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New Synthesis of 5-Arylfuran-2,3-diones 5-芳基呋喃-2,3-二酮的新合成方法
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025603905
A. O. Derevnina, Yu. V. Shklyaev, A. N. Maslivets
{"title":"New Synthesis of 5-Arylfuran-2,3-diones","authors":"A. O. Derevnina,&nbsp;Yu. V. Shklyaev,&nbsp;A. N. Maslivets","doi":"10.1134/S1070428025603905","DOIUrl":"10.1134/S1070428025603905","url":null,"abstract":"<p>Literature data on the main preparative methods of synthesis of 5-arylfuran-2,3-diones have been considered. A new convenient protocol has been proposed for the synthesis of these compounds by heating 4-aryl-2,4-dioxobutanoic acids with acetyl bromide in anhydrous chloroform under reflux conditions. The structure of 5-(4-methoxyphenyl)furan-2,3-dione has been confirmed by X-ray analysis.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2286 - 2289"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070428025603905.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of New Functional Compounds Based on Bis(1,3-Benzothiazol-2-yl) Disulfide and Unsaturated Hydrocarbons 基于双（1,3-苯并噻唑-2-基）二硫化物和不饱和烃的新功能化合物的合成
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025605539
R. S. Ishigeev, S. A. Zhivet’eva, V. A. Potapov
{"title":"Synthesis of New Functional Compounds Based on Bis(1,3-Benzothiazol-2-yl) Disulfide and Unsaturated Hydrocarbons","authors":"R. S. Ishigeev,&nbsp;S. A. Zhivet’eva,&nbsp;V. A. Potapov","doi":"10.1134/S1070428025605539","DOIUrl":"10.1134/S1070428025605539","url":null,"abstract":"<p>Regioselective methods have been developed for the synthesis of previously unknown 2-func­tionalized 2,3-dihydro[1,3]thiazolo[2,3-<i>b</i>][1,3]benzothiazolium and 2-[1-(chloromethyl)organylsulfanyl]-1,3-benzothiazole derivatives in high yields on the basis of reactions of 2-(chlorosulfanyl)-1,3-benzothiazole with linear and cyclic alkenes and dienes.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2259 - 2266"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070428025605539.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New Aspects of Thiomorpholine Chemistry 硫吗啡啉化学新进展
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025605540
N. A. Makhaeva, V. A. Potapov
{"title":"New Aspects of Thiomorpholine Chemistry","authors":"N. A. Makhaeva,&nbsp;V. A. Potapov","doi":"10.1134/S1070428025605540","DOIUrl":"10.1134/S1070428025605540","url":null,"abstract":"<p>The review analyzes literature data published mainly over the past 10–15 years on the synthesis and properties of thiomorpholines, primarily new methods for constructing the thiomorpholine ring and new aspects of the chemistry of thiomorpholines. The formation of thiomorpholine derivatives from sulfur dichloride and primary or secondary amines, 2-aminoethanethiol, and other S,N-containing initial compounds is considered.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2247 - 2258"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070428025605540.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pharmacological Potential and Biological Applications of Various Schiff Base Analogues 各种希夫碱类似物的药理潜力和生物学应用
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025601554
H. A. Dahlawi, M. Asif
{"title":"Pharmacological Potential and Biological Applications of Various Schiff Base Analogues","authors":"H. A. Dahlawi,&nbsp;M. Asif","doi":"10.1134/S1070428025601554","DOIUrl":"10.1134/S1070428025601554","url":null,"abstract":"<p>Organic compounds play a crucial role in medicinal chemistry and chemical industry. Among them, Schiff bases formed by the condensation of aldehydes or ketones with amines are of significant importance. These compounds can be synthesized through various methods, including conventional heating, ultrasonic irradiation, catalyst-mediated processes, and microwave-assisted techniques. The azomethine linkage –HC=N– present in Schiff bases