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Chimica Techno Acta最新文献

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Electrochemical creatinine determination with metal-organic framework catalyst based on copper and acetylenedicarboxylic acid 基于铜和乙炔二羧酸的金属-有机骨架催化剂电化学测定肌酸酐
Chimica Techno Acta Pub Date : 2023-03-29 DOI: 10.15826/chimtech.2023.10.2.01
Andrei Viktorovich Okhokhonin, Alsu A. Ibatullina, Yulia V. Izmozherova, Marina I. Stepanova, Anatoliy I. Matern, A. Kozitsina
{"title":"Electrochemical creatinine determination with metal-organic framework catalyst based on copper and acetylenedicarboxylic acid","authors":"Andrei Viktorovich Okhokhonin, Alsu A. Ibatullina, Yulia V. Izmozherova, Marina I. Stepanova, Anatoliy I. Matern, A. Kozitsina","doi":"10.15826/chimtech.2023.10.2.01","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.2.01","url":null,"abstract":"Fast and accurate determination of creatinine is critical in kidney function diagnostics. This paper discusses the usage of the metal-organic framework based on copper(II) and acetylenedicarboxylic acid (CuADCA) as a catalyst of electrochemical oxidation of creatinine, glucose and urea. CuADCA was synthesized by deprotonation with triethylamine for the first time. Successful synthesis was confirmed by FTIR and EDS. The material was characterized by SEM, EIS, and CV. CuADCA forms laminated-like flakes with diameter from 1 µm to 20 µm, which is consistent with the polymer-like structure. CV and EIS analyses showed that CuADCA immobilized on GCE acts as a catalyst in electrooxidation reaction of glucose, urea, and creatinine. The sensitivity of creatinine detection, 1057±99 µA/mM, was higher than the detection sensitivity of glucose and urea by more than 100 times with the limit of detection of 2 µM, so CuADCA is a promising material for further development of enzymeless sensors for creatinine.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49646370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An overview of wastewater treatment using combined heterogeneous photocatalysis and membrane distillation 多相光催化与膜蒸馏联合处理废水的研究进展
Chimica Techno Acta Pub Date : 2023-03-22 DOI: 10.15826/chimtech.2023.10.1.14
Sarah A. Abdulrahman, Salah S. Ibraheem, Z. Shnain
{"title":"An overview of wastewater treatment using combined heterogeneous photocatalysis and membrane distillation","authors":"Sarah A. Abdulrahman, Salah S. Ibraheem, Z. Shnain","doi":"10.15826/chimtech.2023.10.1.14","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.14","url":null,"abstract":"The need for efficient remediation solutions to wastewater has risen due to the concerning prevalence of toxic organic pollutants. It is possible for the linked photocatalysis-membrane separation system to concurrently achieve the photoreaction of pollutants and their removal from wastewater in order to accomplish the goal of completely purifying the wastewater. This investigation's objective is to provide analytical overview of the photocatalytic and membrane coupling process, photocatalytic membrane reactors, and the potential applications of these technologies in the treatment of wastewater for the persistent organic matter removal. In the review, an examination of photocatalytic and membrane processes to remove organic compounds from wastewater is presented. Based on the literature analysis, it was observed that the application of photocatalytic membrane reactors is significantly influenced by a wide variety of factors. Some of these factors include pollutant concentration, dissolved oxygen, aeration, pH, and hydraulic retention time. Light intensity is another factor that has a significant influence. It was also revealed how distillation membranes work when integrated with photocatalytic process. This brief overview will help researchers understand how successful coupled photocatalytic and membrane distillation are in the treatment of wastewater containing organic pollutants.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48745195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The oligosuccinimide and modified polysuccinimide as green corrosion and scale inhibitors 低聚琥珀酰亚胺和改性聚琥珀酰亚胺作为绿色缓蚀剂和阻垢剂
Chimica Techno Acta Pub Date : 2023-03-17 DOI: 10.15826/chimtech.2023.10.1.12
