Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-03-10 DOI:10.1134/S0022476625020040

A. S. Zavgorodnii, M. A. Kryukova, A. Y. Timoshkin

引用次数: 0

Abstract

Donor-acceptor complexes of the Ga[N(C₆F₅)₂]₃ Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.