Carbon Neutralization最新文献_第9页

Molecular engineering assembly of mesoporous carbon onto Ti3C2Tx MXene for enhanced lithium-ion storage 介孔碳在Ti3C2Tx MXene上的分子工程组装用于增强锂离子存储

Carbon Neutralization Pub Date : 2023-10-13 DOI: 10.1002/cnl2.93

Haitao Li, Fengting Lv, Xiao Fang, Guanjia Zhu, Wei Yu, Haijiao Zhang

{"title":"Molecular engineering assembly of mesoporous carbon onto Ti3C2Tx MXene for enhanced lithium-ion storage","authors":"Haitao Li, Fengting Lv, Xiao Fang, Guanjia Zhu, Wei Yu, Haijiao Zhang","doi":"10.1002/cnl2.93","DOIUrl":"10.1002/cnl2.93","url":null,"abstract":"The rational construction of Ti3C2Tx MXene-based composites has been deemed as a popular way to improve their electrochemical energy storage performances owing to the unique two-dimensional (2D) structure, excellent conductivity, and good flexibility. However, it remains a major challenge to assemble mesoporous carbon onto Ti3C2Tx with fewer oxygen-containing groups by using surfactants with short hydrophilic segments. In the work, we propose a molecular engineering assembly strategy for the growth of N,P co-doped mesoporous carbon onto Ti3C2Tx nanosheets (NPMC/Ti3C2Tx) under the assistance of phytic acid by using melamine-formaldehyde resin and pluronic P123 (PEO20PPO70PEO20) as the carbon/nitrogen source and soft template, respectively. The detailed investigations reveal that phytic acid with abundant hydroxyl groups can effectively enhance the hydrogen bond interactions among P123, carbon precursor, and Ti3C2Tx nanosheets, thus ensuring the efficient assembly of mesoporous carbon onto Ti3C2Tx. The obtained NPMC/Ti3C2Tx composite demonstrates a set of merits, including cylindrical mesopore, N,P co-doping, and a good combination of mesoporous carbon and Ti3C2Tx nanosheets. As a result, it exhibits an improved lithium-ion storage performance, delivering a high reversible capacity of 556.3 mA h g−1 after 100 cycles at 0.1 A g−1. The present work provides a feasible molecular engineering assembly route for the rational design of high-performance Ti3C2Tx MXene-based electrodes.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 6","pages":"678-688"},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.93","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135854606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Transport channel engineering between MXene interlayers for Zn-ion hybrid microsupercapacitor with enhanced energy output and cycle stability 具有增强能量输出和循环稳定性的锌离子混合微超级电容器的MXene中间层间传输通道工程

Carbon Neutralization Pub Date : 2023-10-05 DOI: 10.1002/cnl2.90

Zhiqian Cao, Guangyao Hu, Weixing Feng, Jie Ru, Yujin Li

{"title":"Transport channel engineering between MXene interlayers for Zn-ion hybrid microsupercapacitor with enhanced energy output and cycle stability","authors":"Zhiqian Cao, Guangyao Hu, Weixing Feng, Jie Ru, Yujin Li","doi":"10.1002/cnl2.90","DOIUrl":"10.1002/cnl2.90","url":null,"abstract":"Two-dimensional (2D) transition metal carbonitrides/nitrides (MXene) materials have proven to be promising alternatives as novel capacitor-type electrodes for aqueous Zn-ion hybrid microsupercapacitors (ZHMSCs). However, during self-assembly processes, serious restacking between 2D MXene nanosheets induced by strong van der Waals forces makes ion transport channels narrow within the compact MXene film electrodes, which would result in poor energy output of ZHMSCs. Herein, interlayer transport channel engineering is designed by intercalating bacterial cellulose (BC) between MXene interlayers to develop MXene/BC electrodes with fast ion transport channels in contrast to pure MXene electrodes. Benefiting from fast anion intercalation/deintercalation on MXene/BC capacitor-type cathode and reversible Zn stripping/plating on Zn foil anode, the fabricated ZHMSCs exhibit wide working potential windows (1.36 V), high areal capacitance (404 mF cm−2), and landmark areal energy density (94 µWh cm−2 at 1 mA cm−2). The areal capacitance and energy density of the developed ZHMSCs are much higher than those of the ZHMSCs based on pure MXene capacitor-type cathode (239 mF cm−2/57 µWh cm−2 at 1 mA cm−2). Besides, the developed ZHMSCs can perform more than 10,000 cycles, showing outstanding capacity retention. In general, our work provides a novel strategy to break through the performance bottlenecks afflicting MXene-based ZHMSCs.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 6","pages":"699-708"},"PeriodicalIF":0.0,"publicationDate":"2023-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.90","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135482592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A combined experimental and theoretical study of a novel corrosion inhibitor derived from thiophen 由硫芬衍生的新型缓蚀剂的实验与理论结合研究