M. J. Baari
{"title":"The oligosuccinimide and modified polysuccinimide as green corrosion and scale inhibitors","authors":"M. J. Baari","doi":"10.15826/chimtech.2023.10.1.12","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.12","url":null,"abstract":"Corrosion and scale formation are crucial issues in the petroleum industry. They can inflict metal or other materials breakdown, leading to environmental pollution. Applying scale and corrosion inhibitors is a cost-effective and efficient way of controlling corrosion and scale formation in a fluid system. Much research has been conducted to obtain cheap and safe corrosion or scale inhibitors. Modified polysuccinimides (PSI) are among the organic compounds reported as effective and environmentally friendly corrosion as well as scale inhibitors. The use of various novel green corrosion and scale inhibitors from modified PSI for controlling corrosion reactions or scale formation has not been extensively reviewed. Hence, this review highlights recent studies on preparing PSI/OSI, modifying PSI, and analyzing their performance as corrosion and scale inhibitors. Adsorption study, biodegradation performance, computational quantum study, limitations, and prospects of the inhibitors are also discussed. Therefore, i this work provides an overview of novel modified PSI as effective and safe corrosion or scale inhibitors in different media, for various metals, and on a different scale.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44751151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Sn doping on sinterability and electrical conductivity of strontium hafnate 锡掺杂对铪酸锶烧结性能和导电性的影响
Chimica Techno Acta Pub Date : 2023-03-17 DOI: 10.15826/chimtech.2023.10.1.13
A. Khaliullina, A. Meshcherskikh, L. Dunyushkina
{"title":"Effect of Sn doping on sinterability and electrical conductivity of strontium hafnate","authors":"A. Khaliullina, A. Meshcherskikh, L. Dunyushkina","doi":"10.15826/chimtech.2023.10.1.13","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.13","url":null,"abstract":"The effect of isovalent substitution of hafnium by tin in strontium hafnate on sinterability and electrical conductivity was studied for the first time. The ceramic samples SrHfxSn1–xO3–δ (x = 0–0.16) were synthesized by solid-state reaction and sintered at 1600 °C for 5 h. The samples were examined using the methods of X-ray diffraction, scanning electron microscopy, impedance spectroscopy, and four-probe direct current technique. It was shown that all samples were phase pure and had the orthorhombic structure of SrHfO3 with the Pnma space group. Sn doping resulted in an increase in grain size, relative density and conductivity; the sample with x = 0.08 demonstrated the highest conductivity, which was ~830 times greater than that of undoped strontium hafnate at 600 °C. The conductivity of SrHf0.92Sn0.08O3–δ was 4.1∙10–6 S cm–1 at 800 °C in dry air. The possible reasons for the effect of Sn on the electrical properties of strontium hafnate were discussed.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44033097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The crystallization of thin Sb2Te films with vacuum annealing and an electron beam 用真空退火和电子束制备Sb2Te薄膜
Chimica Techno Acta Pub Date : 2023-03-03 DOI: 10.15826/chimtech.2023.10.1.11
A. A. Yushkov, V. Kolosov
{"title":"The crystallization of thin Sb2Te films with vacuum annealing and an electron beam","authors":"A. A. Yushkov, V. Kolosov","doi":"10.15826/chimtech.2023.10.1.11","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.11","url":null,"abstract":"Thin Sb2Te films with a thickness gradient were studied via transmission electron microscopy. The processes of forced crystallization were examined with thermal annealing and an electron beam. The crystallization’s general tendencies, including competitive nucleation and growth crystallization, were revealed. As the thickness of the sample increases, the size of the crystals growing in the film enlarges. As the temperature increases, the number of crystals in the film grows. Crystallization under the action of an electron beam occurs mainly by nucleation mechanism.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46694473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, computational study, solvatochromism and biological studies of thiazole-owing hydrazone derivatives 噻唑类腙衍生物的合成、计算、溶剂化变色及生物学研究
