arXiv: Soft Condensed Matter最新文献

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Effective toughness of periodic heterogeneous materials: the role of rate-dependent fracture energies 周期性非均质材料的有效韧性:速率相关断裂能的作用
arXiv: Soft Condensed Matter Pub Date : 2020-03-30 DOI: 10.26226/morressier.5f5f8e69aa777f8ba5bd5fd2
G. Albertini, Mathias Lebihain, F. Hild, L. Ponson, David S. Kammer
{"title":"Effective toughness of periodic heterogeneous materials: the role of rate-dependent fracture energies","authors":"G. Albertini, Mathias Lebihain, F. Hild, L. Ponson, David S. Kammer","doi":"10.26226/morressier.5f5f8e69aa777f8ba5bd5fd2","DOIUrl":"https://doi.org/10.26226/morressier.5f5f8e69aa777f8ba5bd5fd2","url":null,"abstract":"Dynamic fracture of heterogeneous materials is investigated by measuring displacement fields as a rupture propagates through a periodic array of obstacles of controlled toughness. We provide direct evidence of crack speed jumps at the boundary of obstacles. Our experiments reveal that such a discontinuous dynamics emerges from rate-dependent fracture energy, which combined with inertia, allows the crack to cross a toughness discontinuity at constant energy release rate. The rate-dependency, a direct consequence of the out-of-equilibrium nature of fracture phenomenon that is often neglected, plays a central role in setting up homogenized toughness, leading ultimately to increased resistance to failure.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"150 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77408206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Role of annealed defects on conformational statistics of a selfavoiding semi-flexible polymer chain: Exact Results (I) 退火缺陷对自向半柔性聚合物链构象统计的作用:精确结果(I)
arXiv: Soft Condensed Matter Pub Date : 2020-03-29 DOI: 10.24327/IJCAR.2020.21291.4179
Pramod Kumar Mishra
{"title":"The Role of annealed defects on conformational statistics of a selfavoiding semi-flexible polymer chain: Exact Results (I)","authors":"Pramod Kumar Mishra","doi":"10.24327/IJCAR.2020.21291.4179","DOIUrl":"https://doi.org/10.24327/IJCAR.2020.21291.4179","url":null,"abstract":"We study equilibrium statistics of single semi-flexible polymer chain in the presence of defects. The defects are lying along a line in the two and three dimensions and the monomers are interacting with the onsite potential of the defects. A fully directed self-avoiding walk model is used in two and three dimensions to describe thermo-dynamical behaviour of the chain in the presence of m defects. We have found that the number of conformations of the semiflexible polymer chain may be controlled by means of introduction of such defects so that a particular fraction of the chain conformations may be either suppressed or populated as per our requirements for synthesizing the polymer-nanoaggregates. We discuss the role of annealed defects for its Q realizations and m defects analytically, i. e. when the defects are in the thermal equilibrium with the monomers of the semi-flexible chain.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"110 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85579075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Singular Nature of the Elastocapillary Ridge 弹性毛细管脊的奇异性
arXiv: Soft Condensed Matter Pub Date : 2020-03-22 DOI: 10.1103/PHYSREVX.10.031067
A. Pandey, A. Pandey, B. Andreotti, S. Karpitschka, G. Zwieten, E. V. Brummelen, J. Snoeijer
{"title":"Singular Nature of the Elastocapillary Ridge","authors":"A. Pandey, A. Pandey, B. Andreotti, S. Karpitschka, G. Zwieten, E. V. Brummelen, J. Snoeijer","doi":"10.1103/PHYSREVX.10.031067","DOIUrl":"https://doi.org/10.1103/PHYSREVX.10.031067","url":null,"abstract":"The functionality of soft interfaces is crucial to many applications in biology and surface science. Recent studies have used liquid drops to probe the surface mechanics of elastomeric networks. Experiments suggest an intricate surface elasticity, also known as the Shuttleworth effect, where surface tension is not constant but depends on substrate deformation. However, interpretations have remained controversial due to singular elastic deformations, induced exactly at the point where the droplet pulls the network. Here we reveal the nature of the elastocapillary singularity on a hyperelastic substrate with various constitutive relations for the interfacial energy. First, we finely resolve the vicinity of the singularity using goal-adaptive finite element simulations. This confirms the universal validity, also at large elastic deformations, of the previously disputed Neumann's law for the contact angles. Subsequently, we derive exact solutions of nonlinear elasticity that describe the singularity analytically. These solutions are in perfect agreement with numerics, and show that the stretch at the contact line, as previously measured experimentally, consistently points to a strong Shuttleworth effect. Finally, using Noether's theorem we provide a quantitative link between wetting hysteresis and Eshelby-like forces, and thereby offer a complete framework for soft wetting in the presence of the Shuttleworth effect.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"62 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83065994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Stability of topological wall defects on spheres with n-atic order n-有序球面上拓扑壁缺陷的稳定性
arXiv: Soft Condensed Matter Pub Date : 2020-03-20 DOI: 10.1103/PHYSREVRESEARCH.2.023215
C. Saichand, Jaya Kumar Alageshan, A. Roy, Y. Hatwalne