Carbon Neutralization Pub Date : 2023-10-05 DOI: 10.1002/cnl2.92

Ali M. Resen, Ayad N. Jasim, Heba S. Qasim, Mahdi M. Hanoon, Mohammed H. H. Al-Kaabi, Ahmed A. Al-Amiery, Waleed K. Al-Azzawi

{"title":"A combined experimental and theoretical study of a novel corrosion inhibitor derived from thiophen","authors":"Ali M. Resen, Ayad N. Jasim, Heba S. Qasim, Mahdi M. Hanoon, Mohammed H. H. Al-Kaabi, Ahmed A. Al-Amiery, Waleed K. Al-Azzawi","doi":"10.1002/cnl2.92","DOIUrl":"10.1002/cnl2.92","url":null,"abstract":"In this study, we synthesized a novel corrosion inhibitor derived from thiophene and conducted a comprehensive evaluation of its inhibitory properties through both experimental and theoretical approaches. Our investigation encompassed experimental assessments employing Mass loss tests and electrochemical techniques. Additionally, we performed computational studies to delve into the electronic structure and bonding characteristics of the inhibitor, aiming to elucidate its inhibitory mechanism. Our findings revealed that the synthesized inhibitor displayed remarkable inhibitory efficiency, demonstrating its effectiveness in preventing the corrosion of mild steel. Specifically, the thiophene derivative exhibited an impressive inhibitory efficiency of 92.8%, underscoring its potential as a robust corrosion inhibitor for mild steel. Furthermore, this study delved into optimizing the conditions for employing the thiophene derivative as a corrosion inhibitor. Our investigation revealed that the most effective inhibition was achieved at a concentration of 0.5 mM and a temperature of 303 K. To elucidate the interaction between the inhibitor and the mild steel surface, we applied the Langmuir adsorption isotherm concept, shedding light on both the physical and chemical adsorption processes of the thiophene derivative on the metal's surface. Our investigations demonstrated that the addition of the inhibitor significantly reduced the corrosion rate of the metal. Our computational results further reinforced these experimental findings, indicating that the inhibitor formed stable adsorption complexes on the metal surface. This dual confirmation from experimental and computational approaches strengthens the confidence in the inhibitor's efficacy in mitigating corrosion.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 6","pages":"661-677"},"PeriodicalIF":0.0,"publicationDate":"2023-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.92","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135482849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrogen storage mechanism of metal–organic framework materials based on metal centers and organic ligands 基于金属中心和有机配体的金属-有机骨架材料储氢机理研究

Carbon Neutralization Pub Date : 2023-10-03 DOI: 10.1002/cnl2.91

Bo Zhang, Yanli Sun, Hong Xu, Xiangming He

{"title":"Hydrogen storage mechanism of metal–organic framework materials based on metal centers and organic ligands","authors":"Bo Zhang, Yanli Sun, Hong Xu, Xiangming He","doi":"10.1002/cnl2.91","DOIUrl":"10.1002/cnl2.91","url":null,"abstract":"The effective storage and utilization of hydrogen energy is expected to solve the problems of energy shortage and environmental pollution currently faced by human society. Metal–organic framework materials (MOFs) have been shown by scientists to be very potential hydrogen storage materials. However, the current design methods and strategies for MOFs are still generally in the trial-and-error stage, and the research works are at the overall level. To solve the problems of directional design and rational construction of new MOFs, this work uses the principles and methods of coordination chemistry and crystal engineering to carry out the theoretical design and mechanism research of new MOFs for high-efficiency hydrogen storage application scenarios. In this study, the structures selected for theoretical calculation were divided into two types: different ligands for the same metal (IRMOFs, MOF-205, and DUT-23-Zn) and different metals for the same ligand (DUT-23-M [(M = Co, Ni, Cu, and Zn]). The model construction process, hydrogen loading with temperature, specific surface area, hydrogen adsorption energy, charge density and hydrogen storage mechanism of the above structures were analyzed, and the key indicators that may affect the hydrogen storage performance of MOFs were summarized: type and quantity of coordination metals, temperature, pressure, adsorption site and specific surface area.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 6","pages":"632-645"},"PeriodicalIF":0.0,"publicationDate":"2023-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.91","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135689673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Back Cover Image: Carbon Neutralization, Volume 2, Issue 5, September 2023 封底图片：碳中和，第2卷，第5期，2023年9月