Chimica Techno Acta Pub Date : 2023-02-20 DOI: 10.15826/chimtech.2023.10.1.10
C. K. Yadav, B. Nandeshwarappa, K. Mussuvir Pasha
{"title":"Synthesis, computational study, solvatochromism and biological studies of thiazole-owing hydrazone derivatives","authors":"C. K. Yadav, B. Nandeshwarappa, K. Mussuvir Pasha","doi":"10.15826/chimtech.2023.10.1.10","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.10","url":null,"abstract":"In the present work, we have synthesized thiazole-hydrazone conjugates 5(a–h) and characterized them using various analytical techniques such as UV, IR, NMR, and mass spectrometry. Solvatochromic properties were evaluated in ten solvents with different polarity and quantum chemical parameters using a DFT study. The antibacterial activity results revealed that compounds 5c, 5d and 5g exhibited good efficacy and that the remaining compounds displayed significant activity. The synthesized compounds were screened for their cytotoxic activity against HepG2 and MCF-7 cell lines, and all the synthesized compounds exhibited significant potency towards the screened cancer cell lines. The anti-inflammatory efficacy of the synthesized thiazole derivatives was determined against MMP-2 and MMP-9, and some of the compounds showed significant activity. Furthermore, the in silico molecular docking was performed with the COX-2 receptor.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44956532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electrochemical detection of simple alkanes by utilizing a solid-state zirconia-based gas sensor 利用固态氧化锆基气体传感器电化学检测烷烃
Chimica Techno Acta Pub Date : 2023-02-14 DOI: 10.15826/chimtech.2023.10.1.09
A. Kalyakin, A. Volkov
{"title":"Electrochemical detection of simple alkanes by utilizing a solid-state zirconia-based gas sensor","authors":"A. Kalyakin, A. Volkov","doi":"10.15826/chimtech.2023.10.1.09","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.09","url":null,"abstract":"Solid-state gas sensors composed of complex oxide electrolytes offer great potential for analyzing various atmospheres at high temperatures. While relatively simple gas mixtures (H2O+N2, O2+N2) have been successfully studied by means of ZrO2-based sensors, the precise detection of more complex compounds represents a challenging task. In this work, we present our findings regarding the analysis of lower alkanes (CH4, C2H6, and C3H8) mixed with nitrogen as an inert gas, utilizing an amperometric ZrO2-based sensor. This sensor, serving as an electrochemical cell with a diffusion barrier, was tested at 500–600 °C to measure the limiting current, which depends on the gas composition and can be further used as a basis for calibration curves. In addition, the diffusion coefficients of the specified gas mixtures were successfully found and compared with references, confirming the applicability of the fabricated sensor for studying diffusion processes in wide concentration and temperature ranges.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44405936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical response of SrTiO3 thin films grown via a sol-gel-hydrothermal method 溶胶-凝胶-水热法制备SrTiO3薄膜的光学响应
Chimica Techno Acta Pub Date : 2023-01-23 DOI: 10.15826/chimtech.2023.10.1.08
Y. E. Putri, Tio Putra Wendari, Restu Aulia Arham, Melvi Muharmi, Dedi Satria, Rahmayeni Rahmayeni, D. V. Wellia
{"title":"Optical response of SrTiO3 thin films grown via a sol-gel-hydrothermal method","authors":"Y. E. Putri, Tio Putra Wendari, Restu Aulia Arham, Melvi Muharmi, Dedi Satria, Rahmayeni Rahmayeni, D. V. Wellia","doi":"10.15826/chimtech.2023.10.1.08","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.08","url":null,"abstract":"The polycrystalline SrTiO3 thin films were prepared by the sol-gel-hydrothermal method on glass substrates. The synthesis pathway was initiated by preparing a clear TiO2 solution using the sol-gel method. This clear solution was then deposited on a glass substrate using the dip coating technique, followed by the transformation of a thin layer of TiO2 into SrTiO3 by the