{"title":"Stability of topological wall defects on spheres with \u0000n\u0000-atic order","authors":"C. Saichand, Jaya Kumar Alageshan, A. Roy, Y. Hatwalne","doi":"10.1103/PHYSREVRESEARCH.2.023215","DOIUrl":"https://doi.org/10.1103/PHYSREVRESEARCH.2.023215","url":null,"abstract":"Topological point defects on orientationally ordered spheres, and on deformable fluid vesicles have been partly motivated by their potential applications in creating super-atoms with directional bonds through functionalization of the \"bald-spots\" created by topological point defects, thus paving the way for atomic chemistry at micron scales. We show that singular wall defects, topologically unstable \"bald lines\" in two dimensions, are stabilized near the order-disorder transition on a sphere. We attribute their stability to free-energetic considerations, which override those of topological stability.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"36 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79781360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Symmetry breaking of dipole orientations on Caspar-Klug lattices Caspar-Klug晶格上偶极子取向的对称性破缺
arXiv: Soft Condensed Matter Pub Date : 2020-03-19 DOI: 10.1103/physrevresearch.2.043199
S. Čopar, A. Božič
{"title":"Symmetry breaking of dipole orientations on Caspar-Klug lattices","authors":"S. Čopar, A. Božič","doi":"10.1103/physrevresearch.2.043199","DOIUrl":"https://doi.org/10.1103/physrevresearch.2.043199","url":null,"abstract":"Anisotropic dipole-dipole interaction often plays a key role in biological, soft, and complex matter. For it to induce non-trivial order in the system, there must be additional repulsive interactions or external potentials involved that partially or completely fix the positions of the dipoles. These positions can often be represented as an underlying lattice on which dipole interaction induces orientational ordering of the particles. On lattices in the Euclidean plane, dipoles have been found to assume different ground state configurations depending on the lattice type, with a global ordering in the form of a macrovortex being observed in many cases. A similar macrovortex configuration of dipoles has recently been shown to be the sole ground state for dipoles positioned on spherical lattices based on solutions of the Thomson problem. At the same time, no symmetric configurations have been observed, even though the positional order of Thomson lattices exhibits a high degree of symmetry. Here, we show that a different choice of spherical lattices based on Caspar-Klug construction leads to ground states of dipoles with various degrees of symmetry, including the icosahedral symmetry of the underlying lattice. We analyze the stability of the highly symmetric metastable states, their symmetry breaking into subsymmetries of the icosahedral symmetry group, and present a phase diagram of symmetries with respect to lattice parameters. The observed relationship between positional order and dipole-induced symmetry breaking hints at ways of fine-tuning the structure of spherical assemblies and their design.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79493188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Dynamics of a viscoelastic liquid filament connected to two mobile droplets 连接两个可移动液滴的粘弹性液体细丝的动力学
arXiv: Soft Condensed Matter Pub Date : 2020-03-17 DOI: 10.1063/5.0004151
Jiajia Zhou, M. Doi
{"title":"Dynamics of a viscoelastic liquid filament connected to two mobile droplets","authors":"Jiajia Zhou, M. Doi","doi":"10.1063/5.0004151","DOIUrl":"https://doi.org/10.1063/5.0004151","url":null,"abstract":"A filament of liquid is usually unstable and breaks up into small droplets, while a filament of polymer solution is known to be quite stable against such instability, and they form a stable configuration of filament connecting two spherical droplets. If the droplets are fixed in space, the liquid flows from the filament region to the droplet region to reduce the surface energy and the filament gets thinner. If the whole liquid is placed in another viscous fluid, the droplets approach each other, and the filament can get thicker. Here we study the dynamics of such system. We derive time evolution equations for the radius and the length of the filament taking into account the fluid flux from filament to droplets and the motion of the droplets. We will show that (a) if the centers of the droplets are fixed, the filament thins following the classical prediction of Entov and Hinch, and that (b) if the droplets are mobile (subject to the Stokes drag in the viscous medium), the thinning of the filament is suppressed, and under certain conditions, the filament thickens. This theory explains the phenomena observed by Yang and Xu [Phys. Fluids 20, 043101 (2008)] in four-roller mill device.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74704371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Electro-osmotic properties of porous permeable films 多孔渗透膜的电渗透特性
arXiv: Soft Condensed Matter Pub Date : 2020-03-14 DOI: 10.1103/physrevfluids.5.123701
Elena F. Silkina, Naren Bag, O. Vinogradova
{"title":"Electro-osmotic properties of porous permeable films","authors":"Elena F. Silkina, Naren Bag, O. Vinogradova","doi":"10.1103/physrevfluids.5.123701","DOIUrl":"https://doi.org/10.1103/physrevfluids.5.123701","url":null,"abstract":"Permeable porous coatings on a flat solid support significantly impact its electrostatic and electrokinetic properties. Existing work has focused on simplified cases, such as weakly charged and/or thick porous films, with limited theoretical guidance. Here, we consider the general case of coatings of any given volume charge density and obtain analytic formulas for electrostatic potential profiles, valid for any film thickness and salt concentration. They allow us to calculate analytically the difference between potentials at solid support and at interface with an outer electrolyte, that is the key parameter ascertaining the functionality of permeable coatings. Our analysis provides a framework for interpreting and predicting specific for porous films super-properties, from an enhanced ion absorption to a giant amplification of electro-osmotic flows. The results are relevant for hydrogel and zeolite coatings, porous carbon and ion-exchange resins, polyelectrolyte brushes, and more.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91190088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Forces between silica particles in isopropanol solutions of 1:1 electrolytes 在1:1电解质的异丙醇溶液中二氧化硅颗粒之间的力
