Corrosion Communications最新文献

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Effects of grain boundary characteristics changing with cold rolling deformation on intergranular corrosion resistance of 443 ultra-pure ferritic stainless steel 晶界特征随冷轧变形变化对443超纯铁素体不锈钢抗晶间腐蚀性能的影响
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.07.002
Binggang Shang, Longlin Lei, Xiangyu Wang, Pei He, Xinzhe Yuan, Wei Dai, Jin Li, Yiming Jiang, Yangting Sun
{"title":"Effects of grain boundary characteristics changing with cold rolling deformation on intergranular corrosion resistance of 443 ultra-pure ferritic stainless steel","authors":"Binggang Shang,&nbsp;Longlin Lei,&nbsp;Xiangyu Wang,&nbsp;Pei He,&nbsp;Xinzhe Yuan,&nbsp;Wei Dai,&nbsp;Jin Li,&nbsp;Yiming Jiang,&nbsp;Yangting Sun","doi":"10.1016/j.corcom.2022.07.002","DOIUrl":"10.1016/j.corcom.2022.07.002","url":null,"abstract":"<div><p>The relationship between evolution in grain boundary characteristics and intergranular corrosion properties of cold rolled 443 ultra-pure ferritic stainless steel was investigated. The results showed that low-angle (LA) grain boundaries, special grain boundaries (SGB), and high-angle (HA) grain boundaries had a high intergranular corrosion sensitivity after cold deformation in reducing acid medium. In oxidative acid medium, the LA and SGB boundaries had a high intergranular corrosion resistance in comparison to HA boundaries, and their inhibitory effect on the corrosion continuance of the dynamic recrystallization high-angle (RHA) grain boundaries can improve the corrosion resistance of the RHA grain boundaries.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 27-39"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000524/pdfft?md5=db8fa0aff2c5817b9f9f5687114daa7e&pid=1-s2.0-S2667266922000524-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90817331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Improving oxidation resistance of Si coating by isolated-particle healing 用隔离粒子愈合提高硅涂层的抗氧化性
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.03.006
Lin Chen , Jia-Hui Li , Guo-Qiang Wang , You-Feng Bo , Guan-Jun Yang
{"title":"Improving oxidation resistance of Si coating by isolated-particle healing","authors":"Lin Chen ,&nbsp;Jia-Hui Li ,&nbsp;Guo-Qiang Wang ,&nbsp;You-Feng Bo ,&nbsp;Guan-Jun Yang","doi":"10.1016/j.corcom.2022.03.006","DOIUrl":"https://doi.org/10.1016/j.corcom.2022.03.006","url":null,"abstract":"<div><p>Atmospheric plasma sprayed dense Si coatings have excellent potential for high-temperature oxidation resistance. However, numerous isolated spherical particles on the coating surface result in rapid oxidation and a large local TGO thickness. In the present study, isolated particle healing (IPH) treatment was proposed to eliminate these isolated particles. Then, the related structure evolution and oxidation kinetics of Si coatings were investigated. Finally, the failure mechanism of TGO after oxidation was identified. The results show that the IPH treatment makes isolated particles diffuse, connect with and then immerse themselves into the bulk coating surface, thereby contributing to both surface smoothing and coating densification. Consequently, the localized large thickness in the TGO scale is eliminated, and the overall oxidation rates of the IPH Si coating decrease by ∼24% compared with the as-sprayed coating. The <em>β</em>→<em>α</em> phase transformation of polymorphic cristobalite with a volume reduction of ∼4.5% is the main cause for TGO channel cracking and is not suppressed by IPH treatment, which points out future directions for better antioxidant Si coatings.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 9-17"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000470/pdfft?md5=a265de78b3c5f110af5ea45d1d04c08f&pid=1-s2.0-S2667266922000470-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92083147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Mechanistic investigations of corrosion and localized corrosion of X80 steel in seawater comprising sulfate-reducing bacteria under continuous carbon starvation 含硫酸盐还原菌的海水中X80钢连续碳饥饿腐蚀及局部腐蚀机理研究
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.08.002
Hongwei Liu , Cuiying Chen , Muhammad Asif , Tong Zhao , Bing Lei , Guozhe Meng , Hongfang Liu