and their derivatives is associated with a wide range of pharmacological activities, such as anticancer, antioxidant, antimicrobial, antiviral, analgesic, anti-inflammatory, antidiabetic, and immuno­suppressive effects. In addition to their biological significance, Schiff bases are widely utilized in chemical industry. They serve as key intermediates in organic synthesis, as ligands in metal complex formation, and in the synthesis of amino acids. This review highlights the diverse applications of Schiff bases and aims to support the development of more potent molecular scaffolds for future drug design.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2367 - 2390"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reactivity of 2,9,16,23-Tetrakis(1H-benzotriazol-1-yl)-3,10,17,24-tetrakis(4-tert-butylphenoxy)phthalocyanine in Acid–Base Interactions with Nitrogen-Containing Organic Bases in Benzene 2,9,16,23-四（1h -苯并三唑-1-基）-3,10,17,24-四（4-叔丁基苯氧基）酞菁与苯中含氮有机碱酸碱相互作用的反应性
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S107042802560442X
O. A. Petrov, G. A. Gamov, S. A. Fedulova
{"title":"Reactivity of 2,9,16,23-Tetrakis(1H-benzotriazol-1-yl)-3,10,17,24-tetrakis(4-tert-butylphenoxy)phthalocyanine in Acid–Base Interactions with Nitrogen-Containing Organic Bases in Benzene","authors":"O. A. Petrov,&nbsp;G. A. Gamov,&nbsp;S. A. Fedulova","doi":"10.1134/S107042802560442X","DOIUrl":"10.1134/S107042802560442X","url":null,"abstract":"<p>The reactions of 2,9,16,23-tetrakis(1<i>H</i>-benzotriazol-1-yl)-3,10,17,24-tetrakis(4-<i>tert</i>-butylphenoxy)­phthalocyanine with pyridine, morpholine, piperidine, benzylamine, <i>n</i>-butylamine, <i>tert</i>-butylamine, diethyl­amine, and triethylamine in benzene have been studied. The acid–base interactions of the title compound with <i>n</i>-butylamine and piperidine are classed with rarely observed slow processes leading to the formation of kinetically stable proton-transfer complexes. Geometry optimization of these complexes has been performed by the B3LYP/6-31+G(<i>d</i>,<i>p</i>) method. The reactivity of 2,9,16,23-tetrakis(1<i>H</i>-benzotriazol-1-yl)-3,10,17,24-tetrakis(4-<i>tert</i>-butylphenoxy)phthalocyanine has been found to depend on the proton-acceptor power of the nitrogen base and its steric structure.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2240 - 2246"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
N-Arylsulfonylation of 2-(Furan-2-yl)- and 2-(Furan-2-ylmethyl)anilines 2-（呋喃-2-基）和2-（呋喃-2-基甲基）苯胺的n-芳基磺酰化
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025604595
S. Annadurdyyeva, G. M. Burkin, E. A. Kvyatkovskaya, L. Cheng, V. N. Khrustalev, P. V. Dorovatovskii, V. P. Zaytsev
{"title":"N-Arylsulfonylation of 2-(Furan-2-yl)- and 2-(Furan-2-ylmethyl)anilines","authors":"S. Annadurdyyeva,&nbsp;G. M. Burkin,&nbsp;E. A. Kvyatkovskaya,&nbsp;L. Cheng,&nbsp;V. N. Khrustalev,&nbsp;P. V. Dorovatovskii,&nbsp;V. P. Zaytsev","doi":"10.1134/S1070428025604595","DOIUrl":"10.1134/S1070428025604595","url":null,"abstract":"<p>2-(Furan-2-yl)anilines reacted with arenesulfonyl chlorides containing electron-withdrawing substituents to give the corresponding <i>N</i>,<i>N</i>-bis(arenesulfonyl) derivatives. Similar reactions of 3- and 4-(furan-2-yl)anilines produced mixtures of <i>N</i>-mono- and <i>N</i>,<i>N</i>-bis(arenesulfonyl) derivatives. The product structure was confirmed by spectroscopic data and X-ray analysis.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2276 - 2285"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rational Design of Recyclable Helical Polymeric Catalysts Bearing Pyrrolidine Motifs for High-Efficiency Asymmetric Aldol Reactions 高效不对称醛醇反应中吡咯烷基序可回收螺旋聚合物催化剂的合理设计
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025601918
Chaoxing Chen, Shuyi Wang, Chonglong Li
