{"title":"New Approaches to Atom Transfer Radical Polymerization and Their Realization in the Synthesis of Functional Polymers and Hybrid Macromolecular Structures","authors":"I. D. Grishin","doi":"10.1134/S1811238222700035","DOIUrl":"10.1134/S1811238222700035","url":null,"abstract":"<p>Recent advances in controlled atom transfer radical polymerization are reviewed. Polymerization techniques carried out in the presence of small catalyst amounts, as well as air oxygen traces, are addressed. Particular attention is given to processes occurring under the action of light and near UV radiation. Latest achievements of Atom Transfer Radical Polymerization in the modification of solid surfaces of inorganic substrates and organic polymers by grafting polymer chains are analyzed. Potential of the method for synthesizing conjugates with proteins and nucleic acids, which are of interest as biosensors and target drug delivery agents, is also demonstrated.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"64 2","pages":"82 - 94"},"PeriodicalIF":2.2,"publicationDate":"2022-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5124415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence","authors":"E. V. Chernikova, K. O. Mineeva","doi":"10.1134/S1811238222200024","DOIUrl":"10.1134/S1811238222200024","url":null,"abstract":"<p>The review addresses the synthesis of copolymers with the controlled distribution of monomer units (random, gradient, block-random, block-gradient, multiblock copolymers) by reversible deactivation radical polymerization and the ways of purposeful variation in the sequence of units in macromolecules during the synthesis. The effect of chain microstructure on the properties of these copolymers is discussed.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"64 1","pages":"1 - 25"},"PeriodicalIF":2.2,"publicationDate":"2022-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5108890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"New Approaches to the Design of Double Polymer Networks: a Review","authors":"A. V. Shibaev, O. E. Philippova","doi":"10.1134/S1811238222200012","DOIUrl":"10.1134/S1811238222200012","url":null,"abstract":"<p>The review addresses modern approaches to the synthesis of mechanically tough polymer hydrogels which are based on the concept of double networks. Various types of double networks, such as covalently crosslinked networks; hybrid networks, in which one network is crosslinked by covalent bonds and another network is crosslinked by labile dynamic bonds; and networks that are constructed using labile bonds in each network, are considered. Double networks consisting of one polymer network and one supramolecular network, nanocomposite double networks, and multicomponent (three-component, four-component, etc.) networks are described. Advantages and disadvantages of new approaches to designing mechanically tough double networks are considered.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"64 1","pages":"26 - 39"},"PeriodicalIF":2.2,"publicationDate":"2022-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4523787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. V. Gudkov, D. Yu. Stolyarova, K. A. Shiyanova, V. P. Mel’nikov
{"title":"Polymer Composites with Graphene and Its Derivatives as Functional Materials of the Future","authors":"M. V. Gudkov, D. Yu. Stolyarova, K. A. Shiyanova, V. P. Mel’nikov","doi":"10.1134/S1811238222010027","DOIUrl":"10.1134/S1811238222010027","url":null,"abstract":"<p>Approaches to the synthesis of polymer composite materials filled with graphene and its derivatives, methods of introducing graphene and its functionalized forms into polymer matrices, and effect of fillers on the electrophysical, mechanical, and electrorheological properties and the structure of the materials are considered. Research trends that can promote the integration of polymer composites with graphene and graphene derivatives into innovative world-class products and in the everyday life are indicated.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"64 1","pages":"40 - 61"},"PeriodicalIF":2.2,"publicationDate":"2022-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4829759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, Properties, and Biological Activity of Poly(1-vinyl-1,2,4-triazole) and Silver Nanocomposites Based on It","authors":"G. F. Prozorova, A. S. Pozdnyakov","doi":"10.1134/S1811238222010015","DOIUrl":"10.1134/S1811238222010015","url":null,"abstract":"<p>The review summarizes the data on the synthesis, physicochemical properties, and biological activity of poly(1-vinyl-1,2,4-triazole) and its nanocomposites with silver nanoparticles. The results of studying the antibacterial and antitumor activity of the polymers and nanocomposites and their immunomodulatory ability, toxicity, and interaction with body cells, as well as the prospects for their use in the development of medical materials, are presented.