{"title":"Mechanistic investigations of corrosion and localized corrosion of X80 steel in seawater comprising sulfate-reducing bacteria under continuous carbon starvation","authors":"Hongwei Liu ,&nbsp;Cuiying Chen ,&nbsp;Muhammad Asif ,&nbsp;Tong Zhao ,&nbsp;Bing Lei ,&nbsp;Guozhe Meng ,&nbsp;Hongfang Liu","doi":"10.1016/j.corcom.2022.08.002","DOIUrl":"10.1016/j.corcom.2022.08.002","url":null,"abstract":"<div><p>Sulfate-reducing bacteria (SRB) corrosion is one of the main reasons leading to the service failure of engineering materials in the marine environment. An understanding of SRB corrosion especially under continuous organic carbon starvation is required. In this work, SRB corrosion of X80 pipeline steel under continuous organic carbon starvation was studied using mass loss, electrochemical measurements, and surface analysis. The effects of initial SRB concentrations on steel corrosion were also studied and discussed. The results indicated that more than 99% population of SRB die after 21 d of testing in various conditions, but there are still amounts of SRB survivors. SRB survivors with continued organic carbon starvation have a better adaptive ability and accelerated steel corrosion. Both the uniform and localized corrosion rates are also proportional to the initial SRB concentration as well as SRB survivors. The localized corrosion rate and density of corrosion pits of specimen corresponding to an initial SRB count of 10<sup>8</sup> cells/mL reach bigger values of (0.693 ± 0.114) mm/y and (1.94 ± 0.39)×10<sup>4</sup> pits/cm<sup>2</sup>, respectively, which are induced by the combination of the sessile and planktonic SRB.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 70-80"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000603/pdfft?md5=cc3bcfbcc59117833bce2d97968a4739&pid=1-s2.0-S2667266922000603-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80473488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Corrosion of X65 steel by Pseudomonas sp. in planktonic and sessile states and inhibition effect of cathodic polarization 假单胞菌对X65钢浮游态和固态的腐蚀及阴极极化的抑制作用
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.05.003
Meiying Lv, Zhenxin Li, Min Du, Guannan Li, Jian Wang, Ting Xu
{"title":"Corrosion of X65 steel by Pseudomonas sp. in planktonic and sessile states and inhibition effect of cathodic polarization","authors":"Meiying Lv,&nbsp;Zhenxin Li,&nbsp;Min Du,&nbsp;Guannan Li,&nbsp;Jian Wang,&nbsp;Ting Xu","doi":"10.1016/j.corcom.2022.05.003","DOIUrl":"10.1016/j.corcom.2022.05.003","url":null,"abstract":"<div><p>In harsh marine environment, corrosion is a serious problem, among which microbiologically influenced corrosion is particularly common and complex. This work studied corrosion of X65 steel by planktonic and sessile iron oxidizing bacteria (IOB), i.e. <em>Pseudomonas</em> sp. isolated from coastal water of Qingdao, and inhibition effect of cathodic polarization. Results demonstrate that both the planktonic and sessile IOB caused the corrosion of X65 steel by promoting the oxidation of ferrous ions, but the contribution of sessile cells was far greater than that of planktonic cells. Cathodic polarization kills sessile cells on the metal surface and prevent attachment of IOB. With a negative shift of the cathodic potential, the inhibition effect was enhanced. Cathodic polarization altered interface properties of X65 steel, affecting adhesion and corrosion process of IOB cells. However, when X65 steel was sufficiently polarized to −1050 mV vs. SCE, IOB produced more extracellular polymeric substances to resist stimulation by an external electric field. Therefore, cathodic polarization could not completely remove sessile IOB cells, and pitting corrosion existed on the metal surface.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 58-69"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000597/pdfft?md5=6793dcec7039a3e35e888ead0abbae41&pid=1-s2.0-S2667266922000597-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79133910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Self healing behavior of enamel incorporated with nickel particles of various sizes during high temperature oxidation process 不同尺寸镍粒子的珐琅在高温氧化过程中的自愈行为
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.07.003
Yimin Liao , Jinlong Wang , Min Feng , Shenglong Zhu , Minghui Chen , Fuhui Wang
{"title":"Self healing behavior of enamel incorporated with nickel particles of various sizes during high temperature oxidation process","authors":"Yimin Liao ,&nbsp;Jinlong Wang ,&nbsp;Min Feng ,&nbsp;Shenglong Zhu ,&nbsp;Minghui Chen ,&nbsp;Fuhui Wang","doi":"10.1016/j.corcom.2022.07.003","DOIUrl":"10.1016/j.corcom.2022.07.003","url":null,"abstract":"<div><p>The self-healing nickel-enamel composite coating can spontaneously heal cracks at a certain temperature, thus ensuring its high-temperature service ability in thermal shock environment. In this study, nickel particles of various sizes (50 nm, 2 <em>µ</em>m and 20 <em>µ</em>m) were incorporated into a silicate enamel. Flexural strength of the pure enamel and its composites