{"title":"Rational Design of Recyclable Helical Polymeric Catalysts Bearing Pyrrolidine Motifs for High-Efficiency Asymmetric Aldol Reactions","authors":"Chaoxing Chen,&nbsp;Shuyi Wang,&nbsp;Chonglong Li","doi":"10.1134/S1070428025601918","DOIUrl":"10.1134/S1070428025601918","url":null,"abstract":"<p>To address the challenges of poor recyclability and stability in small-molecule catalysts for asym­metric synthesis, this study developed a helical polymer catalyst with precisely engineered pyrrolidine catalytic centers through rational molecular design. A novel helical polymer catalyst (<b>Poly-1</b><sub><b>200</b></sub>) was successfully synthesized via palladium-initiated isocyanide monomer polymerization followed by Boc-deprotection. This catalyst demonstrated outstanding stereocontrol in isopropyl alcohol without additives. Using cyclohexanone and 4-nitrobenzaldehyde as model substrates, the reaction achieved 98% enantiomeric excess (<i>ee</i>). Notably, substituting cyclohexanone with cyclopentanone and employing trifluoromethyl-substituted benzaldehydes (4-CF<sub>3</sub> or 2-CF<sub>3</sub>) significantly enhanced stereoselectivity, yielding 99% <i>ee</i> with improved diastereomeric ratio (<i>dr</i>) values of 72:28 and 67:33, respectively. Importantly, the catalyst retained 94% <i>ee</i> and over 93% recovery rate after three cycles, overcoming the technical bottleneck of poor recyclability in conventional organocatalysts. This work provides an innovative design paradigm for developing highly efficient and recyclable polymer-based catalytic systems, merging macromolecular engineering with advanced stereochemical control.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2431 - 2440"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Pyrene-Based Chemosensor for Relay Fluorescence Recognition of Trivalent Cations and HS– Anion with Logic Gate Function and Its Applications 具有逻辑门功能的三价阳离子和HS -阴离子继电荧光识别化学传感器及其应用
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025601451
Yang Liu, Jin Tong, Mengfan Su, Shu-Yan Yu
{"title":"A Pyrene-Based Chemosensor for Relay Fluorescence Recognition of Trivalent Cations and HS– Anion with Logic Gate Function and Its Applications","authors":"Yang Liu,&nbsp;Jin Tong,&nbsp;Mengfan Su,&nbsp;Shu-Yan Yu","doi":"10.1134/S1070428025601451","DOIUrl":"10.1134/S1070428025601451","url":null,"abstract":"<p>Three pyridinyl-functionalized pyrene derivatives <b>L</b><sup><b>1</b></sup>, <b>L</b><sup><b>2</b></sup>, and <b>L</b><sup><b>3</b></sup> were synthesized, and they demonstrated colorimetric and ratiometric fluorescent responses to trivalent metal cations M<sup>3+</sup> (M = Cr, Fe, Al) over a variety of mono- and divalent metal cations. Cation to anion relay recognition was further studied with sequential specificity (M<sup>3+</sup> → HS<sup>–</sup>) using a fluorescence “off–on–off” mechanism. Compounds <b>L</b><sup><b>1</b></sup>–<b>L</b><sup><b>3</b></sup> are receptors with high selectivity for HS<sup>–</sup>, Fe<sup>3+</sup>, Al<sup>3+</sup>, and Cr<sup>3+</sup> ions in methanol/water solution. Absorption and fluorescence spectra were used to investigate the sensing process. Green or yellow fluorescence emission of <b>L</b><sup><b>1</b></sup>–<b>L</b><sup><b>3</b></sup> appeared (switch “on”) after the addition of Fe<sup>3+</sup>, Al<sup>3+</sup>, and Cr<sup>3+</sup>. Surprisingly, the complex <b>L</b>+Fe<sup>3+</sup> or <b>L</b>+Cr<sup>3+</sup> or <b>L</b>+Al<sup>3+</sup> is recovered with addition of HS<sup>–</sup> to the complex (switch “off”). Consequently, the implication (from emission) logic gate was constructed at the molecular level. The gates operate in fluorescence mode when Fe<sup>3+</sup> and HS<sup>–</sup> or Al<sup>3+</sup> and HS<sup>–</sup> or Cr<sup>3+</sup> and HS<sup>–</sup> are used as input materials, and the fluorescence intensity as outputs. Based on reversible and reproducible systems, a sequential memory unit with integrated “Writing–Reading–Erasing–Reading” behavior is developed.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2320 - 2331"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-Free Sonochemical Synthesis, In Silico Molecular Docking, and ADME Profiling of 2-Aryl-1H-benzimidazoles as Promising Antimicrobial Agents 2-芳基- 1h -苯并咪唑的无金属声化学合成、硅分子对接及ADME谱分析
