Journal of Phase Equilibria and Diffusion最新文献_第8页

Thermodynamic Reassessment of the Binary Cu-Sn, Cu-P, and Sn-P and Ternary Cu-Sn-P Systems 铜-锡、铜-锡、锡-锡二元体系和铜-锡-锡-锡三元体系的热力学再评估

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-05-14 DOI: 10.1007/s11669-024-01112-z

Katsunari Oikawa, Nobufumi Ueshima

引用次数: 0

Phase Relations in the Cu-As-S System and Thermodynamic Properties of Copper-Arsenic Sulfides Cu-As-S 系统中的相关系和铜砷硫化物的热力学性质

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-05-11 DOI: 10.1007/s11669-024-01115-w

Leyla F. Mashadiyeva, Dunya M. Babanly, Ziver T. Hasanova, Yusif A. Yusibov, Mahammad B. Babanly

{"title":"Phase Relations in the Cu-As-S System and Thermodynamic Properties of Copper-Arsenic Sulfides","authors":"Leyla F. Mashadiyeva, Dunya M. Babanly, Ziver T. Hasanova, Yusif A. Yusibov, Mahammad B. Babanly","doi":"10.1007/s11669-024-01115-w","DOIUrl":"10.1007/s11669-024-01115-w","url":null,"abstract":"<div>Here, a complete phase equilibria picture in the Cu-As-S system was obtained by experimental study of carefully crystallized via long-term thermal annealing alloys by means of methods of differential thermal analysis and powder x-ray diffraction, as well as using the available literature data. The projection of the liquidus surface, the isothermal section at 300 K, and some vertical sections of the phase diagram are presented and discussed. The fields of primary crystallization of phases, types, and coordinates of invariant and monovariant phase equilibria are determined. The presented phase diagram reflects four ternary compounds Cu3AsS4, Cu12As4S13, Cu6As4S9, and CuAsS, which are synthetic analogues of natural copper-arsenic sulfide minerals. Particular attention is paid to the Cu2S-As2S3 section. It is shown that this section, in contrast to the literature data, is not quasi-binary. The thermodynamic data for copper-arsenic sulfides, previously obtained by the authors by the electromotive force method with Cu4RbCl3I2 solid electrolyte, have also been revised. Experimental data on the partial thermodynamic functions of copper in some phase regions of the Cu-As-S system were processed taking into account the constructed new version of the solid-phase equilibria diagram and updated data on the standard thermodynamic functions of formation and standard entropies of the ternary compounds Cu3AsS4, Cu12As4S13, Cu6As4S9, and CuAsS were obtained.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 3","pages":"567 - 582"},"PeriodicalIF":1.5,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140936627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Re-investigation of the Phase Equilibria and Thermodynamic Assessment of the Mg-Sm Binary System 镁锑二元体系相平衡的再研究与热力学评估

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-05-11 DOI: 10.1007/s11669-024-01111-0

Ruyi Jiang, Xiaofen Duan, Dashi Li, Cuiyun He

{"title":"Re-investigation of the Phase Equilibria and Thermodynamic Assessment of the Mg-Sm Binary System","authors":"Ruyi Jiang, Xiaofen Duan, Dashi Li, Cuiyun He","doi":"10.1007/s11669-024-01111-0","DOIUrl":"10.1007/s11669-024-01111-0","url":null,"abstract":"<div>The Mg-Sm phase diagram has been experimentally studied by x-ray diffraction, scanning electron microscope equipped with energy dispersive spectrometer, and differential scanning calorimetry. Five binary compounds, Mg41Sm5, Mg5Sm, Mg3Sm, Mg2Sm and MgSm were confirmed to exist in the Mg-Sm system. In addition to Mg2Sm and MgSm, Mg3Sm was found to be a congruently melting phase. The Mg5Sm and Mg2Sm were found to be only stable at high temperatures and decompose above 400 °C in this work. A special effort was made to determine the extent of the solid solubility ranges of Mg3Sm, Mg2Sm, MgSm and, γ-Sm. The Mg-Sm binary system was modeled using the Calphad approach based on new experimental data of this work and all reliable experimental information from literature. A complete thermodynamic description of the Mg-Sm system is obtained and extensive comparisons between calculated and experimental data are presented, indicating that almost all available experimental and theoretical data are fitted satisfactorily.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 3","pages":"520 - 536"},"PeriodicalIF":1.5,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140936625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in CALPHAD Methodology for Modeling Hydrides: A Comprehensive Review 用于模拟氢化物的 CALPHAD 方法的进展：全面回顾

