Acta crystallographica Section B, Structural science, crystal engineering and materials最新文献

筛选
英文 中文
Low-dimensional metal-organic frameworks: a pathway to design, explore and tune magnetic structures. 低维金属有机框架:设计、探索和调整磁性结构的途径。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-18 DOI: 10.1107/S2052520624008023
Stuart Calder, Raju Baral, C Charlotte Buchanan, Dustin A Gilbert, Rylan J Terry, Joseph W Kolis, Liurukara D Sanjeewa
{"title":"Low-dimensional metal-organic frameworks: a pathway to design, explore and tune magnetic structures.","authors":"Stuart Calder, Raju Baral, C Charlotte Buchanan, Dustin A Gilbert, Rylan J Terry, Joseph W Kolis, Liurukara D Sanjeewa","doi":"10.1107/S2052520624008023","DOIUrl":"https://doi.org/10.1107/S2052520624008023","url":null,"abstract":"<p><p>The magnetic structure adopted by a material relies on symmetry, the hierarchy of exchange interactions between magnetic ions and local anisotropy. A direct pathway to control the magnetic interactions is to enforce dimensionality within the material, from zero-dimensional isolated magnetic ions, one-dimensional (1D) spin-chains, two-dimensional (2D) layers to three-dimensional (3D) order. Being able to design a material with a specific dimensionality for the phenomena of interest is non-trivial. While many advances have been made in the area of inorganic magnetic materials, organic compounds offer distinct and potentially more fertile ground for material design. In particular magnetic metal-organic frameworks (mMOFs) combine magnetism with non-magnetic property functionality on the organic linkers within the structural framework, which can further be tuned with mild perturbations of pressure and field to induce phase transitions. Here, it is examined how neutron scattering measurements on mMOFs can be used to directly determine the magnetic structure when the magnetic ions are in a 2D layered environment within the wider 3D crystalline framework. The hydrated formate, in deuterated form, Co(DCOO)<sub>2</sub>·2D<sub>2</sub>O, which was one of the first magnetic MOFs to be investigated with neutron diffraction, is reinvestigated as an exemplar case.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142455736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of magnetic structures in JANA2020. JANA2020 中的磁结构分析。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-19 DOI: 10.1107/S2052520624008163
M S Henriques, V Petříček, S Goswami, M Dušek
{"title":"Analysis of magnetic structures in JANA2020.","authors":"M S Henriques, V Petříček, S Goswami, M Dušek","doi":"10.1107/S2052520624008163","DOIUrl":"10.1107/S2052520624008163","url":null,"abstract":"<p><p>JANA2020 is a program developed for the solution and refinement of regular, twinned, modulated, and composite crystal structures. In addition, JANA2020 also includes a magnetic option for solving magnetic structures from powder and single-crystal neutron diffraction data. This tool uses magnetic space and superspace symmetry to describe commensurate and incommensurate magnetic structures. The basics of the underlying formulation of magnetic structure factors and the use of magnetic symmetry for handling modulated and non-modulated magnetic structures are presented here, together with the general features of the magnetic tool. Examples of structures solved in the magnetic option of JANA2020 are given to illustrate the operation and capabilities of the program.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457105/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Search for missing symmetry in the Inorganic Crystal Structure Database (ICSD). 在无机晶体结构数据库(ICSD)中搜索缺失的对称性。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-17 DOI: 10.1107/S2052520624008229
Maxim Avdeev
{"title":"Search for missing symmetry in the Inorganic Crystal Structure Database (ICSD).","authors":"Maxim Avdeev","doi":"10.1107/S2052520624008229","DOIUrl":"10.1107/S2052520624008229","url":null,"abstract":"<p><p>An exhaustive search for missing symmetry was performed for 223 076 entries in the ICSD (2023-2 release). Approximately 0.65% of them can be described with higher symmetry than reported. Out of the identified noncentrosymmetric entries, ∼74% can be described by centrosymmetric space groups; this has implications for compatible physical properties. It is proposed that the information on the correct space group is included in the ICSD.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457106/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of an organic-inorganic hybrid crystal: 2[Co(en)3](V4O13)·4H2O. 有机-无机杂化晶体:2[Co(en)3](V4O13)-4H2O 的合成与表征。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-03 DOI: 10.1107/S2052520624007509
Emilie Skytte Vosegaard, Mohammad Aref Hasen Mamakhel, Vijay Singh Parmar, Andreas Dueholm Bertelsen, Bo Brummerstedt Iversen
