Baghdad Science Journal最新文献

{"title":"التحقق من مصدوقية طريقة تحليل S-phenyl mercapturic acid بالبول باستخدام الاستشراب السائل عالي الأداء مع كاشف الصمام الثنائي الضوئي","authors":"Mohammad Nour Albitar, Sophie Barguil","doi":"10.21123/bsj.2023.8107","DOIUrl":"https://doi.org/10.21123/bsj.2023.8107","url":null,"abstract":"تم تطوير وتوثيق مصدوقية طريقة تحليلية باستخدام جهاز الاستشراب السائل عالي الأداء HPLC تتمتع بالبساطة والانتقائية والدقة وذلك من أجل تعيين حمض س-فينيل ميركابتوريك. حُقّق الفصل الاستشرابي بواسطة استخدام عمود فصل من نوع (ODS-3 Inertsil) بأبعاد (5μ, 150 mm x 4.6 mm). وكانت درجة حرارة العمود 45 درجة مئوية. واستُخدم طور متحرك مؤلف من أسيتونتريل: ميتانول: ماء منزوع الشوارد محمض بحمض فوق الكلور (4/1/5 حجم/ حجم/حجمpH=3 ,) بمعدل جريان 1.5 مل/دقيقة واستخدام طول موجة مكشاف 225 نانومتر. أُجريت اختبارات ملاءمة النظام لتقييم مدى ملاءمة وفعالية النظام الاستشرابي بأكمله. حُسب زمن احتباس مادتي حمض س-فينيل ميركابتوريك وحمض البنزوئيك فقد وجدتا 17.3 و  15.6دقيقة، على التوالي، وأُجري التحقق من مصدوقية الطريقة المطورة من حيث الخطية والدقة والمضبوطية والنوعية وحد الكشف وحد التقدير الكمي. حيث كان حد الكشف: 126.0 مكغ/مل وحد التقدير الكمي: 0.38 مكغ/مل لمادة س-فينيل ميركابتوريك، وبمردود97.183% :. أظهرت المادة استجابة خطية ضمن المجال 0.5-20 مكغ/مل. تهدف هذه الدراسة إلى تطوير طريقة تحليلية باستخدام جهاز الاستشراب عالي الأداء والتحقق من مصدوقيتها، ويمكن استخدام الطريقة المقترحة لتقدير مستقلب البنزن هذا في البول كونها بسيطة ودقيقة وانتقائية.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"56 5","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Production of Biosynthesized Silver Nanoparticles using Metarhizium anisopliae fungus for the Treatment of Petroleum Pollutants in Water","authors":"M. Alnuaimi, Z. Aljanabi, Sarah Ibrahim Mahmood, Ula Farooq Ramzy","doi":"10.21123/bsj.2023.8577","DOIUrl":"https://doi.org/10.21123/bsj.2023.8577","url":null,"abstract":"In this study, a silver nanoparticle (AgNPs) was created using a biological technique from an extract of the fungus Metarhizium anisopliae. The characteristics of the prepared AgNPs were identified by utilizing the optical, ultraviolet, and infrared absorbance spectroscopy. The shape, size, and charge distribution on the particles were determined by using scanning electron microscopy and zeta voltage analysis. The analysis of biological activity of the silver nanoparticles showed its effectiveness in treating pollutants, as confirmed by the reduction of higher than 93% weight of crude oil in contaminated water samples. The crude oil mass was effectively transformed into the gelatinous mass that lacks consistency and emulsification. The chemical analysis of NP-treated and untreated crude oil- contaminated water samples was performed using gas chromatography mass spectrometry (GC MASS). The results displayed the emergence of 55 graphic peaks, each of them indicating a chemical compound, in the control sample, while in the study sample, about 51 of these peaks disappeared and the area of the remaining 4 peaks was reduced. The silver nanoparticles' capability to maintain their effectiveness under cryogenic storage conditions for six months was tested and compared to that of the fungal isolation before the production of the silver nanoparticles. The results showed no significant changes in the shape, size, and efficiency of the silver nanoparticles in the treatment of oil pollutants in water. The results indicated the higher efficiency of the silver nanoparticles, as compared to chemicals, in treating petroleum pollutants as well as enhancing the solubility, emulsification, and degradation of hydrocarbons.  In addition, the AgNPs are characterized by the availability of inexpensive, easy, fast to produce, and environmentally friendly production materials, as compared to the usage of chemical products that are highly toxic to aquatic organisms, expensive to produce, and highly accumulative in the ecosystem, i.e. environmentally unsafe.