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-05-10 DOI: 10.1007/s11669-024-01113-y

M. Palumbo, E. M. Dematteis, L. Fenocchio, G. Cacciamani, M. Baricco

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Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the Latest Experimental Phase Diagram 参照最新实验相图对铁锌二元体系进行热力学评估

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-05-05 DOI: 10.1007/s11669-024-01110-1

Ikuo Ohnuma, Kwangsik Han, Inho Lee, Takako Yamashita, Ryosuke Kainuma

{"title":"Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the Latest Experimental Phase Diagram","authors":"Ikuo Ohnuma, Kwangsik Han, Inho Lee, Takako Yamashita, Ryosuke Kainuma","doi":"10.1007/s11669-024-01110-1","DOIUrl":"10.1007/s11669-024-01110-1","url":null,"abstract":"<div>The phase diagram of the Fe-Zn binary system was evaluated based on the CALPHAD method with reference to the latest experimental data. The solubility ranges of the intermetallic compound phases, Γ-Fe4Zn9, Γ1-Fe11Zn40, δ1k-FeZn7, δ1p- Fe13Zn126, and ζ-FeZn13 were modeled considering their structures consisting of Zn12 icosahedra with Fe at the center (Fe1Zn12 clusters) as well as glue-like Fe and Zn atoms, and the miscibility gap between the δ1k and δ1p phases was also taken into account in the present calculations. The solubility of Fe in the liquid and (ηZn) phases that was confirmed as dozens of times larger than the values reported in the earlier literature could be calculated by introducing Fe1Zn12 associates to these solution phases. Consequently, all phase equilibria were adequately reproduced by the thermodynamic models and parameters revised in the present study.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 3","pages":"537 - 546"},"PeriodicalIF":1.5,"publicationDate":"2024-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140887803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Singular Interfacial Structures at Two Levels: Their Roles in the Development of Phase Transformation Crystallography 两级奇异界面结构：它们在相变晶体学发展中的作用

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-04-28 DOI: 10.1007/s11669-024-01107-w

Wenzheng Zhang

{"title":"Singular Interfacial Structures at Two Levels: Their Roles in the Development of Phase Transformation Crystallography","authors":"Wenzheng Zhang","doi":"10.1007/s11669-024-01107-w","DOIUrl":"10.1007/s11669-024-01107-w","url":null,"abstract":"<div>Faceted morphology is common in the microstructures resulting from solid-state phase transformations in a wide range of crystalline materials. This study explains the faceted interfaces based on the concept of singular interfaces, which are characterized by key interfacial structures at two levels: the singular dislocation structure and the preferred state existing between the dislocations. It identifies interface geometries required by these structures at two stages: before and after dislocation generation. Methods to determine the interface geometries are reviewed. These methods enable quantitative interpretation of phase transformation crystallography features, including the interface orientations and the orientation relationship between the two phases, irrespective of whether these features are described as rational or irrational. The agreement achieved across different systems indicates the crucial role of geometric matching in the development of phase transformation crystallography. An example is provided for an illustration of the application of the two-stage approach, especially with an analysis in reciprocal space using a superimposed diffraction pattern.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 3","pages":"256 - 272"},"PeriodicalIF":1.5,"publicationDate":"2024-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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First Principles Evaluation of Phase Stability in the In-Sn Binary System 铟硒二元体系相位稳定性的第一原理评估

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-04-23 DOI: 10.1007/s11669-024-01109-8

Michael Widom

引用次数: 0

Interdiffusion Coefficients and Strengthening Effects of Nb, Ta, and Zr in the α2-Ti3Al Phase α2-Ti3Al相中Nb、Ta和Zr的相互扩散系数和强化效应

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-04-16 DOI: 10.1007/s11669-024-01105-y

L. Haußmann, J. Bresler, S. Neumeier, F. Pyczak, M. Göken

引用次数: 0

Experimental Investigation and Thermodynamic Assessment of Phase Equilibria in the Al-Ta-V Ternary System 铝-钽-钒三元体系相平衡的实验研究和热力学评估

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-04-07 DOI: 10.1007/s11669-024-01102-1