{"title":"Synthesis and characterization of an organic-inorganic hybrid crystal: 2[Co(en)<sub>3</sub>](V<sub>4</sub>O<sub>13</sub>)·4H<sub>2</sub>O.","authors":"Emilie Skytte Vosegaard, Mohammad Aref Hasen Mamakhel, Vijay Singh Parmar, Andreas Dueholm Bertelsen, Bo Brummerstedt Iversen","doi":"10.1107/S2052520624007509","DOIUrl":"10.1107/S2052520624007509","url":null,"abstract":"<p><p>Organic-inorganic hybrid crystals have diverse functionalities, for example in energy storage and luminescence, due to their versatile structures. The synthesis and structural characterization of a new cobalt-vanadium-containing compound, 2[Co(en)<sub>3</sub>]<sup>3+</sup>(V<sub>4</sub>O<sub>13</sub>)<sup>6-</sup>·4H<sub>2</sub>O (1) is presented. The crystal structure of 1, consisting of [Co(en)<sub>3</sub>]<sup>3+</sup> complexes and chains of corner-sharing (VO<sub>4</sub>) tetrahedra, was solved by single-crystal X-ray diffraction in the centrosymmetric space group P1. Phase purity of the bulk material was confirmed by infrared spectroscopy, scanning electron microscopy, elemental analysis and powder X-ray diffraction. The volume expansion of 1 was found to be close to 1% in the reported temperature range from 100 to 300 K, with a volume thermal expansion coefficient of 56 (2) × 10<sup>-6</sup> K<sup>-1</sup>. The electronic band gap of 1 is 2.30 (1) eV, and magnetic susceptibility measurements showed that the compound exhibits a weak paramagnetic response down to 1.8 K, probably due to minor Co<sup>II</sup> impurities (<1%) on the Co<sup>III</sup> site.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457104/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142131594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A recapitulation of magnetic space groups and their UNI symbols. 磁空间群及其 UNI 符号概述。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-17 DOI: 10.1107/S2052520624008084
B J Campbell, H T Stokes, J M Perez-Mato, J Rodriguez-Carvajal
{"title":"A recapitulation of magnetic space groups and their UNI symbols.","authors":"B J Campbell, H T Stokes, J M Perez-Mato, J Rodriguez-Carvajal","doi":"10.1107/S2052520624008084","DOIUrl":"10.1107/S2052520624008084","url":null,"abstract":"<p><p>The mathematical structure, description and classification of magnetic space groups is briefly reviewed, with special emphasis on the recently proposed notation, the so-called UNI symbols [Campbell et al. (2022). Acta Cryst. A78, 99-106]. As illustrative examples, very simple magnetic space groups from each of the four possible types are described in detail.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determining magnetic structures in GSAS-II using the Bilbao Crystallographic Server tool k-SUBGROUPSMAG. 利用毕尔巴鄂晶体学服务器工具 k-SUBGROUPSMAG 确定 GSAS-II 中的磁结构。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-20 DOI: 10.1107/S2052520624008436
Robert B Von Dreele, Luis Elcoro
{"title":"Determining magnetic structures in GSAS-II using the Bilbao Crystallographic Server tool k-SUBGROUPSMAG.","authors":"Robert B Von Dreele, Luis Elcoro","doi":"10.1107/S2052520624008436","DOIUrl":"10.1107/S2052520624008436","url":null,"abstract":"<p><p>The embedded call to a special version of the web-based Bilbao Crystallographic Server tool k-SUBGROUPSMAG from within GSAS-II to form a list of all possible commensurate magnetic subgroups of a parent magnetic grey group is described. It facilitates the selection and refinement of the best commensurate magnetic structure model by having all the analysis tools including Rietveld refinement in one place as part of GSAS-II. It also provides the chosen magnetic space group as one of the 1421 possible standard Belov-Neronova-Smirnova forms or equivalent non-standard versions.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457102/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A short note on the use of irreducible representations for tilted octahedra in perovskites. 关于在过氧化物中使用倾斜八面体不可还原表征的简短说明。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-08-08 DOI: 10.1107/S2052520624006668
A M Glazer
{"title":"A short note on the use of irreducible representations for tilted octahedra in perovskites.","authors":"A M Glazer","doi":"10.1107/S2052520624006668","DOIUrl":"10.1107/S2052520624006668","url":null,"abstract":"<p><p>It is pointed out that many authors are unaware that the particular choice of unit-cell origin determines the irreducible representations to which octahedral tilts in perovskites belong. Furthermore, a recommendation is made that the preferred option is with the origin at the B-cation site rather than that of the A site.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457109/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142103254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
K0.72Na1.71Ca5.79Si6O19 - the first oligosilicate based on [Si6O19]-hexamers and its stability compared to cyclosilicates. K0.72Na1.71Ca5.79Si6O19--第一种基于[Si6O19]六聚物的低硅酸盐及其与环硅酸盐相比的稳定性。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-08-30 DOI: 10.1107/S2052520624007352
Volker Kahlenberg, Hannes Krüger, Sonja Garber, Biljana Krüger, Eugen Libowitzky, Stefanie Kröll, Thomas S Hofer, Josef M Gallmetzer, Felix R S Purtscher