was investigated to analyze their thermal shock and crack healing behavior. Results indicated that nickel particles incorporation enhanced strength and thermal shock resistance of enamel, but such an enhancement depended on the size of particles. When nickel particles were in a scale of 2 <em>µ</em>m, the composite performed the highest flexural strength, 34% higher than the enamel free of nickel particles. Moreover, its critical thermal shock temperature (Δ<em>T</em><sub>C</sub>) was increased by 100 ℃. In the meantime, the composite was endowed with the optimum ability of cracks self-healing. After cracks nucleation in the process of thermal shock, they were largely healed in subsequent oxidation stage. Flexural strength was recovered to 87.9% of the value before thermal shock.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 49-57"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000573/pdfft?md5=cd61f57e13977dc9b7e048c585f7ff8b&pid=1-s2.0-S2667266922000573-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79475221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Effects of heat treatment on precipitation and corrosion resistance of cerium-containing super austenitic stainless steel S31254 热处理对含铈超级奥氏体不锈钢S31254析出及耐蚀性的影响
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.06.001
Xiaoli Zhang , Maonian Xun , Jinyao Ma , Xiaohong Liang , Caili Zhang , Huabing Li , Zhouhua Jiang , Guangwei Fan , Peide Han
{"title":"Effects of heat treatment on precipitation and corrosion resistance of cerium-containing super austenitic stainless steel S31254","authors":"Xiaoli Zhang ,&nbsp;Maonian Xun ,&nbsp;Jinyao Ma ,&nbsp;Xiaohong Liang ,&nbsp;Caili Zhang ,&nbsp;Huabing Li ,&nbsp;Zhouhua Jiang ,&nbsp;Guangwei Fan ,&nbsp;Peide Han","doi":"10.1016/j.corcom.2022.06.001","DOIUrl":"https://doi.org/10.1016/j.corcom.2022.06.001","url":null,"abstract":"<div><p>The influence of a combined process, involving air cooling and heat treatment at 300 ℃, on precipitation behavior and corrosion resistance of a S31254-Ce steel was explored through scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), electron backscatter diffraction (EBSD) and electrochemical analysis. After air cooling and heat treatment at 300 ℃, the S31254-Ce steel was conducive to the enrichment of Ce along the grain boundary and the content of Σ3 twins in aged samples increased. The composite heat treatment process is beneficial to inhibit the precipitation of precipitates in the aging process and improve the corrosion resistance of S31254-Ce steel.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 1-8"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000500/pdfft?md5=328e44b413f92f7250486974d0398fcb&pid=1-s2.0-S2667266922000500-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92083146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Corrosion behavior of wire arc additive manufactured and wrought 309 stainless steel in acidic solution 丝弧添加剂制造和变形309不锈钢在酸性溶液中的腐蚀行为
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.08.001
Atinuke Oladoye, Lawrence Osoba
{"title":"Corrosion behavior of wire arc additive manufactured and wrought 309 stainless steel in acidic solution","authors":"Atinuke Oladoye,&nbsp;Lawrence Osoba","doi":"10.1016/j.corcom.2022.08.001","DOIUrl":"https://doi.org/10.1016/j.corcom.2022.08.001","url":null,"abstract":"<div><p>In this study, 309 stainless steel (309SS) was fabricated by wire arc additive manufacturing (WAAM) process and characterized using optical microscopy and X-ray diffractometry. Corrosion behavior of WAAM 309SS in 1 mol/L H<sub>2</sub>SO<sub>4</sub> solution at room temperature was investigated in comparison to that of wrought 309SS using electrochemical impedance spectroscopy, pontentiodynamic polarization, and immersion test. Mott-Schottky analysis, double loop electrochemical potentiokinetic reactivation (DLEPR) test and galvanic corrosion test using zero resistance ammeter (ZRA) technique were also conducted. The results showed that WAAM 309SS exhibited lower corrosion resistance than AISI 309SS due to microstructural differences engendered by the additive manufacturing process. Galvanic corrosion test showed that galvanic effect between the two stainless steels was minimal despite the microstructural differences while DLEPR test revealed the absence of chromium-depleted zones in both WAAM 309SS and AISI 309SS.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 81-90"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000585/pdfft?md5=5eb1b399918b179484ef59568e8a8139&pid=1-s2.0-S2667266922000585-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92060979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Preparation and properties of α-Al2O3 diffusion barrier on stainless steel 316 316不锈钢α-Al2O3扩散阻挡层的制备及性能