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139259997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A comparative study of preimplantation embryos development of young and aged mice treated with L-carnitine","authors":"Amjed T. Al-Rudaini, Saad S. Al-Dujaily, Lina A. Salih","doi":"10.21123/bsj.2023.8923","DOIUrl":"https://doi.org/10.21123/bsj.2023.8923","url":null,"abstract":"Female aging is one of the main factors influencing reproductive fertility. The existing experimental study was planned to investigate the L-carnitine (LC) treatment effect on the body weight of adult young 8–10 weeks old and aged 26–28 weeks old female mice and the preimplantation embryonic development of their embryos. This study involved 40 mature young (n=20) and aged (n=20) old female mice. The animals were weighed and divided into 4 groups according to their age (n = 10).  The control groups of young and aged mice groups were orally administered distilled water, while the young and aged mice that were treated orally with 10 mg/kg LC daily for 2-3 estrous cycles were considered as treated groups. Then, all female mice were mated with adult males. The weight of pregnant mice on 1-day post coitum was recorded and then euthanized to harvest early cleavage embryos. The embryo development was examined and evaluated their grading according to A, B, C and D. The results showed that the body weight of mice in both young LC and aged LC groups reduced significantly (P≤0.01). The grade A embryo in 1-day post coitum in young and aged LC groups improved significantly (P≤0.01). However, the development of embryos grade A in the young LC group was higher than that of the aged LC group. It was concluded from these findings that the oral supplementation of LC can reduce body weight and improve the preimplantation embryonic development proportions.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"36 4","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Characterization, Thermal Analysis Study and Antioxidant Activity for Some Metal Ions Cr (III), Fe (III), Mn (II) and Pd(II) Complexes with Azo Dye Derived from p-methyl-2-hydroxybenzaldehyde","authors":"Adhraa Ghazi Abdulrazzaq, A. A. Al-Hamdani","doi":"10.21123/bsj.2023.8188","DOIUrl":"https://doi.org/10.21123/bsj.2023.8188","url":null,"abstract":"A new Azo Dye ligand HL was 4-((3-formyl-2-hydroxyphenyl)diazenyl)-N-(5-methylisoxazol-3-yl)benzenesulfonamide,this synthesized ligand was used for complexation with different metal ions like Cr(III), Fe(III), Mn(II) and Pd(II) by using a molar ratio of ligand: metalas 1:1. Resulted compounds were characterized by NMR (1H and 13C), UV–vis spectroscopy, TGA, DSC, FT‐IR, MS, elemental analysis, magnetic moment and molar conductivity studies. The results showed that the geometrical structural were octahedral geometries for the Cr(III), Mn(II) and Fe(III) complexes, square planer for Pd(II) complex. The antioxidant activities of the prepared compounds were assessed by using 1.1‐diphenyl‐2‐picrylhydrazyl as the free radical, and the results showed that the complex azo dye were found to possess potent antioxidant activity. The structure–activity relationship of the ligand and its complexes indicates that the presence of electron‐donating moieties, such as Cr(III), Mn(II) and Fe(III), in the chemical structure increases the antioxidant activity, whereas the Pd(II) complexes diminished the antioxidant activity, indicating the superior activity of the hydroxyl radical (OH·) over the superoxide radical.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"6 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green Synthesis and Evaluation of ZnO NPs and study the effect of Their toxic on Honey Bee (Apis mellifera)","authors":"Ayoub Sabir Karim, Fuad Othman Abdullah, Najat Zaid Mohammad Mohammad","doi":"10.21123/bsj.2023.8664","DOIUrl":"https://doi.org/10.21123/bsj.2023.8664","url":null,"abstract":"The research interest in nanomaterials preparation from natural products as a green method and their application in various fields applications, tremendous attention has been taken to the green composition of nanoparticles. ZnO can be considered one of the most widely used metal oxides for most requirements of daily used products. In this research ZnO NPs prepared by using Petroselinum crispum (parsley) extract and to make the first study of toxicological evaluation of ZnO NPs their effect aspects on Honey bees (Apis mellifera). ZnO NPs have been charactarized by using SEM, EDX, XRD, UV-Vis and