{"title":"K<sub>0.72</sub>Na<sub>1.71</sub>Ca<sub>5.79</sub>Si<sub>6</sub>O<sub>19</sub> - the first oligosilicate based on [Si<sub>6</sub>O<sub>19</sub>]-hexamers and its stability compared to cyclosilicates.","authors":"Volker Kahlenberg, Hannes Krüger, Sonja Garber, Biljana Krüger, Eugen Libowitzky, Stefanie Kröll, Thomas S Hofer, Josef M Gallmetzer, Felix R S Purtscher","doi":"10.1107/S2052520624007352","DOIUrl":"10.1107/S2052520624007352","url":null,"abstract":"<p><p>Synthesis experiments were conducted in the quaternary system K<sub>2</sub>O-Na<sub>2</sub>O-CaO-SiO<sub>2</sub>, resulting in the formation of a previously unknown compound with the composition K<sub>0.72</sub>Na<sub>1.71</sub>Ca<sub>5.79</sub>Si<sub>6</sub>O<sub>19</sub>. Single crystals of sufficient size and quality were recovered from a starting mixture with a K<sub>2</sub>O:Na<sub>2</sub>O:CaO:SiO<sub>2</sub> molar ratio of 1.5:0.5:2:3. The mixture was confined in a closed platinum tube and slowly cooled from 1150°C at a rate of 0.1°C min<sup>-1</sup> to 700°C before being finally quenched in air. The structure has tetragonal symmetry and belongs to space group P4<sub>1</sub>22 (No. 91), with a = 7.3659 (2), c = 32.2318 (18) Å, V = 1748.78 (12) Å<sup>3</sup>, and Z = 4. The silicate anion consists of highly puckered, unbranched six-membered oligomers with the composition [Si<sub>6</sub>O<sub>19</sub>] and point group symmetry 2 (C<sub>2</sub>). Although several thousands of natural and synthetic oxosilicates have been structurally characterized, this compound is the first representative of a catena-hexasilicate anion, to the best of our knowledge. Structural investigations were completed using Raman spectroscopy. The spectroscopic data was interpreted and the bands were assigned to certain vibrational species with the support of density functional theory at the HSEsol level of theory. To determine the stability properties of the novel oligosilicate compared to those of the chemically and structurally similar cyclosilicate combeite, we calculated the electronegativity of the respective structures using the electronegativity equalization method. The results showed that the molecular electronegativity of the cyclosilicate was significantly higher than that of the oligostructure due to the different connectivities of the oxygen atoms within the molecular units.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11457099/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142103256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The magnetic structure and spin-reorientation of ErGa. ErGa 的磁性结构和自旋取向。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-10-01 Epub Date: 2024-09-30 DOI: 10.1107/S205252062400862X
J M Cadogan, D H Ryan, R A Susilo, S Muñoz Pérez, R Cobas, N R Lee-Hone, B R Hansen, M Avdeev
{"title":"The magnetic structure and spin-reorientation of ErGa.","authors":"J M Cadogan, D H Ryan, R A Susilo, S Muñoz Pérez, R Cobas, N R Lee-Hone, B R Hansen, M Avdeev","doi":"10.1107/S205252062400862X","DOIUrl":"https://doi.org/10.1107/S205252062400862X","url":null,"abstract":"<p><p>The magnetic structure of the intermetallic compound ErGa has been determined using high-resolution neutron powder diffraction. This compound crystallizes in the orthorhombic (Cmcm, No. 63) CrB-type structure and orders ferromagnetically at 32 (2) K, with the Er moments initially aligned along the b axis. Upon cooling below 16 K, the Er magnetic moments cant away from the b axis towards the c axis. At 3 K, the Er moment is 8.7 (3) μ<sub>B</sub> and the Er magnetic moments point in the direction 31 (3)° away from the crystallographic b axis, within the bc plane. <sup>166</sup>Er Mössbauer spectroscopy work supports this structure and shows clear signals of the spin-reorientation in both the magnetic and electric quadrupole hyperfine interactions.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142455737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Following the guidelines for communicating commensurate magnetic structures: real case examples. 遵循沟通相称磁结构的准则:真实案例。
IF 1.3 3区 化学
Acta crystallographica Section B, Structural science, crystal engineering and materials Pub Date : 2024-08-01 Epub Date: 2024-07-17 DOI: 10.1107/S2052520624005407
F Damay
{"title":"Following the guidelines for communicating commensurate magnetic structures: real case examples.","authors":"F Damay","doi":"10.1107/S2052520624005407","DOIUrl":"10.1107/S2052520624005407","url":null,"abstract":"<p><p>A few real case examples are presented on how to report magnetic structures, with precise step-by-step explanations, following the guidelines of the IUCr Commission on Magnetic Structures [Perez-Mato et al. (2024). Acta Cryst. B80, 219-234]. Four examples have been chosen, illustrating different types of single-k magnetic orders, from the basic case to more complex ones, including odd-harmonics, and one multi-k order. In addition to acquainting researchers with the process of communicating commensurate magnetic structures, these examples also aim to clarify important concepts, which are used throughout the guidelines, such as the transformation to a standard setting of a magnetic space group.</p>","PeriodicalId":7320,"journal":{"name":"Acta crystallographica Section B, Structural science, crystal engineering and materials","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11301900/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141970355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信