{"title":"HSbCl6, HGaCl4, HGaBr4配合酸二水合物的振动光谱研究H5O2+离子","authors":"G. Picotin, J. Roziere, J. Potier, A. Potier","doi":"10.1016/0001-8716(75)80024-1","DOIUrl":null,"url":null,"abstract":"<div><p>These dihydrates are halogenometallates of dioxonium. Their infrared and Raman spectra show that the central hydrogen bond is short and centered with a single minimum (isotopic effect). δ and γ OH vibration of that bond are very close, showing a very weak interaction with terminal H<sub>2</sub>O groups. Furthermore, terminal <em>v</em>OH show that H<sub>5</sub>O<sub>2</sub><sup>+</sup> is quite free, with a greater liberty in the hexachloroantimonate.</p></div>","PeriodicalId":100050,"journal":{"name":"Advances in Molecular Relaxation Processes","volume":"7 3","pages":"Pages 177-188"},"PeriodicalIF":0.0000,"publicationDate":"1975-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0001-8716(75)80024-1","citationCount":"21","resultStr":"{\"title\":\"Spectroscopie de vibration des dihydrates des acides complexes HSbCl6, HGaCl4, HGaBr4 étude d'ions H5O2+ peu engagés\",\"authors\":\"G. Picotin, J. Roziere, J. Potier, A. Potier\",\"doi\":\"10.1016/0001-8716(75)80024-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>These dihydrates are halogenometallates of dioxonium. Their infrared and Raman spectra show that the central hydrogen bond is short and centered with a single minimum (isotopic effect). δ and γ OH vibration of that bond are very close, showing a very weak interaction with terminal H<sub>2</sub>O groups. Furthermore, terminal <em>v</em>OH show that H<sub>5</sub>O<sub>2</sub><sup>+</sup> is quite free, with a greater liberty in the hexachloroantimonate.</p></div>\",\"PeriodicalId\":100050,\"journal\":{\"name\":\"Advances in Molecular Relaxation Processes\",\"volume\":\"7 3\",\"pages\":\"Pages 177-188\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1975-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0001-8716(75)80024-1\",\"citationCount\":\"21\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Molecular Relaxation Processes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0001871675800241\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0001871675800241","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Spectroscopie de vibration des dihydrates des acides complexes HSbCl6, HGaCl4, HGaBr4 étude d'ions H5O2+ peu engagés
These dihydrates are halogenometallates of dioxonium. Their infrared and Raman spectra show that the central hydrogen bond is short and centered with a single minimum (isotopic effect). δ and γ OH vibration of that bond are very close, showing a very weak interaction with terminal H2O groups. Furthermore, terminal vOH show that H5O2+ is quite free, with a greater liberty in the hexachloroantimonate.
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