FTIR Spectroscopy. The toxicological evaluation of ZnO NPs has been applied to a honey bee. The lethal ZnO concentration was obtained, and the LC50 range calculation values ​​were changed during 288 hours of feeding to ZnO nanoparticles at different concentrations (25, 50, 250, 500 mg per 100 ml) and the obtained LC50 values changed from 275, decreasing to 162.55 for the research range times after every 24 hours of exposure feeding calculations. In addition, for the group treated with 500 mg of ZnO per 100 ml, higher mortality was observed compared to other concentrations as it increased more than all other items indicating the above concentrations but not with the control group. The ergonomic design for creating a honey bee shelter was first introduced and no similar investigations were found in the literature.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"20 4","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Multi-Objective Facility Coverage Location Problem for Emergency Medical Service Decisions in Hajj","authors":"H. Naji, Mohanad Al-Behadili, Mohammad Sari Kadim","doi":"10.21123/bsj.2023.8737","DOIUrl":"https://doi.org/10.21123/bsj.2023.8737","url":null,"abstract":"This paper proposes a multi-objective facility model of coverage location problem to determine the number, locations, and redeployments of Emergency Medical Services (EMS) system. The EMS runs with two types of ambulances, Basic Life Support (BLS) and Advance Life Support (ALS). The suggested Multi-objective Coverage Location model (MO-CL) considers a bi-objective function, which is minimizing the EMS costs and the fatigue of EMS crew members. This can be managed by reducing the number of redeployments for both types of ambulances while still providing the required coverage levels. The MO-CL model is based on the approximation hypercube model that eliminates the assumptions of autonomous ambulance operation and system-wide busy probability. It can be solved by applying a modified MO-CL search algorithm. The model and solution method have been applied for a case study based on real data collected from the Al Noor Specialist Hospital in Makkah, Saudi Arabia during the period of fifteen days of Hajj pilgrimage. The results showed that, to achieve the 95% coverage threshold of critical and non-critical demand, the MO-CL model needs at least 64 ambulances (29 ALS, 12 for BLS backups, and 23 for BLS) and 19 redeployments for every day (9 for ALS, 2 for BLS backup, and 8 for BLS).","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"47 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation Nonlinear Properties (First and Second Hyperpolarizabilities) of The Nitro-thieno [3,2-b] thiophene -fullerene (C20) Molecule","authors":"S. Resan, M. Al-Anber","doi":"10.21123/bsj.2023.8659","DOIUrl":"https://doi.org/10.21123/bsj.2023.8659","url":null,"abstract":"In this study, nonlinear optical (NLO) properties of nitro-thieno [3,2-b] thiophene-fullerene (C20) molecule was systematically investigated using density functional theory (DFT) methods at the B3LYP level with a 6-31 + G(d,p) basis set. Fullerene (electron-donor) is associated with thieno [3,2-b] thiophene (π-conjugated bridge), forming a charge-transfer framework, and nitro is a strong electron-acceptor. The dynamic properties of the molecule, including first and second hyperpolarizability, resulting from second harmonic generation β(-2ω; ω,ω), third harmonic generation γ(– 2ω; ω, ω, ω), Pockels effect β(-ω; ω,0), and Kerr effect γ(–ω; ω, 0, 0), were investigated, which are essential evaluation indexes for creating nonlinear materials. The molecule exhibits excellent nonlinear responses, where it was found that the highest linear response of the coefficients above at the wavelength 455.6 nm. Absorption spectra reveal that these molecules have infrared transparent regions and are novel nonlinear molecules. Therefore, linking nitro-thieno[3,2-b]thiophene with fullerene (C20) efficiently designs high-performance nonlinear molecules.