hydrothermal method. The crystal structure, bond interactions, and band gap energy of SrTiO3 thin layers were characterized using X-ray Diffraction (XRD), Fourier Transform Infra-Red spectroscopy (FTIR), and UV–Vis Diffuse Reflectance Spectroscopy (UV-DRS). The XRD patterns of all SrTiO3 thin layers indicated the perovskite structure of the samples. The FTIR spectrum showed an interaction of the silanol groups on the surface of the glass substrate with Ti–O–Ti of SrTiO3 layers. The characteristics of the UV-DRS spectrum were influenced by the thickness of the SrTiO3 layer formed on the glass substrate. The findings of this work provide insights for producing SrTiO3 layers with specified thickness and morphology.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46886488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Membrane techniques for removal detergents and petroleum products from carwash effluents: a review 膜技术去除汽车洗涤废水中的洗涤剂和石油产品的研究进展
Chimica Techno Acta Pub Date : 2023-01-11 DOI: 10.15826/chimtech.2023.10.1.07
E. Awad, S. M. Abdulla, T. M. Sabirova, Q. Alsalhy
{"title":"Membrane techniques for removal detergents and petroleum products from carwash effluents: a review","authors":"E. Awad, S. M. Abdulla, T. M. Sabirova, Q. Alsalhy","doi":"10.15826/chimtech.2023.10.1.07","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.07","url":null,"abstract":"One of the most significant urban services is the carwash, which generates large amounts of wastewater containing a variety of pollutants, including sand, gravel, suspended solids, surfactants, oil products, diesel cleaners, etc., that may cause environmental pollution when transferred to the sewage system without any treatment. The effective treatment is crucial to prevent environmental pollution as well as to recycle the water source. Contaminants are removed from carwash effluent using a variety of treatment technologies. This review focuses on identifying and comparing efficiency of using advanced commercial and modified membrane filtration techniques, meeting discharge standard regulations, to treat carwash impurities, especially detergents/surfactants (anionic surfactant) and petroleum products (oil/grease). The results of this review indicate that ultrafiltration membrane (UF) is the most common membrane filtration technology for carwash wastewater treatment. Additionally, the adoption of traditional pre-treatment processes may be advantageous before utilization of membrane process for treating carwash wastewater; although conventional treatment processes can produce a high quality of effluent, they are less effective than membrane systems.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41585519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
2-(4-Oxo-1,3-thiazolidin-2-ylidene)acetamid as promising scaffold for designing new antifungal compounds 2-(4-氧基-1,3-噻唑烷-2-酰基)乙酰酰胺是设计新型抗真菌化合物的有前途的支架
Chimica Techno Acta Pub Date : 2022-12-29 DOI: 10.15826/chimtech.2023.10.1.06
K. Obydennov, T. Kalinina, D. Ryabova, M. Kosterina, T. Glukhareva
{"title":"2-(4-Oxo-1,3-thiazolidin-2-ylidene)acetamid as promising scaffold for designing new antifungal compounds","authors":"K. Obydennov, T. Kalinina, D. Ryabova, M. Kosterina, T. Glukhareva","doi":"10.15826/chimtech.2023.10.1.06","DOIUrl":"https://doi.org/10.15826/chimtech.2023.10.1.06","url":null,"abstract":"1,3-Thiazolidin-4-one derivatives with a exocyclic C=C double bond in position 2 of the hetero ring have a wide spectrum of biological activity, but their fungicidal activity has not been studied as much as it should be. This paper presents a simple and convenient approach for obtaining potential antifungal agents based on 2-(4-oxo-1,3-thiazolidin-2-ylidene)acetamides. The first examples of evaluating the fungicidal activity of 8 obtained compounds on 8 strains of phytopathogenic fungi are presented. A highly active compound 4e with EC50 of 0.85 and 2.29 µg/mL against A. solani and P. lingam, respectively, was found to be promising for further study.","PeriodicalId":9964,"journal":{"name":"Chimica Techno Acta","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67255667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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