Advances in Molecular Relaxation Processes最新文献_第7页

Dynamics of small molecule-micelle interactions. A stopped-flow investigation of the kinetics of absorption of acridine (and related) dyes into anionic 小分子-胶束相互作用动力学。吖啶(及相关)染料进入阴离子吸收动力学的停流研究

Advances in Molecular Relaxation Processes Pub Date : 1975-12-01 DOI: 10.1016/0001-8716(75)80033-2

Brian H. Robinson, Neal C. White, Cecilia Mateo

引用次数: 29

CNDO/2 Molecular orbital studies on π hydrogen bonding CNDO/2分子轨道对π氢键的研究

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80029-0

A.S.N. Murthy, G.R. Saini, Kamla Devi, S.B. Shah

引用次数: 4

Correlation analysis of experimental permittivity data 实验介电常数数据的相关分析

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80022-8

K. Giese

引用次数: 0

Structure des associations nitrile—phénol: étude expérimentale et théorique 丁腈-酚结合的结构:实验和理论研究

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80023-X

M.-I. Baraton, S. Besnaïnou

引用次数: 3

Dielectric relaxation of short-chain alkyl bromides 短链烷基溴的介电弛豫

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80028-9

Martin S. Beevers, Graham Williams

引用次数: 9

Dielectric absorption of liquid normal alkanes in the microwave and far infrared regions 液体正构烷烃在微波和远红外区的介电吸收

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80025-3

Ulrich Stumper

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引用次数: 23

Spectroscopie de vibration des dihydrates des acides complexes HSbCl6, HGaCl4, HGaBr4 étude d'ions H5O2+ peu engagés HSbCl6, HGaCl4, HGaBr4配合酸二水合物的振动光谱研究H5O2+离子

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80024-1

G. Picotin, J. Roziere, J. Potier, A. Potier

引用次数: 21

Un exemple de relaxation nucléaire controlée par un échange chimique: la solvatation du cation Mn2+ dans le diméthylsulfoxyde par RMN du proton 由化学交换控制的核松弛的一个例子:质子核磁共振在二甲基亚砜中溶解Mn2+阳离子

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80026-5

Jean-Claude Boubel, Jean-Jacques Delpuech

{"title":"Un exemple de relaxation nucléaire controlée par un échange chimique: la solvatation du cation Mn2+ dans le diméthylsulfoxyde par RMN du proton","authors":"Jean-Claude Boubel, Jean-Jacques Delpuech","doi":"10.1016/0001-8716(75)80026-5","DOIUrl":"10.1016/0001-8716(75)80026-5","url":null,"abstract":"<div>Proton relaxation times of dimethylsulfoxide containing 10−2–10−1 M manganese (II) perchlorate are measured at two frequencies, 8 and 60 MHz, and sixteen temperatures (20–165 °C). These data allow us to compute: the contact shift ΔωM = 748 ± 13 Hz (25 °C and 60 MHz); the hyperfine coupling constant; the kinetic parameters for the exchange: bound DMSO <figure><img></figure> bulk DMSO: kM = (6.3 ± 2.3) × 106 s−1; ΔH≠ = 7.4 ± 0.5 kcal mol−1; ΔS≠ = −2.4 ± 0.5 u.e (25 °C), the rotational correlation time: τC = (9.65 ± 0.63) × 10−11 s and the distance between protons and Mn2+ cation: r = 4.37 ± 0.05 Å (25 °C); the electronic relaxation time: 1/T1e = (5.0 ± 1.0) × 107 s−1. These results describe the geometry and mobility of the first solvation shell and are compared with other examples from the literature.</div>","PeriodicalId":100050,"journal":{"name":"Advances in Molecular Relaxation Processes","volume":"7 3","pages":"Pages 209-220"},"PeriodicalIF":0.0,"publicationDate":"1975-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0001-8716(75)80026-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79294509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 6

Influence of dipole inclination to principal axes on molecular relaxation time 偶极子主轴倾角对分子弛豫时间的影响

Advances in Molecular Relaxation Processes Pub Date : 1975-10-01 DOI: 10.1016/0001-8716(75)80027-7

B.J. Cooke, S. Walker

引用次数: 2

Electron spin relaxation studies of spin—phonon interactions in sodium and potassium metals 钠和钾金属中自旋声子相互作用的电子自旋弛豫研究

Advances in Molecular Relaxation Processes Pub Date : 1975-08-01 DOI: 10.1016/0001-8716(75)80016-2

Ron Catterall, Peter P. Edwards

引用次数: 6