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"64 1","pages":"62 - 72"},"PeriodicalIF":2.2,"publicationDate":"2022-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4095734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Erratum to: Modern Porous Polymer Implants: Synthesis, Properties, and Application","authors":"R. S. Kovylin, D. Ya. Aleynik, I. L. Fedushkin","doi":"10.1134/S1811238221330018","DOIUrl":"10.1134/S1811238221330018","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 2","pages":"272 - 272"},"PeriodicalIF":2.2,"publicationDate":"2021-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4698083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reversible Deactivation Radical Polymerization Mediated by Nitroxides and Green Chemistry","authors":"M. Yu. Zaremski, N. S. Melik-Nubarov","doi":"10.1134/S1811238221020120","DOIUrl":"10.1134/S1811238221020120","url":null,"abstract":"<p>This review is the first attempt to consider application of some principles of green chemistry to reversible-deactivation radical polymerization mediated by nitroxides. The results of controlled synthesis of easily degradable polymers and polymers synthesized under conditions of green chemistry by photopolymerization, polymerization in supercritical carbon dioxide, and polymerization of monomers from renewable raw materials are discussed.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 2","pages":"126 - 143"},"PeriodicalIF":2.2,"publicationDate":"2021-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4989772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanisms of Reactions of Green Chemistry of Polyurethanes and Problems of Using Renewable Vegetable Raw Materials","authors":"R. P. Tiger, M. V. Zabalov, M. A. Levina","doi":"10.1134/S1811238221020090","DOIUrl":"10.1134/S1811238221020090","url":null,"abstract":"<p>A brief overview of works in the field of mechanisms of reactions underlying the green chemistry of polyurethanes is presented. The main attention is paid to the processes of the formation of nonisocyanate urethanes from cyclocarbonates and amines and the thermal decomposition of acyl azides as a phosgene-free method for the preparation of isocyanates in statu nascendi. The results of the study of the functional composition of cyclocarbonate-containing triglycerides the derivatives of soybean and sunflower oils, and the prospects for using renewable plant raw materials for the synthesis of new urethanes are also discussed.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 2","pages":"113 - 125"},"PeriodicalIF":2.2,"publicationDate":"2021-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4989754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Polymer Materials for Membrane Separation of Gas Mixtures Containing CO2","authors":"A. Yu. Alentiev, V. E. Ryzhikh, N. A. Belov","doi":"10.1134/S1811238221020016","DOIUrl":"10.1134/S1811238221020016","url":null,"abstract":"<p>In recent decades, the need to capture carbon dioxide from industrial gas streams, its storage, and utilization has been justified as a rule by environmental problems. However, the capture of CO<sub>2</sub> from industrial gas mixtures is an independent important issue of chemical technology. The review addresses consideration and analysis of polymer materials for the membrane separation of CO<sub>2</sub>-containing mixtures which are of interest for purification of natural gas, biogas, and flue gases and separation of hydrogen from methane and water gas conversion products. Therefore, gas pairs CO<sub>2</sub>/CH<sub>4</sub>, CO<sub>2</sub>/N<sub>2</sub>, and CO<sub>2</sub>/H<sub>2</sub> are relevant for membrane separation. Promising polymer materials should possess the beneficial combination of CO<sub>2</sub> permeability and selectivity for the gas pair of interest, that is, should be located near the upper bound of the Robeson diagram or be above it. For separation of the first two gas pairs good gas-separation parameters are exhibited by rigid-chain highly permeable glassy polymers of various classes (polymers of intrinsic microporosity, polyimides, polynorbornenes, polybenzoxazoles). For separation of the gas pair CO<sub>2</sub>/N<sub>2</sub> the most advantageous properties are shown by polymers bearing functional groups capable of specific interactions with carbon dioxide (aliphatic polyethers and polyimides with their oligomer moieties, polynorbornenes carrying Si‒O–C and Si–O–Si groups, polymers with ionogenic groups). Thermally stable barrier polymers based on polybenzoxazoles show promise for purification of hydrogen from carbon dioxide at high temperatures.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 2","pages":"181 - 198"},"PeriodicalIF":2.2,"publicationDate":"2021-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4989762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. A. Smirnov, D. A. Tolmachev, A. D. Glova, M. P. Sokolova, P. V. Geydt, N. V. Lukasheva, S. V. Lyulin
{"title":"Combined Use of Atomic Force Microscopy and Molecular Dynamics in the Study of Biopolymer Systems","authors":"M. A. Smirnov, D. A. Tolmachev, A. D. Glova, M. P. Sokolova, P. V. Geydt, N. V. Lukasheva, S. V. Lyulin","doi":"10.1134/S1811238221020089","DOIUrl":"10.1134/S1811238221020089","url":null,"abstract":"<p>Publications showing the prospects of combining computer simulation with atomic force microscopy in the study of polymer biological objects and materials for various purposes are analyzed. The problems that arise when these methods are used together are described. Three main directions are presented in which atomic force microscopy is used in conjunction with computer simulation: study of the surface topography of polymer materials; measurement of the force curve of the interaction of the atomic force probe with polymer structures; and determination of the energy of intermolecular interactions.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 2","pages":"256 - 271"},"PeriodicalIF":2.2,"publicationDate":"2021-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4697548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}