from 347 to 242 μA/cm²) and corrosion rate (from 7.94 to 5.54 mm/year), with electrochemical data suggesting a tendency toward more uniform degradation, consistent with post-corrosion observations from the same alloy processed by an alternative SPD method. The improved corrosion resistance is attributed to reduced galvanic potential differences between the α−Mg matrix and β-phase precipitates, secondary-phase fragmentation, and modification of the grain boundary network. These findings demonstrate that multiaxial forging is an effective thermomechanical processing route for optimising the property profile of Mg-Nd-Zr alloys for bioresorbable implant applications.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100240"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147384705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of heat treatment temperature on the wear resistance of 42CrMo steel hardfacing with Fe–Cr–C alloy 热处理温度对Fe-Cr-C合金堆焊42CrMo钢耐磨性的影响
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-01-30 DOI: 10.1016/j.jalmes.2026.100235
Junke Hao, Huiying Que
{"title":"The effect of heat treatment temperature on the wear resistance of 42CrMo steel hardfacing with Fe–Cr–C alloy","authors":"Junke Hao,&nbsp;Huiying Que","doi":"10.1016/j.jalmes.2026.100235","DOIUrl":"10.1016/j.jalmes.2026.100235","url":null,"abstract":"<div><div>Fe–Cr–C hardfacing alloys are widely used in hardfacing applications because of their high strength. In this study, a Fe–Cr–C hardfacing layer was deposited on a 42CrMo steel plate by manual arc welding. The effects of post-weld heat treatment at 400 ℃, 600 ℃, and 800 ℃ on residual stress in the hardfaced layer were examined by finite element simulation. The simulation results showed that heat treatment at 600 ℃ effectively reduced the residual stress. Optical microscopy, X-ray diffraction, energy-dispersive spectroscopy, microhardness, wear testing and scanning electron microscope were then used to evaluate how heat treatment influences the microstructure and wear behavior of the hardfacing alloy. After hardfacing, a dendritic structure formed at the weld interface. Following heat treatment at 600 ℃, carbides diffused along grain boundaries into the ferrite matrix, and the dendritic structure transformed into a carbide-rich dendritic morphology. After heat treatment at 600 °C, the hardness of the hardfacing alloy increased to 551.3 HV, the friction coefficient rose to 1.17, and the volume wear loss decreased by 26.1 %. The wear mechanism of the hardfacing alloy was dominated by abrasive wear. These results indicate that, for 42CrMo steel hardfaced with a Fe–Cr–C alloy, selecting an appropriate heat treatment temperature can not only relieve residual stress but also enhance the wear resistance of the material.</div></div>","PeriodicalId":100753,"journal":{"name":"Journal of Alloys and Metallurgical Systems","volume":"13 ","pages":"Article 100235"},"PeriodicalIF":0.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146077440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser shock processing: An effective post-treatment process to enhance mechanical performances of laser additive manufactured parts 激光冲击加工:提高激光增材制造零件机械性能的有效后处理工艺
Journal of Alloys and Metallurgical Systems Pub Date : 2026-03-01 Epub Date: 2026-02-04 DOI: 10.1016/j.jalmes.2026.100236
Cheng He , Youze Xu , Xiaodie Cao , Jibin Zhao , Lihong Li , Bingqi Zhou , Zhongfa Mao , Jiajun Wu , Xinhui Chen
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