Carbon Neutralization Pub Date : 2023-09-27 DOI: 10.1002/cnl2.89

Zhenhai Gao, Haicheng Xie, Xianbin Yang, Lisheng Zhang, Hanqing Yu, Wentao Wang, Yongfeng Liu, Youqing Xu, Bin Ma, Xinhua Liu, Siyan Chen

{"title":"Back Cover Image: Carbon Neutralization, Volume 2, Issue 5, September 2023","authors":"Zhenhai Gao, Haicheng Xie, Xianbin Yang, Lisheng Zhang, Hanqing Yu, Wentao Wang, Yongfeng Liu, Youqing Xu, Bin Ma, Xinhua Liu, Siyan Chen","doi":"10.1002/cnl2.89","DOIUrl":"https://doi.org/10.1002/cnl2.89","url":null,"abstract":"Back cover image: The electric mobility is considered to be a key step towards achieving the vision of carbon neutrality, and the high carbon footprint of electric vehicle (EV) power batteries is a critical factor affecting the ability of EV to reduce carbon emissions. In 10.1002/cnl2.81, the researchers organize the carbon accounting standards of the automotive industry and compare the lifecycle carbon emissions of various types of vehicles, pointing out the advantages of EV in reducing carbon emissions, as well as the concentration of carbon emissions in EV lifecycle. And the researchers elaborated how to reduce the lifecycle carbon emissions of EV from the automobile industry chain. Finally, focusing on power batteries, it concludes that fine management, echelon utilization, and efficient recycling are ways to reduce their contribution to the carbon emissions of EV.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 5","pages":"ii"},"PeriodicalIF":0.0,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.89","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50155090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Carbon Neutralization, Volume 2, Issue 5, September 2023 封面：碳中和，第2卷，第5期，2023年9月

Carbon Neutralization Pub Date : 2023-09-27 DOI: 10.1002/cnl2.88

Yuhan Wu, Ziqi Zhao, Xiaorui Hao, Rui Xu, Laishi Li, Dan Lv, Xianglong Huang, Qing Zhao, Yang Xu, Yusheng Wu

引用次数: 0

Graphitic carbon nitride nanomaterials for high-performance supercapacitors 用于高性能超级电容器的石墨氮化碳纳米材料

Carbon Neutralization Pub Date : 2023-09-19 DOI: 10.1002/cnl2.87

Yunxuan Chen, Chao Lu

{"title":"Graphitic carbon nitride nanomaterials for high-performance supercapacitors","authors":"Yunxuan Chen, Chao Lu","doi":"10.1002/cnl2.87","DOIUrl":"https://doi.org/10.1002/cnl2.87","url":null,"abstract":"Graphitic carbon nitride is a promising material as an electrode material for advanced electrochemical energy storage devices because of its controllable structure, physicochemical properties, and abundant active sites. However, its intrinsic properties as electrode materials can not be fully expressed owing to limited electrical properties, which impede charge transfer and material exchange inside devices. During the past decade, the challenge has been addressed through material engineering strategies, such as exfoliation and composition, and then advanced energy devices, such as supercapacitors, have been assembled. In this regard, a timely review of graphitic carbon nitride for high-performance supercapacitors requires to be put forward for summarizing past studies and inspiring future research works as well. This review article summarizes recent progress in material synthesis and property regulation of graphitic carbon nitride nanomaterials and their application in assembling advanced supercapacitors with high energy density and superior working stability. Finally, based on existing research and our experimental experience, a perspective for directing future research has been presented concerning material synthesis and electrochemical application of graphitic carbon nitride.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 5","pages":"585-602"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.87","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50138157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Triple kill: Fabrication of composites coming from waste face masks, polystyrene microplastics, graphene, and their electromagnetic interference shielding behaviors 三杀：由废弃口罩、聚苯乙烯微塑料、石墨烯制成的复合材料及其电磁干扰屏蔽行为

Carbon Neutralization Pub Date : 2023-09-18 DOI: 10.1002/cnl2.86

Meng Xiang, Wangxi Fan, Wei Lin, Shilong Zhou, Fengman Li, Zhou Yang, Shuang Dong