Corrosion Communications Pub Date : 2022-12-01 DOI: 10.1016/j.corcom.2022.04.004
Changxuan Wang, Jinning Huang, Yanli Wang
{"title":"Preparation and properties of α-Al2O3 diffusion barrier on stainless steel 316","authors":"Changxuan Wang,&nbsp;Jinning Huang,&nbsp;Yanli Wang","doi":"10.1016/j.corcom.2022.04.004","DOIUrl":"10.1016/j.corcom.2022.04.004","url":null,"abstract":"<div><p>A compact and adherent Al<sub>2</sub>O<sub>3</sub> diffusion barrier was obtained between a Ni coating and stainless steel 316 (316SS) through double-pulse composite plating coupled with in-situ thermal growth. To promote the formation of <em>α</em>-Al<sub>2</sub>O<sub>3</sub> at low temperature, a Cr<sub>2</sub>O<sub>3</sub> film was firstly prepared by pre-oxidation of 316SS. Then a Ni-Al/NiO composite coating was deposited on 316SS in a modified Watts’ bath with a Zeta potential of about +21.89 mV, a favorable condition for the co-deposition of double particles and nickel, followed by heat treatment in Ar at 800 ℃ for 12 h. Results of diffusion resistance tests at 750 and 800 ℃ for 100 h in Ar suggest that the Ni/<em>α</em>-Al<sub>2</sub>O<sub>3</sub> composite coating changes slightly during the annealing treatment and significantly prevents the diffusion of Fe and Cr from 316SS substrate to the upper Ni layer. Furthermore, corrosion resistance of the composite coating is higher than that of the 316SS/Ni sample.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"8 ","pages":"Pages 18-26"},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000512/pdfft?md5=b5fdc9519b8988e6cd70e020951a085f&pid=1-s2.0-S2667266922000512-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75744241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion behaviour of wire arc additive manufactured and wrought 309 stainless steel in acidic solution 电弧添加剂制造和锻造309不锈钢在酸性溶液中的腐蚀行为
Corrosion Communications Pub Date : 2022-11-01 DOI: 10.1016/j.corcom.2022.08.001
A. Oladoye, L. Osoba
{"title":"Corrosion behaviour of wire arc additive manufactured and wrought 309 stainless steel in acidic solution","authors":"A. Oladoye, L. Osoba","doi":"10.1016/j.corcom.2022.08.001","DOIUrl":"https://doi.org/10.1016/j.corcom.2022.08.001","url":null,"abstract":"","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"137 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86448590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Pitting corrosion of 304 stainless steel in secondary water supply system 二次供水系统304不锈钢的点蚀
Corrosion Communications Pub Date : 2022-09-01 DOI: 10.1016/j.corcom.2021.11.010
Kuijiao Li , Li Sun , Wenkai Cao , Si Chen , Zhiwei Chen , Yanli Wang , Weihua Li
{"title":"Pitting corrosion of 304 stainless steel in secondary water supply system","authors":"Kuijiao Li ,&nbsp;Li Sun ,&nbsp;Wenkai Cao ,&nbsp;Si Chen ,&nbsp;Zhiwei Chen ,&nbsp;Yanli Wang ,&nbsp;Weihua Li","doi":"10.1016/j.corcom.2021.11.010","DOIUrl":"10.1016/j.corcom.2021.11.010","url":null,"abstract":"<div><p>The effect of NaClO solution on pitting behavior of 304 stainless steel was investigated by electrochemical tests and composition analysis. The results show that the open circuit potential (OCP) shifts to the positive direction with the increase of [ClO<sup>−</sup>], indicating that the passivation film formed on the sample surface is faster, but, has no effect on pitting potential (<em>E</em><sub>b</sub>) in the first stage (&lt; 24 h). After 24 h immersion, the pitting occurs because Cl<sup>−</sup> is detected in the wake of the decomposition of ClO<sup>−</sup> for its thermodynamics instability. In the later stage, the [Cl<sup>−</sup>] increases with the increase of [ClO<sup>−</sup>], correspondingly resulting in lower pitting resistance. X-ray photoelectron spectroscopy (XPS) reveals that the Cr/Fe atomic ratio in the passivation film decreases with the increase of [ClO<sup>−</sup>], because Cr(III) is oxidized to Cr(VI) and dissolves in the solution, which further weakens the pitting resistance of 304 stainless steel. The electrochemical impedance spectroscopy (EIS), combined with the Mott-Schottky analysis (MSA) was employed to verify the properties of the passivation film related to pitting.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"7 ","pages":"Pages 43-50"},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266922000457/pdfft?md5=acbc9bdcc3dcc6e444419bc510c41b99&pid=1-s2.0-S2667266922000457-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80474698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
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