Journal of Structural Chemistry最新文献_第5页

Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals 双吡唑基硝基氮氧化物双自由基的合成与结构

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-29 DOI: 10.1134/S0022476625080165

S. E. Tolstikov, G. V. Romanenko, E. V. Tretyakov, A. S. Bogomyakov

引用次数: 0

Non-Trivial Hexanuclear Copper(II) Complex Based on 4‑(1H-tetrazole-5-yl)Benzoic Acid and 1,10-Phenanthroline 基于4 - （1h -四唑-5-基）苯甲酸和1,10-菲罗啉的非平凡六核铜（II）配合物

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-29 DOI: 10.1134/S0022476625080062

E. A. Ermakova, K. S. Smirnova, E. V. Lider

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Effect of the Crystallization Temperature and the N-donor Ligand Nature on the Crystal Structure of {EuCd} Complexes with Pentafluorobenzoic Acid Anions 结晶温度和n给体性质对五氟苯甲酸配合物晶体结构的影响

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070133

M. A. Shmelev, Yu. K. Voronina, A. S. Chistyakov, G. A. Razgonyaeva, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko

{"title":"Effect of the Crystallization Temperature and the N-donor Ligand Nature on the Crystal Structure of {EuCd} Complexes with Pentafluorobenzoic Acid Anions","authors":"M. A. Shmelev, Yu. K. Voronina, A. S. Chistyakov, G. A. Razgonyaeva, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko","doi":"10.1134/S0022476625070133","DOIUrl":"10.1134/S0022476625070133","url":null,"abstract":"Variation of the crystallization temperature of cadmium pentafluorobenzoate {[Cd(H2O)4(pfb)](pfb)}n (Hpfb = pentafluorobenzoic acid), europium pentafluorobenzoate [Eu2(H2O)8(pfb)6]·2H2O, and pyrazino[2,3-f][1,10]phenanthroline (pzphen) in MeCN results in the isolation of crystals: coordination polymer [Eu2(H2O)2Cd2(pzphen)2(pfb)10]n (1) at 25 °C and [Eu2Cd4(pzphen)4(pfb)14]n·4nMeCN (2) and [Eu2Cd2(pzphen)4(pfb)10]·10MeCN (3) compounds at 75 °C. When bathophenanthroline (bphen) and 2,9-dimethylbathophenanthroline (mbphen) are used as N-donor ligands, the crystallization temperature does not affect the compositions and structures of the compounds formed, and therefore, [Eu2Cd2(bphen)2 (pfb)10]n·2nMeCN (4) and [Eu2Cd2(mbphen)2(pfb)10]·H2O (5) complexes are formed. The synthesized compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the CHN analysis. The structures and crystal packings of the obtained complexes are examined in detail. The main contribution to the stabilization of crystal packings is made by π⋯π, C–H⋯F, C–F⋯π interactions.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 7","pages":"1474 - 1490"},"PeriodicalIF":1.4,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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New Mixed-Valence Trinuclear {CoIII-CoII-CoIII}-Cluster Based on bis-Chelating N2O2-Donor Macrocyclic Schiff Base Supported by the Calix[4]Arene Platform: Synthesis and Structure 杯形[4]芳烃平台支持的双螯合n2o2给体大环席夫碱新混价三核{CoIII-CoII-CoIII}簇的合成与结构

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070169

Yu. V. Strelnikova, A. A. Iova, A. S. Ovsyannikov, D. R. Islamov, V. A. Burilov, P. V. Dorovatovskii, S. E. Solovieva, I. S. Antipin

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Synthesis and Structure of a Metal-Organic Framework Based on Lanthanum(III) and Diacetylenedibenzoic Acid 基于镧（III）和二乙酰二苯甲酸的金属-有机骨架的合成与结构

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070054

A. A. Osipov, S. A. Nayfert, A. N. Efremov, V. S. Senchurin, K. Radzhakumar, P. V. Dorovatovskiy, D. A. Zherebtsov

{"title":"Synthesis and Structure of a Metal-Organic Framework Based on Lanthanum(III) and Diacetylenedibenzoic Acid","authors":"A. A. Osipov, S. A. Nayfert, A. N. Efremov, V. S. Senchurin, K. Radzhakumar, P. V. Dorovatovskiy, D. A. Zherebtsov","doi":"10.1134/S0022476625070054","DOIUrl":"10.1134/S0022476625070054","url":null,"abstract":"Metal-organic frameworks (MOFs) are a widely studied class of compounds characterized by porous structure and large surface area. MOFs are highly promising materials for practical applications as pollution sensors, selective sorbents, etc. There has been increasing recent interest in MOFs containing a long rigid linear linker that can significantly increase the size and area of MOF pores. Derivatives of diacetylenedibenzoic acid can be used as such ligands. In this work, a metal-organic framework based on diacetylenedibenzoic acid and lanthanum is prepared, its single crystals are obtained, and their structure is studied. The synthesis is performed by the solvothermal method using N,N-dimethylformamide (DMF) as a solvent. The structure of the obtained single crystal is determined by single crystal XRD. it is shown that this compound contains a 3D network with stretched (~4×31 Å) orthorhombic channels filled with water and DMF molecules. Lanthanum cations are interconnected into 1D chains by carboxylic groups. The coordination number of lanthanum is eight. Two neighboring La3+ ions are connected into linear motifs by the oxygens of carboxylic groups. Each water molecule participates in the formation of hydrogen bonds or in the coordination of La3+ ions or in these both interactions. Only half of the DMF molecules have hydrogen bonds; the other half fill MOF pores and form weak van der Waals contacts. Due to the presence of solvent filled pores, this MOF can have a developed surface area.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 7","pages":"1385 - 1394"},"PeriodicalIF":1.4,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145162336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Supramolecular System: Rhenium γ-Cyclodextrin Cluster Complex - Keggin-Structure Polyoxometalate 超分子体系：铼γ-环糊精团簇配合物-凯金结构多金属氧酸盐

