Bulletin of Chemical Reaction Engineering & Catalysis最新文献

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Xylene Isomerization using Hierarchically Mesoporous ZSM-5 分级介孔ZSM-5的二甲苯异构化
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-08-30 DOI: 10.9767/bcrec.19270
Ahmed El Fadaly, M. A. Sayed, Ahmed O. Abo El Naga, Mohamed El Saied, Seham Ali Shaban, Fouad I. Elhosiny
{"title":"Xylene Isomerization using Hierarchically Mesoporous ZSM-5","authors":"Ahmed El Fadaly, M. A. Sayed, Ahmed O. Abo El Naga, Mohamed El Saied, Seham Ali Shaban, Fouad I. Elhosiny","doi":"10.9767/bcrec.19270","DOIUrl":"https://doi.org/10.9767/bcrec.19270","url":null,"abstract":"The current study described the synthesis of H-ZSM-5 zeolites with hierarchical micro-meso- porosity (HM-ZSM-5-x) via the soft-templating route, employing organosilane surfactant, 3-[(trimethoxysilyl) propyl]octyldimethyl-ammonium chloride, as the mesoporous template. The catalytic performance was examined in the isomerization of o-xylene in a fixed-bed reactor at atmospheric pressure. Many techniques were conducted to characterize the catalysts. The X-ray diffraction (XRD) and Fourier Transform Infra Red (FTIR) results affirmed that all mesoporous zeolites possess the characteristic MFI structure, as well as good crystallinity. The N2 physisorption measurements signified that all HM-ZSM-5-x samples have higher surface areas and pore volumes than the micro-ZSM-5 sample, with the mesopores accounting for the vast majority of the total surface areas and pore volumes of HM-ZSM-5-x samples. Moreover, the mesoporosity of the obtained HM-ZSM-5-x zeolites can be simply tuned via the variation of the amount of TPOAC used. Compared with classical micro-ZSM-5, the HM-ZSM-5-0.15 sample possessed a higher o-xylene conversion and p-xylene yield that was attributed to its remarkable textural characteristics in terms of higher surface area and prevailing mesoporous character that led to a reduced diffusion limitation. Importantly, the catalyst manifested superb operational stability within 50 h, indicating high resistance against deactivation through coke deposition. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136239657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Backmatter (Publication Ethics, Copyright Transfer Agreement for Publishing Form) Backmatter(出版道德、版权转让协议出版表格)
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-08-20 DOI: 10.9767/bcrec.19842
Istadi Istadi
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引用次数: 0
Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents) 封面(封面、编辑团队、索引、目录)
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-08-20 DOI: 10.9767/bcrec.19873
Istadi Istadi
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引用次数: 0
Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands 6-苯基吡啶-2-羧酸- 4,4′-联吡啶配体新型Gd(III)配位聚合物的合成、结构表征及光催化CO2还原活性
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-08-09 DOI: 10.9767/bcrec.19540
Xi-Shi Tai, Yuan-Fang Wang, Li-Hua Wang, Xi-Hai Yan
{"title":"Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands","authors":"Xi-Shi Tai, Yuan-Fang Wang, Li-Hua Wang, Xi-Hai Yan","doi":"10.9767/bcrec.19540","DOIUrl":"https://doi.org/10.9767/bcrec.19540","url":null,"abstract":"A new Gd(III) coordination polymer, {[Gd(L1)3(H2O)2]∙L2}n (1) (HL1 = 6-phenylpyridine-2-carboxylic acid, L2 = 4,4’-bipyridine) was synthesized using 6-phenylpyridine-2-carboxylic acid, 4,4’-bipyridine, NaOH and GdCl3∙6H2O. The structure of Gd(III) coordination polymer has been characterized by IR and X-ray single crystal diffraction. The result of single crystal analysis indicates that fundamental unit of Gd(III) coordination polymer contains one Gd(III) ion, three L1 ligands, two coordinated water molecules and one uncoordinated 4,4’-bipyridine. In 1, the Gd(III) ion is eight-coordinated and surrounded by six O atoms from three L1 ligands and two O atoms from two coordinated water molecules, respectively. The complex 1 exhibits 1D chained structure by the bridging interactions of two carboxyl-oxygen atoms and O−H∙∙∙N hydrogen bonds interactions. The 1D chains are further connected by - stacking interactions to form 3D network architecture. The photocatalytic CO2 reduction activity of complex 1 has also been investigated. The complex 1 exhibits good CO2 reduction activity. With the increase of time, the yield of CO from 18.2 mmol/g in the first hour to 60.3 mmol/g in the third hour. And the CO selectivity has reached 100%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135698576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Backmatter (Publication Ethics, Copyright Transfer Agreement for Publishing Form) Backmatter(出版道德、版权转让协议出版表格)
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-04-30 DOI: 10.9767/bcrec.18018
Istadi Istadi
{"title":"Backmatter (Publication Ethics, Copyright Transfer Agreement for Publishing Form)","authors":"Istadi Istadi","doi":"10.9767/bcrec.18018","DOIUrl":"https://doi.org/10.9767/bcrec.18018","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135563931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents) 封面(封面、编辑团队、索引、目录)
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2023-04-30 DOI: 10.9767/bcrec.18017
Istadi Istadi
{"title":"Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents)","authors":"Istadi Istadi","doi":"10.9767/bcrec.18017","DOIUrl":"https://doi.org/10.9767/bcrec.18017","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"222 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135563930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4. Engineering technology 4. 工程技术
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2020-02-10 DOI: 10.1515/9783110614435-004
{"title":"4. Engineering technology","authors":"","doi":"10.1515/9783110614435-004","DOIUrl":"https://doi.org/10.1515/9783110614435-004","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"102 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76889635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontmatter
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2020-02-10 DOI: 10.1515/9783110614435-fm
{"title":"Frontmatter","authors":"","doi":"10.1515/9783110614435-fm","DOIUrl":"https://doi.org/10.1515/9783110614435-fm","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89748757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preface to the first edition 第一版的序言
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2020-02-10 DOI: 10.1515/9783110614435-202
{"title":"Preface to the first edition","authors":"","doi":"10.1515/9783110614435-202","DOIUrl":"https://doi.org/10.1515/9783110614435-202","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"23 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73958853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Index 指数
Bulletin of Chemical Reaction Engineering & Catalysis Pub Date : 2020-02-10 DOI: 10.1515/9783110614435-007
{"title":"Index","authors":"","doi":"10.1515/9783110614435-007","DOIUrl":"https://doi.org/10.1515/9783110614435-007","url":null,"abstract":"","PeriodicalId":9329,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"44 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77053676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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