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"11 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing Cloud Resource Management Based on Intelligent System","authors":"Manal Fadhil Younis","doi":"10.21123/bsj.2023.8507","DOIUrl":"https://doi.org/10.21123/bsj.2023.8507","url":null,"abstract":"Cloud computing is a significant technology model with the strongest potential to change the way IT activities are carried out. The cloud offers low-cost and scalable IT resources. Cloud providers strive to improve business outcomes so cloud systems become more complex. The intelligent cloud has a number of issues, including optimizing the cloud service and designing and distributing resources adaptively and economically. There is a rising trend toward adopting intelligent technologies to better cloud management in particular. This paper introduces an intelligent method to manage cloud resources without delay or trouble. Starting with designing a system based on a genetic algorithm (GA) as a computational tool to achieve the goal and plan a predictive request then depending on the round robin (RR) algorithm to allocate the requests for processing. To evaluate the performance of this method, the proposed algorithm was verified in 145 requests. Where the implementation system achieved a reasonable result.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"43 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139260668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"تأثير الانتقال الحراري والدوران على التدفق التمعجي لسائل سوتربي في قناة مائلة وغير متماثلة ذات مسامية","authors":"Asmaa A. Mohammed, Liqaa Zeki Hummady","doi":"10.21123/bsj.2023.8312","DOIUrl":"https://doi.org/10.21123/bsj.2023.8312","url":null,"abstract":"في هذا البحث تم دراسة تأثير متغير الدوران والمتغيرات الأخرى على التدفق التمعجي لسائل سوتربي في قناة غير متماثلة مائلة تحتوي على وسط مسامي مع انتقال الحرارة. في وجود الدوران، تم تطوير النمذجة الرياضية باستخدام المعادلات الاساسية القائمة على نموذج سائل سوتربي. في تحليل التدفق، يتم استخدام افتراضات مثل تقريب طول الموجة الطويلة وانخفاض عدد رينولدز. تم حل المعادلة التفاضلية الاعتيادية غير الخطية الناتجة تحليلياً باستخدام طريقة الاضطراب. يتم تحليل تأثيرات رقم كراشوف، ورقم هارتمان، ورقم رينولد، ورقم فرود، ومعلمة هال، ورقم دارسي، والمجال المغناطيسي، ومعلمة سائل سوتربي، وتحليل نقل الحرارة على وظيفة التدفق وتدرج الضغط بيانياً. باستخدام برنامج ماثيماتيكا، تم حساب النتائج العددية. تم اكتشاف أن حجم الفقاعات يتناقص مع زيادة بعض المعلمات ، بينما يتناسب تدرج الضغط تناسب طردي مع غالبية المعلمات.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"87 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135570258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Characterization , Thermal Studies and Antioxidant Activities of Transition Metal Complexes with Azo Dye ligand","authors":"Amnah Mahdi Abdullah, Abbas Ali Salih Al-Hamdani","doi":"10.21123/bsj.2023.8365","DOIUrl":"https://doi.org/10.21123/bsj.2023.8365","url":null,"abstract":"Diazotization reaction between 1-(2,4,6-Trihydroxy-phenyl)-ethanone and diazonium salts was carried out resulting in ligand 4-(3-Acetyl-2,4,6-trihydroxy-phenylazo)-N-(5-methyl-isoxazol-3-yl)-benzenesulfonamide, this in turn reacted with the next metal ions (V4+ , Cr3+ , Mn2+ and Cu2+) forming stable complexes with unique geometries such as (Octahedral for both Cr3+ , Mn2+ and Cu2+ ,squar pyramidal for V4+). The creation of such complexes was detected by employing spectroscopic means involving ultraviolet-visible which proved the obtained geometries, fourier transfer proved the formation of azo group and and the coordination with metal ion through it. Pyrolysis (TGA & DSC) studies proved the coordination of water residues with metal ions inside the coordination sphere as well as chlorine atoms. Moreover, element micro-analysis and AAS that gave corresponding outcome with theoretically counting outcome. (1H &13C-NMR) and magnetic quantifications can also indicate the formation of ligand-H3L and occurrence of coordination. The thermodynamic constants (∆H, ∆S and ∆G) were calculated. The DPPH radical scavenging method will be used to assess the antioxidant activities of the compounds the compounds showed antioxidant abilities to scavenge free radical.","PeriodicalId":8687,"journal":{"name":"Baghdad Science Journal","volume":"139 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135616764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}