Cuiping Wang, Debin Zheng, Zhangcan Zheng, Lianzhang Wu, Jianping Le, Yihui Guo, Yixiong Huang, Jinbin Zhang, Yong Lu, Xingjun Liu

{"title":"Experimental Investigation and Thermodynamic Assessment of Phase Equilibria in the Al-Ta-V Ternary System","authors":"Cuiping Wang, Debin Zheng, Zhangcan Zheng, Lianzhang Wu, Jianping Le, Yihui Guo, Yixiong Huang, Jinbin Zhang, Yong Lu, Xingjun Liu","doi":"10.1007/s11669-024-01102-1","DOIUrl":"10.1007/s11669-024-01102-1","url":null,"abstract":"<div>The phase equilibria in the Al-Ta-V ternary system at 1000 °C and 1200 °C have been studied by using electron probe microanalysis and x-ray diffraction. τ-Al2.9Ta2.7V1.4 phase was found in the Al-Ta-V ternary system in both isothermal sections. The addition of V stabilizes the Al69Ta39 phase at 1000 °C. The line compound Al3(V,Ta) (D022-type) forms a continuous phase region from the Al-V side to the Al-Ta side at the two temperatures. Based on our experimental results, reported liquidus projection of the ternary Al-Ta-V system and thermodynamic data of the binary systems of Al-V, Al-Ta and V-Ta, a thermodynamic evaluation of Al-Ta-V system was carried out by CALPHAD method. A set of reliable thermodynamic parameters for the Al-Ta-V system was obtained. The current calculation results agree well with the available experimental data. The invariant reaction scheme of Al-Ta-V ternary system was presented. The present study could provide essential experimental and thermodynamic data for establishing a comprehensive Co-based superalloy database.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 2","pages":"156 - 174"},"PeriodicalIF":1.5,"publicationDate":"2024-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140576523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Phase Equilibria in the Ti-Rich Portion of the Ti-Ga-Sn System 钛-镓-硒体系富钛部分的相平衡

IF 1.5 4区材料科学

Journal of Phase Equilibria and Diffusion Pub Date : 2024-03-29 DOI: 10.1007/s11669-024-01100-3

M. Bulanova, I. Fartushna, A. Samelyuk, K. Meleshevich, J.–C. Tedenac

{"title":"Phase Equilibria in the Ti-Rich Portion of the Ti-Ga-Sn System","authors":"M. Bulanova, I. Fartushna, A. Samelyuk, K. Meleshevich, J.–C. Tedenac","doi":"10.1007/s11669-024-01100-3","DOIUrl":"10.1007/s11669-024-01100-3","url":null,"abstract":"<div>Phase equilibria of the Ti-Ga-Sn system have been determined at primary crystallization and at 1000 °C in the composition interval ~ 50-100 at.% Ti based on differential thermal analysis, x-ray powder diffraction, scanning electron microscopy and electron microprobe analysis. Partial liquidus and solidus projections, the melting diagram, a number of vertical sections, isothermal section at 1000 °C, as well as the reaction scheme (Scheil diagram) for the Ti-Ga-Sn system were constructed. A ternary compound Ti5GaSn2 (τ) (Nb5SiSn2-type structure, tI32-I4/mcm), found by us previously, forms by peritectic reaction L + Ti2(Sn, Ga) + Ti5(Sn, Ga)3-4 ⇄ τ at 1500 °C and has a wide homogeneity range from 9 to 23.5 at.% Ga at solidus temperature and from 4 to 34 at.% Ga at 1000 °C, and located along constant composition of ~ 62.5 at.% Ti. D88-type compounds Ti5Sn3 and Ti5Ga4 form a continuous solid solution, denoted Ti5(Sn, Ga)3-4, at all investigated temperatures. Ga-poor part of it (below ~ 12.5 at.% Ga) forms by an interstitial mechanism, while in the interval above ~ 12.5 at.% Ga it is a substitutional phase. Isostructural compounds Ti2Sn and Ti2Ga also form a continuous solid solution Ti2(Sn, Ga) at solidus temperatures, which decomposes with decreasing temperature. Meanwhile, at 1000 °C, one more continuous solid solution Ti3(Sn, Ga) forms between isostructural compounds Ti3Sn and Ti3Ga.</div>","PeriodicalId":657,"journal":{"name":"Journal of Phase Equilibria and Diffusion","volume":"45 2","pages":"132 - 155"},"PeriodicalIF":1.5,"publicationDate":"2024-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140324200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0