{"title":"Triple kill: Fabrication of composites coming from waste face masks, polystyrene microplastics, graphene, and their electromagnetic interference shielding behaviors","authors":"Meng Xiang, Wangxi Fan, Wei Lin, Shilong Zhou, Fengman Li, Zhou Yang, Shuang Dong","doi":"10.1002/cnl2.86","DOIUrl":"https://doi.org/10.1002/cnl2.86","url":null,"abstract":"Conducting polymer composites possessing excellent electromagnetic interference shielding effectiveness (EMI SE) are effective methods to prevent the harm caused by electromagnetic pollution. Since COVID-19 in 2019, people have made a lot of progress in the recycling of waste face masks (FMs). Besides, effective measures are needed to reduce the harm of microplastics (MPs) pollution in the water environment. However, so far, no publications are available in the literature that simultaneously solve the problem of electromagnetic pollution, FM pollution, and MP pollution. Herein, FMs, polystyrene MPs (PS MPs), and graphene (Gr) were used to fabricate EMI shielding composites with isolated conductive network structures via the adhesion of polydopamine (PDA). The effects of isolated conductive networks, different sizes of PS MPs, and different layers of FMs on the adsorption properties of FMs-PDA-Gr, as well as electrical performance for the obtained polypropylene-PDA-Gr composites, were studied. The composites displayed EMI SE for 29.3 dB in X-band with 2 vol.% Gr content due to the isolated conductive network structure, which may be useful to the simultaneous elimination of garbage from electromagnetic pollution, FMs pollution, and MPs pollution to a certain degree.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 5","pages":"616-628"},"PeriodicalIF":0.0,"publicationDate":"2023-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.86","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50152160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cathode materials for calcium-ion batteries: Current status and prospects 钙离子电池正极材料的现状与展望

Carbon Neutralization Pub Date : 2023-08-27 DOI: 10.1002/cnl2.85

Yuhan Wu, Ziqi Zhao, Xiaorui Hao, Rui Xu, Laishi Li, Dan Lv, Xianglong Huang, Qing Zhao, Yang Xu, Yusheng Wu

{"title":"Cathode materials for calcium-ion batteries: Current status and prospects","authors":"Yuhan Wu, Ziqi Zhao, Xiaorui Hao, Rui Xu, Laishi Li, Dan Lv, Xianglong Huang, Qing Zhao, Yang Xu, Yusheng Wu","doi":"10.1002/cnl2.85","DOIUrl":"https://doi.org/10.1002/cnl2.85","url":null,"abstract":"In the post-lithium-ion battery era, calcium-ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of electrode materials. The large ionic radius of Ca2+ especially increases the challenge to design cathode materials for reversible Ca2+ uptake/removal. Despite the inspiring achievements, various challenges still need to be further resolved. Here, this review systematically summarizes the recent advances in CIB cathode materials, including Prussian blue and its analogues, metal oxides, metal chalcogenides, polyanionic compounds, and organic materials. We first provide a brief introduction to CIBs and compare their advantages with other battery technologies. Then, preparation methods are introduced, and breakthrough investigations are highlighted. Finally, some possible research directions are discussed to promote the development of this emerging battery technology.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 5","pages":"551-573"},"PeriodicalIF":0.0,"publicationDate":"2023-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.85","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50121918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Review of carbon dioxide mineralization of magnesium-containing materials 含镁材料的二氧化碳矿化研究进展

Carbon Neutralization Pub Date : 2023-08-23 DOI: 10.1002/cnl2.80

Jia Li, Mingzhi Luo, Kun Wang, Gaomiao Li, Guoquan Zhang

{"title":"Review of carbon dioxide mineralization of magnesium-containing materials","authors":"Jia Li, Mingzhi Luo, Kun Wang, Gaomiao Li, Guoquan Zhang","doi":"10.1002/cnl2.80","DOIUrl":"https://doi.org/10.1002/cnl2.80","url":null,"abstract":"The increasing utilization of fossil fuels and industrial activities has resulted in a surge of CO2 emissions, which have significantly impacted global climate change. Carbon capture and utilization technologies offer a promising solution to decrease atmospheric CO2 concentrations and convert CO2 into valuable products. This study focuses on the capture and storage of CO2 through the mineralization of magnesium-containing materials. The analysis encompasses the mineralization process of solid and liquid minerals, the various mineralization processes of magnesium-containing minerals categorized as direct and indirect mineralization, and the latest research advancements in magnesium-containing minerals. Brine and seawater from salt lakes are considered the most appropriate materials for mineralization due to their abundance and the simplicity of the process compared to solid mineralization. This paper analyzes the impact of temperature, impurity ions, additives, and microorganisms on the process of magnesium carbonate synthesis crystallization. The use of magnesium-containing materials for carbon dioxide sequestration can effectively reduce carbon emission. The review offers guidance on carbon dioxide mineralization and explores the potential applications of magnesium mineralization.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"2 5","pages":"574-584"},"PeriodicalIF":0.0,"publicationDate":"2023-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.80","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50141333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0