arXiv: Soft Condensed Matter Pub Date : 2020-03-09 DOI: 10.1103/PHYSREVRESEARCH.2.023315
B. Stojimirović, M. Galli, G. Trefalt
{"title":"Forces between silica particles in isopropanol solutions of 1:1 electrolytes","authors":"B. Stojimirović, M. Galli, G. Trefalt","doi":"10.1103/PHYSREVRESEARCH.2.023315","DOIUrl":"https://doi.org/10.1103/PHYSREVRESEARCH.2.023315","url":null,"abstract":"Interactions between silica surfaces across isopropanol solutions are measured with colloidal probe technique based on atomic force microscope. In particular, the influence of 1:1 electrolytes on the interactions between silica particles is investigated. A plethora of different forces are found in these systems. Namely, van der Waals, double-layer, attractive non-DLVO, repulsive solvation, and damped oscillatory interactions are observed. The measured decay length of the double-layer repulsion is substantially larger than Debye lengths calculated from nominal salt concentrations. These deviations are caused by pronounced ion pairing in alcohol solutions. At separation below 10 nm, additional attractive and repulsive non-DLVO forces are observed. The former are possibly caused by charge heterogeneities induced by strong ion adsorption, whereas the latter originate from structuring of isopropanol molecules close to the surface. Finally, at increased concentrations the transition from monotonic to damped oscillatory interactions is uncovered.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75201285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Bending-induced director reorientation of a nematic liquid crystal elastomer bonded to a hyperelastic substrate 结合超弹性基底的向列液晶弹性体的弯曲诱导定向重定向
arXiv: Soft Condensed Matter Pub Date : 2020-03-09 DOI: 10.1063/5.0038822
Yang Liu, Wendi Ma, H. Dai
{"title":"Bending-induced director reorientation of a nematic liquid crystal elastomer bonded to a hyperelastic substrate","authors":"Yang Liu, Wendi Ma, H. Dai","doi":"10.1063/5.0038822","DOIUrl":"https://doi.org/10.1063/5.0038822","url":null,"abstract":"In this paper, the two-dimensional pure bending of a hyperelastic substrate coated by a nematic liquid crystal elastomer (abbreviated as NLCE) is studied within the framework of nonlinear elasticity. The governing system, arising from the deformational momentum balance, the orientational momentum balance and the mechanical constraint, is formulated, and the corresponding exact solution is derived for a given constitutive model. It is found that there exist two different bending solutions. In order to determine which the preferred one is, we compare the total potential energy for both solutions and find that the two energy curves may have an intersection point at a critical value of the bending angle $alpha_c$ for some material parameters. In particular, the director $bm n$ abruptly rotates $dfrac{pi}{2}$ from one solution to another at $alpha_c$, which indicates a director reorientation (or jump). Furthermore, the effects of different material and geometric parameters on the bending deformation and the transition angle $alpha_c$ can be revealed using the obtained bending solutions. Meanwhile, the exact solution can offer a benchmark problem for validating the accuracy of approximated plate models for liquid crystal elastomers.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90545030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Towards a soft magnetoelastic twist actuator 一种软磁弹性扭致动器
arXiv: Soft Condensed Matter Pub Date : 2020-03-09 DOI: 10.1103/PHYSREVRESEARCH.2.023383
Lukas P. Fischer, A. Menzel
{"title":"Towards a soft magnetoelastic twist actuator","authors":"Lukas P. Fischer, A. Menzel","doi":"10.1103/PHYSREVRESEARCH.2.023383","DOIUrl":"https://doi.org/10.1103/PHYSREVRESEARCH.2.023383","url":null,"abstract":"Soft actuators allow to transform external stimuli to mechanical deformations. Because of their deformational response to external magnetic fields, magnetic gels and elastomers represent ideal candidates for such tasks. Mostly, linear magnetostrictive deformations, that is, elongations or contractions along straight axes are discussed in this context. In contrast to that, we here suggest to realize a twist actuator that responds by torsional deformations around the axis of the applied magnetic field. For this purpose, we theoretically investigate the overall mechanical response of a basic model system containing discrete magnetizable particles in a soft elastic matrix. Two different types of discrete particle arrangements are used as starting conditions in the nonmagnetized state. These contain globally twisted anisotropic particle arrangements on the one hand, and groups of discrete helical-like particle structures positioned side by side on the other hand. Besides the resulting twist upon magnetization, we also evaluate different other modes of deformation. Our analysis supports the construction of magnetically orientable and actuatable torsional mixing devices in fluidic applications or other types of soft actuators that initiate relative rotations between different components.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"74 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74045780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
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