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070108

D. I. Konovalov, M. A. Shestopalov, A. A. Ivanov, Yu. A. Vorotnikov

{"title":"Supramolecular System: Rhenium γ-Cyclodextrin Cluster Complex - Keggin-Structure Polyoxometalate","authors":"D. I. Konovalov, M. A. Shestopalov, A. A. Ivanov, Yu. A. Vorotnikov","doi":"10.1134/S0022476625070108","DOIUrl":"10.1134/S0022476625070108","url":null,"abstract":"Three-component supramolecular system NaH[{Re6S8}(H2O)6]@γ-CD@[SiW12O40]·12H2O is obtained by slow evaporation of an aqueous solution containing the [{Re6S8}(H2O)6]2+ cluster complex, [SiW12O40]4– polyoxometalate (POM), and γ-cyclodextrin (γ-CD). The composition of the synthesized compound is confirmed by the elemental analysis, IR spectroscopy, and the single crystal X-ray diffraction analysis. The compound crystallizes in the orthorhombic crystal system, space group P212121 with unit cell parameters a = 22.7524(13) Å, b = 23.8164(14) Å, c = 23.9121(12) Å, V = 12957.5(12) Å3, Z = 4. It is shown that the compound does not exhibit luminescent properties in the solid state. The luminescence intensity of the cluster complex in an aqueous solution decreases with increasing concentrations of both POM and POM@γ-CD, which can indicate the possible electron/energy transfer from the cluster excited state to POM or POM@γ-CD inclusion compound.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 7","pages":"1431 - 1439"},"PeriodicalIF":1.4,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, Structure, and Photoluminescent Properties of Copper(I) Complexes with N-(diphenylphosphino)-4-Phenylpyrimidineamine 铜与N-（二苯基膦）-4-苯基嘧啶胺配合物的合成、结构及光致发光性能

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070042

M. D. Taigina, M. I. Rakhmanova, T. S. Sukhikh, K. A. Vinogradova

{"title":"Synthesis, Structure, and Photoluminescent Properties of Copper(I) Complexes with N-(diphenylphosphino)-4-Phenylpyrimidineamine","authors":"M. D. Taigina, M. I. Rakhmanova, T. S. Sukhikh, K. A. Vinogradova","doi":"10.1134/S0022476625070042","DOIUrl":"10.1134/S0022476625070042","url":null,"abstract":"Complexes of copper(I) iodide, bromide, and chloride with N-(diphenylphosphino)-4-phenylpyrimidineamine (L) are synthesized. The [Cu2L2I2] (I), [Cu2L2I2]·2.3MeCN (II), [Cu2L2Br2] ·1.5MeCN·0.5CH2Cl2 (III), and CuLCl (IV) complexes are prepared by reactions of the corresponding copper(I) salts and L in organic solvents in the 1:1 molar ratio. It is shown by XRD that II and III have a binuclear molecular structure; the L molecule is coordinated to copper atoms in a bidentate cyclic mode via P and N1 atoms of the pyrimidine ring; the distorted tetrahedral environment of Cu atoms is supplemented by halide ions; the coordination polyhedron is CuNPI2 (II) and CuNPBr2 (III). The structure of II has two crystallographically independent molecules containing a {Cu2I2} fragment in rhombus and butterfly conformations, respectively. In the molecule of II, all {Cu2Br2} fragments have a planar rhombic structure. Solid-state photoluminescent properties of L and I, III, IV complexes are studied. The I, III, IV complexes demonstrate single-band red emission with a microsecond lifetime (λexc = 400 nm) at 635 nm, 625 nm, and 640 nm, respectively. The L compound exhibits solid-state fluorescence with two emission bands at 400 nm and 480 nm.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 7","pages":"1369 - 1384"},"PeriodicalIF":1.4,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Sodium Salts of Octahedral Molybdenum Complexes with Acrylate and Methacrylate Ligands 丙烯酸酯和甲基丙烯酸酯配体八面体钼配合物的钠盐

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070078

N. A. Vorotnikova, A. S. Berezin, N. V. Kuratieva, M. A. Shestopalov, Y. A. Vorotnikov

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X-Ray Certification of Si, Ge, LaB6, and InSb Single Crystals Si, Ge， LaB6和InSb单晶的x射线认证

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070157

P. S. Serebrennikova, S. A. Gromilov

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Double Complex Salts [Mo6I8(DMSO)6] [PM12O40](NO3) (M = Mo, W) 双络合盐[Mo6I8(DMSO)6] [PM12O40](NO3) （M = Mo， W）

IF 1.4 4区化学

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI: 10.1134/S0022476625070066

E. V. Pronina, T. S. Sukhikh, M. A. Shestopalov, A. A. Ivanov, Y. A. Vorotnikov

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