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S1070428025601566
K. Saravate, N. Kulkarni, M. Kulkarni
{"title":"Metal-Free Sonochemical Synthesis, In Silico Molecular Docking, and ADME Profiling of 2-Aryl-1H-benzimidazoles as Promising Antimicrobial Agents","authors":"K. Saravate,&nbsp;N. Kulkarni,&nbsp;M. Kulkarni","doi":"10.1134/S1070428025601566","DOIUrl":"10.1134/S1070428025601566","url":null,"abstract":"<p>A sustainable green protocol has been developed for the metal-free sonochemical synthesis of 2-aryl-1<i>H</i>-benzimidazoles through the condensation of <i>o</i>-phenylenediamine and diverse aromatic aldehydes using L-aspartic acid as a novel recyclable organocatalyst. This methodology overcomes the shortcomings of utilizing harmful metal catalysts, resulting in eco-friendly protocol and mild reaction conditions with high atom efficiency. The molecular docking studies with DNA gyrase subunit B revealed strong binding interactions with a highest binding energy of –115.867 kcal/mol. The ADME properties of the synthesized compounds revealed their drug-likeness. The compounds displayed good to excellent antimicrobial activity.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2391 - 2400"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acetophenone-Substituted 5-(Methylamino)benzotriazole Mannich Bases: Synthesis, Molecular Modeling, and Antioxidant Potential 苯乙酮取代的5-（甲氨基）苯并三唑曼尼希碱：合成、分子模拟和抗氧化潜力
IF 0.9 4区 化学
Russian Journal of Organic Chemistry Pub Date : 2026-02-08 DOI: 10.1134/S107042802560158X
D. Tatipaka, R. Porapu, S. Telajala, M. Tummalapalli, R. S. R. Dontireddy
{"title":"Acetophenone-Substituted 5-(Methylamino)benzotriazole Mannich Bases: Synthesis, Molecular Modeling, and Antioxidant Potential","authors":"D. Tatipaka,&nbsp;R. Porapu,&nbsp;S. Telajala,&nbsp;M. Tummalapalli,&nbsp;R. S. R. Dontireddy","doi":"10.1134/S107042802560158X","DOIUrl":"10.1134/S107042802560158X","url":null,"abstract":"<p>The condensation of 5-amino-1<i>H</i>-benzotriazole with substituted acetophenones and formaldehyde in the presence of an acid catalyst under microwave irradiation to produce 3-[(1<i>H</i>-benzotriazol-5-yl)amino]-1-phenylpropan-1-one derivatives. The structure of the synthesized compounds was confirmed by IR, <sup>1</sup>H and <sup>13</sup>C NMR, and mass spectra, and their antioxidant activity was evaluated by different assay procedures. Compounds <b>6a</b>, <b>6c</b>, and <b>6d</b> at concentrations of 100 and 200 μg/mL showed higher activity in hydrogen peroxide scavenging by the replacement titration method. Compounds <b>6c</b>–<b>6f</b> and <b>6h</b> exhibited potency in total antioxidant capacity by the phosphomolybdenum method, and <b>6a</b>–<b>6e</b> displayed higher activity than the standard in nitric oxide radical scavenging assay at 100 and 200 μg/mL concentrations. Molecular docking of the compounds with three receptors, nitric oxide synthase, sphingomyelinase-2, and xanthine oxidase, was performed to identify and confirm the best ligand–protein interactions. Among the examined compounds, <b>6a</b> and <b>6e</b> showed a good binding affinity against all three receptors and potent radical scavenging activity surpassing that of ascorbic acid. Molecular dynamics studies showed that compound <b>6e</b> formed the most stable complex at the binding pocket of sphingomyelinase-2.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"61 12","pages":"2446 - 2456"},"PeriodicalIF":0.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147337539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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